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1.
Surface measurements of aerosol physical properties were made at Anantapur(14.62°N,77.65 °E,331 m a.s.l),a semiarid rural site in India,during August 2008-July 2009.Measurements included the segregated sizes of aerosolsas as well as total mass concentration and size distributions of aerosols measured at low relative humidity(RH<75%) using a Quartz Crystal Microbalance(QCM) in the 25-0.05 μm aerodynamic diameter range.The hourly average total surface aerosol mass concentration in a day varied from 15 to 70 μg m-3,with a mean value of 34.02±9.05μgm-3 for the entire study period.A clear diurnal pattern appeared in coarse,accumulation and nucleation-mode particle concentrations,with two local maxima occurring in early morning and late evening hours.The concentration of coarse-mode particles was high during the summer season,with a maximum concentration of 11.81±0.98μgm-3 in the month of April,whereas accumulationmode concentration was observed to be high in the winter period contributed >68% to the total aerosol mass concentration.Accumulation aerosol mass fraction,A f(=Ma/Mt) was highest during winter(mean value of Af～0.80) and lowest(Af～0.64) during the monsoon season.The regression analysis shows that both R eff and R m are dependent on coarse-mode aerosols.The relationship between the simultaneous measurements of daily mean aerosol optical depth at 500 nm(AOD500) and PM 2.5 mass concentration([PM2.5]) shows that surface-level aerosol mass concentration increases with the increase in columnar aerosol optical depth over the observation period.  相似文献   

2.
Ground-based aerosol instrumentation covering particle size diameters from 25 nm to 32 µm was deployed to determine aerosol concentration and cloud condensation nuclei (CCN)-activation properties at water vapor supersaturations in the range of S = 0.20–1.50 % in the remote Brazilian northeast semi-arid region (NEB) in coastal (maritime) and continental (inland) regimes. The instruments measured aerosol number concentration and activation spectra for CCN and revealed that aerosol properties are sensitive with respect to the sources as a function of the local wind circulation system. The observations show that coastal aerosol total number concentrations are above 3,000 cm?3 on average, exhibiting concentration peaks depending on the time of the day in a consistent daily pattern. The variation on aerosol concentration has also influences on the fraction of particles active as CCN. At 1.0 % water vapor supersaturation, the fraction can reach as high as 80 %. Inland aerosol total concentrations were about 1,800–1,900 cm?3 and did not show much diurnal variation. The fraction of particles active as CCN observed inland depend on the history of the air masses, and was much higher when air masses were originated over the sea. It was found that (NH4)2SO4 and NaCl are the major soluble inorganic fraction of the aerosols at the coast. The major fraction of NaCl was present in the coarse mode, while ammonium sulfate dominates the inorganic fraction at the submicron range, with about 10 % of the total aerosol mass at 0.32 µm. Inorganic compounds are almost absent in particles with sizes around 0.1 μm. The study suggests that the air masses with high concentration of CCN originate at the sea. The feasible explanation lies in the fact that the NEB’s beaches have a particular morphology that produces a wide surf zone and creates a large load of aerosols when combined with strong and permanent winds of the region.  相似文献   

3.
Temporal variations in atmospheric hydrogen sulphide concentrations and its biosphere-atmosphere exchanges were studied in the World’s largest mangrove ecosystem, Sundarbans, India. The results were used to understand the possible contribution of H2S fluxes in the formation of atmospheric aerosol of different size classes (e.g. accumulation, nucleation and coarse mode). The mixing ratio of hydrogen sulphide (H2S) over the Sundarban mangrove atmosphere was found maximum during the post-monsoon season (October to January) with a mean value of 0.59?±?0.02 ppb and the minimum during pre-monsoon (February to May) with a mean value of 0.26?±?0.01 ppb. This forest acted as a perennial source of H2S and the sediment-air emission flux ranged between 1213?±?276 μg S m?2 d?1(December) and 457?±?114 μg S m?2 d?1 (August) with an annual mean of 768?±?240 μg S m?2d?1. The total annual emissions of H2S from the Indian Sundarban were estimated to be 1.2?±?0.6 Tg S. The accumulation mode of aerosols was found to be more enriched with non-sea salt sulfate with an average loading of 5.74 μg m?3 followed by the coarse mode (5.18 μg m?3) and nucleation mode (1.18 μg m?3). However, the relative contribution of Non-sea salt sulfate aerosol to total sulfate aerosol was highest in the nucleation mode (83%) followed by the accumulation (73%) and coarse mode (58%). Significant positive relations between H2S flux and different modes of NSS indicated the likely link between H2S, a dominant precursor for the non-sea salt sulfate, and non-sea sulfate aerosol particles. An increase in H2S emissions from the mangrove could result in an increase in enhanced NSS in aerosol and associated cloud albedo, and a decrease in the amount of incoming solar radiation reaching the Sundarban mangrove forest.  相似文献   

