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1.
Globally, aquatic ecosystems are highly polluted with heavy metals arising from anthropogenic and terrigenous sources. The objective of this study was to investigate the pollution of stream sediments and possible sources of pollutants in Nakivubo Channel Kampala, Uganda. Stream sediments were collected and analysed for heavy metal concentration using flame atomic absorption spectrophotometer. The degree of pollution in Nakivubo channelized stream sediments for lead, cadmium, copper, zinc, manganese and iron was assessed using enrichment factor, geo-accumulation index and pollution load index. The results indicated that (1) the sediments have been polluted with lead, cadmium and zinc and have high anthropogenic influences; (2) the calculation of geo-accumulation index suggest that Nakivubo stream sediments have background concentration for copper, manganese and Fe (I geo ≤ 0); (3) factor analysis results reveal three sources of pollutants as explained by three factors (75.0 %); (i) mixed origin or retention phenomena of industrial and vehicular emissions; (ii) terrigenous and (iii) dual origin of zinc (vehicular and industrial). In conclusion, the co-precipitation (inclusion, occlusion and adsorption) of lead, cadmium and zinc with manganese and iron hydroxides, scavenging ability of other metals, very low dissolved oxygen and slightly acidic to slightly alkaline pH in stream water could account for the active accumulation of heavy metals in Nakivubo stream sediments. These phenomena may pose a risk of secondary water pollution under sediment disturbance and/or changes in the geo-chemistry of sediments.  相似文献   

2.
Biological technologies for wastewater remediation techniques employed to remove contaminants in urban stream water are increasingly receiving attention worldwide. The purpose of this study was therefore to determine the concentrations of lead, cadmium, copper, zinc, manganese and iron in algal biomass and establish the feasibility of using algae in phytoextraction and bio-monitoring of environmental quality. Analysis of algal biomass samples in the Nakivubo urban stream ecosystem, Kampala, Uganda, showed that there was contamination by lead, cadmium, copper and zinc as indicated by enrichment factor and pollution load index values. It is suspected that industrial and vehicular emissions are the major sources of these pollutants. Calculated bio-concentration factor was >- 1000 but with low concentration thresholds in each element, suggesting that algal biomass was a very good heavy metal accumulator. The bio-concentration values in algal biomass were found to be in the order of copper > zinc > lead > cadmium in the Nakivubo Channelized stream. In conclusion, algae can be a promising aquatic bio-filter plant for phytoextraction and bio-monitoring of polluted urban stream ecosystems and wastewater.  相似文献   

3.
The present study aims at assessing water quality of river Yamuna in one of the world’s most polluted and populated megacities, Delhi. Conductivity, salinity and sodium content were within the permissible categories. Chloride concentration exceeded acceptable levels of drinking water guidelines. Water quality was poor at all locations with respect to heavy metal contamination, especially along the lower section of the Delhi stretch. Heavy metal concentrations were manifold higher than the acceptable limits of drinking water according to the BIS guidelines and reached ~29, 4.9, 10, 31, 27, 83, 7.3 and 27 times higher, respectively, for metals aluminum, copper, chromium, cadmium, iron, lead, manganese and nickel. The Najafgarh and the Shahdara drains are major point sources. Low oxidation–reduction potential reflected high organic loads and traces of eutrophication together with significant levels of nitrate and total phosphate. Discharges from agriculture, sewage and power plants could be important sources of high metal concentration. This calls for urgent measures to be taken for prevention of metal contamination in the river, through both, technology as well as implementation of regulations in order to sustain huge populations in megacities like Delhi. Waste water treatment from point sources needs tremendous improvement on the city. Treatment of the entire waste generated up to the tertiary level is required for minimizing dissolved solids, especially toxic metals, and rendering reuse in agriculture suitable. Treatment plants need proper operation, maintenance, uninterrupted power supply and regular monitoring. Various measure and programmes need to be undertaken to ensure safe reuse of wastewater.  相似文献   

