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1.
The history of the discovery of hot gas in galaxies is briefly reviewed, and the main properties of this gas described, emphasizing the need to refine these properties, in particular, the mass of the gas. It is proposed to do this via observations of the Sunyaev-Zel’dovich (SZ) effect due to hot gas in the coronas of elliptical galaxies. The absolute and relative perturbations of the spectrum of the cosmic microwave background (CMB) radiation due to scattering of the CMB photons by electrons with a Maxwellian energy distribution are calculated. The possibility of observing the SZ effect is demonstrated using three elliptical galaxies as examples. The kinematic SZ effect arising due to the peculiar motions and rotations of the galaxies is also accessible to observations. Together with X-ray data, such observations would enable refinement of the properties of gas in galaxies, and also yield additional information about the rotation of galaxies, possible accretion flows in the galactic gas, and hot galactic winds.  相似文献   

2.
Theoretical spectral energy distributions for Sakurai's object at 300–1000 nm are derived. A model-atmosphere grid with T eff=5000–6250 K and logg=0.0–1.0 is computed for the chemical composition of Sakurai's object using opacity sampling including molecular and atomic absorption. Opacity due to absorption in 20 band systems of diatomic molecules is computed using the JOLA technique. The theoretical fluxes are compared with the observed energy distribution in a spectrum of Sakurai's object taken in April 1997. It is shown that (a) the theoretical energy distributions agree well qualitatively with the observed spectrum and depend strongly on the effective temperature; (b) C2 and CN molecular bands are dominant in the visible and near-infrared spectrum, while atomic absorption is important at UV and blue wavelengths; and (c) comparison of the observed and computed spectra yields an effective temperature for Sakurai's object in April 1997 T eff≈5250–5500 K. The dependence of the computed spectra at 300–1000 nm on the input parameters and adopted approximations is also discussed.  相似文献   

3.
Partitioning of oxygen and silicon between molten iron and (Mg,Fe)SiO3 perovskite was investigated by a combination of laser-heated diamond-anvil cell (LHDAC) and analytical transmission electron microscope (TEM) to 146 GPa and 3,500 K. The chemical compositions of co-existing quenched molten iron and perovskite were determined quantitatively with energy-dispersive X-ray spectrometry (EDS) and electron energy loss spectroscopy (EELS). The results demonstrate that the quenched liquid iron in contact with perovskite contained substantial amounts of oxygen and silicon at such high pressure and temperature (P–T). The chemical equilibrium between perovskite, ferropericlase, and molten iron at the P–T conditions of the core–mantle boundary (CMB) was calculated in Mg–Fe–Si–O system from these experimental results and previous data on partitioning of oxygen between molten iron and ferropericlase. We found that molten iron should include oxygen and silicon more than required to account for the core density deficit (<10%) when co-existing with both perovskite and ferropericlase at the CMB. This suggests that the very bottom of the mantle may consist of either one of perovskite or ferropericlase. Alternatively, it is also possible that the bulk outer core liquid is not in direct contact with the mantle. Seismological observations of a small P-wave velocity reduction in the topmost core suggest the presence of chemically-distinct buoyant liquid layer. Such layer physically separates the mantle from the bulk outer core liquid, hindering the chemical reaction between them.  相似文献   

4.
Ma  Shuqi  Gutierrez  Marte 《Acta Geotechnica》2021,16(2):581-594

Shales play important roles in various civil, energy and environmental engineering applications. Shales are categorized as poroelastic materials due to their tight and very stiff structure, and reliable poroelastic properties are required when dealing with shales. This paper presents simple procedures to determine the poroelastic properties of rocks using oedometer and triaxial consolidation tests. The procedures, which avoid the difficulty to perform determination of the unjacketed bulk modulus of the rock minerals, are demonstrated on a North Sea shale. The experimentally obtained Biot coefficient α and the drained bulk modulus K of the shale range from 0.95 to 0.99, and from 0.17 to 2.00 GPa, respectively. The Biot coefficient α and the drained bulk modulus K values determined from the oedometer and triaxial tests are compared and show good agreement and consistency between the two test procedures. The Skempton’s coefficient B-value of the triaxial samples was also experimentally measured prior to the triaxial consolidation tests. The theoretically predicted B-value varies from 0.81 to 0.96 which is, on the average, only about 10% higher than the experimentally obtained B-value which range from 0.80 to 0.85.

