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1.
Fine-grained clayey subfractions (SF) with particle sizes of 1–2, 0.6–1.0, 0.3–0.6, 0.2–0.3, 0.1–0.2, and <0.1 μm were extracted from shales of the Vendian Staraya Rechka Formation in the Anabar Massif and studied by XRD and Rb-Sr methods. All the clayey subfractions are represented by illite with high crystallinity indices, which are characteristic of the low-temperature diagenesis/catagenesis zone and grow with the decrease of the particle size. The Rb-Sr systematics in clayey subfractions combined with mineralogical data provide grounds for the conclusion that illite from clayey rocks of the Staraya Rechka Formation was forming during two periods: approximately 560 and 391–413 Ma ago. The first illite generation was likely formed in the course of lithostatic subsidence of the Staraya Rechka sediments and the second one, during the Devonian lithogenesis stage. It is assumed that age of the first generation (∼560 Ma) is close to that of the Staraya Rechka Formation. This inference is consistent with biostratigraphic, chemostratigraphic, and geochronological data obtained for both rocks of the Anabar Massif and Vendian sediments from other regions of Siberia.  相似文献   

2.
Fine-grained clay subfractions, SFs (particle size <0.1, 0.1–0.4, 0.4–0.6, and 0.6–2.0 μm) separated from a sample of the Lower Cambrian blue clay of the Lontova Formation were studied with XRD and Sm-Nd methods. The relatively coarse-grained SFs include illite with a small admixture of chlorite, while the finegrained SF (<0.1 μm) consists of mixed-layer illite-smectite. The illite crystallinity index (I c ) increases with decreasing particle size. The leaching of SFs with 1N HCl, analysis of Sm-Nd systematics of leachates and residues, as well as XRD data and results of chemical analysis show that the studied rocks contain at least two generations of minerals. The first (detrital) generation is related to the transformation of provenance material, whereas the second (authigenic) generation was formed at the postsedimentary stage of the evolution of the Lontova sediments. The Sm-Nd date of the first generation (790±90 Ma) is considered a minimal age of rocks in the northeastern and southwestern regions of the East European Platform that served as a source of sedimentary material of the Lower Cambrian blue clay. The date of the second generation of minerals reflects the timing of authigenic mineral formation in the course of burial and diagenetic and catagenetic reworking of clay sediments.  相似文献   

3.
Fine-grained clay subfractions (SFs) with a particle size of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2.0, and 2–5 m separated from the claystone of Upper Precambrian Pumanskaya and Poropelonskaya formations on the Srednii Peninsula were studied by transmission electron microscopy, X-ray diffraction, and Rb–Sr methods. All subfractions consist of the low-temperature illite and chlorite, and the contribution of chlorite decreases with diminishing particle size. The crystallinity index and I 002/I 001 ratio increase from coarse- to fine-grained SFs. The leaching by ammonium acetate solution and the Rb–Sr systematics in combination with mineralogical and morphological data indicate that illite in Upper Proterozoic claystone from the Srednii Peninsula was formed during three time intervals: 810–830, 610–620, and about 570 Ma ago. The first generation of this mineral with a low Rb/Sr ratio dominates in coarse-grained SFs while the second and third generations with a high Rb/Sr ratio prevail in fine-grained SFs. All of the three generations are known in the Poropelon claystone, whereas the Puman claystone contains only illite of the first and second generations. Geological processes responsible for the multistage illite evolution in claystones are discussed.  相似文献   

