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1.
Olive oil is a typical and valuable agro-industrial product in Mediterranean countries. In Tunisia, olive mill wastewaters (OMW) reach an amount of about 1,000,000 t year−1 and constitute a serious organic pollution risk because of the high chemical oxygen demand values and the presence of phytotoxic and antibacterial polyphenols. OMW have been generally stored in pond sites to be eliminated by natural evaporation or valorised by spreading on cultivated soils or by composting. Many researches on the interactions of OMW with soils at laboratory scale (columns) have been reported, but less attention have been paid to the effect of OMW on soils at field scale. The aim of this work is to investigate an area used for >15 years as an uncontrolled OMW pond site. The transformations of soil properties and groundwater occurring during OMW storage were characterised by the pH, phenolic contents, electrical conductivity (EC), moisture content and organic contents. The soil samples were taken from two borings and compared to those of a control one located near the pond site. Groundwater samples were taken on the accessible and nearest water wells to the evaporation ponds. The permeable silty and sandy layers in the site support the infiltration of OMW near the evaporation ponds. This infiltration has reached a depth of 6 m at a distance of almost 50 m laterally. The results show that the OMW infiltration in the subsoil has affected the pH, EC, organic content, phenolic compounds and the moisture.  相似文献   

2.
To evaluate the effect of olive mill wastewater (OMW) application on soil hydraulic and transport properties, two treatment sites, which had been irrigated with OMW for 5 and 15 years, and one control site being irrigated with freshwater were compared. The transport and leaching experiment results showed that a portion of the total soil water was available for transport processes while the remaining of the soil water was considered immobile and not readily accessible for solutes. The separation in water fractions of different mobilities was surprisingly consistent among OMW treatments. The bromide recovery rate decreased with the application of OMW showing that tracer molecules became trapped within immobile water phases. The application of OMW increased significantly the soil water-holding capacity, whereas the soil hydraulic conductivity in the near saturation range decreased significantly with long-term OMW application. The soil irrigated with OMW had significantly higher organic matter content, lower bulk density and relatively higher total porosity, but lower macroporosity than that of control sites. We concluded that the soil was increasingly coated with complex organic molecules originating from OMW, as a result, solute exchange between inter- and intrasoil aggregate water was hindered. Although OMW could cause soil and water pollution, its use in agriculture is promoted because of high nutrients and organic matter contents.  相似文献   

3.
基于GIS的农业面源硝酸盐地下水污染动态风险评价   总被引：1，自引：0，他引：1  
地下水中的硝酸盐污染具有全球性,这不仅是一个环境问题,也是一个经济和人类健康问题。DRASTIC方法可以进行地下水污染的脆弱性评价,但是却没有涵盖风险的概念,也忽视了污染物随地表水流运动的动态特性。因此,所得结果可能有碍于“欧洲水管理框架指南”在地下水水质管理中的执行。笔者基于DRASTIC方法开发了一个动态风险评价方法,并将其运用于英国北爱尔兰Upper Bann流域中的一个小流域。研究区地下水硝酸盐污染风险评价结果表明,此方法将有效地帮助决策者在流域范围内开展农业面源地下水污染预防措施。“非常高风险”和“高风险”区分别占研究区面积的5.1%和10.5%。此结果可帮助当地政府针对流域内这些“非常高风险”和“高风险”区的特点制订地下水质保护政策。此方法同样适用于任何面源可溶性污染物的地下水污染动态风险评价。  相似文献   

4.
Risk assessment and management, are increasingly established as key procedures in dealing with the range of environmental issues at different scales and of different nature. Although at the EU and international policy level requirements for the use of risk assessment and management are being established through emerging policy and legislation, this demand has not been followed with common guidance on how to do so. This has proven to hinder the effective adoption of such processes, and posed a barrier more so in its implementation for large transboundary issues. In this paper is presented a Decision Support System (DSS) designed to provide a common framework and procedure for environmental risk assessment and management. The DSS is web-based and was developed to enable the formalized and more systematic utilization of risk assessment and management procedures in environmental decision making processes, in particular for users such as public authority officials charged with the responsibility of implementing risk management legal and policy obligations, yet which have limited know how in the field of risk. The DSS presented herein enables environmental administrators and decision makers to undertake generic risk assessment and management identifying areas where detailed risk assessment is required, proposing as well as appropriate risk management options. The web DSS was developed and piloted as part of the STRiM project funded by the European Union. Herein are shown results from the web application which has been trailed successfully in four pilot trials addressing risks of forest damage from storms, water pollution from olive mill waste discharges, wetland loss from water abstraction, and damage from flooding.  相似文献   

