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1.
Aquifers from the same typology can have strongly different groundwater chemistry. Deducing the groundwater quality of less well-characterized aquifers from well-documented aquifers belonging to the same typology should be done with great reserve, and can only be considered as a preliminary approach. In the EU’s 6th FP BRIDGE project “Background cRiteria for the IDentification of Groundwater thrEsholds”, a methodology for the derivation of threshold values (TV) for groundwater bodies is proposed. This methodology is tested on four aquifers in Flanders of the sand and gravel typology. The methodology works well for all but the Ledo-Paniselian aquifer, where the subdivision into a fresh and saline part is disproved, as a gradual natural transition from fresh to saline conditions in the aquifer is observed. The 90 percentile is proposed as natural background level (NBL) for the unconfined Pleistocene deposits, ascribing the outliers to possible influence of pollution. For the Tertiary aquifers, high values for different parameters have a natural origin and the 97.7 percentile is preferred as NBL. The methodology leads to high TVs for parameters presenting low NBL, when compared to the standard used as a reference. This would allow for substantial anthropogenic inputs of these parameters.  相似文献   

2.
The European Water Framework Directive (WFD) has driven the protection of groundwater and characterization of water bodies. Development of appropriate and efficient approaches which consider the special features of the hydrologic regime is essential. The results of different projects that have been carried out to integrate characterization and protection of water bodies are summarized herein. In the Les eaux de la Mediterranée (AQUAMED) Project, applicability to the Mediterranean Region of guidelines provided by the European Commission to facilitate the WFD implementation has been verified. The Background criteria for the identification of groundwater thresholds (BRIDGE) Project developed a methodology to establish threshold values of pollutants contributing to the chemical status of groundwater bodies. This method has been applied to pollutants used to classify groundwater bodies as at risk of not achieving objectives of the WFD. Selected features of protection areas for drinking water and safeguard zones are analyzed, as well as the possibility of using wellhead protection areas.  相似文献   

3.
The aim of the study was the determination of the natural background levels (NBLs) for the ions Na+, Cl?, SO4 2?, As3+, F?, Fe2+, and Mn2+, in some groundwater bodies of the Campania region (southern Italy). The ??Protocol to evaluate the natural background concentrations?? proposed in 2009 by ISPRA (Italian Institute for Environmental Protection and Research) has been applied to the chemical data set of groundwater of the examined groundwater bodies. These analyses have also been examined following the guidelines of the BRIDGE project (Background cRiteria for the IDentification of Groundwater thrEshold). These approaches to evaluate the Threshold Values (TVs) and the NBLs, based on probability distribution functions, have been applied in many countries by various authors during the last 5?years. Changes applied to ISPRA Protocol in this study concern mainly the preselection criteria, in particular threshold values of specific ions, deriving from the aquifers geochemical features. The preselection criteria of the ISPRA Protocol have been merged with those of the BRIDGE Project in order to define a procedure suitable for the definition of the NBLs in the examined aquifers. The NBL of fluoride for the ??Phlegrean Fields?? and the ??eastern Plain of Naples?? groundwater bodies shows values deeply exceeding the reference value (REF) of 1,500???g/L, ranging between 3,600 and 15,000???g/L. The cause of this very high fluoride content is in the natural features of the aquifers constituted by volcanic and pyroclastic rocks. The volcanic origin of the aquifers is also the reason for the high arsenic content in ??Phlegrean Fields?? groundwater. Here the NBL calculated was about 47???g/L against the drinking water standard value of 10???g/L. The widespread high content of manganese and iron for the groundwater body of the ??eastern Plain of Naples?? is due to the reducing conditions related to the extensive marshlands present in the past. The very high NBL of all the examined ions for the groundwater body of ??Ischia Island?? depends on the existence of a geothermal system.  相似文献   

