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1.
微山稀土矿床位于华北克拉通郯庐断裂西侧,为中国第三大碳酸岩型稀土矿床。微山稀土矿床碳酸岩脉具有明显的分带性,共识别出4类不同岩性的碳酸岩脉,并划分了4个岩性带。基于详细的岩相学研究,在含矿碳酸岩脉中识别出4个世代方解石、4个世代氟碳铈矿和3个世代萤石。单矿物原位微区分析结果显示,第一世代方解石(Cal-1)和磷灰石为岩浆成因,而第三世代方解石(Cal-3)为热液成因。矿物地球化学数据显示,萤石可分为岩浆成因(Tb/La值为0.005～0.043)及热液成因(Tb/La值为0.17～0.28)两类。磷灰石富F(含量(质量分数,下同)为3.86%～5.82%)、贫Cl(<0.03%)的地球化学特征表明其为碳酸盐-硅酸盐系列岩浆结晶作用的产物。磷灰石具有较高的Sr/Y、Th/U值,和极高的Sr含量((8 615～19 985)×10-6)、Ba含量((47～107)×10-6),表明微山稀土矿床岩浆源区可能为富集岩石圈地幔,并受到了富稀土元素流体的改造。萤石地球化学特征指示该稀土矿床中的成矿热液源自碳酸岩熔体,且随着成矿流体的演化,成矿环境由... 相似文献
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为了研究漠河盆地中侏罗统漠河组泥岩中微量元素和稀土元素的地球化学特征及其地质意义,采用ICP-MS对研究区内33个泥岩样品进行了微量元素和稀土元素分析,分析结果表明,该地区样品微量元素中Cr、B、Ba等元素的纵向变化较明显,而Ni、Co、Sr、V、Nb、Ta、Th等元素的差异不大,纵向变化不明显;稀土元素总量(∑REE)较低,LREE/HREE、(La/Yb)N、(La/Sm)N、(Gd/Yb)N等值均表明轻重稀土元素分异明显;REE配分模式图显示轻稀土元素(LREE)富集,重稀土(HREE)元素相对亏损,Eu为明显的负异常。对古盐度、Sr/Ba值、V/(V+Ni)值和Ceanom值等特征参数及其垂向变化趋势的研究表明,研究区中侏罗统泥岩处于缺氧、还原、微咸水-半咸水的沉积环境,可以识别出4个层序界面;综合稀土元素组合特征和野外地质调查资料,表明漠河盆地中侏罗世的沉积物源具有多源性,以沉积岩、花岗岩和长英质的变质岩为主,可能混有部分外来的火山物质,这些结论对揭示盆地内物质的组成、古沉积环境的恢复等研究具有重要指示意义。 相似文献
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A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）. 相似文献
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在稀土元素钇、镧共存时 ,以变色酸双偶氮类试剂为显色剂 ,在 pH为 2的介质中 ,加入乙醇 ,利用溶剂化效应 ,提高Y ,La络合物性质的差异 ,从而可在一阶导数光谱上消除La的影响而直接测定Y。测定波长 675nm ,摩尔吸光系数ε为 1 .73× 1 0 4 L·mol- 1 ·cm- 1 ,九次测定变异系数为 1 .92 % ,Y3 含量在 0～ 40 0 μg/L范围内符合比耳定律 ,该方法快速简便 ,适合于矿物原料、钢铁、合金中钇的测定。 相似文献
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何良彪 《中国海洋湖沼学报》1995,13(2):183-190
Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene. 相似文献
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Ten actinomycete strains isolated from the Yellow Sea off China's coasts were identified as belonging to two genera by 16 S r DNA phylogenetic analysis: Streptomyces and Nocardiopsis. Six Streptomyces strains(MA10, 2SHXF01-3, MA35, MA05-2, MA05-2-1 and MA08-1) and one Nocardiopsis strain(MA03) were predicted to have the potential to produce aromatic polyketides based on the analysis of the KSα(ketoacyl-synthase) gene in the type II PKS(polyketides synthase) gene cluster. Four strains(MA03, MA01, MA10 and MA05-2) exhibited significant inhibitory effects on mycelia growth(inhibition rate 50%) and subsequent aflatoxin production(inhibition rate 75%) of the mutant aflatoxigenic Aspergillus parasiticus NFRI-95. The ethyl acetate extracts of the broth of these four strains displayed significant inhibitory effects on mycelia growth, and the IC50 values were calculated(MA03: 0.275 mg m L-1, MA01: 0.106 mg m L-1, MA10: 1.345 mg m L-1 and MA05-2: 1.362 mg m L-1). Five strains(2SHXF01-3, MA03, MA05-2, MA01 and MA08-1) were selected based on their high cytotoxic activities. The ethyl acetate extract of the Nocardiopsis strain MA03 was particularly noted