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1.
Mixed layer clay minerals, vitrinite reflectance and geochemical data from Rock-Eval pyrolysis were used to constrain the burial evolution of the Mesozoic–Cenozoic successions exposed at the Kuh-e-Asmari (Dezful Embayment) and Sim anticlines (Fars province) in the Zagros fold-and-thrust belt. In both areas, Late Cretaceous to Pliocene rocks, show low levels of thermal maturity in the immature stages of hydrocarbon generation and early diagenetic conditions (R0 I–S and Ro% values < 0.5). At depths of 2–4 km, Tmax values (435–450 °C) from organic-rich layers of the Sargelu, Garau and Kazhdumi source rocks in the Kuh-e-Asmari anticline indicate mid to late mature stages of hydrocarbon generation. One dimensional thermal models allowed us to define the onset of oil generation for the Middle Jurassic to Eocene source rocks and pointed out that sedimentary burial is the main factor responsible for measured levels of thermal maturity. Specifically, the Sargelu and Garau Formations entered the oil window prior to Zagros folding in Late Cretaceous times, the Kazhdumi Formation during middle Miocene (syn-folding stage), and the Pabdeh Formation in the Late Miocene–Pliocene after the Zagros folding. In the end, the present-day distribution of oil fields in the Dezful Embayment and gas fields in the Fars region is primarily controlled by lithofacies changes and organic matter preservation at the time of source rock sedimentation. Burial conditions during Zagros folding had minor to negligible influence. 相似文献
2.
Cretaceous sedimentary rocks of the Mukalla, Harshiyat and Qishn formations from three wells in the Jiza sub-basin were studied to describe source rock characteristics, providing information on organic matter type, paleoenvironment of deposition and hydrocarbon generation potential. This study is based on organic geochemical and petrographic analyses performed on cuttings samples. The results were then incorporated into basin models in order to understand the burial and thermal histories and timing of hydrocarbon generation and expulsion.The bulk geochemical results show that the Cretaceous rocks are highly variable with respect to their genetic petroleum generation potential. The total organic carbon (TOC) contents and petroleum potential yield (S1 + S2) of the Cretaceous source rocks range from 0.43 to 6.11% and 0.58–31.14 mg HC/g rock, respectively indicating non-source to very good source rock potential. Hydrogen index values for the Early to Late Cretaceous Harshiyat and Qishn formations vary between 77 and 695 mg HC/g TOC, consistent with Type I/II, II-III and III kerogens, indicating oil and gas generation potential. In contrast, the Late Cretaceous Mukalla Formation is dominated by Type III kerogen (HI < 200 mg HC/g TOC), and is thus considered to be gas-prone. The analysed Cretaceous source rock samples have vitrinite reflectance values in the range of 0.37–0.95 Ro% (immature to peak-maturity for oil generation).A variety of biomarkers including n-alkanes, regular isoprenoids, terpanes and steranes suggest that the Cretaceous source rocks were deposited in marine to deltaic environments. The biomarkers also indicate that the Cretaceous source rocks contain a mixture of aquatic organic matter (planktonic/bacterial) and terrigenous organic matter, with increasing terrigenous influence in the Late Cretaceous (Mukalla Formation).The burial and thermal history models indicate that the Mukalla and Harshiyat formations are immature to early mature. The models also indicate that the onset of oil-generation in the Qishn source rock began during the Late Cretaceous at 83 Ma and peak-oil generation was reached during the Late Cretaceous to Miocene (65–21 Ma). The modeled hydrocarbon expulsion evolution suggests that the timing of oil expulsion from the Qishn source rock began during the Miocene (>21 Ma) and persisted to present-day. Therefore, the Qishn Formation can act as an effective oil-source but only limited quantities of oil can be expected to have been generated and expelled in the Jiza sub-basin. 相似文献
3.