4.

Size-segregated aerosol particles were collected using a high volume MOUDI sampler at a coastal urban site in Xiamen Bay, China, from March 2018 to June 2020 to examine the seasonal characteristics of aerosol and water-soluble inorganic ions (WSIIs) and the dry deposition of nitrogen species. During the study period, the annual average concentrations of PM1, PM2.5, PM10, and TSP were 14.8?±?5.6, 21.1?±?9.0, 35.4?±?14.2 μg m?3, and 45.2?±?21.3 μg m?3, respectively. The seasonal variations of aerosol concentrations were impacted by the monsoon with the lowest value in summer and the higher values in other seasons. For WSIIs, the annual average concentrations were 6.3?±?3.3, 2.1?±?1.2, 3.3?±?1.5, and 1.6?±?0.8 μg m?3 in PM1, PM1-2.5, PM2.5–10, and PM>10, respectively. In addition, pronounced seasonal variations of WSIIs in PM1 and PM1-2.5 were observed, with the highest concentration in spring-winter and the lowest in summer. The size distribution showed that SO42?, NH4+ and K+ were consistently present in the submicron particles while Ca2+, Mg2+, Na+ and Cl? mainly accumulated in the size range of 2.5–10 μm, reflecting their different dominant sources. In spring, fall and winter, a bimodal distribution of NO3? was observed with one peak at 2.5–10 μm and another peak at 0.44–1 μm. In summer, however, the fine mode peak disappeared, likely due to the unfavorable conditions for the formation of NH4NO3. For NH4+ and SO42?, their dominant peak at 0.25–0.44 μm in summer and fall shifted to 0.44–1 μm in spring and winter. Although the concentration of NO3–N was lower than NH4–N, the dry deposition flux of NO3–N (35.77?±?24.49 μmol N m?2 d?1) was much higher than that of NH4–N (10.95?±?11.89 μmol N m?2 d?1), mainly due to the larger deposition velocities of NO3–N. The contribution of sea-salt particles to the total particulate inorganic N deposition was estimated to be 23.9—52.8%. Dry deposition of particulate inorganic N accounted for 0.95% of other terrestrial N influxes. The annual total N deposition can create a new productivity of 3.55 mgC m?2 d?1, accounting for 1.3–4.7% of the primary productivity in Xiamen Bay. In light of these results, atmospheric N deposition could have a significant influence on biogeochemistry cycle of nutrients with respect to projected increase of anthropogenic emissions from mobile sources in coastal region.

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5.
南京北郊2011年春季气溶胶粒子的散射特征   总被引：3，自引：2，他引：1       下载免费PDF全文
利用南京北郊2011年春季积分浊度仪的观测资料,结合PM2.5质量浓度、能见度和常规气象资料,分析了南京北郊春季气溶胶散射系数的变化特征、散射系数与PM2.5质量浓度和能见度的关系。结果表明,观测期间气溶胶散射系数平均值为311.5±173.3 Mm-1,小时平均值出现频率最高的区间为100~200 Mm-1;散射系数的日变化特征明显,总体为早晚大,中午及午后小。散射系数与PM2.5质量浓度的变化趋势基本一致,但与能见度呈负相关关系。霾天气期间散射系数日平均值为700.5±341.4 Mm-1,最高值达到近1 900 Mm-1;结合地面观测资料、NCEP/NCAR再分析资料和后向轨迹模式分析显示,霾期间气块主要来自南京南部和东南方向。  相似文献   