for its high antitumor activity against human carcinomas of the cervix(He La), lung(A549), kidney(Caki-1) and liver(Hep G2)(IC50: 2.890, 1.981, 3.032 and 2.603 μg m L-1, respectively). The extract also remarkably inhibited colony formation of He La cells at an extremely low concentration(0.5 μg m L-1). This study highlights that marine-derived actinomycetes are a huge resource of compounds for the biological control of aflatoxin contamination and the development of novel drugs for human carcinomas. 相似文献
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为厘定塔里木南缘铁克里克东段花岗闪长岩形成时代并探讨岩石成因,开展了地球化学、锆石 UＧPb年代学及 Hf同位素研究.LAＧICPＧMS锆石 UＧPb年代学的结果显示其形成于晚奥陶世(４４４Ma).地球化学数据表明其具有类似于 C型埃达克岩的高Sr及Sr/Y 和(La/Yb)N,低 Y 和 Yb地球化学特征,１７６Hf/１７７Hf和εHf(t)分别介于０．２８２３９７~０．２８２４９７和－３．７~＋０．１之间,富含暗色微粒包体以及高 Mg＃ ,指示其具有一定的幔源岩浆印记,可能是玄武质下地壳部分熔融过程中加入一定程度幔源物质,在角闪岩－榴辉岩相条件下部分熔融形成具壳－幔混源特征的富钠、钾 C型埃达克岩.结合区域地质资料认为,铁克里克岩体形成于活动大陆边缘环境。 相似文献
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伊宁地块南构造带出露大面积的晚泥盆世—早石炭世岩浆岩,其形成与南天山洋演化密切相关,在岩石成因与产出环境方面尚存争议。在伊宁地块南构造带科克苏林场一带新发现了赋存于下石炭统大哈拉军山组火山岩中的高镁安山岩,对其进行了详细的野外地质调查和室内分析工作,并探讨了该时期的大地构造背景。结果表明：区内大哈拉军山组岩石类型以安山岩类为主,含少量玄武岩及火山碎屑岩;安山岩样品具有高的MgO、TiO2、Al2O3含量和低的P2O5含量、里特曼指数,表现出中—高钾钙碱性系列岩石特征,结合其高的Sr、Y含量和低的Ni、Co含量,低的Sr/Y、La/Yb值,呈现出赞岐质高镁安山岩的地球化学特征;样品的稀土元素总含量变化范围大,具有高的(La/Yb)N、(La/Sm)N和(Gd/Yb)N值,显示出轻稀土元素显著富集特征;样品富集K、Ba、Th、U、Pb等大离子亲石元素,相对亏损Nb、Ta、Ti、P等高场强元素和负的Eu异常。结合区域资... 相似文献
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宁蒗地区中泥盆统大槽子组页岩地球化学特征及地质意义 总被引：1，自引：1，他引：0
《东北石油大学学报》2020,(2)
为评价宁蒗地区中泥盆统大槽子组页岩气资源潜力,选择4条典型泥盆系剖面(大槽子剖面、三股水剖面、野麻地剖面、岩口剖面),在地质调查基础上,对页岩样品进行矿物、微量元素分析和有机地球化学测试。结果表明:宁蒗地区中泥盆统大槽子组富有机质页岩为陆棚沉积,岩性主要为黑色富有机质页岩,主要矿物成分为石英及黏土矿物。研究区大槽子组页岩TOC质量分数多数大于1.0%,镜质体反射率介于1.23%～2.31%,有机质类型表现为Ⅱ_1型—Ⅱ_2型。V/(V+Ni)、V/Cr及U/Th指示研究区大槽子组页岩形成于缺氧—厌氧环境沉积。在宁蒗地区4个剖面控制区域中,野麻地剖面—岩口剖面一线具有较好的勘探潜力,大槽子剖面—三股水剖面一线勘探潜力较差。 相似文献
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ZHANG Dan ZHANG Yu MORAWSKA Ewa BIELAWSKI Leszek KRASINSKA Grazyna DREWNOWSKA Ma gorzata PANKAVEC Sviatlana SZYMANSKA Karolina FALANDYSZ Jerzy 《山地科学学报》2013,10(4):621-627
In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively. 相似文献
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Based on the hydrographic data in austral summer during the 22nd Antarctic Expedition of China(2005/2006),some features can be found about the northern margin of Emery ice shelf as follows.The heat content in the surface layer(0-50 m) at the eastern end and the western end of the ice-shelf margin is much higher than that at the middle.The upper mixing-layer depth and the seasonal thermocline depth at the middle of the ice-shelf northern margin are much shallower than those at the both ends.However there is much less difference between the middle and the ends in the bottom layer.The remote sensing photos show that the inhomogeneity in the surface-layer water is closely related to the spatial distribution of the floes and polynia in the area. 相似文献