The Upper Cretaceous Mukalla coals and other organic-rich sediments which are widely exposed in the Jiza-Qamar Basin and believed to be a major source rocks, were analysed using organic geochemistry and petrology. The total organic carbon (TOC) contents of the Mukalla source rocks range from 0.72 to 79.90% with an average TOC value of 21.50%. The coals and coaly shale sediments are relatively higher in organic richness, consistent with source rocks generative potential. The samples analysed have vitrinite reflectance in the range of 0.84–1.10 %Ro and pyrolysis Tmax in the range of 432–454 °C indicate that the Mukalla source rocks contain mature to late mature organic matter. Good oil-generating potential is anticipated from the coals and coaly shale sediments with high hydrogen indices (250–449 mg HC/g TOC). This is supported by their significant amounts of oil-liptinite macerals are present in these coals and coaly shale sediments and Py-GC (S2) pyrograms with n-alkane/alkene doublets extending beyond nC30. The shales are dominated by Type III kerogen (HI < 200 mg HC/g TOC), and are thus considered to be gas-prone.One-dimensional basin modelling was performed to analysis the hydrocarbon generation and expulsion history of the Mukalla source rocks in the Jiza-Qamar Basin based on the reconstruction of the burial/thermal maturity histories in order to improve our understanding of the of hydrocarbon generation potential of the Mukalla source rocks. Calibration of the model with measured vitrinite reflectance (Ro) and borehole temperature data indicates that the present-day heat flow in the Jiza-Qamar Basin varies from 45.0 mW/m2 to 70.0 mW/m2 and the paleo-heat flow increased from 80 Ma to 25 Ma, reached a peak heat-flow values of approximately 70.0 mW/m2 at 25 Ma and then decreased exponentially from 25 Ma to present-day. The peak paleo-heat flow is explained by the Gulf of Aden and Red Sea Tertiary rifting during Oligocene-Middle Miocene, which has a considerable influence on the thermal maturity of the Mukalla source rocks. The source rocks of the Mukalla Formation are presently in a stage of oil and condensate generation with maturity from 0.50% to 1.10% Ro. Oil generation (0.5% Ro) in the Mukalla source rocks began from about 61 Ma to 54 Ma and the peak hydrocarbon generation (1.0% Ro) occurred approximately from 25 Ma to 20 Ma. The modelled hydrocarbon expulsion evolution suggested that the timing of hydrocarbon expulsion from the Mukalla source rocks began from 15 Ma to present-day. 相似文献
4.
《Marine and Petroleum Geology》2012,37(1):13-34
Structured organic matters of the Palynomorphs of mainly dinoflagellate cysts are used in this study for dating the limestone, black shale, and marl of the Middle Jurassic (Bajocian–Bathonian) Sargelu Formation, Upper Jurassic (Upper Callovian – Lower Oxfordian) Naokelekan Formation, Upper Jurassic (Kimeridgian and Oxfordian) Gotnia and Barsarine Formations, and Upper Jurassic – Lower Cretaceous (Tithonian-Beriassian) Chia Gara source rock Formations while spore species of Cyathidites australis and Glechenidites senonicus are used for maturation assessments of this succession. Materials' used for this palynological study are 320 core and cutting samples of twelve oil wells and three outcrops in North Iraq.Terpane and sterane biomarker distributions, as well as stable isotope values, were determined for oils potential source rock extracts of Jurassic-Lower Cretaceous strata to determine valid oil-to-source rock correlations in North Iraq. Two subfamily carbonate oil types-one of Middle Jurassic age (Sargelu) carbonate rock and the other of mixed Upper Jurassic/Cretaceous age (Chia Gara) with Sargelu sources as well as a different oil family related to Triassic marls, were identified based on multivariate statistical analysis (HCA & PCA). Middle Jurassic subfamily A oils from Demir Dagh oil field correlate well with rich, marginally mature, Sargelu source rocks in well Mk-2 near the city of Baiji. In contrast, subfamily B oils have a greater proportion of C28/C29 steranes, indicating they were generated from Upper Jurassic/Lower Cretaceous carbonates such as those at Gillabat oil field north of Mansuriyah Lake. Oils from Gillabat field thus indicate a lower degree of correlation with the Sargelu source rocks than do oils from Demir Dagh field.Palynofacies assessments are performed for this studied succession by ternary kerogen plots of the phytoclast, amorphous organic matters, and palynomorphs. From the diagram of these plots and maturation analysis, it could be assessed that the formations of Chia Gara and Sargelu are both deposited in distal suboxic to anoxic basin and can be correlated with kerogens classified microscopically as Type A and Type B and chemically as Type II. The organic matter, comprised principally of brazinophyte algae, dinoflagellate cysts, spores, pollen, foraminifera test linings, and phytoclasts in all these formations and hence affected with upwelling current. These deposit contain up to 18 wt% total organic matters that are capable to generate hydrocarbons within mature stage of thermal alteration index (TAI) range in Stalplin's scale (Staplin, 1969) of 2.7–3.0 for the Chia Gara Formation and 2.9–3.1 for the Sargelu Formation. Case study examples of these oil prone strata are; one 7-m (23-ft) thick section of the Sargelu Formation averages 44.2 mg HC/g S2 and 439 °C Tmax (Rock-Eval pyrolysis analyses) and 16 wt% TOC especially in well Mk-2 whereas, one 8-m (26-ft) thick section of the Chia Gara and 1-m (3-ft) section of Naokelekan Formations average 44.5 mg HC/g S2 and 440 °C Tmax and 14 wt% TOC especially in well Aj-8. One-dimension, petroleum system models of key wells using IES PetroMod Software can confirm their oil generation capability.These hydrocarbon type accumulation sites are illustrated in structural cross sections and maps in North Iraq. 相似文献
5.
