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1.
梁清玲  江思宏  刘翼飞 《地质论评》2013,59(6):1119-1130
本文对河北丰宁地区前人所定的东猴顶正长斑岩和石英正长斑岩进行了岩石学、锆石U Pb年代学、元素地球化学以及Sr—Nd—Pb—Hf同位素分析。LA MC ICP MS锆石U Pb测年和岩石学显示东猴顶岩体为早白垩世(~129Ma)钾长花岗斑岩,而非前人认为的侏罗纪—白垩纪正长斑岩和石英正长斑岩。东猴顶岩体具有高硅(6907%~7300%)、富碱(Na2O+K2O:900%~1056%)和FeO(全铁)/MgO比值大的特征,属高钾钙碱性系列;岩石富集轻稀土,负铕异常明显(δEu:025~041),相对富集K、Rb等大离子亲石元素和Zr、Hf、Th、U、Y等高场强元素,亏损Ca、Ba、Sr、P、Ti、Cr、Ni、Co等元素,Ga/Al比值高,具A型花岗岩特征,可能形成于伸展环境构造体制。岩体n(87Sr)/n(86Sr)i=070815~071197,εNd(t)值为-132~-168,对应的二阶段模式年龄(T2DM)为20~23Ga;全岩n(206Pb)/n(204Pb)i=16745~16765,n(207Pb)/n(204Pb)i=15372~15394,n(208Pb)/n(204Pb)i=37706~37794;锆石Hf同位素组成为εHf(t)值=-207 ~ -92,二阶段模式年龄(TDMC)为19~26 Ga。同位素特征表明岩体源岩可能主要来自壳源物质。考虑到华北克拉通东部地壳生长的主要时期为新太古代,因此,东猴顶岩体的岩浆来源于太古代地壳物质和部分亏损地幔物质的混合源区,是华北克拉通北缘中生代岩石圈强烈减薄、地壳伸展作用的结果。  相似文献   

2.
冀北窟窿山流纹斑岩位于赤峰—开原断裂以南、尚义—平泉断裂带以北的华北克拉通北缘隆起带和沽源—红山子铀成矿带的西南段,主要分布于窟窿山北西部,出露面积约25 km~2。本文通过SHRIMP锆石U-Pb定年和主量元素、微量元素、稀土元素、Sr—Nd—Pb—O同位素组成测试,查明流纹斑岩形成的地质时代,探讨流纹斑岩的物质来源和形成的构造背景,分析流纹斑岩与铀矿化的关系。分析结果显示:流纹斑岩SHRIMP锆石n(~(206)Pb)/n(~(238)U)年龄为138.4±1.3 Ma(n=12,MSWD=0.25),属早白垩世早期;流纹斑岩具有高硅、富钾、钠,高FeO~T/MgO值,贫Al、Mg、Ca、P的高分异特征,属准铝质—弱过铝质高钾钙碱性系列岩石,在SiO_2—[(Na_2O+K_2O)—CaO]和SiO_2—FeO~T/(FeO~T+MgO)图解中落于A型花岗岩区;∑REE含量较低,Eu负异常明显,具轻稀土富集型稀土配分曲线特征,富集Rb、Th、U、Nb、Ta、Zr、Hf、Y等元素,亏损Sr、Ba、P、Ti等元素,10000Ga/Al=3.74~4.29(2.6),Zr+Nb+Ce+Y=374×10~(-6)~402×10~(-6)(350×10~(-6)),显示A型花岗岩微量元素的特征。流纹斑岩的[n(~(87)Sr)/n(~(86)Sr)]_i值变化范围较大(=0.690385~0.724000),ε_(Nd)(t)值较低(=-16.2~-14.9)、T_(DM2)较大(=2163~2244 Ma),Pb同位素比值较低{[n(~(206)Pb)/n(~(204)Pb)]_i=16.893~16.922、[n(~(207)Pb)/n(~(204)Pb)]_i=15.393~15.424、[n(~(208)Pb)/n(~(204)Pb)]_i=37.716~37.771},在铅同位素图解中窟窿山流纹斑岩同时带有下地壳物质和富集地幔印记;δ~(18)O_(V-SMOW)=3.5‰~4.9‰,低于正常地幔的δ~(18)O_(V-SMOW)值(=5.3‰±0.3‰),具低氧流纹岩特征。Sr—Nd—Pb—O同位素特征显示,流纹斑岩可能是源于DMM型、EMI型地幔和少量古老下地壳混合形成的年轻下地壳部分熔融的产物,而且与高温热液蚀变有关。对比表明,窟窿山流纹斑岩与中国东部绝大多数与火山岩有关的热液型铀矿的赋矿围岩时代一致,特别是与沽源—红山子铀成矿带西南段张麻井铀矿的赋矿流纹斑岩特征一致,而且在流纹斑岩的接触带内已揭露到铀矿化,指示窟窿山流纹斑岩的内、外接触带具有良好的找矿前景。  相似文献   

