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1.
Jian Pang Jialiang Han Xuelu Fan Chan Li Xian Dong Longchao Liang Zhuo Chen 《Acta Geochimica》2019,(3):391-403
Mercury(Hg) is a global pollutant and can be accumulated in the food chain, posing exposure risks to humans. In this study, rice plants and corresponding rhizosphere soil samples were collected from a watershed of the Wawu River Basin that is heavily impacted by historic Hg mining and retorting activities. Total mercury(THg)and methylmercury(MeHg) in rice grains, as well as other tissues and soil samples, were measured. Five soil Hg fractions, as well as soil parameters, were also determined.The results show that the average concentrations of THg and MeHg in rice grains were 14 ± 7.0 lg kg-1 and7.2 ± 4.0 lg kg-1. Soil organic-bound(Hg-o) and strong complex-bound(Hg-s) were the main Hg fractions,accounting for 44% of the total. To estimate the Hg–ligand interaction in the soils, soil-N/Hg(R = 0.451, p \ 0.05),-S/Hg(R = 0.372, p \ 0.1), and-OM/Hg ratio(R = 0.320,p \ 0.5) with MeHgsoil were observed with significant positive correlations, indicating that the formation of Hg–OM, Hg–N–OM or Hg–S–OM complexes could prevent Hg(II) from methylation in soils. The significant positive correlations of the-N/Hg ratio,-S/Hg ratio and-OM/Hg ratio with MeHg in rice tissues suggested that Hg methylation and MeHg demethylation occurred throughout the rice paddy ecosystem. The estimated MeHg daily intake(EDI) was 0.075 ± 0.041 lg kg-1 bw d-1 and was lower than the RfD level of 0.1 lg kg-1 bw d-1 recommended by the US EPA. However, approximately 29% of the hazardous index(HI) of MeHg in grain exceeded 1, posing a potential threat to local populations, particularly pregnant women and children. 相似文献
2.
Improving Universal Soil Loss Equation (USLE)-based models has large interest because simple and reliable analytical tools are necessary in the perspective of a sustainable land management. At first, in this paper, a general definition of the event rainfall- runoff erosivity factor for the USLE-based models, REFe = (QR)b1(EI30)b2, in which QR is the event runoff coefficient, EI30 is the single-storm erosion index, and b1 and b2 are coefficients, was introduced. The rainfall-runoff erosivity factors of the USLE (b1 = 0 and b2 = 1), USLE-M (b1 = b2 = 1), USLE-MB (b1 ≠ 1 and b2 = 1), USLE-MR (b1 = 1 and b2 ≠ 1), USLE-MM (b1 = b2 ≠ 1), and USLE-M2 (b1 ≠ b2 ≠ 1) can be defined using REFe. Then the different expressions of REFe were simultaneously tested against a data set of normalized bare plot soil losses, AeN, collected at the Sparacia (south Italy) site. As expected, the poorest AeN predictions were obtained with the USLE. The observed tendency of this model to overestimate small AeN values and underestimate high AeN values was reduced by introducing in the soil loss prediction model both QR and an exponent for the erosivity term. The fitting to the data was poor with the USLE-MR as compared with the USLE-MB and the USLE-MM. Estimating two distinct exponents (USLE-M2) instead of a single exponent (USLE-MB, USLE-MR, and USLE-MM) did not appreciably improve soil loss prediction. The USLE-MB and the USLE-MM were recognized to be the best performing models among the possible alternatives, and they performed similarly with reference to both the complete data set and different sub-data sets, only including small, intermediate, and severe erosion events. In conclusion, including the runoff coefficient in the soil loss prediction model is important to improve the quality of the predictions, but a great importance has to be paid to the mathematical structure of the model. 相似文献
3.