4.
The present work investigates the long-term effects of human intervention on groundwaters based on the determination of natural background levels (NBLs) and threshold values (TVs) for groundwater electrical conductivity, chloride, ammonium, sulphates and nitrates. The methodology adopted is the one proposed in the 6th Framework European Project ??BRIDGE??, which was applied with some adjustments in Rhodope area (Northern Greece). The study area was especially selected because it incorporates two distinct subareas: the northern one which can be safely considered as a pristine area, where NBLs for groundwaters were assessed from; the southern part which forms a typical Mediterranean region, intensively cultivated for the last 40?years. Groundwater TVs were determined considering two types of groundwater receptors: (a) groundwater ??itself?? and (b) groundwater dependent lagoons in the coastal part of the study area. Results showed that groundwater quality is altered seriously from its natural background composition indicating how human activities have affected groundwater quality and showed that chemical status of groundwater has been seriously aggravated. The number and the spatial distribution of monitoring locations exceeding TVs revealed that chloride and nitrates are the most serious threats for groundwater in the study area.  相似文献   

5.
Natural background levels (NBL) and threshold values (TV) derivation is an important task for EU Member States to correctly assess the chemical status of groundwater bodies within the context of the recently adopted Groundwater Directive. Attempts are being made both by water authorities and scientific community to test application viability of proposed methods to different real situations and to develop tailored adjustments and refinements. The aim of this paper is to describe a methodological case study of NBL and TV determination in a large area (5,500 km2) located in Central Italy where both natural and anthropogenic contamination occurs, resulting in several substances be detected in ground waters with concentration frequently exceeding drinking water standards. This paper shows the key role played in the determination process by knowledge on the hydrogeological setting and hydrogeochemical features. The adoption of appropriate pre-selection criteria of samples, the establishment of TV at the groundwater body scale for natural origin substances, and the evaluation of TVs exceedances in a multiparameter context are experimentally discussed. Beyond the critical evaluation of NBL and TV determination method, this research aims at increasing consciousness in the water management agencies that groundwater status assessment should be conceived as a scientific evaluation procedure and not as a mere technical/administrative exercise to be performed using any set of available data. As such, it should be supported by adequate knowledge of hydrogeological setting, hydrochemical processes occurring in groundwater bodies, and human activities acting overland to be progressively verified.  相似文献   

6.
A barium anomaly with a maximum Ba2+ concentration of 6.37 mg/l was distinguished in a Cambrian-Vendian (Cm-V) aquifer system that is widely used as a drinking water source in the towns Kunda, Rakvere and Kohtla-Järve of North-Estonia. The modelling results show that at low sulphate concentrations (below 3 mg/l) Ba2+ contents can exceed the limit values for drinking water (such as 2 mg/l set by US EPA). Bicarbonate ions in their common concentration range in groundwater cannot limit Ba2+ at its content below 10 mg/l. The probable natural sources of the anomaly are the crystalline basement and its weathering zone. Groundwater in the clayey weathering core is hydraulically connected with the overlying Cm-V aquifer system, thus the upconing of deeper-seated groundwater, caused by intensive exploitation of wells, is possible.  相似文献   

7.
Eighty-seven groundwater samples have been collected from a mountainous region (Alvand, Iran) for hydrochemical investigations to understand the sources of dissolved ions and assess the chemical quality of the groundwater. Most water quality parameters are within World Health Organization acceptable limits set for drinking water. The least mineralized water is found closest to the main recharge zones and the salinity of water increased towards the north of the basin. The most prevalent water type is Ca–HCO3 followed by water types Ca–NO3, Ca–Cl, Ca–SO4 and Mg–HCO3. The Ca–NO3 water type is associated with high nitrate pollution. Agricultural and industrial activities were associated with elevated level of NO3−. Mineral dissolution/weathering of evaporites dominates the major element hydrochemistry of the area. Chemical properties of groundwater in Alvand region are controlled both by natural geochemical processes and anthropogenic activities.  相似文献   

8.
Groundwater arsenic distribution in South-western Uruguay   总被引：1，自引：0，他引：1  
This is the first specific information regarding arsenic distribution of groundwater in SW Uruguay. Twenty-eight wells were sampled on the aquifers of Mercedes, Raigón and Chuy in five localities. The pH, specific conductivity and temperature were determined in the field. The hydrochemical characterization (major and trace elements) was carried out by both inductively coupled plasma-optical emission spectrometry and inductively coupled plasma-mass spectrometry. The occurring arsenic concentrations exceed the recommended threshold for drinking water of the World Health Organization (10 μg/l of As) in 22 samples, with more than 50 μg/l of As in two cases. The median, minimum and maximum concentrations were 0.1, 16.9 and 58.0 μg/l of As, respectively. The studied aquifers present a horizontal and a vertical variation of the concentrations as a whole as well as individually. The highest values were observed in the Mercedes Aquifer in the areas near the Uruguay River.  相似文献   