4.
The present paper undertakes a study of the physico-chemical properties and toxic heavy metals content in the untreated and treated pharmaceutical effluents in order to evaluate the working efficiency of industrial effluent treatment plants. The treatment efficiency achieved for various parameters was conductivity (79.94%), alkalinity (93.91%), hardness (87.70%), chloride (89.24%), cyanide (79.66%), phosphate (99.19%), total dissolved solids (85.89%), total suspended solids (96.87%), salinity (52.41%), dissolved oxygen (27.32%), biochemical oxygen demand (83.39%) and chemical oxygen demand (72.21%). The removal efficiency achieved for different heavy metals was Cu2+ (79.66%), Ni2+ (69.22%), Cr6+ (80.15%), Pb2+ (72.14%), Fe3+ (92.59%) and Zn2+ (90.61%). The level of biochemical oxygen demand (64 mg L?1) in the treated effluents was above the limit of 30.0 mg L?1, chemical oxygen demand level (208 mg L?1) was close to a limit of 250 mg L?1, while average Pb2+ concentration (0.10 mg L?1) was on the borderline of maximum permissible limit of 0.10 mg L?1 set by Central Pollution Control Board for safe discharge of industrial effluent in inland surface water. The average concentration of cyanide (0.01 mg L?1) in the treated industrial effluent of our study is of great concern to the fisheries of freshwater ecosystem in which the effluents finally get discharged. Based on the results of the present study, it is concluded that the pollution level in the discharged pharmaceutical effluent is of the great concern requiring proper treatment and regular scientific monitoring so as to protect the environmental degradation of water resources and facilitate the propagation of the aquatic life.  相似文献   

5.
Serpentinite soils, common throughout the world, are characterized by low calcium-to-magnesium ratios, low nutrient levels and elevated levels of heavy metals. Yet the water quality and heavy metal concentrations in sediments of streams draining serpentine geology have been little studied. The aim of this work was to collect baseline data on the water quality (for both wet and dry seasons) and metals in sediments at 11 sites on the Marlborough Creek system, which drains serpentine soils in coastal central Queensland, Australia. Water quality of the system was characterized by extremely hard waters (555–698 mg/L as CaCO3), high dissolved salts (684–1285 mg/L), pH (8.3–9.1) and dissolved oxygen (often >110% saturation). Cationic dominance was Mg > Na > Ca > K and for anions HCO3 > Cl > SO4. Al, Cu and Zn in stream waters were naturally high and exceeded Australian and New Zealand Environment and Conservation Council guidelines. Conductivity displayed the highest seasonal variability, decreasing significantly after wet season flows. There was little seasonal variation in pH, which often exceeded regional guidelines. Stream sediments were enriched with concentrations of Ni, Cr, Co and Zn up to 35, 21, 10 and 2 times the world average for shallow sediments, respectively. Concentrations for Ni and Cr were up to 60 and 16 times those of the relevant Interim Sediment Quality Guidelines Low Trigger Values, respectively. The distinctive nature of the water and sediment data suggests that it would be appropriate to establish more localized water quality and sediment guidelines for the creek system for the water quality parameters conductivity, Cu and Zn (and possibly Cr and Cd also), and for sediment concentrations of Cd, Cr and Ni.  相似文献   

6.
Chromium and lead concentrations and distribution have been fully studied within Bahía Blanca estuary inner area, which is strongly influenced by urban and industrial stress. Not only metals dissolved in estuarine water but also those included in sediments and suspended particulate matters (SPM) were measured. In all cases, internationally standardized protocols were applied to metal measurements, including analytical quality check test through analysis of certified reference materials. Total metal contents from surface sediments and SPM were compared with those from a historical database of the area, as well as with values representing the natural geochemical baseline within the system. Results showed that heavy metal pollution is mainly localized in the areas close to both industrial effluents discharge system and urban sewage outfall discharge. Data from sequential extractions indicate that metals from anthropogenic sources (i.e., Pb) are potentially more mobile than those inherited from geological parent material (i.e., Cr). The influences of other potential sources of metals (i.e., streams, runoff) were also considered. SPM was clearly identified as the main carrier of the studied heavy metals within the system, and its significance to metals input into sediments and/or biota was verified. Finally, the normalization of measured metal concentrations against background reference elements (i.e., Al or Fe) has allowed to identify that most of the measured Cr was lithogenic, while a significant percentage of Pb was from anthropogenic origin within Bahía Blanca estuary.  相似文献   