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5.
A new method for removing point radio sources and other non-Gaussian noise is proposed as a means of improving the accuracy of estimates of the angular power spectrum of the cosmic microwave background (CMB). The main idea of the method is to reconstruct fluctuations of the CMB in places contaminated by such emission, while traditional methods simply exclude these regions from consideration, leading to the appearance of “holes” in the resulting maps. The fundamental possibility of reconstructing the CMB signal in such holes follows from the analytical properties of a function with a finite spatial spectrum (the Silk damping frequency). A two-dimensional median filter is used to localize the point radio sources. Results of simulations of the method for maps of modest size are presented. The efficiency of applying the method to reconstruct the CMB from data with limited resolution and contaminated by appreciable pixel noise is investigated. The fundamental possibility of applying the method to reconstruct the CMB distribution in the region of the Galaxy is also demonstrated.  相似文献   

6.
Lost primordial continents   总被引：7，自引：2，他引：5  
We investigate the bulk density variations of some representative compositions for the lower mantle based on the pressure–volume–temperature equation of state of the constituent mineral phases. The density variations of pyrolite, harzburgite, mid-ocean ridge basalt (MORB), tonalite–trondhjemite–granodiorite (TTG), and anorthosite are studied at a temperature of 300 K and at lower mantle pressures. The density of MORB is greater than that of pyrolite throughout the lower mantle, while the density of harzburgite is slightly lower than that of pyrolite. The density of anorthosite is comparable to that of pyrolite in the lower mantle in general, and greater in the lowermost mantle, while the density of TTG is lower than pyrolite throughout the lower mantle. The above results have important implications for the fate of primordial continents, TTG and anorthosite crust. While subducted TTG might be stagnant in the mantle transition zone, dense subducted anorthositic crust could be expected to sink to the core–mantle boundary (CMB) and thus might be a major component of the D" layer immediately above the CMB. Thus, we propose that significant bodies of continental material could be present in the mantle in the transition zone and immediately above the CMB, in addition to the continents on the Earth's surface.  相似文献   

7.
A local density approximation (LDA) band structure method, the Linear Muffin-Tin Orbital Atomic Sphere Approximation (LMTO-ASA) method has been used to calculate the electronic structures of the pyrite-type disulphides (MS2, where M = Mn, Fe, Co, Ni, Cu, Zn). The total density of states has been calculated for 10 eV above and below the Fermi Level, along with the separate contributions from metal and sulphur and shows that the metal d band occurs above the sulphur p bands in MnS2, FeS2, CoS2 and NiS2, whereas in CuS2, the d band passes through the sulphur p band and in ZnS2, it lies below the sulphur p band. Substantial hybridization of the metal d states with the sulphur states occurs. FeS2 is calculated to be a semiconductor with a direct band gap of 0.64 eV in good agreement with experiment. The calculated local densities of states have been used in turn to calculate X-ray photoelectron spectra and Bremsstrahlung Isochromat spectra for this series of compounds, and these also show reasonable agreement with experimental data. A particular strength of the LMTO-ASA method is the ability to calculate and predict certain bulk properties of solids of interest in mineral physics. This has enabled the first reasonably accurate calculations of the total energy of the valence electrons of the system for pyrite (FeS2), given as — 345.885 rydbergs per unit cell, and the equilibrium unit cell volume which is within 3.3% of that determined experimentally. A theoretical pressure vs. volume curve for pyrite was also calculated along with values for the bulk modulus. However, our calculations predict a bulk modulus of 6.75 Mbar which is too high by a factor of 4.6 due to the simplifying assumption of a uniform scaling of interatomic distances on compression.  相似文献   