Uppermost Jurassic and Lower Cretaceous strata of the Silesian Nappe of the Outer Western Carpathians contain large amounts of shale, which can, under favourable conditions, become source rocks for hydrocarbons. This study analysed 45 samples from the area of Czech Republic by the means of palynofacies analysis, thermal alteration index (TAI) of palynomorphs and total organic carbon (TOC) content to determine the kerogen type, hydrocarbon source rock potential, and to interpret the depositional environment. Uppermost Jurassic Vendryně Formation and Lower Cretaceous Formations (Těšín Limestone, Hradiště and Lhoty) reveal variable amount of mostly gas prone type III kerogen. Aptian Veřovice Formation has higher organic matter content (over 3 wt.%) and oil-prone type II kerogen. Organic matter is mature to overmature and hydrocarbon potential predisposes it as a source of gas. Aptian black claystones of the Veřovice Fm. are correlatable with oceanic anoxic event 1 (OAE1). 相似文献
6.
Two petroleum source rock intervals of the Lower Cretaceous Abu Gabra Formation at six locations within the Fula Sub-basin, Muglad Basin, Sudan, were selected for comprehensive modelling of burial history, petroleum maturation and expulsion of the generated hydrocarbons throughout the Fula Sub-basin. Locations (of wells) selected include three in the deepest parts of the area (Keyi oilfield); and three at relatively shallow locations (Moga oilfield). The chosen wells were drilled to depths that penetrated a significant part of the geological section of interest, where samples were available for geochemical and source rock analysis. Vitrinite reflectances (Ro %) were measured to aid in calibrating the developed maturation models.The Abu Gabra Formation of the Muglad Basin is stratigraphically subdivided into three units (Abu Gabra-lower, Abu Gabra-middle and Abu Gabra-upper, from the oldest to youngest). The lower and upper Abu Gabra are believed to be the major source rocks in the province and generally contain more than 2.0 wt% TOC; thus indicating a very good to excellent hydrocarbon generative potential. They mainly contain Type I kerogen. Vitrinite reflectance values range from 0.59 to 0.76% Ro, indicating the oil window has just been reached. In general, the thermal maturity of the Abu Gabra source rocks is highest in the Abu Gabra-lower (deep western part) of the Keyi area and decreases to the east toward the Moga oilfied at the Fula Sub-basin.Maturity and hydrocarbon generation modelling indicates that, in the Abu Gabra-Lower, early oil generation began from the Middle- Late Cretaceous to late Paleocene time (82.0–58Ma). Main oil generation started about 58 Ma ago and continues until the present day. In the Abu Gabra-upper, oil generation began from the end of the Cretaceous to early Eocene time (66.0–52Ma). Only in one location (Keyi-N1 well) did the Abu Gabra-upper reach the main oil stage. Oil expulsion has occurred only from the Abu Gabra-lower unit at Keyi-N1 during the early Miocene (>50% transformation ratio TR) continuing to present-day (20.0–0.0 Ma). Neither unit has generated gas. Oil generation and expulsion from the Abu Gabra source rocks occurred after the deposition of seal rocks of the Aradeiba Formation. 相似文献
7.