6.
Continuous measurements of surface ozone (O3), NOx (NO + NO2) and meteorological parameters have been made in Kannur (11.9?°N, 75.4?°E, 5?m asl), India from November 2009 to October 2010. It was observed that O3 and NOx showed distinct diurnal and seasonal variabilities at this site. The annual average diurnal profile of O3 showed a peak of (30.3?±?10.4) ppbv in the late afternoon and a minimum of (3.2?±?0.7) ppbv in the early morning. The maximum value of O3 mixing ratio was observed in winter (44?±?3.1) ppbv and minimum during monsoon (18.46?±?3.5) ppbv. The rate of production of O3 was found to be higher in December (10.1?ppbv/h) and lower in July (1.8?ppbv/h) during the time interval 0800?C1000?h. A correlation coefficient of 0.52 for the relationship between O3 and [NO2]/[NO] reveals the role of NO2 photolysis that generates O3 at this site. The correlation between O3 and meteorological parameters indicate the influence of seasonal changes on O3 production. Investigations were further extended to explore the week day weekend variations in O3 mixing ratio at an urban site reveals the enhancement of O3. The variations of O3 mixing ratio with seasonal air mass flows were elucidated with the aid of backward air trajectories. This study also indicates how vapor phase organic species present in the ambient air at this location may influence the complex chemistry involving (VOCs) that enhances the production of O3 at this location.  相似文献   

7.
Simultaneous observations of surface ozone (O3) with its precursors namely, carbon monoxide (CO) and oxides of nitrogen (NOx) have been taken on diurnal scale from a tropical semi-urban site, Pune (18.54°N, 73.81°E) in India. We present the data for one year (2003–2004) period to study the salient features of these trace gases. The peak in amplitude of ozone is found during the noontime whereas in CO and NOX it is observed in the morning hours between 0800 and 0900 H. The concentration of these pollutants drop down considerably during southwest monsoon months and the diurnal pattern also become very weak. The diurnal trends of these gases are found to be different for different seasons, which are specific to the receptor site. Model simulations using 3-D chemical-transport model with regional emission inventories and observed winds have also been carried out. The comparison of model results with observations, on seasonal basis yielded a reasonable qualitative agreement. The relative role of local emissions and long range transport in the diurnal pattern for different seasons has been outlined, which reveals that the ozone is highly influenced by regional/long range transport in this region. The effect of precursor amounts in the morning on afternoon ozone peak levels has been investigated using the lag correlation study, which reveals that a time lag of 5–7 h is required for most of these precursor gases to photo-chemically produce ozone to its maximum potential. Results are discussed in the light of available topographic and meteorological conditions.  相似文献   

8.
This study investigated meteorological, physical, and chemical characteristics of 2 severe Hwangsa (Asian dust, maximum average of PM10 above 1000 μg m?3) observed in Seoul, the capital city of Korea, during 30～31st May, 2008 (DSS2008) and 25～26th December, 2009 (DSS2009). DSS2008 and DSS2009 had a same source region and route. However, they have different meteorological conditions. DSS2009 had a shorter travel time from the source region to Korea and shorter duration time in Korea than DSS2008 due to a strong winter Siberian anticyclone. One of DSS2008 sample was affected by not only Asian dust but also a long-range transported haze due to consecutive influx after low pressure passed while DSS2009 sample collected only dust aerosol. For both cases, the mass concentration of coarse particles (PM10-1) increased by 3～14 times compared to that during non Asian dust period, however, that of fine particles (PM1) increased only in DSS2008. For DSS2008 water-soluble ion balance between anions and cations in fine mode was close to 1:1 while cations were higher than anions in coarse mode. NH4 + and Ca2+ were found to be the main contributing factors for the neutralization. Cl? loss was observed about 60% indicating an active interaction of Na+ with pollutants. Reconstruction of chemical compositions showed relatively high concentrations of secondary pollutants (NH4NO3 and (NH4)2SO4), CaCO3, and Ca(NO3)2 compared to that during non Asian dust period. DSS2009 exhibited the typical characteristics of Asian dust having a high concentration of Ca2+ with higher equivalent concentration of cations than anions in all size bins. Cl? loss was hardly observed. The secondary pollutants were lower than that of non Asian dust cases. The result of reconstruction of ionic components indicated the CaCO3 derived from soil particle, CaSO4, and Ca (NO3)2 were dominant in DSS2009.  相似文献   