8.
Using energy and entropy constraints applicable to the Earth's core, the heat flow at the core–mantle boundary (CMB) needed to sustain a given total dissipation in the core can be computed. Reasonable estimates for the present Joule dissipation in the core gives a present heat flow of 6 to 10 TW at the CMB. Palaeointensity data acquired from rocks younger than 3.5 Ga provide support that the Joule dissipation in the core before inner core crystallization was between today's value and four times lower than today. Prior to inner core crystallization (around 1 Ga), the magnetic field was maintained by thermal convection driven by core cooling, and our calculations of the two extreme cases predict that the heat flow at the CMB at that time was either 14 to 24 TW in the case of constant dissipation, or essentially the same as today in the lower field intensity case.  相似文献   

9.
Ivanov  V. P.  Ipatov  A. V.  Rakhimov  I. A.  Grenkov  S. A.  Andreeva  T. S. 《Astronomy Reports》2019,63(8):642-651

Measurements of the flux densities of the supernova remnant G21.5-0.9 at 4840 and 8450 MHz were performed in 2013–2018 on the 32-m telescope of the Svetloe Observatory of the Institute of Applied Astronomy, Russian Academy of Sciences. Multiple measurements revealed source variability. The flux densities of G21.5-0.9 for 1967–2010 from previously published data are used to compare the intensity of G21.5-0.9 and standard sources. An artificial-Moon flux scale is used to bring all the data into a single system and determine a refined spectrum. Analysis of the resulting data indicates that, first, the observed break in the source spectrum is not associated with energy losses of relativistic electrons due to synchrotron emission and, second, the source variability is manifest as flux-density changes described by one of two power-law dependencies for the flux versus frequency. The spectral indices of each of these dependencies have one of two constant values. Possible origins of the detected changes in the spectrum of G21.5-0.9 are discussed.

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10.
An 40Ar/39Ar thermochronological investigation of upper greenschist to granulite facies gneiss, amphibolite and marble was conducted in the Central Metasedimentary Belt (CMB), Ontario, to constrain its cooling history. Incremental 40Ar/39Ar release spectra indicate that substantial differential unroofing occurred in the CMB between 1000 and 600 Ma. A consistent pattern of significantly older hornblende and phlogopite 40Ar/3Ar cooling ages on the southeast sides of major northeast striking shear zones is interpreted to reflect late displacement due to extensional deformation. Variations in hornblende 40Ar/39Ar age plateaus exceeding 200 Ma occur over distances less than 50 km with major age discontinuities occurring across the Robertson Lake shear zone and the Sharbot Lake mylonite zone which separate the Sharbot Lake terrane from the Elzevir and Frontenac terranes. Extensional displacements of up to 14 km are inferred between the Frontenac and Elzevir terranes of the CMB. No evidence for significant post argon-closure vertical displacement is indicated in the vicinity of the Perth Road mylonite within the Frontenac terrane. Variations of nearly 100 Ma in phlogopite 40Ar/39Ar plateau ages occur in undeformed marble on either side of the Bancroft Shear Zone. Phlogopites from sheared and mylonitized marble within the shear zone yield 40Ar/39Ar diffusional loss profiles, but have older geologically meaningless ages thought to reflect incorporation of excess argon. By 900 Ma, southeast directed extension was occurring throughout the CMB, possibly initiated along previous zones of compressional shearing. An easterly migration of active zones of extension is inferred, possibly related to an earlier, overall easterly migration of active zones of regional thrusting and easterly migration of an ancient subduction zone. The duration of extensional shearing is not well constrained, but must have ceased before 600 Ma as required by the deposition of overlying undeformed Cambrian and/or Ordovician sedimentary rocks.Contribution No. 481 from the Mineralogical Laboratory, University of Michigan  相似文献   