5.
This study presents a diagnostic of the current state of 114 stream sediment samples by their elemental concentrations (Sb, Cd, Pb, As, Cu, Zn, Ni, Cr, and Hg), collected from Ighardayane upstream on an area of 15 km2 located at the SE part of central Morocco where Tourtit and Ichoumellal, two abandoned mining sites of Stibnite, are located. Several approaches were used to model the analysis (i) enrichment factor (EF), (ii) sediment pollution index (IPS), (iii) probable effect concentration-quotients (PEC-Qs), and (iv) potential ecological risk index (PERI). Results show highly contaminated areas around the old mining sites by Sb As, Pb, and Cd. Cadmium and lead show 86.9 and 12.29% (respectively) of trace element pollution according to sediment pollution index. Twenty-eight percent of the sampled area is potentially highly toxic because of the presence of Hg, Pb, and Cd. The very similar distribution of pollution and toxicity of most analyzed trace elements may originate from the same source, which corresponds to mining wastes where we recorded the highest pollution and toxicity degrees. This environmental issue represents the combination of Tourtit and Ichoumellal anthropic sources responsible of Sb, As, Pb, and Cd release and a probable natural source of Hg “that needs a further study,” which contribute in the degradation of an aquatic ecosystem of the same area. Therefore, both ecotoxicological analysis and stream sediment quality management should be carried out to control this aquatic ecosystem toxication.  相似文献   

6.
This study aims to attempt a treatment strategy based on fungi immobilized on silica-alginate (biocomposites) for removal of phenolic compounds in olive oil mill wastewater (OMW), OMW supplemented (OMWS) with phenolic compounds and water supplemented (WS) with phenolic compounds, thus decreasing its potential impact in the receiving waters. Active (alive) or inactive (death by sterilization) Pleurotus sajor caju was encapsulated in alginate beads. Five beads containing active and inactive fungus were placed in a mold and filled with silica hydrogel (biocomposites). The biocomposites were added to batch reactors containing the OMW, OMWS and WS. The treatment of OMW, OMWS and WS by active and inactive biocomposites was performed throughout 28 days at 25 °C. The efficiency of treatment was evaluated by measuring the removal of targeted organic compounds, chemical oxygen demand (COD) and relative absorbance ratio along the time. Active P. sajor caju biocomposites were able to remove 64.6–88.4 % of phenolic compounds from OMW and OMWS and 91.8–97.5 % in water. Furthermore, in the case of OMW there was also a removal of 30.0–38.1 % of fatty acids, 68.7 % of the sterol and 35 % of COD. The silica–alginate–fungi biocomposites showed a high removal of phenolic compounds from OMW and water. Furthermore, in the application of biocomposites to the treatment of OMW it was observed also a decrease on the concentration of fatty acids and sterols as well as a reduction on the COD.  相似文献   

7.
The Bavarian Alps region is strongly affected by various natural hazards, mainly hydrological events (floods, debris flows), geomorphic/geological events (landslides, rock falls), and avalanches. Extraordinary floods, like in 2002 or in the summer of 2005 in south Bavaria, have again posed the question of the possible extent and frequency of recurrence of catastrophic events. To put risk assessment on a broader basis historical data about all kinds of past natural hazards were detected in the archives of local authorities and administrative offices for water management. More than 10,000 sources (written accounts, maps, and photographs) were collated in a database. The majority of this information reaches back to the middle of the 19th century. In addition, many documents referring to events dating back even as far as the middle age were found. The Historische Analyse von NaturGefahren (HANG, historical analysis of natural hazards) project at the University of Eichstaett mainly focuses on a small-scale examination of the data. Initial results of the data analysis show that most catastrophic events in the Bavarian Alps only affect parts of the area, but not the whole region. Therefore it is necessary to assess the risk potential on a local scale like valleys, the catchment areas of mountain streams, or even single streams. Firstly the presented data is aimed to help engineers in future planning of hazard-protection measures. Secondly the information can form a vital component to enhance our knowledge of hydrological and geomorphic/geological dynamics in the Alps.  相似文献   

8.
During more than a century of gold mining in South Africa large amounts of tailings were produced, which now cover vast areas in densely populated regions. These dumps contain elevated levels of uranium and other toxic heavy metals associated with gold in the mined ore. Large-scale extraction of uranium from auriferous ore only took place during the cold war, leaving tailings with high uranium concentrations that were deposited before and after this period. Recent studies found elevated levels of the radioactive heavy metal in groundwater and streams, mainly attributed to the discharge of contaminated water from mines. In this paper the contribution of seepage from slimes dams to the uranium pollution of adjacent streams is analysed. Based on geochemical analyses of samples, field observations and long-term in situ measurements of hydraulic and hydrochemical parameters at selected mining sites across the Witwatersrand goldfields, the extent, mechanisms and dynamics of diffuse stream contamination by tailings seepage is characterised. Temporal and spatial variations of the process and the associated hazard potential are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