7.
Heavy metal contamination and its indexing approach for river water   总被引：9，自引：2，他引：7  
The objective of the study is to reveal the seasonal variations in the river water quality with respect to heavy metals contamination. To get the extend of trace metals contamination, water samples were collected from twelve different locations along the course of the river and its tributaries on summer and the winter seasons. The concentrations of trace metals such as cadmium, cromium, copper, cobalt, iron, manganese, nickel, lead, mercury and zinc were determined using atomic absorption spectrophotometer. Most of the samples were found within limit of Indian drinking water standard (IS: 10500). The data generated were used to calculate the heavy metal pollution index of river water. The mean values of HPI were 36.19 in summer and 32.37 for winter seasons and these values are well below the critical index limit of 100 because of the sufficient flow in river system. Mercury and chromium could not be traced in any of the samples in the study area.  相似文献   

8.
金矿区河水和底泥中重金属含量分布与耦合关系   总被引：3，自引：1，他引：2  
河流中河水与底泥中重金属含量之间的关系对于河流污染防治意义重大。对某金矿区3种典型河流的河水与底泥中的重金属含量进行分析,发现4条河流均有超过国家标准限值的情况,河水中7种重金属元素均出现超标,Cr、As元素超标不严重;底泥中Hg、Pb、Cr、Cu、Zn超标,其中Hg超标最严重,河水和底泥中Hg最大超标倍数分别达到3099倍和244倍。河流中重金属主要赋存形态为沉积态,底泥的吸附解吸作用是河流底泥和河水中重金属沿程变化的主控因素;金矿区区域上河水和底泥中重金属很好地服从Langmuir等温吸附模式。矿业活动、地层岩性均会影响底泥对重金属的平均最大吸附容量,流径黄土区的双桥河平均最大吸附容量最大。研究结果为矿山河流污染防治与预警提供了参考依据。  相似文献   

9.
Stream water composition, measured weekly for 8–9 months in 1994 in three arctic catchments on and around the Kola Peninsula (Russia, Finland and Norway), is presented in the form of time-series. In all three catchments, snowmelt causes a major dilution of the stream water, as reflected by marked dips in electrical conductance. In the most polluted catchment (C2), the snowmelt flood (the major hydrological event at these latitudes) is reflected in the stream water by a pH dip and a pulse in technogenic heavy metals (Cu, Ni, etc.), Al and S. This results from melting of the snow laden with heavy metals and sulphate, and from leaching of the topsoil layer. In the most pristine catchment (C8), snowmelt causes no heavy metal pulse (remote location) but yields an increase in stream water Al (acidic lithology/overburden). In the intermediate catchment (C5), very subdued heavy metal and S increases are noticeable in the stream water, whilst its pH increases steadily until summer (basic lithology). Some elements (Cl, S) may be mobilised out of the snowpack before its complete thawing and reach the stream 1–2 weeks ahead of the heavy metals. The substrate (soil, overburden and bedrock) of a catchment controls to a large extent its ability to buffer acid inputs.  相似文献   

10.
Attention is drawn to the fact that the warm geothermal brines of Matupi Harbour (New Britain) are of sea water origin, contain amounts of total dissolved solids comparable to those in sea water, but are remarkably enriched in heavy metals (Ferguson and Lambert, 1972). This evidence supports the proposal that metal enriched brines, of sea water origin, may be generated in sub-sea-floor geothermal systems by a high temperature leaching process, and may form a metal enriched sedimentary component on discharge back into sea water (Spooner and Fyfe, 1973).The chloride contents of the Matupi Harbour brines are low, relative to other known hydrothermal solutions which carry comparable amounts of heavy metals in solution. This evidence indicates that high dissolved chloride contents of the order of 160000 ppm, compared with sea water which contains 19800 ppm, are not a prerequisite for a high metal carrying capacity in natural brines.  相似文献   