The regional burial history pattern, thermal maturity variations and source rock assessment of the sedimentary succession in the eastern Taurus region, in the southern part of Turkey, have been studied on surface samples collected from the six different sections which represent the entire region. Organic petrography (Thermal Alteration Index) and geochemical data (TOC content, Tmax and HI values) were obtained from transmitted-light microscopy and Rock-Eval pyrolysis.The Lower Paleozoic (Cambrian, Ordovician and Silurian) strata were not investigated and modeled in terms of the maturity and hydrocarbon source rock potential, because of their poor organic matter content and their over maturity resulting from great burial depth (more than 7630 m). Other Paleozoic strata, except the Lower Devonian Ayitepesi Formation, generally have the values of more than 0.5% TOC. Organic matter of the Middle Devonian Safaktepesi sediments are composed of highly terrestrial organic material (type III kerogen), while samples from other three formations (Gumusali, Ziyarettepe and Yigilitepe Formations), while samples from other organic matter (type II and type III kerogen). The average TAI values are as high as 3.4 (equivalent to 1.42 of R0%) for Ayitepesi and as low as 2.75 (equivalent to 0.77 of R0%) for Yigilitepe Formations. Time-temperature index values (TTI) indicate that Ziyarettepe and Yigilitepe sediments are marginally mature to mature, while the Devonian strata are overmature. There are minor discrepancies between ΣTTI values and geochemical data in terms of the organic maturity for Devonian strata. In contrast, the e is a consistency between those values for the Ziyarettepe and the Yigilitepe Formations. The onset of oil generation time in the region was initiated from as early as the Norian (216 Ma) to as late as the Lutetian (45 Ma).Regional variations in the level of thermal and source-rock maturities of the Upper Paleozoic sediments in the eastern Taurus region largely depend on burial depth. 相似文献
8.
Deposition of organic rich black shales and dark gray limestones in the Berriasian-Turonian interval has been documented in many parts of the world. The Early Cretaceous Garau Formation is well exposed in Lurestan zone in Iran and is composed of organic-rich shales and argillaceous limestones. The present study focuses on organic matter characterization and source rock potential of the Garau Formations in central part of Lurestan zone. A total of 81 core samples from 12 exploratory wells were subjected to detailed geochemical analyses. These samples have been investigated to determine the type and origin of the organic matter as well as their petroleum-generation potential by using Rock-Eval/TOC pyrolysis, GC and GCMS techniques. The results showed that TOC content ranges from 0.5 to 4.95 percent, PI and Tmax values are in the range of 0.2 and 0.6, and 437 and 502 °C. Most organic matter is marine in origin with sub ordinary amounts of terrestrial input suggesting kerogen types II-III and III. Measured vitrinite reflectance (Rrandom%) values varying between 0.78 and 1.21% indicating that the Garau sediments are thermally mature and represent peak to late stage of hydrocarbon generation window. Hydrocarbon potentiality of this formation is assessed fair to very good capable of generating chiefly gas and some oil. Biomarker characteristics are used to provide information about source and maturity of organic matter input and depositional environment. The relevant data include normal alkane and acyclic isoprenoids, distribution of the terpane and sterane aliphatic biomarkers. The Garau Formation is characterized by low Pr/Ph ratio (<1.0), high concentrations of C27 regular steranes and the presence of tricyclic terpanes. These data indicated a carbonate/shale source rock containing a mixture of aquatic (algal and bacterial) organic matter with a minor terrigenous organic matter contribution that was deposited in a marine environment under reducing conditions. The results obtained from biomarker characteristics also suggest that the Garau Formation is thermally mature which is in agreement with the results of Rock-Eval pyrolysis. 相似文献
9.
The evaporite-cored Hoodoo Dome on southern Ellef Ringnes Island, Sverdrup Basin, was examined to improve the understanding of its structural geological history in relation to hydrocarbon migration. Data from geological mapping, reflection seismic, thermal maturity and detrital apatite (U–Th)/He cooling ages are presented. Five stages of diapirism are interpreted from Jurassic to Recent times:1. 180 to 163 Ma (pre-Deer Bay Formation; development of a diapir with a circular map pattern).2. 163 to 133 Ma (Deer Bay to lower Isachsen formations; development of salt wings).3. 115 to 94 Ma (Christopher and Hassel formations; ongoing diapirism and development of an oval map pattern)4. 79 Ma (Kanguk Formation; reactivation of the central diapir).5. 42 Ma to 65 Ma (Eurekan Orogeny; tightening of the anticline).During phase1, the Hoodoo diapir was circular. During phase 2, salt wings formed along its margin. During phase 3, the Hoodoo Dome geometry evolved into a much larger, elongate, doubly plunging anticline. Phase 4 is inferred from thermochronology data as indicated by a cluster of cooling ages, but the extent of motion during that time is unknown. During Phase 5 the dome was tightened creating approximately 700 m of structural relief. Denudation since the end of the Eurekan Orogeny is estimated to be about 600 m.A one dimensional burial history model predicts hydrocarbon generation from Middle and Late Triassic source rocks between 140 and 66 Ma, with majority of hydrocarbon expulsion between 117 and 79 Ma. Hydrocarbon generation post-dates salt wing formation, so that this trap could host natural gas expelled from Triassic source rocks. 相似文献
10.