4.
In unaltered volcanogenic massive sulfide (VMS) ore deposits, variable Rb/Sr ratios in the ore mineral permits application of the Rb-Sr isotopic method to directly date the time of ore formation. In contrast, post-crystallization deformation and metamorphism would open the system to metamorphic fluids that would alter elemental ratios. To test whether the Rb-Sr isotopic systematics in the ore minerals had preserved the formation time in the ∼800 Ma metamorphosed VMS ores within the ∼1 Ga Ambaji-Sendra arc terrain, Rajasthan, NW India, common sulfides, pyrite and sphalerite from the Pipela Cu-Zn prospect, were analyzed for their geochemistry and Rb-Sr isotopic systematics. Trace and rare earth elements in these minerals are resident probably at crystal defects, whereas all inclusions (including those from metamorphic fluids) were removed by a simple crush leach method. Results of direct dating by the Rb-Sr method to the hydrothermal pyrite yielded an isochron age of 1025±76 Ma with an initial Sr ratio of 0.7051±0.0006, similar to previously determined zircon U-Pb age of 987 Ma from associated rhyolites. This suggests the applicability of the crush leach method to date formation time of metamorphosed pyrite ores.  相似文献   

5.
胡振铎  朱杰辰 《铀矿地质》1998,14(4):218-226
笔者对沧参1井石炭、二叠纪地层中的粘土矿物特征进行研究,并对不同深度的粘土矿物进行了K－Ar、40Ar－39Ar及Rb－Sr法同位素地质年龄测定,得出至少存在三期伊利石的结论;碎屑伊利石,年龄为400Ma左右,在235—243Ma时受到热扰动;海西期末一印支早期形成的高温伊利石,其年龄为214—234Ma,在145Ma时经受一次热扰动;早侏罗世时期形成的伊利石,年龄为180Ma左右,分布比较普遍。这一研究结果无疑将有助于深入探讨区域地热场的演化,以及进一步研究有关地层的生、储油气能力。  相似文献   

6.
江西大吉山钨矿成矿年代学研究   总被引：25，自引：0，他引：25  
大吉山钨矿床是一个大型的石英脉型钨矿床。矿床在空间上与燕山早期复式花岗岩相伴。利用云母单矿物的K Ar同位素年龄测试方法,测定了矿床有关的花岗岩及矿脉的同位素年龄。结果表明,黑云母花岗岩中黑云母K Ar年龄为(160 3±3 03)Ma和(164 2±3 5)Ma,二云母花岗岩中白云母K Ar年龄为(160 6±2 8)Ma,含钨石英脉中白云母K Ar年龄为(152 6±2 35)Ma和(158 1±2 8)Ma。钨成矿与花岗岩的成岩基本不存在时差,推测含钨石英脉的形成可能与岩浆分异出的富含矿化剂和成矿元素的流体有关。  相似文献   

7.
从内蒙古包头至白云鄂博地区,横跨高、中、低级变质岩区,都发现有金矿及金矿化点。对三个主要金矿床的Pb、S、Rb—Sr、K—Ar等同位素的研究表明,成矿物质来自变质岩和花岗岩,成矿时代与古生代晚期华北陆台活化的岩浆作用有关。铅的混合模型说明在不同变质岩区变质岩和花岗岩对矿源的贡献不同。  相似文献   

8.
黄陵变质地区的同位素地质年代及地壳演化   总被引：5，自引：0，他引：5  
研究表明,黄陵变质地区崆岭群是神农架群之下的古老结晶基底,其中、下部为典型的孔兹岩系。作者首次在崆岭群孔兹岩系地层中取得可信度较高的锆石UPb一致线年龄2332Ma。同时利用K-Ar稀释法和Rb-Sr全岩等时线法获得的年龄值分别为1891和2010Ma.。这些数据证实,崆岭群属下元古界。由此认为,黄陵变质地区及扬子地台结晶基底的形成时代绝不是中晚元古,而是早元古初期。  相似文献   

9.
微区-微量样品Rb-Sr同位素分析技术及其应用前景   总被引：1，自引：0，他引：1  
利用微钻取样技术和微量样品Rb-Sr同位素分析方法,本文对出露在东秦岭造山带的中生代合峪花岗岩的自形钾长石巨晶进行微区-微量样品Rb-Sr同位素组成分析。分析结果表明,钾长石斑晶具有显著的Rb/Sr比值和Sr同位素组成变化,斑晶和基质钾长石均构成年龄为132~133Ma的Rb-Sr等时线,代表岩浆的后期冷却时代。钾长石晶体的初始87Sr/86Sr比值由边缘相到中心相没有明显的变化,代表花岗质岩浆结晶阶段的Sr同位素组成,暗示合峪花岗岩的钾长石巨晶为原生成因。以高空间分辨率为特征,微区取样技术已经广泛地应用在变质岩和深成岩浆岩的同位素年代学和成因研究。结合微量样品同位素分析技术,微区-微量样品Rb-Sr同位素方法有望在火山岩的成因和年代学方面得到应用。  相似文献   