9.
Simultaneous analysis of micro-X-ray diffraction (μ-XRD) and micro-X-ray fluorescence (μ-XRF) based on synchrotron light sources, and electron microprobe (EMP) analyses, were performed on iron terrace samples taken from Tinto-Odiel river system from the Iberian Pyrite Belt (IBP, SW Iberian Peninsula). Iron terraces are formed during the oxidation and precipitation of dissolved iron along the riverbeds impacted by acid mine drainage (AMD). This paper includes the study of actively-forming current terraces and fossil terraces isolated from the stream courses due to the river migration over time. The results of the study of current terrace samples from AMD-affected streams of two IPB abandoned mines (Tinto Santa Rosa and Cueva de la Mora) showed that fresh precipitates at the surface are composed primarily of metastable schwertmannite, which is gradually transformed at depth over short-time scales into goethite. Sediments of ancient terraces are composed mainly of goethite, which most likely originated from the re-crystallization of a precursor schwertmannite. However, at century-time scale, goethite partially re-crystallizes to hematite due to diagenetic processes. The transformation rate of goethite into hematite is negatively correlated with grain size and the crystallinity of goethite. Moreover, this transformation is accompanied by an increase in grain size and a decrease in surface area of hematite, and a concomitant decrease in arsenic trapped in the solid. This increase in the arsenic mobility during the diagenetic maturation should be considered in the development of conceptual and analytical models describing long-term fate, transport and bioavailability of arsenic in environmental systems.  相似文献   

10.
The concentration of chloride (Cl?) in streams in northern regions has increased as a result of applications of deicers. This study focused on quantifying the relationship between land use and stream Cl? concentrations. The study area comprises two adjacent watersheds in central Illinois, with similar geology and climate but different land uses (agricultural and urban). GIS analysis delineated watershed land use and calculated road surface areas. Stream water samples were collected and analyzed for anionic composition. During the winter months, streams dominated with urban land use experienced a 20-fold increase in Cl? concentrations (range between 36 and 1350 mg L?1); Cl? concentrations in agricultural dominated streams also increased, but the increase was smaller (3X) and concentrations remained low (between 11 and 58 mg L?1). As road salts are not the sole source of Cl? in a stream, Cl? and bromide (Br?) mass ratios (Cl/Br) and Cl? and sodium (Na) molar ratios ([Cl]/[Na]) were used to identify potential sources of Cl?. The ratios indicate urbanized watersheds were impacted by road salts; agricultural watersheds ratios indicate other anthropogenic sources. A nonlinear relationship between urban land use and stream Cl? concentrations indicates urban land use as low as 23% results in elevated Cl? concentrations (greater than 150 mg L?1) in stream waters.  相似文献   

11.
The amount of pollution from non-point sources flowing in the streams of the Wujiang River watershed in Guizhou Province, SW China, is estimated by a GIS-based method using rainfall, surface runoff and land use data. A grid of cells, 100 m in size, is laid over the landscape. For each cell, mean annual surface runoff is estimated from rainfall and percent land use, and expected pollutant concentration is estimated from land use. The product of surface runoff and concentration gives expected pollutant loading from that cell. These loadings are accumulated going downstream to give expected annual pollutant loadings in streams and rivers. By dividing these accumulated loadings by the similarly accumulated mean annual surface runoff, the expected pollutant concentration from non-point sources is determined for each location in a stream or river. Observed pollutant concentrations in the watershed are averaged at each sample point and compared to the expected concentrations at the same locations determined from the grid cell model. In general, annual non-point source nutrient loadings in the Wujiang River watershed are seen to be predominantly from the agricultural and meadow areas.  相似文献   