Bulk density effects on soil hydrologic and thermal characteristics: A numerical investigation 
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下载免费PDF全文 Soil bulk density (ρb) is commonly treated as static in studies of land surface dynamics. Magnitudes of errors associated with this assumption are largely unknown. Our objectives were to (a) quantify ρb effects on soil hydrologic and thermal properties and (b) evaluate effects of ρb on surface energy balance and heat and water transfer. We evaluated 6 soil properties, volumetric heat capacity, thermal conductivity, soil thermal diffusivity, water retention characteristics, hydraulic conductivity, and vapour diffusivity, over a range of ρb, using a combination of 6 models. Thermal conductivity, water retention, hydraulic conductivity, and vapour diffusivity were most sensitive to ρb, each changing by fractions greater than the associated fractional changes in ρb. A 10% change in ρb led to 10–11% change in thermal conductivity, 6–11% change in saturated and residual water content, 49–54% change in saturated hydraulic conductivity, and 80% change in vapour diffusivity. Subsequently, 3 field seasons were simulated with a numerical model (HYDRUS‐1D) for a range of ρb values. When ρb increased 25% (from 1.2 to 1.5 Mg m?3), soil temperature variation decreased by 2.1 °C in shallow layers and increased by 1 °C in subsurface layers. Surface water content differed by 0.02 m3 m?3 for various ρb values during drying events but differences mostly disappeared in the subsurface. Matric potential varied by >100 m of water. Surface energy balance showed clear trends with ρb. Latent heat flux decreased 6%, sensible heat flux increased 9%, and magnitude of ground heat flux varied by 18% (with a 25% ρb increase). Transient ρb impacted surface conditions and fluxes, and clearly, it warrants consideration in field and modelling investigations. 相似文献
4.
Earlier modelling studies have shown the difficulty of accurately simulating snowmelt infiltration into frozen soil using the hydraulic model approach. Comparison of model outputs and field measurements have inferred the occurrence of rapid flow even during periods when the soil is still partly frozen. A one-dimensional, physically based soil water and heat model (SOIL) has been complemented with a new two-domain approach option to simulate preferential flow through frozen layers. The ice is assumed to be first formed at the largest water filled pore upon freezing. Infiltrating water may be conducted rapidly through previously air-filled pores which are not occupied by ice. A minor fraction of water is slowly transferred within the liquid water domain, which is absorbed by the solid particles. A model validation with field measurements at a location in the middle-east of Sweden indicated that the two-domain approach was suitable for improving the prediction of drainage during snowmelting. In particular, the correlation between simulated and observed onset of drainage in spring was improved. The validation also showed that the effect of the high flow domain was highly sensitive to the degree of saturation in the topsoil during freezing, as well as to the hydraulic properties at the lower frost boundary regulating the upward water flow to the frozen soil and ice formation. 相似文献
5.
M. H. G. AMIN R. J. CHORLEY K. S. RICHARDS L. D. HALL T. A. CARPENTER MELENA CISLEROVA THOMAS VOGEL 《水文研究》1997,11(5):471-483
In this paper, the feasibility of using magnetic resonance imaging (MRI) to study water infiltration into a heterogeneous soil is examined, together with its difficulties and limitations. MRI studies of ponded water infiltration into an undisturbed soil core show that the combination of one- and two-dimensional imaging techniques provides a visual and non-destructive means of monitoring the temporal changes of soil water content and the moisture profile, and the movement of the wetting front. Two-dimensional images show air entrapment in repetitive ponded infiltration experiments. During the early stages of infiltration, one-dimensional images of soil moisture profiles clearly indicate preferential flow phenomena. The observed advance of wetting fronts can be described by a linear relationship between the square root of infiltration time (√t) and the distance of the wetting front from the soil surface. Similarly, the cumulative infiltration is also directly proportional to √t. Furthermore, from the MRI infiltration moisture profiles, it is possible to estimate the parameters that feature in infiltration equations. © 1997 by John Wiley & Sons, Ltd. 相似文献
6.
Soil hydraulic functions for runoff simulation were collected in three catchments in a loess region of The Netherlands. To obtain these functions each soil horizon was sampled and water retention and hydraulic conductivity characteristics were determined. A simulation with the computer program SWMS_2D was used to quantify runoff generation during standard rain events. Based on the simulation outcome, soil horizons were merged. This resulted in a database of 25 soil hydraulic functions, each representing a soil horizon or a specific condition of the top layer. Maps showing the soil physical composition of the area were constructed using these soil physical building blocks. The maps can be used as input for soil and water erosion models to be applied on the catchment scale. Comparison of potential runoff figures with measured data showed that the soil physical schematization appeared to be appropriate. The soil physical schem-atization in the areas studied was based on structural rather than on textural differences of the top soil. 相似文献
7.
Introduction
A good deal of attention was paid to the amplification response of soil layers under the earthquake waves,especially by the engineering seismologists. 相似文献
8.