10.
Thirty-five illite and muscovite concentrates were extracted from Triassic and Permian claystones, shales, slates and phyllites along a cross-section from the diagenetic Alpine foreland (Tabular Jura and borehole samples beneath the Molasse Basin) to the anchi- and epimetamorphic Helvetic Zone of the Central Alps. Concentrates and thin sections were investigated by microscopic, X-ray, infrared, Mössbauer, thermal (DTA and TG), wet chemical, electron microprobe, K-Ar, Rb-Sr, 40Ar/39Ar and stable isotope methods.With increasing metamorphic grade based on illite crystallinity data (XRD and IR) the following continuous changes are observed: (i) the 1Md2M1 polymorph transformation is completed in the higher grade anchizone; (ii) K2O increases from 6–8 wt. % (diagenetic zone) to 8.5–10% (anchizone) to 10–11.5% (epizone), reflecting an increase in the total negative layer charge from 1.2 to 2.0; (iii) a decrease of the chemical variation of the mica population with detrital muscovite surviving up to the anchizone/ epizone boundary; iv) a shift of an endothermic peak in differential thermal curves from 500 to 750° C; (v) K-Ar and Rb-Sr apparent ages of the fraction <2 m decrease from the diagenetic zone to the epizone, K-Ar ages being generally lower than Rb-Sr ages. The critical temperature for total Ar resetting is estimated to be 260±30° C. K-Ar and Rb-Sr ages become concordant when the anchizone/ epizone boundary is approached. The stable isotope data, on the other hand, show no change with metamorphic grade but are dependent on stratigraphic age.These results suggest that the prograde evolution from 1 Md illite to 2M1 muscovite involves a continuous lattice restructuration without rupture of the tetrahedral and octahedral bonds and change of the hydroxyl radicals, however this is not a recrystallization process. This restructuration is completed approximately at the anchizone/epizone boundary. The isotopic data indicate significant diffusive loss of 40Ar and 87Sr prior to any observable lattice reorganization. The restructuration progressively introduces a consistent repartition of Ar and K in the mineral lattices and is outlined by the 40Ar/39Ar age spectra.Concordant K-Ar and Rb-Sr ages of around 35-30 Ma. with concomitant concordant 40Ar/39Ar release spectra are representative for the main phase of Alpine metamorphism (Calanda phase) in the Glarus Alps. A second age group between 25 and 20 Ma. can probably be attributed to movements along the Glarus thrust (Ruchi phase), while values down to 9 Ma., in regions with higher metamorphic conditions, suggest thermal conditions persisting at least until the middle Tortonian.  相似文献   