9.
张丽  张立杰  力梅 《广东气象》2014,36(6):50-52
利用深圳国家基本气象站观测数据和竹子林大气成分站颗粒物、污染气体的浓度资料,对典型灰霾过程粒子浓度的日变化的特征进行了对比分析,结果表明:在变性高压脊控制下,污染物浓度在晚上交通高峰期达到最大值,人为排放和稳定的层结提供了有利的条件;在热带气旋外围下沉气流控制时,污染物浓度日变化有3个峰值,并且中午的峰值高于早、晚交通高峰期的峰值,光化学污染明显;在低槽或切变线影响下,早、晚交通高峰期的峰值高于中午的峰值,人为源排放成为主要的污染物来源。  相似文献   

10.
Continuous in-situ measurements of surface ozone (O3), carbon monoxide (CO) and oxides of nitrogen (NOx) were conducted at Udaipur city in India during April 2010 to March 2011. We have analyzed the data to investigate both diurnal and seasonal variations in the mixing ratios of trace gases. The diurnal distribution of O3 showed highest values in the afternoon hours and lower values from evening till early morning. The mixing ratios of CO and NOx showed a sharp peak in the morning hours but lowest in the afternoon hours. The daily mean data of O3, CO and NOx varied in the ranges of 5–51 ppbv, 145–795 ppbv and 3–25 ppbv, respectively. The mixing ratios of O3 were highest of 28 ppbv and lowest 19 ppbv during the pre-monsoon and monsoon seasons, respectively. While the mixing ratios of both CO and NOx showed highest and lowest values during the winter and monsoon seasons, respectively. The diurnal pattern of O3 is mainly controlled by the variations in photochemistry and planetary boundary layer (PBL) depth. On the other hand, the seasonality of O3, CO and NOx were governed by the long-range transport associated mainly with the summer and winter monsoon circulations over the Indian subcontinent. The back trajectory data indicate that the seasonal variations in trace gases were caused mainly by the shift in long-range transport pattern. In monsoon season, flow of marine air and negligible presence of biomass burning in India resulted in lowest O3, CO and NOx values. The mixing ratios of CO and NOx show tight correlations during winter and pre-monsoon seasons, while poor correlation in the monsoon season. The emission ratio of ?CO/?NOx showed large seasonal variability but values were lower than those measured over the Indo Gangetic Plains (IGP). The mixing ratios of CO and NOx decreased with the increase in wind speed, while O3 tended to increase with the wind speed. Effects of other meteorological parameters in the distributions of trace gases were also noticed.  相似文献   

11.
The main goal of this work is to describe the anthropogenic energy flux (Q F) in the city of S?o Paulo, Brazil. The hourly, monthly, and annual values of the anthropogenic energy flux are estimated using the inventory method, and the contributions of vehicular, stationary, and human metabolism sources from 2004 to 2007 are considered. The vehicular and stationary sources are evaluated using the primary consumption of energy based on fossil fuel, bio fuel, and electricity usage by the population. The diurnal evolution of the anthropogenic energy flux shows three relative maxima, with the largest maxima occurring early in the morning (??19.9 Wm?2) and in the late afternoon (??20.3 Wm?2). The relative maximum that occurs around noontime (??19.6 Wm?2) reflects the diurnal pattern of vehicle traffic that seems to be specific to S?o Paulo. With respect to diurnal evolution, the energy flux released by vehicular sources (Q FV) contributes approximately 50% of the total anthropogenic energy flux. Stationary sources (Q FS) and human metabolism (Q FM) represent about 41% and 9% of the anthropogenic energy flux, respectively. For 2007, the monthly values of Q FV, Q FS, Q FM, and Q F are, respectively, 16.8?±?0.25, 14.3?±?0.16, 3.5?±?0.03, and 34.6?±?0.41?MJ?m?2?month?1. The seasonal evolution monthly values of Q FV, Q FS, Q FM, and Q F show a relative minimum during the summer and winter vacations and a systematic and progressive increase associated with the seasonal evolution of the economic activity in S?o Paulo. The annual evolution of Q F indicates that the city of S?o Paulo released 355.2?MJ?m?2?year?1 in 2004 and 415.5?MJ?m?2?year?1 in 2007 in association with an annual rate of increase of 19.6?MJ?m?2?year?1 (from 2004 to 2006) and 30.5?MJ?m?2?year?1 (from 2006 to 2007). The anthropogenic energy flux corresponds to about 9% of the net radiation at the surface in the summer and 15% in the winter. The amplitude of seasonal variation of the maximum hourly value of the diurnal variation increases exponentially with latitude.  相似文献   