Evidence for the functioning of macropores and the presence of preferential flow in forest soils is equivocal. This is partly because many workers use only one diagnostic technique to indicate whether or not macropore flow occurs. In this paper three lines of evidence are used to suggest that preferential flow does not occur in the percolating waters of a coniferous forest soil under the range of hydrological conditions that prevail in the field. To simulate field conditions, realistic rainfall intensities were used in conservative solute transport experiments on four undisturbed soil columns. A method is described in which breakthrough data can be used to calculate the percentage of antecedent water displaced from a soil column during frontal-type breakthrough experiments. Calculations based on this method using the experimental data show that as little as five percent of the antecedent water was immobile. The simple form of the functional advection–dispersion equation, based on a single value for linear velocity and the dispersion coefficient was fitted to two of the breakthrough curves with reasonable accuracy, further suggesting that preferential flow did not occur in the experiments. Finally, soil moisture characteristic curves were determined for replicate soil samples from the forest soil. The operational water contents of the columns during the breakthrough experiments were compared with the soil moisture characteristics and it was found that pores exerting pressure heads greater than −0·5 kPa did not appear to contribute to flow through the columns, again suggesting an absence of preferential flow. © 1997 by John Wiley & Sons, Ltd. 相似文献
9.
Sanhita Majumdar Pijush Kanti Mandal Sudip Kumar Das Rabindranath Majumdar 《洁净——土壤、空气、水》2013,41(3):291-297
Carbon bearing materials derived from rice husk (RH) have long been recognized as sorbents for diverse chemicals – both organic and inorganic. This work presents an overview of studies demonstrating a single step process of carbonization of chemically pretreated RH to produce metal impregnated silica‐carbon char designated as silicarbon materials that can be utilized in sorbing out water‐borne organic and inorganic hazardous substances (such as phenol, hexavalent chromium, fluoride, and arsenic) and air‐borne volatile organic chemicals (such as acetone, chloroform, benzene, and pyridine). The metal‐impregnated silicarbon solids derived from RH appear to constitute renewable, low‐cost, user‐friendly, and efficient materials for control systems for indoor air contamination and for industrial as well as non‐industrial hazardous aqueous pollution. 相似文献
10.
覆盖土层场地地震断裂反应分析方法 总被引：7，自引：1，他引：7
基于有限元和拟静力的根本原理，提出了一种基于断层位错的覆盖土层场地地震断裂反应弹塑性有限元分析方法，计算中考虑了土层厚度、断层种类和倾角、软弱夹层以及土的非线性等因素，通过编制的程序计算了地表断裂位移，模拟了土层的破裂过程。 相似文献
11.
Freeze-thaw processes in soils,including changes in frost and thaw fronts(FTFs),are important physical processes.The movement of FTFs affects soil hydrothermal characteristics,as well as energy and water exchanges between the land surface and the atmosphere and hydrothermal processes in the land surface.This paper reduces the issue of soil freezing and thawing to a multiple moving-boundary problem and develops a soil water and heat transfer model which considers the effects of FTF on soil hydrothermal processes.A local adaptive variable-grid method is used to discretize the model.Sensitivity tests based on the hierarchical structure of the Community Land Model(CLM)show that multiple FTFs can be continuously tracked,which overcomes the difficulties of isotherms that cannot simultaneously simulate multiple FTFs in the same soil layer.The local adaptive variable-grid method is stable and offers computational efficiency several times greater than the high-resolution case.The simulated FTF depths,soil temperatures,and soil moisture values fit well with the observed data,which further demonstrates the potential application of this simulation to the land-surface process model. 相似文献
12.
This study presents a novel hysteresis model based on van Genuchten's soil‐moisture relationships. The proposed model yields a series of closed‐form relationships in which two shape factors α and η are determined from the main drying and wetting curves. Experimental and literature‐cited data were used to assess model accuracy. The proposed model was also compared with the Scott and KP models. Analytical results indicate that the present model is simple, accurate and effective in constructing the series of wetting and drying scanning curves. Notably, the proposed model outperforms the Scott and KP models in terms of model accuracy. Moreover, the novel model eliminates the pumping effect and has perfect closure at scanning curve reversal points. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
13.
A conceptual model for determining soil erosion by water 总被引：1，自引：0，他引：1
Anthony J. Parsons John Wainwright D. Mark Powell Jrg Kaduk Richard E. Brazier 《地球表面变化过程与地形》2004,29(10):1293-1302
Current estimates of rates of soil erosion by water derived from plots are incompatible with estimates of long‐term lowering of large drainage basins. Traditional arguments to reconcile these two disparate rates are ?awed. The ?ux of sediment leaving a speci?ed area cannot be converted to a yield simply by dividing by the area, because there is no simple relationship between ?ux and area. Here, we develop an approach to the determination of erosion rates that is based upon the entrainment rates and travel distances of individual particles. The limited available empirical data is consistent with the predictions of this approach. Parameterization of the equations to take account of such factors as gradient and sediment supply is required to proceed from the conceptual framework to quantitative measurements of erosion. However, our conceptual model solves the apparent paradox of the sediment delivery ratio, resolves recent discussion about the validity of erosion rates made using USLE erosion plots, and potentially can reconcile erosion rates with known lifespans of continents. Our results imply that previous estimates of soil erosion are fallacious. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
14.