11.
Detailed Rb-Sr and Sm-Nd isotopic analyses have been completed on the lherzolitic shergottites ALH77005 and LEW88516. ALH77005 yields a Rb-Sr age of 185 ± 11 Ma and a Sm-Nd age of 173 ± 6 Ma, whereas the Rb-Sr and Sm-Nd ages of LEW88516 are 183 ± 10 and 166 ± 16 Ma, respectively. The initial Sr isotopic composition of ALH77005 is 0.71026 ± 4, and the initial εNd value is +11.1 ± 0.2. These values are distinct from those of LEW88516, which has an initial Sr isotopic composition of 0.71052 ± 4 and an initial εNd value of +8.2 ± 0.6. Several of the mineral and whole rock leachates lie off the Rb-Sr and Sm-Nd isochrons, indicating that the isotopic systematics of the meteorites have been disturbed. The Sm-Nd isotopic compositions of the leachates appear to be mixtures of primary igneous phosphates and an alteration component with a low 143Nd/144Nd ratio that was probably added to the meteorites on Mars. Tie lines between leachate-residue pairs from LEW88516 mineral fractions and whole rocks have nearly identical slopes that correspond to Rb-Sr ages of 90 ± 1 Ma. This age may record a major shock event that fractionated Rb/Sr from lattice sites located on mineral grain boundaries. On the other hand, the leachates could contain secondary alteration products, and the parallel slopes of the tie lines could be coincidental.Nearly identical mineral modes, compositions, and ages suggest that these meteorites are very closely related. Nevertheless, their initial Sr and Nd isotopic compositions differ outside analytical uncertainty, requiring derivation from unique sources. Assimilation-fractional-crystallization models indicate that these two lherzolitic meteorites can only be related to a common parental magma, if the assimilant has a Sr/Nd ratio near 1 and a radiogenic Sr isotopic composition. Further constraints placed on the evolved component by the geochemical and isotopic systematics of the shergottite meteorite suite suggest that it (a) formed at ∼4.5 Ga, (b) has a high La/Yb ratio, (c) is an oxidant, and (d) is basaltic in composition or is strongly enriched in incompatible elements. The composition and isotopic systematics of the evolved component are unlike any evolved lunar or terrestrial igneous rocks. Its unusual geochemical and isotopic characteristics could reflect hydrous alteration of an evolved Martian crustal component or hydrous metasomatism within the Martian mantle.  相似文献   

12.
The results of the K-Ar, Rb-Sr, and U-Pb (SHRIMP zircon method) dating of the Middle Paleozoic volcanogenic rocks of the Omolon Massif are summarized. It was concluded that they are principally consistent with each other, as well as with the geological data. The formation of the Kedon Group, which makes up the main volume of the Middle Paleozoic volcanics, began at the Early-Middle Devonian boundary about 400 Ma ago (U-Pb dates of 400.5 ± 4.4 and 387 ± 6.4; Rb-Sr isochron age of 402 ± 6 Ma). The isotopic age of the upper boundary of the Kedon Group remains unclear due to disagreements concerning its stratigraphic assignment. The histogram based on the 111 K-Ar dates of the volcanic rocks from the Kedon Group gives a polymodal distribution, which indicates that the K-Ar isotopic system was disturbed by thermal events, which occurred 310–290 (terminal Carboniferous—beginning of the Permian) and 240–220 (Middle-beginning of the Late Triassic) Ma ago. Both thermal events were associated with mantle (ultrabasic-basic) magmatism, which spanned a significantly wider territory than the distribution area of the Kedon Group  相似文献   

13.
石广仁 《沉积学报》2007,25(5):693-700
提出了改进的溶解沉淀数学模型，在塔里木盆地塔中4井应用获得成功。该井石炭系的实例表明:该模型在粘土矿物内的模拟结果，与K Ar定年分析吻合，并接近于粘土矿物分析数据。实例指出:在较早提出的化学动力学模型、新近提出的溶解沉淀模型中，最敏感的参数都是活化能；将粘土矿物分析数据作为约束条件来校准活化能，是获得正确的蒙皂石史和伊利石史之关键。采用最佳活化能计算，可获得最佳模拟结果:①算出的伊利石开始生长的年代与K Ar定年分析吻合；②模拟结果与粘土矿物分析数据接近。通过实例还发现:溶解沉淀模型仅适用于粘土矿物内的转化问题，而化学动力学模型仅适用于伊/蒙间层内的转化问题。  相似文献   