11.
Metal L2,3, sulfur K and oxygen K near-edge X-ray absorption fine structure (NEXAFS) spectra for chalcopyrite, bornite, chalcocite, covellite, pyrrhotite and pyrite have been determined from single-piece natural mineral specimens in order to assess claims that chalcopyrite should be regarded as CuIIFeIIS2 rather than CuIFeIIIS2, and that copper oxide species are the principal initial oxidation products on chalcopyrite and bornite exposed to air. Spectra were obtained using both fluorescence and electron yields to obtain information representative of the bulk as well as the surface. Where appropriate, NEXAFS spectra have been interpreted by comparison with the densities of unfilled states and simulated spectra derived from ab initio calculations using primarily the FEFF8 code and to a lesser extent WIEN2k. Metal 2p and S 2p photoelectron spectra excited by monochromatised Al Kα X-rays were determined for each of the surfaces characterised by NEXAFS spectroscopy. The X-ray excited Cu LMM Auger spectrum was also determined for each copper-containing sulfide. FEFF8 calculations were able to simulate the experimental NEXAFS spectra quite well in most cases. For covellite and chalcocite, it was found that FEFF8 did not provide a good simulation of the Cu L3-edge spectra, but WIEN2k simulations were in close agreement with the experimental spectra. Largely on the basis of these simulations, it was concluded that there was no convincing evidence for chalcopyrite to be represented as CuIIFeIIS2, and no strong argument for some of the Cu in either bornite or covellite to be regarded as Cu(II). The ab initio calculations for chalcopyrite and bornite indicated that the density of Cu d-states immediately above the Fermi level was sufficient to account for the Cu L3-edge absorption spectrum, however these incompletely filled Cu d-states should not be interpreted as indicating some Cu(II) in the sulfide structure. It was also concluded that the X-ray absorption spectra were quite consistent with the initial oxidation products on chalcopyrite and bornite surfaces being iron oxide species, and inconsistent with the concomitant formation of copper-oxygen species.  相似文献   

12.
在核幔界面之上的下地幔一侧,地震波速分布极不均匀,厚度在50~300 km范围内变化的一层物质称为地幔底层。地幔底层由具有高地震波速和高密度的D″区和超低速带(ULVZ)组成。地幔底层是地核热能向地幔传播的必经之路,也是地幔中温度和温度梯度最高的地区。地幔底层既是俯冲板块的最终归宿,又是热柱和超级热柱的源区。因此,地幔底层既是全地幔对流的起点,又是全地幔对流的终点。在地幔底层可能发生地幔物质(包括俯冲板块物质在内)的部分熔融作用,也可能存在外核液态铁与地幔硅酸盐的化学反应。所以地幔底层在全球物质演化中占有重要的地位。  相似文献   

13.
Detailed experimental and theoretical studies of the k=0 vibrational spectra of anhydrite and gypsum are reported. The dielectric constants and the infrared reflection and Raman spectra of the single crystal have been measured. The frequencies of the phonon spectrum, the contribution of potential terms to potential energy and detailed mode assignments have been determined based on a polarizable-ion model. The relative experimental intensity of the spectra, the observed crystal field effects, the rotatory lattice modes of the H2O molecule and the mixed character of translatory and rotatory modes of the Ca, SO4, and H2O groups are discussed based on the theoretical vibrational modes and the potential energy distribution. The principal moments of inertia of the water molecule and the Lennard-Jones potential constants for nonbonded oxygen-oxygen interactions are presented.  相似文献   