12.
PM10 samples were collected to characterize the seasonal and annual trends of carbonaceous content in PM10 at an urban site of megacity Delhi, India from January 2010 to December 2017. Organic carbon (OC) and elemental carbon (EC) concentrations were quantified by thermal-optical transmission (TOT) method of PM10 samples collected at Delhi. The average concentrations of PM10, OC, EC and TCA (total carbonaceous aerosol) were 222?±?87 (range: 48.2–583.8 μg m?3), 25.6?±?14.0 (range: 4.2–82.5 μg m?3), 8.7?±?5.8 (range: 0.8–35.6 μg m?3) and 54.7?±?30.6 μg m?3 (range: 8.4–175.2 μg m?3), respectively during entire sampling period. The average secondary organic carbon (SOC) concentration ranged from 2.5–9.1 μg m?3 in PM10, accounting from 14 to 28% of total OC mass concentration of PM10. Significant seasonal variations were recorded in concentrations of PM10, OC, EC and TCA with maxima during winter and minima during monsoon seasons. In the present study, the positive linear trend between OC and EC were recorded during winter (R2?=?0.53), summer (R2?=?0.59) and monsoon (R2?=?0.78) seasons. This behaviour suggests the contribution of similar sources and common atmospheric processes in both the fractions. OC/EC weight ratio suggested that vehicular emissions, fossil fuel combustion and biomass burning could be the major sources of carbonaceous aerosols of PM10 at the megacity Delhi, India. Trajectory analysis indicates that the air mass approches to the sampling site is mainly from Indo Gangetic plain (IGP) region (Uttar Pradesh, Haryana and Punjab etc.), Thar desert, Afghanistan, Pakistan and surrounding areas.  相似文献   

13.
中国大陆降水日变化研究进展   总被引：32，自引：4，他引：28  
文章概述了中国大陆降水日变化的最新研究成果,给出了中国大陆降水日变化的整体图像,指出目前数值模式模拟降水日变化的局限性,为及时了解和掌握降水日变化研究进展、开展相关科学研究和进行降水预报服务提供了有价值的科学依据和参考。现有研究表明：（1）中国大陆夏季降水日变化的区域特征明显。在夏季,东南和东北地区的降水日峰值主要集中在下午;西南地区多在午夜达到降水峰值;长江中上游地区的降水多出现在清晨;中东部地区清晨、午后双峰并存;青藏高原大部分地区是下午和午夜峰值并存。（2）降水日变化存在季节差异和季节内演变。冷季降水日峰值时刻的区域差异较暖季明显减小,在冷季南方大部分地区都表现为清晨峰值;中东部地区暖季降水日变化随季风雨带的南北进退表现出清晰的季节内演变,季风活跃（间断）期的日降水峰值多发生在清晨（下午）。（3）持续性降水和局地短时降水的云结构特性以及降水日峰值出现时间存在显著差异。持续性降水以层状云特性为主,地表降水和降水廓线的峰值大多位于午夜后至清晨;短时降水以对流降水为主,峰值时间则多出现在下午至午夜前。（4）降水日变化涉及不同尺度的山-谷风、海-陆风和大气环流的综合影响,涉及复杂的云雨形成和演变过程,对流层低层环流日变化对降水日变化的区域差异亦有重要影响。（5）目前数值模式对中国降水日变化的模拟能力有限,且模拟结果具有很强的模式依赖性,仅仅提高模式水平分辨率并不能总是达到改善模拟结果的目的,关键是要减少存在于降水相关的物理过程参数化方案中的不确定性问题。  相似文献   