12.
笔者应用因子克里格分析方法,研究了珠江口西部海域388个表层沉积物中7种重金属元素Cd, Ni,Cu,Zn,Pb,Cr和As的空间结构特征,识别并分离了重金属元素不同尺度的空间主成分及其分布特征,探讨了不同空间尺度重金属的物源及控制因素。结果显示,研究区7种重金属元素在空间上存在块金尺度、局部尺度(变程为60 km的球状结构)和区域尺度(变程为160 km的球状结构)3种尺度的空间变化。以迭代算法模拟了研究区重金属元素线性协同区域化模型。根据不同尺度上区域化因子的主成分得分分布特征可知:局部尺度上,F1因子(Zn,Cr,Ni,Cu)和F2因子(As)的高值区表现为"牛眼"状局部特征,并分布在陆地沿海的河口或者港湾区,指示了可能受人为污染成分影响的重金属区域。其中,雷州半岛东部沿海是最可能的重金属污染区,其空间分布主要受控于局部的地形、海流等因素。F2因子不同于F1的空间分布,主要在于As不同于Zn,Cr,Ni,Cu等的地球化学行为。区域尺度上,F1(Zn,Cr,Ni)和F2(As)因子主要反映了不同陆源母岩物质的影响。Zn,Cr,Ni等主要源于华南大陆陆源母岩物质,而As主要受到海南岛陆源母岩物质的控制。F1和F2因子得分高值区整体上表现为NNE向自陆地向较深海域延伸的"片状"分布特征,推测其主要受到海平面变化及NNE向区域性海洋环流的控制。  相似文献   

13.
The understanding of alpine groundwater dynamics and the interactions with surface stream water is crucial for water resources research and management in mountain regions. In order to characterize local spring and stream water systems, samples at 8 springs, 5 stream gauges and bulk samples of precipitation at 4 sites were regularly collected between January 2012 and January 2016 in the Berchtesgaden Alps for stable water isotope analysis. The sampled hydro-systems are characterized by very different dynamics of the stable isotope signatures. To quantify those differences, we analyzed the stable isotope time series and calculated mean transit times (MTT) and young water fractions (YWF) of the sampled systems. Based on the data analysis, two groups of spring systems could be identified: one group with relatively short MTT (and high YWF) and another group with long MTT (and low YWF). The MTT and the YWF of the sampled streams were intermediate, respectively. The reaction of the sampled spring and stream systems to precipitation input was studied by lag time analysis. The average lag times revealed the influence of snow and ice melt for the hydrology in the study region. It was not possible to determine the recharge elevation of the spring and stream systems due to a lack of altitude effect in the precipitation data. For two catchments, the influence of the spring water stable isotopic composition on the streamflow was shown, highlighting the importance of the spring water for the river network in the study area.  相似文献   

14.
The areal distribution of stream sediment and source-rock heavy mineralogy was studied to determine the mineralogical relations between source and derived sediment in the Piney Creek drainage basin of Wyoming. Heavy-mineral distribution in the streams was characterized using factor analysis. The results of analyses show that for an actively degrading stream system, the heavy-mineral composition of stream sediment is controlled to a considerable extent by the composition of local sediment sources and by continuous addition of detritus from bank cutting. Only the most common minerals from upstream sources persist as statistically significant variables downstream. In some cases the heavy-mineral mineral composition of stream sediment can be controlled by comparatively few, or volumetrically rare source rocks, even though more abundant source rocks supply a wide range of heavy minerals. Specific drainage configurations such as lakes and proximity of streams to major sediment sources significantly modify sediment mineralogy immediately downstream.  相似文献   

15.
《Applied Geochemistry》2002,17(10):1273-1286
The pH of mine impacted waters was estimated from the spectral reflectance of resident sediments composed mostly of chemical precipitates. Mine drainage sediments were collected from sites in the Anthracite Region of eastern Pennsylvania, representing acid to near neutral pH. Sediments occurring in acidic waters contained primarily schwertmannite and goethite while near neutral waters produced ferrihydrite. The minerals comprising the sediments occurring at each pH mode were spectrally separable. Spectral angle difference mapping was used to correlate sediment color with stream water pH (r2=0.76). Band-center and band-depth analysis of spectral absorption features were also used to discriminate ferrihydrite and goethite and/or schwertmannite by analyzing the 4T1←6A1 crystal field transition (900–1000 nm). The presence of these minerals accurately predicted stream water pH (r2=0.87) and provided a qualitative estimate of dissolved SO4 concentrations. Spectral analysis results were used to analyze airborne digital multispectral video (DMSV) imagery for several sites in the region. The high spatial resolution of the DMSV sensor allowed for precise mapping of the mine drainage sediments. The results from this study indicate that airborne and space-borne imaging spectrometers may be used to accurately classify streams impacted by acid vs. neutral-to-alkaline mine drainage after appropriate spectral libraries are developed.  相似文献   

16.
In this study, we propose a kriging algorithm, multiscale kriging model, to incorporate geochemical data observed at multiscales (multiresolutions). We assume that there are a number of measurements at different scales, and that the target scale at which the parameter values are needed may be different from the measurement scales. Several synthetic examples and the vanadium geochemical data from 8402 stream sediment samples in Zhejiang Province, China, have been used to illustrate the method. These examples demonstrate that, by incorporating measurements from all scales, the estimated field is better than the field estimated using measurements from any individual scale. This method also allows us to estimate a parameter field at the scale that does not have any measurements.  相似文献   