3.
《地学前缘》2016,(1):264-275
冲巴淡色花岗岩位于大喜马拉雅淡色花岗岩带的东部,岩石地球化学研究结果显示,其具有高的SiO2(73.87%~74.95%)、Al2O3(14.20%~14.74%)和K2O(4.44%~4.89%),高的K2O/Na2O比值(1.19~1.42)和A/CNK比值(1.18~1.22),富集Rb、Th和U,亏损Ba、Nb、Sr和Zr,具有强烈的负Eu异常(δEu=0.27~0.37),属于高钾钙碱性过铝质S型花岗岩。冲巴淡色花岗岩具有较高的Rb/Sr比值(2.6~8.6),低的CaO/Na2O比值(0.18~0.20),指示源区可能为泥质岩区,(87 Sr/86 Sr)i和εNd(t)值分别为0.763 199~0.778 799和-16.7~-16.3,与大喜马拉雅结晶杂岩(GHC)中变泥质岩一致,表明其来自GHC变泥质岩的部分熔融。淡色花岗岩具有高的(87Sr/86Sr)i而低的Sr含量,且随着Ba含量增加,Rb/Sr比值降低。这些特征表明,冲巴淡色花岗岩是无水条件下变泥质岩发生白云母脱水熔融的产物,部分熔融可能与STDS伸展拆离导致的构造减压密切相关。  相似文献   

4.
西藏厅宫斑岩铜钼矿床是冈底斯成矿带上最早开发的斑岩铜矿之一,矿区大面积分布的黑云母花岗闪长岩、二长花岗岩、钾长花岗岩均为容矿岩体,因此详细开展这几套岩体的评价工作,对于今后的找矿勘探工作具有重要的指导意义。本文通过分析上述三类岩体LA-ICP-MS锆石U-Pb测年,全岩主微量、稀土元素,Rb-Sr、Sm-Nd、Pb同位素,结果显示三类岩体锆石结晶年龄分别为50.32 Ma、48.34 Ma、49.41 Ma,早于成矿事件,与成矿事件无关。三类岩体均属高钾钙碱性,弱过铝质I型花岗岩,稀土元素呈轻稀土富集的右倾V型模式图,重稀土分馏不明显,明显负δEu,δEu随Si O2含量的升高而降低,推测与岩浆结晶分异的程度有关,微量元素均明显亏损高场强元素Ba、Nb、Sr、Ti,富大离子亲石元素Th、U、K、Cs、Rb。Pb同位素结果表明初始n(206Pb)/n(204Pb)、n(207Pb)/n(204Pb)、n(208Pb)/n(204Pb)计算值较为分散,分别为18.414~18.5137、15.616~15.7039、38.6394~39.0029,放射成因Pb含量较高。初始n(87Sr)/n(86Sr)同位素较为均一,主要介于0.70320~0.70477之间。初始n(143Nd)/n(144Nd)同位素介于0.51260~0.51265之间,计算得出的εNd(t)为0.51~1.44,均大于0。上述分析结果表明,厅宫矿区大面积分布的容矿始新世岩体并非为成矿岩体,上述岩体具有同源复式侵入特征,岩浆起源与特提斯洋发生的板片前端的拖拽作用造成板片的回旋、断离有关,岩浆起源于新生下地壳/地幔,并在岩浆侵位过程中经历过AFC过程。  相似文献   

5.
内蒙古中部红格尔地区碱长花岗岩是白音乌拉-东乌旗A型花岗岩带的重要组成部分,其LA-ICP-MS锆石U-Pb年龄为286~294 Ma,表明其形成时代为早二叠世。岩石富硅(SiO_2=75.13%~80.17%)、富碱(Na_2O+K_2O=7.33%~9.11%)、富铁(TFe_2O_3=1.01%~2.31%)、贫镁(MgO=0.09%~0.27%)和贫钙(CaO=0.12%~0.52%)。微量元素中大离子亲石元素(LILE)Rb、Th、K和Pb明显富集,Sr、Ba强烈亏损;高场强元素(HFSE)Nb、Ti、La和Ce亏损明显,Zr、Hf相对富集。岩体稀土总量较低且变化大(∑REE=33~165μg/g),轻重稀土分异程度低且轻稀土弱富集,具明显的Eu负异常(δEu=0.06~0.13),稀土元素分布模式表现为较平缓、轻微右倾的海鸥型分布型式。εNd(t)为正值(+1.08~+3.18),tDM2变化于805~965 Ma之间;有较高的放射成因铅,(~(206)Pb/~(204)Pb)i为18.710~19.280,(207Pb/204Pb)i为15.557~15.597,(~(208)Pb/~(204)Pb)i为37.887~38.330。岩石学、主元素和微量元素地球化学特征显示红格尔地区碱长花岗岩属于铝质A型花岗岩,其形成于碰撞后伸展构造背景,是后碰撞俯冲板片断离诱发中下地壳镁铁质岩石部分熔融的产物。红格尔地区A型花岗岩的发育可能反映了内蒙古中部古亚洲洋在二叠纪前已经闭合。  相似文献   