14.
Effects of process parameters such as concentrations of FeCl2, NaOH, and drying temperature on the formation mechanism and chemical characteristics of ferrihydrite-modified diatomite are studied by using X-ray absorption near-edge structure spectroscopy. The spectra were recorded in total electron yield mode and/or fluorescence yield mode to investigate the chemical nature of Fe and Si on the surface and/or in the bulk of ferrihydrite-modified diatomite, respectively. It was found that only the surface SiO2 was partially dissolved in the NaOH solution with stirring and heating, whereas the bulk of diatomite seemed to be preserved. The dissolved Si was incorporated into the structure of ferrihydrite to form the 2-line Si-containing ferrihydrite on the surface of diatomite. The crystalline degree of ferrihydrite increased with the increasing FeCl2 concentration and the Brunauer–Emmett–Teller specific surface area of ferrihydrite-modified diatomite decreased with the increasing FeCl2 concentration. The crystalline degree of ferrihydrite decreased with the increase of NaOH concentration. The high temperature calcination caused an energy shift in the Si L-edge spectra to the high energy side and a transformation of Si-containing ferrihydrite to crystallized hematite might occur when ferrihydrite-modified diatomite is calcined at 900°C. In this study, the optimal synthesis conditions for the ferrihydrite-modified diatomite with the least crystalline Si-containing ferrihydrite and the highest surface area were found to be as the follows: 0.5 M FeCl2 solution, 6 M NaOH solution and drying temperature of 50°C.  相似文献   

15.
Optical absorption spectra obtained on glasses quenched from sodium silicate melts show Mn3+ to be the dominant species for melts heated in air and Mn2+ to be the dominant species for melts heated at Po2 = 10?17 bar. The absorption spectrum of Mn3+ consists of an intense band at 20,000cm?1 with a 15,000cm?1 satellite possibly arising from the Jahn-Teller effect. The independence of the spectrum from melt composition and the high band intensity is offered as evidence for a distinct Mn3+ complex in the melt. The spectrum of Mn2+ is weak and many expected bands are not observed. A two-band luminescence spectrum from Mn2+ has been tentatively interpreted as due to Mn2+ in interstitial sites in the network and Mn2+ coordinated by non-bridging oxygens.  相似文献   

16.
The X-ray emission of the kiloparsec-scale jets of core-dominant quasars is usually interpreted as inverse Compton scattering on the cosmic microwave background (CMB) emission (Sample I). By analogy with the situation on parsec scales, ultrarelativistic motion along a jet oriented at a small angle to the line of sight is usually invoked to explain the X-ray emission while also satisfying the condition of equipartition between the energies associated with the relativistic particles and the magnetic field on kiloparsec scales. This leads to an increase in the energy flux of the CMB radiation in the rest frame of the kiloparsec-scale jets. Consequently, the intensity of the CMB radiation is enhanced to the level required for detectable X-ray emission. This suggests that kiloparsec jets of quasars with similar extents and radio flux densities that are not detected in the X-ray (Sample II) could have subrelativistic speeds and larger angles to the line of sight, due to deceleration and bending of the jet between parsec and kiloparsec scales. This suggests the possible presence of differences in the distributions of the difference between the position angle for the parsec-scale and kiloparsec-scale jets for these two groups of quasars; this is not confirmed by a statistical analysis of the data for Samples I and II. It is deduced that most of the sources considered exhibit bending of their jets by less than about 1.5 times the angle of the parsec-scale jet to the line of sight. This suggests that the X-ray emission is generated by other mechanisms that there is no equipartition.  相似文献   