11.
The town of Salihli is situated in Gediz Graben in the western Anatolia. This region is important in terms of industry, mining, geothermal energy, water sources, and agricultural production. Geothermal flow and anthropogenic activities in Salihli threaten the surrounding environment due to the contamination of cold groundwater, surface water, and soil. The goal of the present study is to determine the environmental effects of the geothermal and anthropogenic activities in Salihli on soil, stream sediments, and water. Stream sediments and farm soil have been contaminated by substances derived from geothermal and industrial effluents. To this end, the quality review of the water was completed and the heavy metal levels in stream sediment samples were measured to determine the extent of contamination. The elements As, B, Br, Fe, and Ni are the major contaminants present in surface water and groundwater in the study area. The concentrations of these elements excess tolerance limits of international water standards. Gibbsite, K-mica, kaolinite, sepiolite, halite, sulfur, willemite, and Pb(OH)2 might be precipitated as scales at low temperatures on the soil; this could be interpreted as a resultant from soil contamination. The concentrations of 17 elements (As, Ba, B, Cd, Co, Cr, Cu, Fe, Hg, Li, Mo, Mn, Ni, Pb, Sb, Sr, and Zn) were measured in samples from stream sediments and surface soils. In the study area, especially geothermal and anthropogenic activities give rise to environmental pollution.  相似文献   

12.
This study assessed the ability of filamentous green algae; Spirogyra aequinoctialis to accumulate manganese, cadmium and lead from water. Water pH was also determined. Samples of S. aequinoctialis and their respective water environments were taken from designated sampling points in the city of Blantyre and Malawi during the rainy and dry season in order to capture seasonal variations. The concentration of metals in S. aequinoctialis were higher than in the corresponding water environment in both seasons, but lower in the rainy season than the dry season. In the rainy season the concentrations were (in S. aequinoctialis and (water)): Mn 0.432–5.641 mg/L (ND-0.530 mg/L), CdND- 0.016 mg/L (0.07–0.111 mg/L) andPbND- 0.965 mg/L (0.011–0.098 mg/L). In the dry season the concentrations were: Mn 0.281-16.132 mg/L (0.035–0.626 mg/L), Cd 0.22–0.912 mg/L (0.014–0.111 mg/L) and Pb ND- 0.972 mg/L (ND- 0.23 mg/L). This study has shown that S. aequinoctialis has the capability of accumulating manganese, cadmium and lead. Therefore it can be used as a biological indicator for long term heavy metal water pollution monitoring.  相似文献   

13.
An integrated physicochemical and hydrogeochemical assessment was carried out at an automobile junk market in Obosi and in residential areas in Anambra State, south-eastern Nigeria to examine the concentration of heavy metals in the groundwater and determine the quality of the water for drinking and other domestic purposes. Forty groundwater samples were collected from boreholes and hand-dug wells (three samples from Obosi and the rest from Onitsha). They were subjected to atomic absorption spectrometry using standard field and laboratory techniques and analysed for physicochemical and hydrogeochemical parameters. Results show that the groundwater in the study area is slightly acidic to neutral, soft to moderately hard when compared with the World Health Organization maximum allowable concentration values and the Nigerian Standards for Drinking Water Quality. The electrical conductivity, dissolved oxygen and biochemical oxygen demand ranged from 58 to 1796 μS/cm, 6.78 to 8.76 and 0.17 to 1.50 mg/L, respectively. Heavy metal concentrations measured (in ppm) in the water included nickel, manganese, copper and zinc and varied from 0 to 1.82, 0 to 0.195, 0 to 0.325 and 0 to 0.09, respectively, while heavy metal concentrations in the soil measured (in ppm) included iron, lead and cadmium and varied from 0 to 3.87, 0 to 1.80 and 0 to 7.38 mg/kg, respectively. Statistical results gave significant correlation (at 0.05) between electrical conductivity and total hardness, biochemical oxygen demand and dissolved oxygen, and several others elements. The study helps in the understanding of the chemistry of groundwater for long-term monitoring and management for the local community.  相似文献   