6.
阿拉尔花岗岩体出露于阿尔泰造山带南缘可可托海地区喀依尔特-乌什托克斯一带,主要由斑状黑云钾长花岗岩、斑状黑云二长花岗岩(中心相),黑云钾长花岗岩、二云钾长花岗岩、二云二长花岗岩(过渡相)和黑云母花岗岩(边缘相)组成。对其进行了LA-ICP-MS锆石U-Pb年代学和岩石地球化学研究。结果显示,中心相的锆石206Pb/238 U年龄加权平均值为210±5Ma和218.7±3.3Ma,限定该岩体的形成时代为晚三叠世。岩石高硅(SiO2=65.33%~74.74%)、富钾(K2O=3.82%~6.02%,K2O/Na2O=1.27~2.32)、铝(Al2O3=12.87%~15.19%,A/CNK=0.85~1.17)、低钛(多小于0.33)和贫镁(MgO=0.16%~1.78%)、铁(Fe2O3T=1.79%~4.98%),为准铝质到弱过铝质的高钾-钾玄岩系列。稀土元素总量较高(123×10-6~363×10-6),轻稀土元素相对富集,有明显的负Eu异常(δEu=0.29~0.60)。微量元素Ba、Sr、Ti、Nb、Ta等具负异常,Rb、Th、Sm等具正异常,Rb/Sr比值较高(0.77~3.56,均值为1.57),显示S型花岗岩特征。结合区域资料,认为阿拉尔花岗岩形成于后碰撞造山向板内环境的转换阶段,是含泥质的变质杂砂岩地壳熔融的产物,且其可能与可可托海3号伟晶岩脉具有成因联系。  相似文献   

7.
于玉帅  周云  鲍波  高原  杨竹森 《地球科学》2019,44(6):1888-1904
为深入了解中北部拉萨地块构造背景,利用LA-ICP-MS技术对洛布勒铁矿床成矿花岗闪长岩锆石进行了U-Th-Pb同位素测定,分析了隆格尔、洛布勒铁矿床侵入岩岩石地球化学和Sr-Nd-Pb同位素组成.获得洛布勒花岗闪长岩锆石U-Pb年龄为111.3±1.6 Ma(MSWD=0.61,n=9).隆格尔和洛布勒铁矿床侵入岩高硅(66.63%~69.02%和64.33%~64.82%)、富碱(全碱为5.91%~6.40%和5.81%~6.05%)、低A/CNK(0.91~0.97和0.94~0.95)、SiO2与P2O5含量负相关;稀土元素总量较低(∑REE为123.11×10^-6~148.83×10^-6和96.17×10^-6~101.92×10^-6),球粒陨石标准化配分模式图右倾,弱Eu负异常(0.70~0.82和0.79~0.81),富集大离子亲石元素Rb、Th、U、K、Pb等,亏损Ba和高场强元素Nb、Ta、Sr、Ti等.隆格尔花岗岩全岩和斜长石(206Pb/204Pb)t为18.474和18.626,(207Pb/204Pb)t为15.657和15.722,(208Pb/204Pb)t为38.592和39.145,(87Sr/86Sr)i为0.704 757 6和0.707 047 3,(143Nd/144Nd)i为0.512 281和0.512 339,εNd(t)为-4.13和-2.99,tDM2为1.15 Ga和1.24 Ga;洛布勒花岗闪长岩(206Pb/204Pb)t比值为18.281,(207Pb/204Pb)t比值为15.616,(208Pb/204Pb)t比值为38.369,(87Sr/86Sr)i为0.706 551 4;(143Nd/144Nd)i为0.512 309,εNd(t)为-3.62,tDM2为1.20 Ga.结果表明,措勤-隆格尔铁矿床成矿侵入岩为中钾-高钾钙碱性岩I型花岗岩,为早白垩世晚期岛弧岩浆活动产物,岩浆源于地壳物质部分熔融,岩浆演化过程经历了壳幔岩浆混合和围岩混染.结合前人研究成果,通过对比白垩纪中北部拉萨地块和南部羌塘地块成矿事件的差异,提出中北部拉萨地块113±3 Ma岩浆活动和Fe(-Cu)成矿事件与向南俯冲的班公湖-怒江洋壳发生断离有关.  相似文献   