9.
A 'first pass' groundwater management policy has been developed for use by non-governmental organisations (NGOs) in Afghanistan, designed to prevent derogation of existing traditional water sources, aquifer over-abstraction and chemical deterioration of soil and groundwater quality. Key elements include (1) continuing promotion of groundwater as a drinking water source, (2) a presumption against use of motorised pumps to abstract groundwater for irrigation unless other options (surface water, qanats) are not available, (3) the use of groundwater for irrigation as a temporary alternative to surface water (i.e. a strategy for drought survival) rather than as a long-term development policy, (4) limiting groundwater abstraction to a long-term average of 1 l s–1 km–2, (5) siting irrigation wells at least 500 m from other groundwater sources and (6) analysing irrigation groundwater for electrical conductivity, sodium absorption ratio, boron and residual sodium carbonate alkalinity. Analyses of these parameters indicate that groundwater from some areas is of dubious suitability for irrigation. In some villages and towns, groundwater contains elevated nitrate and faecal bacteria concentrations, probably derived from latrines, sewage or animal wastes. Electronic Publication  相似文献   

10.
Punjab is the most cultivated state in India with the highest consumption of fertilizers. Patiala and Muktsar districts are two agricultural dominated districts of Punjab located in extreme south-east and south-west of the state. This paper highlights temporal variations of the groundwater quality and compares its suitability for irrigation and drinking purpose in these two districts. Water samples were collected in March and September 2003, representing the pre-monsoon and post-monsoon seasons, respectively. Water samples were analysed for almost all major cations, anions, dissolved heavy metals and turbidity. Parameters like sodium adsorption ratio, % sodium, residual sodium carbonate, total hardness, potential salinity, Kelley’s ratio, magnesium ratio, index of base exchange and permeability index were calculated on the basis of chemical data. A questionnaire was also used to investigate perception of villagers on taste and odour. Comparison of the concentration of the chemical constituents with WHO (world health organization) drinking water standards of 2004 and various classifications show that present status of groundwater in Patiala is better for irrigation and drinking purposes except for a few locations with a caution that it may deteriorate in near future. In Muktsar, groundwater is not suitable for drinking. Higher total hardness (TH) and total dissolved solids at numerous places indicate the unsuitability of groundwater for drinking and irrigation. Results obtained in this forms baseline data for the utility of groundwater. In terms of monsoon impact, Patiala groundwater shows dilution and flushing but Muktsar samples show excessive leaching of different chemical components into the groundwater leading to the enrichment of different anions and cations indicating pollution from extraneous sources. No clear correlation between the quality parameters studied here and perceived quality in terms of satisfactory taste response were obtained at electrical conductivity values higher than the threshold minimum acceptable value.  相似文献   

11.
A study was undertaken to examine the content and spatial distribution of fluoride in drinking water. Water samples (735) from public water systems covering all Estonian territory were analysed using SPADNS method. In order to specify the natural source of fluoride, the chemistry data from five aquifer systems utilised for water supply were included into the study. Fluoride concentrations in tap water, to a great extent, ranged from 0.01 to 6.95 mg/l. Drinking water in southern Estonia, where terrigenous Middle-Devonian aquifer system is exploited, has a fluoride concentration lower than recommended level (0.5 mg/l), thus promoting susceptibility to dental caries. The western part of the country is supplied by water with excess fluoride content (1.5–6.9 mg/l). Groundwater abstracted for drinking purposes originates from Ordovician and Silurian carbonate rocks. The content of fluoride in Silurian–Ordovician aquifer system is associated with the groundwater abstraction depth and the main controlling factors of dissolved fluoride are the pH value and the chemical type of water.  相似文献   