14.
为了解不同水位变化影响下的河水与地下水侧向交互带地球化学特征动态,以重庆市马鞍溪为研究对象,选取丰水期向枯水期过渡的10-12月为研究期,对河水、地下水及交互带的水位、水温、溶解氧（DO）、pH值、电导率（EC）进行监测,结合对水体主要离子浓度的分析。结果表明,随枯水期到来,侧向交互带水位发生较大变化,交互带与河水间的水位梯度缩小,河水入渗动力逐渐减弱。水位的变化及入渗水温的降低,使交互带微生物活动减弱,pH值上升且变幅减小,DO上升。在其影响下,交互带EC下降,变幅减小,交互带对NO3-、SO42-的净化能力降低,对Mn、Zn等重金属固定能力增强。通过分析交互带地球化学特征的变化,可推断出随马鞍溪枯水期的到来,侧向交互带边界由距河岸30~50 cm移动至距河岸30 cm以内。  相似文献   

15.
Hydrochemical and isotopic researches were conducted in El-Sadat City groundwater system to identify groundwater alteration, recharge, residence time and extent of pollution. The groundwater salinity gradually increases as the groundwater moves from northeastern to southwestern parts of the city. Groundwater generally shows mineralization decreasing with depth, indicating that the possibility of recent water penetration far below the surface is limited. Shallow groundwater has an elevated level of nitrate, which is attributed to anthropogenic sources due to intensive agricultural activity. The limit of high nitrate water may mark the maximum penetration of groundwater from the surface, which is found in depths <100 m. The northeastern and southwestern industrial areas are highly contaminated by some heavy metals, which may originate from some local industrial effluents. The sewage oxidation ponds seem to show no effect on groundwater; hence, these ponds are not a point source for these heavy metals. Dissolved ions depict five different hydrochemical facies, and stable isotopes define the recharge mechanisms, the origin of groundwater and the hydraulic confinement of deep groundwater. The deep groundwater is untritiated and has long residence times (in the order of thousands of years). Three different hydrochemical groups have been recognized and mapped in El-Sadat City, based on the chemical and isotopic information of the groundwater. These groups have different levels of contamination. The deep groundwater samples are significantly less impacted by surface activities and it appears that these important water resources have very low recharge rates and would, therefore, be severely impacted by overabstraction. The extensive exploitation of groundwater for drinking water supply would shortly be reflected by a gradual decline of the groundwater table in El-Sadat City. Amelioration of groundwater quality requires further management strategies and efforts in the forthcoming years.  相似文献   

16.
Stream sediments and aquatic bryophytes were used as exploration samples during a mineral reconnaissance survey of Chandalar Quadrangle, Alaska. Comparative data demonstrate that aquatic bryophytes accumulate copper, lead, zinc and mercury and locate massive sulfide mineralization better than stream sediments.Aquatic bryophytes are effective because of their ability to chemically bind dissolved trace elements, and physically trap micron-sized particulates. The former regulates mercury and manganese accumulation while the latter is more important for copper, lead, zinc and iron accumulation.Species effects seem to be negligible since statistical tests for measurable differences between bryophyte trace-element accumulations are not strongly positive. Therefore, the bryophyte data can be biogeochemically interpreted without rigorous species identification and statistical treatment.Overall, aquatic bryophytes are effective exploration samples in areas where they are abundant and stream sediments are not.  相似文献   

17.
Heavy metals contamination in road dust in Delhi city,India   总被引：1，自引：1，他引：0  
Road dust samples were collected from four different areas having different landuse patterns: industrial, heavy traffic, residential and mixed use in Delhi city of India. The samples were analyzed for Ba, Co, Cr, Cu Fe, Mn, Ni, Pb and Zn by ICP-AES. Results indicate high levels of Co, Cr, Cu, Mn and Ni in samples collected from industrial area. Ba, Pb and Zn showed higher concentration levels in heavy traffic area while Fe did not show any discernible variation between the localities. The concentrations of Fe, Mn, Ba, Zn, Cr, Cu, Pb, Ni and Co showed a decreasing trend. The content of heavy metals was comparable to those in other cities in the world. A multivariate statistical approach which includes Pearson’s correlations and principal component analysis was used to identify the possible sources of metals in the road dust. Enrichment factors were estimated for further confirming the sources of contamination. Significant positively correlations between road dust metals Cu–Mn–Co–Cr–Ni suggest that major common source of origin is industrial activities. A meaningful correlation between Ba and Zn, and a moderate positive correlation between Pb and Ba indicate the influence of traffic activities. Enrichment factors calculation indicated that Pb, Cu, Cr and Zn are moderately enriched whereas Co, Ni and Mn are less enriched while Ba exhibited very low enrichment in the dust samples. The results indicate that industrial and vehicular traffic are the two major sources. Traffic appears to be responsible for the high levels of Zn, Cu and Ba. High concentration of Co, Cr, Cu and Mn may be due to industrial sources.  相似文献   