T.K. Al-Ameri 《Marine and Petroleum Geology》2011,28(4):880-894
This work presents new insights of the generation, quality and migration pathways of the hydrocarbons in the East Baghdad Oil Field.The Khasib and Tannuma formations in East Baghdad are considered as oil reservoirs according to their high porosity (15-23%) and permeability (20-45 mD) in carbonate rocks. The hydrocarbons are trapped by structural anticline closure trending NW-SE. Gas chromatography analysis on these oil reservoirshave shown biomarkers of abundant ranges of n-alkanes of less than C22 (C17-C21) with C19 and C18 peaks. This suggests mainly liquid oil constituents of paraffinic hydrocarbons from marine algal source of restricted palaeoenvironments in the reservoir. The low non aromatic C15 + peaks are indicative for slight degradation and water washing. Oil biomarkers of Pr./Ph. = 0.85, C31/C30 < 1.0, location in triangle of C27-C29 sterane, C28/C29 of 0.6 sterane, Oleanane of 0.01 and CPI = 1.0, indicate an anoxic marine environment with carbonate deposits of Upper Jurassic to Early Cretaceous age. Four Miospores, seven Dinoflagellates and one Tasmanite species confirm affinity to the upper most Jurassic to Lower Cretaceous Chia Gara and Ratawi Formations.The recorded palynomorphs from the Khasib and Tannuma Formations are of light brown color of TAI = 2.8-3.0 and comparable to the mature palynomorphs that belong to the Chia Gara and the Lower part of Ratawi Formations.The Chia Gara Formation generated oil during Upper Cretaceous to Early Palaeogene and accumulated in structural traps of Cretaceous age, such as the Khasib and Tannuma reservoirs. The Chia Gara Formation generated and expelled high quantities of oil hydrocarbons according to their TOC wt% of 0.5-8.5 with S2 = 2.5-18.5 mg Hc/g Rock, high hydrogen index of the range 150-450 mg Hc/g Rock, good petroleum potential of 4.5-23.5 mg Hc/g Rock, mature (TAI = 2.8-3.0 and Tmax = 428-443C), kerogen type II and palynofacies parameters of up to 100% AOM (Amorphous Organic Matters). This includes algae deposits in a dysoxic-anoxic to suboxic-anoxic environment.Alternative plays are discussed according to the migration pathways. 相似文献
11.
An evaluation of the petroleum generating potential of onshore Eocene-Miocene sequences of Western Sabah, Malaysia was performed based on organic petrological and geochemical methods. The sequences analysed are the Belait, Meligan, Temburong and West Crocker formations of western Sabah. The Belait Formation which is Stage IV equivalent in the offshore represents one of the major source rock/reservoirs of the petroleum-bearing Sabah Basin. The Eocene-Early Miocene West Crocker and Temburong formations are deepwater turbidites whilst the Miocene Meligan and Belait formations are shallow marine fluvio-deltaic deposits. The vitrinite reflectance and pyrolysis Tmax values show that the Belait samples are generally immature for hydrocarbon generation, whereas the Meligan, Temburong and West Crocker samples are in the mature to late maturity stage of hydrocarbon generation. The overall bulk source rock properties of the Belait and Meligan show fair to good petroleum source rock potential with TOC more than 1 wt %, hydrocarbon yield in the range of 400–1300 ppm and moderately high HI for many of the samples. Most of the samples representing the Temburong and West Crocker formations have TOC less than 1 wt% and have no to fair hydrocarbon generating potential. Interestingly, the samples collected in the West Crocker Formation characterized by slump deposits (MTD) have TOC>2 and possess good to excellent hydrocarbon generating potential. The organic matter present in all of the studied formations is mainly of terrigenous origin based on the abundance of woody plant materials observed under the microscope. Consequently, the analysed sequences are predominantly gas prone, dominated by Type III and Type III-IV kerogen except for minor occurrence of mixed oil-gas prone Type II-III kerogen in the Belait Formation and in the slump mass transport deposits (MTD) of the West Crocker Formation. 相似文献
12.