12.
Groundwater data (water level, electrical conductivity (EC) and temperature) have been collected since 1995 from the national groundwater-monitoring stations in South Korea. Recently, substantial groundwater-level decline and deterioration of groundwater quality were reported at several stations. Relevant authorities undertook to investigate the groundwater hazards and to devise mitigation measures for selected monitoring stations. However, there were no criteria to determine the status of the groundwater level and EC, compared with historic data. A methodology is presented, which defines the groundwater condition. Using the suggested criteria, water level and EC data are classified into normal, watch and warning levels, leading to different administrative measures and technical investigations. The primary criterion compares the observed values for the evaluation year (e.g. 2003) and the historic values of normal years preceding the evaluation year (e.g. 1996–2002), using box plots. The secondary criterion uses variation trends of the values with the aid of parametric and non-parametric trend tests. Final decisions are dependent on scores assigned to each test. According to the criteria suggested, detailed investigations and mitigation measures for water level decline are required for seven stations and those for water quality are needed for 18 stations because they reside within the warning classification.  相似文献   

13.
Aquifer vulnerability is frequently estimated through methodologies that don’t consider most physical and chemical soil parameters. A soil attenuation index is proposed to estimate groundwater chemical pollution risk, that takes into account organic carbon content, pH, cation exchange capacity, clay content, phreatic depth and landscape position. The attenuation index is constructed by a methodology similar to that developed for water quality index. P, Mn and Zn concentrations in groundwater from selected places were used to validate the proposed index.  相似文献   

14.
Hydrogeochemical investigations are carried out in the different blocks of Burdwan district, West Bengal, India in order to assess its suitability for drinking as well as irrigation water purpose. Altogether 49 representative groundwater samples are collected from bore wells and the water chemistry of various ions viz. Ca2+, Mg2+, Na+, K+, CO32−, HCO3−, Cl−, SO42− and NO3− are carried out. The chemical relationships in Piper and Gibbs diagram suggest that the groundwater mainly belongs to alkali type and Cl− group and are controlled by rock dominance. A comparison of groundwater quality in relation to drinking water quality standards proves that most of the water samples are suitable for drinking water purpose whereas groundwater in some areas of the district has high salinity and high sodium adsorption ratio (SAR), indicating unsuitability for irrigation water and needs adequate drainage.  相似文献   

15.
Groundwater of Egypt: “an environmental overview”   总被引：1，自引：0，他引：1  
Although Egypt has the great Nile River, which is the main supply of water, Egypt’s water is limited to 55.5 billion m3 per annum. Owing to the rapid growth of the population and the increasing consumption of water in agriculture, industry, domestic use, etc., it is expected that Egypt will rely to some extent on groundwater to develop the new projects such as Tushka in Upper Egypt and East Oweinat. Issues related to groundwater in Egypt are identified with the common geological features associated with formation of the aquifers and demonstrating the location of the main resources of groundwater, followed by the main objective of this paper, which is addressing the environmental issues related to groundwater in Egypt. Several studies have been reviewed and personal communication made with the authorities to introduce this work and provide an overview of the groundwater quality problems in Egypt with examples from different parts of the country.  相似文献   

16.
Cities have a negative impact on the quality of shallow groundwater. Many of Lithuania's urban residents drink water from dug wells. Moreover, polluted shallow groundwater contaminates deeper aquifers of fresh drinking water. Therefore, this situation should be controlled and managed, as far as possible. In order to evaluate the quality of shallow groundwater in an urban area and to create an optimal monitoring system, an original methodology for groundwater mapping has been proposed. It resembles the GIS (geographical information system) technologies. The set of maps, laid one over another, consists of the following: (1) urbanization map, (2) geological-hydrogeological map, (3) groundwater chemistry map, (4) resulting groundwater chemistry factorial analysis map, and (5) pollution and pollutant transport map. The data obtained from studies on dug and geotechnical wells have been used for compilation of the maps. The system for shallow groundwater monitoring in the city with an area of 70 sq km and a population of 140,000 is proposed to consist of about 30 monitoring wells and several dug wells.  相似文献   