17.
The distribution of As in a variety of sample materials was studied at different scales, from continental to local, combining published data sets with the aim of delineating the impact and relative importance of geogenic vs. anthropogenic As sources. Geochemical mapping of As with a variety of sample materials demonstrates that variation is high at all scales (local to continental) – from sample densities of 400 sites per km2 to 1 site per 5000 km2. Different processes govern the As distribution at different scales. A high sample density is needed to reliably detect mineralisation or contamination in soil samples. In both cases the impact on the much larger geochemical background variation is limited to a local scale. Distribution patterns in geochemical maps on the sub-continental to continental scale are dominated by natural variation. Given that the geochemical background is characterised by a high variation at all scales, it appears impossible to establish a reliable single value for “good soil quality” or a “natural background concentration” for As for any sizeable area, e.g., for Europe. For such a differentiation, geochemical maps at a variety of scales are needed.  相似文献   

18.
地下水水质监测与评价   总被引：16，自引：5，他引：11  
地下水由于分布广、水质好且开发费用低而成为全世界重要的供水水源。中国北方生活供水的一半来自地下水,地下水也是干旱期重要的农业灌溉水源。然而,地下水水质日益面临来自农业、工业和城市污染源的威胁。地下水水质监测是评价水质状况最可靠的方法,并可作为供水水源保护的早期预警系统。它为水管理部门和水用户提供可靠的科学数据以便更好地管理和保护地下水资源。世界上正在执行两个巨大的地下水质监测和评价项目:一个是欧盟的水框架计划;另一个是美国的国家水质评价计划。文章评述了地下水水质监测的现状,介绍了地下水易污性评价、地下水污染源分级和地下水污染风险评价的方法。地下水易污性分区图是土地利用规划和供水水源保护的基础。地下水污染源分级结果为污染源治理提供了优先顺序。地下水污染风险分区图圈划出地下水污染的高风险区,为地下水资源保护和地下水污染监测提供重要的依据。  相似文献   

19.
This research is to analyze the composition of stream networks of drainage basins in Japan and to discuss the characteristics of drainage basins in the Japanese Islands. Study areas were selected for 180 drainage basins in the entire country. In this study, a topographic map with a scale of 1:50,000 was used and inserted into the valley line by V-shaped-contour methods in each drainage basin. The streams are ordered according to Strahler's system and measured by the stream number, stream length, stream slope, drainage area, and stream fall in each drainage basin. Horton's law of drainage network composition holds good in most drainage basins in Japan. The average values of the bifurcation ratio, stream length ratio, stream slope ratio, drainage area ratio, and stream fall ratio are 4.24, 1.91, 1.98, 4.52, and 1.04, respectively. The mean bifurcation ratio of drainage basins in Japan is 4.24, and this ratio is slightly greater than in other countries. It is also greater than the theoretical value of 4.0. This implies that the slope of drainage basins in Japan is so steep and the relief energy so large that excess streams have developed to a rather marked degree. The average stream fall ratio is 1.04 for drainage basins in Japan. It suggests that drainage basins are generally considered to be in a stage of maturity in stream channel development for the Japanese Islands. The stream fall ratio, however, is slightly greater than 1.0. Although, the stream beds are nearly in dynamic equilibrium in most cases, it tends to be in a slightly aggrading state.  相似文献   

20.
Rocky intertidal communities are structured by local environmental drivers, which can be dynamic, fluctuating on various temporal scales, or static and not greatly varying across years. We examined the role of six static drivers (distance to freshwater, tidewater glacial presence, wave exposure, fetch, beach slope, and substrate composition) on intertidal community structure across the northern Gulf of Alaska. We hypothesized that community structure is less similar at the local scale compared with the regional scale, coinciding with static drivers being less similar on smaller than larger scales. We also hypothesized that static attributes mainly drive local biological community structure. For this, we surveyed five to six sites in each of the six regions in the mid and low intertidal strata. Across regions, static attributes were not consistently different and only small clusters of sites had similar attributes. Additionally, intertidal communities were less similar on the site compared with the region level. These results suggest that these biological communities are not strongly influenced by the local static attributes measured in this study. An alternative explanation is that static attributes among our regions are not different enough to influence the biological communities. This lack of evidence for a strong static driver may be a result of our site selection, which targeted rocky sheltered communities. This suggests that this habitat may be ideal to examine the influence of dynamic drivers. We recommend that future analyses of dynamic attributes may best be performed after analyses have demonstrated that sites do not differ in static attributes.  相似文献   

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