Upper Jurassic organic matter-rich, marine shales of the Mandal Formation have charged major petroleum accumulations in the North Sea Central Graben including the giant Ekofisk field which straddles the graben axis. Recent exploration of marginal basin positions such as the Mandal High area or the Søgne Basin has been less successful, raising the question as to whether charging is an issue, possibly related to high thermal stability of the source organic matter or delayed expulsion from source to carrier.The Mandal Formation is in part a very prolific source rock containing mainly Type II organic matter with <12 wt.-% TOC and HI < 645 mg HC/g TOC but Type III-influenced organofacies are also present. The formation is therefore to varying degrees heterogeneous. Here we show, using geochemical mass balance modelling, that the petroleum expulsion efficiency of the Mandal Formation is relatively low as compared to the Upper Jurassic Draupne Formation, the major source rock in the Viking Graben system. Using maturity series of different initial source quality from structurally distinct regions and encompassing depositional environments from proximal to distal facies, we have examined the relationship between free hydrocarbon retention and organic matter structure. The aromaticity of the original and matured petroleum precursors in the Mandal source rock plays a major role in its gas retention capacity as cross-linked monoaromatic rings act on the outer surface of kerogen as sorptive sites. However, oil retention is a function of both kerogen and involatile bitumen compositions. Slight variations in total petroleum retention capacities within the same kerogen yields suggest that texture of organic matter (e.g. organic porosity) could play a role as well. 相似文献
13.
鄂尔多斯盆地北部主力气源岩太原组、山西组煤系地层热成熟史的研究对本区天然气充注过程和有利目标区预测具有重要的参考价值。在对研究区烃源岩评价和一维、二维地质建模研究的基础上。利用BasinMod盆地模拟软件对单井以及研究区内二维剖面、平面进行了煤系烃源岩热演化史模拟研究。研究结果表明：（1）该区在中三叠世进入生烃门限，中侏罗世以后，烃源岩持续埋深，早白垩世末期至最大埋深（4000m左右），绝大多数的天然气都在这一阶段生成，早白垩世末构造抬升以后只有少量天然气生成；（2）研究区上古生界太原组和山西组煤系源岩最大累积生烃强度可达到2200×10^8m^3／km^2，对现今天然气的分布具有较强的控制作用。 相似文献
14.
Sedimentary heterogeneities are ubiquitous in nature and occur over a range of scales from core, reservoir to basin scales. They may thus exert significant influences on hydrocarbon generation, migration and accumulation. The sedimentary heterogeneities of the Permian Shanxi Formation in the Ordos Basin, China were modelled using Sedsim, a stratigraphic forward modelling program. The simulation results were then used to construct a 3D petroleum system model using PetroMod. The effects of sedimentary heterogeneities on hydrocarbon accumulations were evaluated by comparing the integrated Sedsim-PetroMod model with the classic 3D basin model. The Sedsim simulation shows that considerable sedimentary heterogeneities are present within the Shanxi Formation, as a result of the interplay of the initial topography, tectonic subsidence, base level change and sediment inputs. A variety of lithologies were developed both laterally and vertically within the Shanxi Formation at kilometre and metre scales, respectively, with mudstones mainly developed in the depositional centre, while sandstones developed in the southern and northern margin areas. A typical source-ward retrogradation is well developed within the Lower Shanxi Formation.A base-case classic 3D basin model was constructed to quantify the Permian petroleum system in the Ordos Basin. The geological and thermal models were calibrated using Vr and borehole temperature data. The source rocks of the Upper Paleozoic became mature (Ro > 0.5%) and high mature (Ro > 1.2%) in the late Triassic and late Jurassic, respectively, in the central and southern areas. During the Early Cretaceous, a tectonically induced geothermal event occurred in the southern Ordos Basin. This caused the source rocks to reach over maturity (Ro > 2.0%) quite rapidly in the early Late Cretaceous in the central and southern areas. All the source rock transformation ratios (TR) at present are greater than 70% in the P1 coal and P1 mudstone layers with TR values approaching 100% in the central and southern areas. The transformation ratios of the P1 limestone are close to 100% over the entire interval.In the base-case model, a large amount of hydrocarbons appear to have been expelled and migrated into the Shanxi Formation, but only a minor amount was accumulated to form reservoirs. In the model, the Shanxi Formation sandstone layer was set to be homogeneous vertically and there was no regional seal rocks present at the top of the Shanxi Formation. Therefore hydrocarbons could not be trapped effectively with only minor accumulations in some local structural highs where hydrocarbons are trapped both at the top and in the up-dip direction by the adjacent mudstone facies. In contrast, the integrated Sedsim-PetroMod model takes into account of the internal lithological and sedimentary facies heterogeneities within the Shanxi Formation, forming complex contiguous sandstone-mudstone stacking patterns. Hydrocarbons were found to have accumulated in multiple intervals of lithological traps within the Shanxi Formation. The results indicate that lithological distinctions, controlled by sedimentary heterogeneities in three dimensions can provide effective sealing in both the top and up-dip directions for hydrocarbon accumulations, with gas being mainly accumulated near the depocentre where lithological traps usually formed due to frequent oscillations of the lake level. 相似文献
15.