8.
粤北笋洞花岗岩的形成时代、地球化学特征与成因   总被引:25,自引:10,他引:25  
笋洞花岗岩体是粤北贵东复式花岗岩体的一个重要组成部分。锆石U-Pb年龄为189.1±0.7Ma,是燕山早期岩浆活动产物。该岩体的主要元素显示富硅、富碱、强过铝质和低 CaO/Na_2O比值等特征;微量元素方面,富集Rb,Th,U,Ce,Sm,Y,亏损 Ba,Sr,P,Ti;LREE轻微富集(LREE/HREE=6.6~8.8,(La/Yb)_N=6.44~10.74),Eu亏损明显(δEu=0.14~0.31);它具有低的ε_(Nd)(t)(-11.4~-9.3),高的δ~(18)O(10.2~12.7‰)、(~(87)Sr/~(86)Sr);(0.72949~0.74923)、~(206)Pb/~(204)Pb(18.180~18.488)、~(207)Pb/~(204)Pb(15.655~15.661)和古老的Nd模式年龄(1762~1933Ma)。上述这些特征表明,笋洞岩体属于典型的壳源型花岗岩,是在地壳伸展-减薄的构造背景下,通过以泥质成分为主的古-中元古代变质沉积岩部分熔融的方式形成。  相似文献   

9.
徐欢  赵慧  罗金海  程佳孝  尤佳  王师迪 《地质论评》2014,60(6):1284-1296
在华北地块西南缘陇县保家山西部铁马河剖面出露钾长花岗斑岩,与其伴生的有蚀变辉绿玢岩,整体沿六盘山断裂带分布。保家山钾长花岗斑岩富钾(Na2O/K2O=1.66~3.36),具钙碱性和准铝—弱过铝质特征(A/CNK=0.85~1.18)。富集轻稀土元素且轻重稀土元素分异明显(LREE/HREE=4.08~12.03),Eu负异常明显(δEu=0.50~0.53)。富集大离子亲石元素K、Rb、Ba、Th,亏损高场强元素Nb、Ta、Ti、Hf,强烈亏损P、Sr,且具有较高的Rb/Sr和Ga/Al比值,表现出A型花岗质岩石的特征。对两个样品进行锆石U-Pb LA-ICP-MS测年,分别获得n(206Pb)/n(207Pb)加权平均年龄1814±12Ma和1781±12Ma,说明岩体属于古元古代岩体。结合区域地质资料的研究表明,华北地块西南缘在古元古代期间处于强烈伸展背景,推测应该与古元古代贺兰坳拉槽的向南延伸有关。  相似文献   

10.
耿雯  秦江锋  李永飞  赖绍聪 《地质通报》2014,33(9):1333-1341
对张广才岭南部一面坡花岗岩的地质学、岩石学、地球化学及锆石U-Pb年龄研究表明,岩石富硅富铝,属于过铝质岩石(A/CNK=1.04~1.07),全碱(K2O+Na2O)含量为8.24%~8.85%,K2O/Na2O值为1.58~1.68,属于高钾钙碱性系列I型花岗岩。岩石富集LREE、Rb、Th、U、K,相对亏损Nb、Ta、P、Ti,具有明显的Eu负异常,LA-ICP-MS锆石206Pb/238U年龄加权平均值为211Ma±4Ma(MSWD=1.4,2σ),代表了花岗岩的结晶年龄。岩石具有相对亏损的锆石Hf同位素组成(εHf(t)=+1.75~+13.81),TDM2为367~1136Ma。结合区域构造环境分析,认为一面坡晚三叠世花岗岩属于I型花岗岩,可能形成于后碰撞伸展构造环境,是岩石圈伸展阶段新增生下地壳物质发生部分熔融的产物。  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

12.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

13.
14.
The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.  相似文献   

15.
The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag2Te) and matildite (AgBiS2). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.  相似文献   

16.
Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N2 in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.  相似文献   

17.
马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。  相似文献   

18.
Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ18O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.  相似文献   

19.
Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.  相似文献   

20.
藏北羌塘丁固—加措地区康托组的时代   总被引:2,自引:0,他引:2  
自西藏区域地质调查大队创建康托组以来,康托组岩石地层单位广泛应用于羌塘地区,普遍认为其时代为新近纪.笔者于丁固-加措地区的康托组地层中采获古近纪轮藻化石Obtusocharat sp.,O.lanpingenis,Gyrogona qinajiangica和部分孢粉化石,并在康托组底部安山岩中获K-Ar年龄65.1~66.5Ma.上述轮藻组合与同位素年龄指示的地层时代为古新世-始新世,据此将测区康托组的时代确定为古近纪.由于测区康托组之上被唢纳湖组或鱼鳞山组角度不整合覆盖,因此康托组时代的确定不仅进一步完善了测区新生代地层系统,还指示测区在康托组与唢纳湖组或鱼鳞山组之间发生了一次强烈的构造运动.  相似文献   

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