14.
To better understand vertical air mass exchange driven by local circulation in the Himalayas, the volume flux of air mass is estimated in the Rongbuk Valley on the northern slope of Mount Everest, based on a volume closure method and wind-profiler measurements during the HEST2006 campaign in June 2006. Vertical air mass exchange was found to be dominated by a strong downward mass transfer from the late morning to late night. The average vertical air volume flux was 0.09 m s-1, which could be equivalent to a daily ventilation of 30 times the enclosed valley volume. This vertical air mass exchange process was greatly affected by the evolution of the South Asian summer monsoon (SASM), with a strong downward transfer during the SASM break stage, and a weak transfer during the SASM active stage.  相似文献   

15.
利用2006年3～5月天空辐射计观测数据反演得到北京地区春季大气气溶胶光学性质参数,包括大气气溶胶光学厚度(0.5μm)、Angstrm指数、单次散射反射比和粒子谱分布特征。结果表明:北京地区春季气溶胶平均光学厚度0.67,Angstrm指数0.54,单次散射比0.88,粒子吸收性质较弱,粒子谱呈双峰形,以粗粒子为主,粗、细模态粒子粒径分别集中在0.17μm和7.7μm左右。相比2004年此次观测期间气溶胶粒径较大,粒子体积浓度较高,散射作用在其消光特性中的比重略有下降。光学厚度日变化呈单峰型,日间单次散射比随时间逐渐递减,Angstrm指数在上午递减趋势明显,午后变得稳定。对同时观测的天空辐射计与CE-318不同波长光学厚度结果进行比较,结果显示两者得到的光学厚度相关性很好,各波长小时平均结果的相对误差小于7%。  相似文献   

16.
The mountain-plains solenoid(MPS) and boundary-layer inertial oscillation(BLO) are two typical regional forcings at the diurnal time scale. Their relative role in regulating the diurnal variations of summer rainfall over North China and their change under different monsoon conditions are studied using a 19-yr archive of satellite rainfall and reanalysis data. It is shown that both a strong MPS and BLO can increase nocturnal rainfall in the North China plains but exhibit evident regional differences. The MPS-induced nocturnal rainfall is relatively confined to the plains adjacent to mountains from late night to morning, due to the upward branch of the nighttime MPS. In contrast, the BLO-induced nocturnal rainfall strengthens from early evening and is more extensive in early morning over the open plains further east. The contrasting effect in the evening is related to the convergent(divergent) easterly anomaly in the plains under the BLO(MPS). The BLO also induces the relatively strong enhancement of moisture convergence and high humidity by the southerly anomaly at late night. On strong monsoon days, the nocturnal rainfall amount associated with the MPS and BLO increases considerably in the plains.Both regional forcings become effective in regulating the rainfall diurnal cycle with enhanced moisture convergence under monsoon conditions. Their induced diurnal amplitudes of moisture convergence can be comparable to the daily mean by monsoon flow. The regional forcings thus couple with monsoon flow to strengthen rainfall in the plains, particularly from late night to morning. The results highlight that a combination of regional and large-scale forcings can strongly regulate the warm-season climate.  相似文献   

17.
This paper reports aerosol chemical properties for the first time over a Korean Global Atmosphere Watch (GAW) supersite, Anmyeon (36°32′N; 126° 19′E), during 2003–2004 period. Total suspended Particulates (TSP) showed significant seasonal variation with consistent higher mass concentrations during spring season (average of up to 230?±?190 μg/m3). PM10 also followed similar trend with higher concentrations during spring (average of up to 170?±?130 μg/m3) and showed reduced concentrations during summer. PM2.5 showed a significant increase during summer (average of up to 60?±?25 μg/m3), which could be due to the influx of fine mode sea salt aerosols associated with the Changma front (summer monsoon). Chemical composition analysis showed enhanced presence of acidic fractions, majorly contributed by sulphates (SO 4 2- ) and nitrates (NO 3 - ) in TSP, PM10 and PM2.5 during different seasons. Enhanced presence of Calcium (Ca2+) was observed during sand storm days during spring. The high correlation obtained on matrix analysis between crustal ions and acidic ions suggests that the ionic compositions over the site are mainly contributed by terrestrial sources of similar origin. The neutralization factors has been estimated to find the extend of neutralization of acidicity by main basic components, and found to have higher value for Ammonium (up to 1.1) in different seasons, indicating significant neutralization of acidic components over the region by NH 4 + . Back trajectory analysis has been performed during different seasons to constrain the possible sources of aerosol origin and the results are discussed in detail.  相似文献   