华南陆缘出露的上三叠统-白垩系,累计厚度超过10 000m,露头调查未见油苗,烃源岩主要为泥岩、碳质泥岩和煤线,有机质类型以Ⅱ-Ⅲ型为主。上三叠统小水组,发育较深水的海相、Ⅱ型良好烃源岩,TOC为1.17%～5.43%;下侏罗统桥源组发育海陆过渡环境的Ⅲ型良好烃源岩,TOC为1.36%～10.37%;下侏罗统其他层系(金鸡组、银瓶山组、上龙水组、长埔组、吉水门组)发育浅海-半深海相的中等-好的烃源岩,TOC为0.5%～1.76%。烃源岩均已处于成熟-过成熟阶段。小水组、蓝塘群烃源岩品质良好,厚度巨大,在南海北部海域开展中生界烃源岩研究时,值得重点关注是否有与之相当的烃源岩层系发育。 相似文献
16.
Organic geochemical and palynofacies studies of 172 ditch cuttings samples of possible source rock shales from the Late Cretaceous Gongila and Fika formations in the Chad Basin of NE Nigeria were carried out to determine their paleoenvironments of deposition. Although dominated by amorphous organic matter, C/S ratios and molecular parameters suggest the mostly organic lean shales (TOC contents typically below 1.5%) were deposited in a normal marine environment. Levels of oxygenation influenced by water depth in the depositional environment appear to control organic richness and quality of the dark grey shales.The organic rich (TOC > 2.0%) upper part of the Fika Formation was deposited under anoxic conditions during the Late Cretaceous and could represent an Oceanic Anoxic Event. Mature intervals where such conditions prevailed would have generated liquid hydrocarbon, although none were sampled here.A trend of increasing organic richness towards the central part of the larger Chad Basin observed in this and other studies supports the development of organic rich marine shales (average TOC contents of 2–3%) of equivalent age in the Termit Basin where water depth would have been deeper and oxygen conditions at levels that permitted preservation of marine organic matter. 相似文献
17.
Composition, porosity, and reservoir potential of the Middle Jurassic Kashafrud Formation, northeast Iran 总被引：1，自引：0，他引：1
In the Kopet-Dagh Basin of Iran, deep-sea sandstones and shales of the Middle Jurassic Kashafrud Formation are disconformably overlain by hydrocarbon-bearing carbonates of Upper Jurassic and Cretaceous age. To explore the reservoir potential of the sandstones, we studied their burial history using more than 500 thin sections, supplemented by heavy mineral analysis, microprobe analysis, porosity and permeability determination, and vitrinite reflectance.The sandstones are arkosic and lithic arenites, rich in sedimentary and volcanic rock fragments. Quartz overgrowths and pore-filling carbonate cements (calcite, dolomite, siderite and ankerite) occluded most of the porosity during early to deep burial, assisted by early compaction that improved packing and fractured quartz grains. Iron oxides are prominent as alteration products of framework grains, probably reflecting source-area weathering prior to deposition, and locally as pore fills. Minor cements include pore-filling clays, pyrite, authigenic albite and K-feldspar, and barite. Existing porosity is secondary, resulting largely from dissolution of feldspars, micas, and rock fragments, with some fracture porosity. Porosity and permeability of six samples averages 3.2% and 0.0023 mD, respectively, and 150 thin-section point counts averaged 2.7% porosity. Reflectance of vitrinite in eight sandstone samples yielded values of 0.64-0.83%, in the early mature to mature stage of hydrocarbon generation, within the oil window.Kashafrud Formation petrographic trends were compared with trends from first-cycle basins elsewhere in the world. Inferred burial conditions accord with the maturation data, suggesting only a moderate thermal regime during burial. Some fractures, iron oxide cements, and dissolution may reflect Cenozoic tectonism and uplift that created the Kopet-Dagh Mountains. The low porosity and permeability levels of Kashafrud Formation sandstones suggest only a modest reservoir potential. For such tight sandstones, fractures may enhance the reservoir potential. 相似文献
18.