17.
Self-regulation of groundwater users offers tremendous potential for effective groundwater management. The attributes of higher-level authorities that are more likely to facilitate the beneficial management of groundwater in economic, social and environmental terms are discussed. For this purpose, eight groundwater user associations in Spain have been compared. Factors that support institutional change were analyzed, namely: salience, common understanding, trust and reciprocity, autonomy, prior organizational experience and local leadership. These factors are complemented by features that strengthen actions by higher-level authorities that oversee self-regulation by water users (clear boundaries, legitimate recognition of appropriators, facilitating roles, trust in cross-scale linkages, clear division of responsibilities, institutional culture and co-management model choices). Self-regulation includes the creation of reflexive organizations that are capable of learning, provided first, the administration itself is modernized to meet the challenges of self-regulation, and second, that ‘regulatory capture’ is avoided by external organizations, ensuring that the regulator and the regulated are not so close in their relationship as to be detrimental to effectiveness.
E. Lopez-GunnEmail:
  相似文献   

18.
 Analyses of 126 samples collected from 18 dug wells in the shallow basaltic aquifer over a period of 7 months have revealed spatial as well as temporal changes in the chemical properties of groundwater. While the temporal changes have been attributed to dilution and concentration phenomena governed by climatic factors, the spatial variations in the geochemical characteristics of groundwater appeared to be related to pollution due to effluents from the Mula Sugar Factory. The cause of groundwater pollution is the effluent carried by a stream flowing through the area. Fluctuations in the groundwater table, influent water quality character of the stream, less capacity to accommodate large volume of effluent and occurrence of zero base flow (under natural conditions) in the stream are the factors favoring infiltration of constituents of waste water into the underlying weathered basaltic aquifer. Pollutants have entered into the shallow aquifer by downward percolation through the zone of aeration to form a recharge mound at the water table and, further, lateral movement below the water table. The plume of polluted groundwater has a lateral extent of a few meters in the upstream area and more than 400 m on either side of the stream in the downstream part. The zone of polluted groundwater has an areal extent of more than 3.5 km2. Groundwater is the only source available for drinking and agricultural purposes. It is recommended that the base of the lagoons and the stream used for release of plant effluent should be waterproofed for the protection of groundwater in the Sonai area. Received: 30 April 1997 · Accepted: 23 September 1997  相似文献   

19.
This paper reviewed the main achievements of hydrogeological survey in China, summarized the significant progress of hydrogeological survey over the past decade, and forecasted the key responsibilities for hydrogeological survey in the p14th Five-year Planq. The significant progress includes: China established the 1: 50 000 standard hydrogeological survey system with Chinese characteristics and produced the new generation of high-quality hydrogeological maps; the national groundwater monitoring project was completed and accepted, which marks China taking the leading position in groundwater monitoring internationally; fruitful results were achieved in the national groundwater quality survey, and groundwater quality background values were basically identified and checked; hydrogeological and environmental geological survey was continuously promoted in karst areas and the ecological restoration of rocky desertification achieved remarkable results; China strengthened layer exploration techniques for groundwater, integrating the key and practical techniques of layer exploration and monitoring; the exploration of groundwater in the poverty-stricken regions and old revolutionary base areas were effectively promoted to strongly guarantee the poverty alleviation and drinking water safety; the mystery of desert groundwater was uncovered, making up for the shortage of 1: 250 000 hydrogeological survey in the Badain Jaran Desert; and more efforts were made to conduct survey on the water resources in the basin, and to finish the unified measurement of national-scale groundwater level.  相似文献   

20.
In the city of Ouro Preto (MG), water catchment for public supply originates from superficial drainage, springs, old abandoned mines and some driven wells. In the rocks of the region, As is originally found in gold-enriched sulphide-bearing mineral deposits. The weathering process introduces As into the hydrological system by dissolution of this element into the leachate. Measurement of the As content in the groundwater of some catchments was carried out during 1 year and these measurements demonstrated high As content—up to 224 μg L−1 of As(V)—during the rainy season (the maximum concentration limit according to World Health Organization is 10 μg L−1). Lower values were observed during the dry season and in some sampling stations, As was not even detected. The As concentration variability during 1 year shows a strict and direct relationship to seasonal and hydrological conditions. For city authorities, responsible for public water supply, it is necessary to perform a complete inventory of the water sources used and constantly monitor the As content in the water.  相似文献   

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