17.
Fracture surfaces of a natural carrollite specimen have been characterised by synchrotron and conventional X-ray photoelectron spectroscopy and near-edge X-ray absorption spectroscopy. For the synchrotron X-ray measurements, the mineral surfaces were prepared under clean ultra high vacuum and were unoxidised. The characterisation was undertaken primarily to establish unequivocally the oxidation state of the Cu in the mineral, but also to obtain information on the electronic environments of the Co and S, and on the surface species. Experimental and simulated Cu L2,3-edge absorption spectra confirmed an oxidation state of CuI, while Co 2p photoelectron and Co L2,3 absorption spectra were largely consistent with the CoIII established previously by nuclear magnetic resonance spectroscopy. S 2p photoelectron spectra provided no evidence for S to be present in the bulk in more than one state, and were consistent with an oxidation state slightly less negative than S-II. Therefore it was concluded that carrollite can be best represented by CuICoIII2(S4)-VII. The CuI oxidation state is in agreement with that expected for Cu tetrahedrally coordinated by S, but is in disagreement with the CuII deduced previously from some magnetic, magnetic resonance and Cu L-edge X-ray absorption spectroscopic measurements. A significant concentration of S species with core electron binding energies both lower and higher than the bulk value were formed at fracture surfaces, and these entities were assigned to monomeric and oligomeric surface S species. The density of Cu d states calculated for carrollite differed from that previously reported but was consistent with the observed Cu L3 X-ray absorption spectrum. The initial oxidation of carrollite in air under ambient conditions was confirmed to be congruent, unlike the incongruent reaction undergone by a number of non-thiospinel sulfide minerals.  相似文献   

18.
F. Malov 《Astronomy Reports》2001,45(2):138-143
A model with synchrotron radiation near the light cylinder is proposed to explain the observed spectra of short-period pulsars (P≤0.1 s). These spectra can be described if a power-law energy distribution of the emitting electrons with exponent γ=2–8 is assumed. For most pulsars, the peak frequency νm is below 10 MHz. The νm(γ) dependence is derived, and shows that the peak frequencies for pulsars with spectral indices α<1.5 may fall in the observable range. In particular, νm may be νm ～ 100 MHz for PSR J0751 + 1807 and PSR J1640 + 2224. The observed radio spectrum of Geminga (PSR J0633 + 1746) can be described by a synchrotron model with a monoenergetic or Maxwellian distribution of relativistic electrons and a small angle β between the spin axis and magnetic moment (β ～ 10°).  相似文献   

19.
A procedure for calculating two-dimensional power spectra of microlensing magnification fields is presented. In the absence of a shift, the one-dimensional projections of the power spectra P(k) corresponding to the light curve of a point source moving in a linear trajectory can be approximated by the expression (a 2 + k 2)?1/2 (where a = const). The power spectrum of an extended source is treated like the product of the power spectrum of a point source and the power spectrum of the brightness distribution of the extended source. The effect of the extent of the source is that it acts like a filter, suppressing high-frequency components in the spectrum. Based on eight years of monitoring of the quad gravitational lens Q2237+0305 by the OGLE group, power spectra for all four images are constructed and the (temporal) size of the radiating region of the quasar in the V filter is estimated to be 24 ± 6 days; given the constraints on the transverse velocity of the lensing galaxy (<600 km/s), the linear size turns out to be <1015 cm.  相似文献   

20.
X-ray photoelectron and absorption spectra have been obtained for natural specimens of cubanite and compared with the corresponding spectra for chalcopyrite. Synchrotron X-ray photoelectron spectra of surfaces prepared by fracture under ultra-high vacuum revealed some clear differences for the two minerals, most notably those reflecting their different structures. In particular, the concentration of the low binding energy S species formed at cubanite fracture surfaces was approximately double that produced at chalcopyrite surfaces. However, the core electron binding energies for the two S environments in cubanite were not significantly different, and were similar to the corresponding values for the single environment in chalcopyrite. High binding energy features in the S 2p and Cu 2p spectra were not related to surface species produced either by the fracture or by oxidation, and most probably arose from energy loss due to inter-band excitation. Differences relating to the Fe electronic environments were detectable, but were smaller than expected from some of the observed physical properties and Mössbauer spectroscopic parameters for the two minerals. X-ray absorption and photoelectron spectra together with the calculated densities of states for cubanite confirmed an oxidation state of CuI in the mineral. It was concluded that the best formal oxidation state representation for cubanite is CuI(Fe2)VS 3 ?II .  相似文献   

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