14.
The intrusive rocks associated with the large Nezhdaninka gold deposit (Au > 470 t) hosted in the Permian carbonaceous terrigenous sequence have been dated on zircon and rock-forming minerals with precision U-Pb (ID-TIMS) and Rb-Sr methods. The lamprophyre of the dike complex that occurs in the ore field and spatially is related to gold mineralization has concordant U-Pb zircon age (121 ± 1 Ma) and the same isochron Rb-Sr age (121.0 ± 2.8 Ma). The concordant U-Pb zircon age of granodiorite that dominates in the Kurum pluton is 94 ± 1 Ma, whereas the Rb-Sr isochron age of various intrusive rocks from this pluton is 1–4 Ma younger. This difference is caused by long-term cooling of the Kurum pluton and later closure of Rb-Sr isotopic system of biotite (300–350°C) and other rock-forming minerals as compared with U-Pb isotopic system of zircon (～ 900°C). The Rb-Sr age of quartz diorite from the Gel’dy group of stocks (92.6 ± 0.8 Ma) coincides within uncertainty limits with the age of the Kurum pluton. Thus, the rocks pertaining to two epochs of magmatic activity, which developed in the South Verkhoyansk Foldbelt and divided by a time span of 25–28 Ma, are documented in the Nezhdaninka ore field. Taking into account that the age of gold mineralization is no less than 120 Ma, the data obtained allow us to specify the previously proposed formation model of the Nezhdaninka deposit. These data give grounds to rule out the Late Cretaceous Kurum pluton and the Gel’dy group of stocks from constituents of the ore-magmatic system, and to suggest that an Early Cretaceous deep-seated magma source existed beneath the deposit. Along with host terrigenous rocks, this magma source participated in the supply of matter to the hydrothermal system. The Nd, Sr, and Pb isotopic systematics of igneous rocks and ore mineralization in the Nezhdaninka ore field show that the Early and Late Cretaceous magma sources were formed in the Precambrian crust dated at ～1.8 Ga.  相似文献   

15.
This paper presents the results of structural, lithologic, and geochronological (K-Ar, Rb-Sr) studies of the Carnian terrigenous rocks in the sedimentary cover of the Chukchi microcontinent and U-Pb dating of detrital zircons. From the lithological features, three types of sections are recognized. Terrigenous sequences of the first type were deposited on the outer shelf in the distal zone of the prograding delta, sequences of the second type accumulated at the rise of continental slope, and sediments of the third type are characteristic of the pelagic zone. In mineralogy and geochemistry, sandstones are rather uniform and inherit the sialic composition of provenance. The detrital zircons comprise several populations with predominance of the varieties derived from igneous rocks. The U-Pb age of the youngest population is 236–255 Ma. The conditions of postsedimentation alteration reached those of greenschist metamorphic facies and anchimetamorphism. Several cleavage systems have been established. Sericite related to the oldest system is distinguished by elevated Ti, Mn, and Fe components. The first stage of deformation of the Carnian sedimentary rocks about 200 Ma ago resulted in the rearrangement of K-Ar and Rb-Sr isotopic systems in whole-rock samples and minerals and is clearly recorded in isotopic data. It is suggested that the deformation related to the normal faulting in Triassic rocks and the emergence of the Lesser Anyui Block were plausible causes of the first structural rearrangement.  相似文献   

16.
An isotopic dating investigation (66 K-Ar and 34 Rb-Sr analyses) provided the geochronological framework for the Alpine events of metamorphism and granitic magmatism on Naxos. The oldest phase of high-pressure/medium-temperature metamorphism, M1, was dated by Rb-Sr and K-Ar analyses of paragonites, phengitic muscovites and muscovites at 45±5 Ma (Middle Eocene). Most of the record of the M1 phase has been eraded by a second phase of medium-pressure/high-temperature metamorphism, M2, which induced a metamorphic zonation with anatectic melting in the highest-grade part, the migmatite dome. Most K-Ar dates of M2 hornblendes, muscovites, biotites and tourmalines range from about 21 Ma in the lower-grade part (biotite-chloritoid zone) to about 11 Ma in the migmatite dome. From the pattern of K-Ar mineral dates it is concluded that the M2 phase took place 25±5 Ma ago (Late Oligocene/Early Miocene) and was followed by a prolonged cooling history until about 11 Ma ago (Late Miocene), when the ambient temperature in the migmatite dome had decreased to below 400–360 °C. A Rb-Sr whole-rock isochron analysis of a granodioritic mass dated the intrusion (and the associated M3 phase of contact-metamorphism) at 11.1±0.7 Ma (Late Miocene), with an initial 87Sr/86Sr ratio of 0.7112 ±0.0001. A local phase of low-grade retrograde metamorphism, M4, probably related to Late Alpine overthrusting, was dated at about 10 Ma (Late Miocene).  相似文献   