18.
An extensive aerosol sampling program was conducted during January-December 2006 over Kolkata (22o33?? N and 88o20?? E), a mega-city in eastern India in order to understand the sources, distributions and properties of atmospheric fine mode aerosol (PM2.5). The primary focus of this study is to determine the relative contribution of natural and anthropogenic as well as local and transported components to the total fine mode aerosol loading and their seasonal distributions over the metropolis. The average concentrations of fine mode aerosol was found to be 71.2?±?25.2???gm-3 varying between 34.5???gm-3 in monsoon and 112.6???gm-3 in winter. The formation pathways of major secondary aerosol components like nitrate and sulphate in different seasons are discussed. A long range transport of dust aerosol from arid and semi-arid regions of western India and beyond was observed during pre-monsoon which significantly enriched the total aerosol concentration. Vehicular emissions, biomass burning and transported dust particles were the major sources of PM2.5 from local and continental regions whereas sea-salt aerosol was the major source of PM2.5 from marine source regions.  相似文献   

19.
The photochemical activation of chlorine by dissolved iron in artificial sea-salt aerosol droplets and by highly dispersed iron oxide (Fe2O3) aerosol particles (mainly hematite, specific surface ~150 m2 g?1) exposed to gaseous HCl, was investigated in humidified air in a Teflon simulation chamber. Employing the radical-clock technique, we quantified the production of gaseous atomic chlorine (Cl) from the irradiated aerosol. When the salt aerosol contained Fe2O3 at pH 6, no significant Cl production was observed, even if the dissolution of iron was forced by “weathering” (repeatedly freezing and thawing for five times). Adjusting the pH in the stock suspension to 2.6, 2.2, and 1.9 and equilibrating for one week resulted in a quantifiable amount of dissolved iron (0.03, 0.2, and 0.6 mmol L?1, respectively) and in gaseous Cl production rates of ~1.6, 6, and 8?×?1021 atoms cm?2 h?1, respectively. In a further series of experiments, the pure Fe2O3 aerosol was exposed to various levels of gaseous hydrogen chloride (HCl). The resulting Cl production rates ranged from 8?×?1020 Cl atoms cm?2 h?1 (at ~4 ppb HCl) to 5?×?1022 Cl atoms cm?2 h?1 (at ~350 ppb HCl) and confirmed the uptake and conversion of HCl to atomic Cl (at HCl to Cl conversion yields of 2–5 %, depending on the relative humidity). The Fe2O3 experiments indicate that iron-induced Cl formation may be important for highly soluble combustion-aerosol particles in marine environments in the presence of gaseous HCl.  相似文献   

20.
Industrial pollution has a significant effect on aerosol properties in Changsha City, a typical city of central China. Therefore, year-round measurements of aerosol optical, radiative and chemical properties from 2012 to 2014 at an urban site in Changsha were analyzed. During the observation period, the energy structure was continuously optimized, which was characterized by the reduction of coal combustion. The aerosol properties have obvious seasonal variations. The seasonal average aerosol optical depth (AOD) at 500 nm ranged from 0.49 to 1.00, single scattering albedo (SSA) ranged from 0.93 to 0.97, and aerosol radiative forcing at the top of the atmosphere (TOA) ranged from ?24.0 to 3.8 W m?2. The chemical components also showed seasonal variations. Meanwhile, the scattering aerosol, such as organic carbon, SO42?, NO3?, and NH4+ showed a decrease, and elemental carbon increased. Compared with observation in winter 2012, AOD and TOA decreased by 0.14 and ?1.49 W m?2 in winter 2014. The scattering components, SO42?, NO3? and NH4+, decreased by 12.8 μg m?3 (56.8%), 9.2 μg m?3 (48.8%) and 6.4 μg m?3 (45.2%), respectively. The atmospheric visibility and pollution diffusion conditions improved. The extinction and radiative forcing of aerosol were significantly controlled by the scattering aerosol. The results indicate that Changsha is an industrial city with strong scattering aerosol. The energy structure optimization had a marked effect on controlling pollution, especially in winter (strong scattering aerosol).  相似文献   

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