The Upper Triassic — Lower Jurassic Kap Stewart Formation (Jameson Land, East Greenland) has been studied by a combination of sedimentological and organic geochemical methods (LECO/Rock Eval, sulphur, gas chromatography) in order to assess the hydrocarbon source potential of the abundant and extensive lacustrine shale intervals present in the formation.The organic matter in the shales is a mixture of algal and higher plant remains (type I and III kerogen). An organic assemblage dominated by algal material, having a rich oil potential, occurs in an interval approximately 10–15 m thick in the uppermost part of the formation. This interval has an organic carbon content up to 10% and Hydrogen Index values up to 700. The interval is consistently traceable along the exposed margins and the central part of the basin. The deposition of the uppermost shale interval coincided with the largest expansion of the lake, during a period with a stratified water column and anoxic bottom-water conditions.Locally the rocks exposed are thermally postmature due to the thermal influence of dolerite sills which intruded the Kap Stewart Formation in Tertiary time. However, the organic-rich shale interval is beyond the influence of the sills and indicates a maturity prior to or in the early stages of oil generation.Calculations of the generative potential of the lacustrine source rocks suggest that significant amounts of petroleum may have been generated in those sediments which have undergone sufficient burial in the southern and central part of the basin. Here, the contemporaneously deposited delta front and barrier island sandstones can thus be considered as potential targets for future hydrocarbon exploration. This type of play may also be of importance in other North Atlantic basins with a similar basin history. 相似文献
19.
Ever since a breakthrough of marine shales in China, lacustrine shales have been attracting by the policy makers and scientists. Organic-rich shales of the Middle Jurassic strata are widely distributed in the Yuqia Coalfield of northern Qaidam Basin. In this paper, a total of 42 shale samples with a burial depth ranging from 475.5 m to 658.5 m were collected from the Shimengou Formation in the YQ-1 shale gas borehole of the study area, including 16 samples from the Lower Member and 26 samples from the Upper Member. Geochemistry, reservoir characteristics and hydrocarbon generation potential of the lacustrine shales in YQ-1 well were preliminarily investigated using the experiments of vitrinite reflectance measurement, maceral identification, mineralogical composition, carbon stable isotope, low-temperature nitrogen adsorption, methane isothermal adsorption and rock eval pyrolysis. The results show that the Shimengou shales have rich organic carbon (averaged 3.83%), which belong to a low thermal maturity stage with a mean vitrinite reflectance (Ro) of 0.49% and an average pyrolytic temperature of the generated maximum remaining hydrocarbon (Tmax) of 432.8 °C. Relative to marine shales, the lacustrine shales show low brittleness index (averaged 34.9) but high clay contents (averaged 55.1%), high total porosities (averaged 13.71%) and great Langmuir volumes (averaged 4.73 cm−3 g). Unlike the marine and marine-transitional shales, the quartz contents and brittleness index (BI) values of the lacustrine shales first decrease then increase with the rising TOC contents. The kerogens from the Upper Member shales are dominant by the oil-prone types, whereas the kerogens from the Lower Member shales by the gas-prone types. The sedimentary environment of the shales influences the TOC contents, thus has a close connection with the hydrocarbon potential, mineralogical composition, kerogen types and pore structure. Additionally, in terms of the hydrocarbon generation potential, the Upper Member shales are regarded as very good and excellent rocks whereas the Lower Member shales mainly as poor and fair rocks. In overall, the shales in the top of the Upper Member can be explored for shale oil due to the higher free hydrocarbon amount (S1), whereas the shales in the Lower Member and the Upper Member, with the depths greater than 1000 m, can be suggested to explore shale gas. 相似文献
20.
The Late Miocene Zeit Formation is exposed in the Red Sea Basin of Sudan and represents an important oil-source rock. In this study, five (5) exploratory wells along Red Sea Basin of Sudan are used to model the petroleum generation and expulsion history of the Zeit Formation. Burial/thermal models illustrate that the Red Sea is an extensional rift basin and initially developed during the Late Eocene to Oligocene. Heat flow models show that the present-day heat flow values in the area are between 60 and 109 mW/m2. The variation in values of the heat flow can be linked to the raise in the geothermal gradient from margins of the basin towards offshore basin. The offshore basin is an axial area with thick burial depth, which is the principal heat flow source.The paleo-heat flow values of the basin are approximately from 95 to 260 mW/m2, increased from Oligocene to Early Pliocene and then decreased exponentially prior to Late Pliocene. This high paleo-heat flow had a considerable effect on the source rock maturation and cooking of the organic matter. The maturity history models indicate that the Zeit Formation source rock passed the late oil-window and converted the oil generated to gas during the Late Miocene.The basin models also indicate that the petroleum was expelled from the Zeit source rock during the Late Miocene (>7 Ma) and it continues to present-day, with transformation ratio of more than 50%. Therefore, the Zeit Formation acts as an effective source rock where significant amounts of petroleum are expected to be generated in the Red Sea Basin. 相似文献