17.
Precambrian granitic basement rocks obtained from well BH-36 of Bombay High Field, western offshore of India has been studied both by Rb-Sr and K-Ar dating methods. Seven basement samples chosen from two cores have yielded whole rock Rb-Sr isochron age of 1446 ± 67 Ma with an initial87Sr/86Sr ratio of 0.7062 ± 0.0012. This age has been interpreted as the formation/emplacement time of the granite. Two biotite fractions of different grain size separated from a sample CC6B2T have yielded Rb-Sr mineral isochron age of 1385 ± 21 Ma. However, these fractions when studied by K-Ar dating method have yielded slightly higher but mutually consistent ages of 1458 ± 43 Ma and 1465 ± 43 Ma, respectively. Further, two biotites separated from additional samples CC5B9T and CC6B3B have yielded K-Ar ages of 1452 ± 42 Ma and 1425 ± 40 Ma with an overall mean age of 1438 ± 19 Ma. This mean K-Ar age is indistinguishable from whole rock Rb-Sr isochron as well as mineral isochron age within experimental error. The similarity in the whole rock and biotite ages obtained by different isotopic methods suggests that no thermal disturbance has occurred in these rocks after their emplacement/formation around 1450 Ma ago. The present study provides the evidence for the existence of an important Middle Proterozoic magmatic event around 1400-1450 Ma on the western offshore of India which, hitherto, was thought to be mainly confined to the eastern Ghats, Satpura and Delhi fold belt of India. This finding may have an important bearing on the reconstruction of Proterozoic crustal evolution of western Indian shield.  相似文献   

18.
油气成藏过程中的同位素测年方法评述   总被引：1，自引：0，他引：1       下载免费PDF全文
笔者对国内外同位素测定年在确定油气成藏方面的应用现状进行评述的基础上,重点分析了K-Ar法,Ar-Ar法,U-Pb法,Rb-Sr法等方法所存在的问题,认为自生伊利石40Ar-39Ar法在不断克服技术难题之后,仍是油气成藏年代学不可缺少的重要手段;激光微区探针40Ar-39Ar法与流体包裹体技术相结合,是油气多期成藏40Ar-39Ar年代学研究取得成功的突破点;利用沥青和干酪根中微量金属U-Pb,Pb-Pb,Rb-Sr,Sm-Nd和Re-Os体系的同位素分析方法获得油气生成、运移的年龄,是成熟的放射性同位素方法在石油地质学中的应用;晶洞充填物U-Pb测年,可能是碳酸盐岩储层油气成藏年代学研究又一新的突破点.  相似文献   

19.
K–Ar clay fraction ages of brittle faults often vary with grain size, decreasing in the finer size fractions, producing an inclined age–grain‐size spectrum. K–Ar ages and mineralogical characterization of gouges from two normal faults in the Kongsberg silver mines, southern Norway, suggest that inclined spectra derived from brittle fault rocks reflect the mixing of inherited components with authigenic mineral phases. The ages of the coarsest and finest fractions constrain faulting at c. 260–270 Ma and reactivation around 200–210 Ma, respectively. This study demonstrates how wall‐rock contamination influences the K–Ar age of the coarsest size fractions and that authigenic illite and K‐feldspar can crystallize synkinematically under equivalent conditions and thus yield the same K–Ar ages.  相似文献   

20.
Geochronology of Intermediate-Acid Intrusive Rocks from Tongling, Anhui   总被引：7，自引：0，他引：7  
1. Introduction Tongling district is situated in the southern part of the middle-lower reaches of the Yangtze River, Anhui province, China (Fig.1). It is one of the most important metal base in China, being rich copper material resources, also named "ancient copper capital of China". Many geologists have been working in petrology, tectonics and ore-deposits in the area for many years. Studies show none of the ore-deposits is not bound up with the intermediate-acid intrusion in the area (Ma…  相似文献   

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