15.
A new semi-empirical formula for evaluating the residual strain of soils under earthquake loading is presented in this paper based on the incremental method and the increment model proposed by the authors. When the incident loading is uniform, the results calculated by the new formula are nearly the same as those by the existing formula. For excitation of the random earthquake loading, the results calculated by the new formula are compared to the results obtained by dynamic triaxial tests. The dynamic triaxial tests had been performed considering different seismic waves, confining stresses,consolidation ratios, and types of cohesive soils. The comparison between the calculated and tested results indicate that the presented formula can efficiently and practically describe the time-dependent process of the soil residual strains under actual seismic loads. 相似文献
16.
利用连续线性系统的随机振动理论,研究非均匀地基土层地震的动力反应问题。假定土层的剪切模量随深度线性变化,得到土层的最大位移反应的均值和方差。引入结构微分算子,采用模态叠加法进行反应分析,与普通的分离变量法相比较,此方法概念明确、步骤简单。 相似文献
17.
A mathematical model was developed for simulating runoff generation and soil erosion on hillslopes. The model is comprised of three modules: one for overland flow, one for soil infiltration, and one for soil erosion including rill erosion and interrill erosion. Rainfall and slope characteristics affecting soil erosion on hillslopes were analysed. The model results show that the slope length and gradient, time distribution rainfall, and distribution of rills have varying influence on soil erosion. Erosion rate increases nonlinearly with increase in the slope length; a long slope length leads to more serious erosion. The effect of the slope gradient on soil erosion can be both positive and negative. Thus, there exists a critical slope gradient for soil erosion, which is about 45° for the rate of erosion at the end of the slope and about 25° for the accumulated erosion. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
18.
A simple water balance model adapted for soil water repellency: application on Portuguese burned and unburned eucalypt stands 总被引：1，自引：0，他引：1 下载免费PDF全文
下载免费PDF全文 João Pedro Nunes Maruxa Malvar Akli Ait Benali María Ermitas Rial Rivas Jan Jacob Keizer 《水文研究》2016,30(3):463-478
Soil water repellency can impact soil hydrology, overland flow generation and associated soil losses. However, current hydrological models do not take it into account, which creates a challenge in repellency‐prone regions. This work focused on the adaptation for soil water repellency of a daily water balance model. Repellency is estimated from soil moisture content using site‐specific empirical relations and used to limit maximum soil moisture. This model was developed and tested using approximately 2 years of data from one long‐unburned and two recently burned eucalypt plantations in northern Portugal, all of which showed strong seasonal soil water repellency cycles. Results indicated important improvements for the burned plantations, with the Nash–Sutcliffe efficiency increasing from ?0.55 and ?0.49 to 0.55 and 0.65. For the unburned site, model performance was already good without the modification and efficiency only improved slightly from 0.71 to 0.74, mostly due to the better simulation of delayed soil wetting after dry periods. Results suggested that even a simple approach to simulate soil water repellency can markedly improve the performance of hydrological models in eucalypt forests, especially after fire. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
19.
基于指数函数的有界性、函数曲线形状和构造土体动力本构模型的一般原则,把函数Y=e^x在（-∞,0]区间上的图像进行翻转、平移、放缩,从而构造出土体的动力本构模型的骨架曲线。在卸载和反向加载时,采用与骨架曲线相同的函数形式,并以前一次卸载开始点作为起点,以土体的极限应力水平作为渐近线,构造出土体动力本构模型的滞回曲线。在此基础上构造出适用于非对称循环荷载的指数形式土体动力本构模型（UE模型）。并用共振柱实验的结果检验了模型的有效性。UE模型具有四个特点：第一,适用于非对称循环荷载;第二,记忆量小;第三,卸载再加载滞回曲线自动满足Masing准则;第四,模型参数少,物理意义明确,可用常规试验确定。 相似文献
20.
软件ABAQUS在饱和土体动力响应分析中的应用 总被引：2，自引：1，他引：1
研究表明:地震作用下土体的动力特性及变形特性与超静孔隙水压力的发展变化密切相关,因此,在土体动力分析过程中考虑孔隙水压的影响是非常必要的。本文通过对基本方程的推导,借助于大型有限元软件ABAQUS,进行了饱和土体在动力作用下孔隙水压变化的数值模拟。计算结果表明,ABAQUS完全适用于此类问题的数值模拟,并且稳定性和收敛性较好。 相似文献