18.
Urbanisation and industrial development lead to contamination of estuaries and streams with dispersed loadings of heavy metals and metalloids. Contributions of these elements also occur from natural sources. This study provides baseline geochemical data on the respective natural and anthropogenic inputs of Cu, Pb, Zn, Cd, As, Sb, Cr, Ni, Mn and S to estuarine, fluvial and wetland sediments, and adjacent soils, in the Kooloonbung Creek catchment that drains the Port Macquarie urban area in north coastal New South Wales. There have been anthropogenic additions of Cu, Pb, Zn and As from dispersed urban sources at Port Macquarie, but they are restricted to the local catchment and do not impact on the adjacent Hastings River estuary. The most contaminated sediments display enrichment factors up to 20 × for Cu and Pb, 9 × for Zn and 5 × for As relative to local background values. However, only one value (for Pb) exceeds National Water Quality Management Strategy interim sediment quality guideline (high) values. On the other hand, sediments and local soils are commonly strongly enriched in Cr, Ni and Mn, reflecting adjacent ultramafic and mafic rock substrate and lateritic regolith. Concentrations of Cr and Ni are commonly well above interim sediment quality guideline (high) values for sediments, but are in mineralogical forms that are not readily bioavailable. Sediment and soil quality guideline values consequently need to recognise natural enrichments and the mineralogical siting of heavy metals. Although dissolved concentrations of heavy metals in stream waters are commonly low, there is evidence for mobility of Cu, Zn, Fe and Al. Parts of the Kooloonbung Creek wetland area lie on sulfidic estuarine sediments (potential acid sulfate soils). Experimental oxidation of uncontaminated and contaminated sulfidic sediments leads to substantial dissolution of heavy metals under acid conditions, with subsequent aquatic mobility. The results warn about disturbance and oxidation of potential acid sulfate soils that have been contaminated by urban and natural heavy-metal sources.  相似文献   

19.
The island city of Bombay is surrounded by Thane creek in the east and Ulhas river on the north. These two aquatic regimes act as receptacles of industrial waste and sewage discharges from the city and also lithogenic fluxes from the adjacent basaltic terrain.

Two consecutive sets of pre-monsoon and post-monsoon samples of water, suspended solids and sediments were collected from the intertidal zone of Thane Creek and along the Ulhas River. These were analysed for toxic heavy metals such as Fe. Mn, Ni, Co, Pb, Zn, Cu, Cr, Hg and Cd and the degree of metal contamination was determined. Using this data the pattern and mechanism of distribution of heavy metals in water, suspended solids and sediments were investigated. These are closely related to discharges of industrial effluents and domestic sewage and largely controlled by basic geochemical processes.  相似文献   


20.
Metal concentrations from stream waters in two geological blocks in Northern Ireland were compared to determine the contributions of catchment characteristics and in-stream conditions. One block is composed of metamorphosed schist and unconsolidated glacial drift with peat or peaty podzol (mainly humic) soils, while the other block consists of tertiary basalt with brown earth and gley soils. Water samples were collected from 52 stream sites and analysed for iron (Fe), manganese (Mn) and aluminium (Al) as well as a range of other chemical determinands known to affect metal solubility. Densities of metal-rich ochre deposit were determined for stream bed stone samples. Higher conductivities and concentrations of bicarbonate, alkalinity, calcium and magnesium occurred on basalt than on schist. Despite higher Fe and Mn oxide concentrations in basalt-derived non-humic soils, stream water concentrations were much lower and ochre deposit densities only one-third of those on schist overlain by humic soils. Neither rock nor soil type predicted Al concentrations, but pH and dissolved oxygen did. Peat-generated acidity and the limited acid neutralising capacity of base-poor metamorphosed schist have resulted in elevated concentrations of metals and ochre deposit in surface waters.  相似文献   

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