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Phylogenetic analysis based on 16S rDNA of 8 strains of cultivable bacteria isolated from Arctic sea-ice was studied.The results showed that strain BJ1 belonged to genus Planococcus,which was a genus of low mole percent G C gram-positive bacteria;strain BJ6 belonged to genus Burkholderia of β-proteobacteria and the rest 6 strain all belonged to γ-proteobacteria,of which strain BJ8 was a species of Pseudoalteromonas,strain BJ2-BJ5 and BJ7 were members of genus Psychrobacter.Phylogenetic analysis also indicated that bacteria of genus Psychrobacter of the isolates formed a relatively independent phylogenetic cluster in comparison with other bacteria belonged to genus Psychrobacter. 相似文献
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《极地研究(英文版)》2014,(3)
正1 Aims and Scope Advances in Polar Science(APS)is an international,peer-reviewed journal jointly sponsored by the Polar Research Institute of China and the Chinese Arctic and Antarctic Administration.APS is a comprchensive academic journal dedicated to presentation of multi-disciplinary achievements in Arctic and Antarctic expeditions and research.Its primary purpose is to publish achievements in fundamental research,applied 相似文献
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《山地科学学报》2014,(4):I0004-I0009
<正>AIMS AND SCOPE(Editorial Policy)The Journal of Mountain Science(JMS)is devoted to mountains and their surrounding lowlands-ecoregions of particular global importance,with a particular emphasis on the important highlands/mountains in the world,such as the Tibetan Plateau,the Himalayas,the Alps,the Andes,the Rockies and many other mountain ranges of our planet. 相似文献
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《山地科学学报》2014,(4)
<正>The Journal of Mountain Science(JMS),founded in2004,is an international English-language journal on mountain sciences.JMS is supervised by the Chinese Academy of Sciences(CAS),sponsored by the Chengdu Institute of Mountain Hazards and Environment,CAS,published by Science Press China,and distributed by Springer exclusively throughout the world(excluding Mainland China).The JMS is published bimonthly,fulltexted in SpringerLink and CNKI,indexed/abstracted by 相似文献
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References： 《极地研究(英文版)》2007,18(1):73-83
Using the NCEP/NCAR reanalysis monthly 500 hPa height data on a 2.5 latitude-longitude grid and 1°×1° sea ice data,the polar vortex area,intensity index and arctic sea ice area index are calculated respectively,and the meridional distribution,period variation and the abrupts in the long range trend are analyzed to study their relationship.The results show that the meridional distribution of sea ice and polar vortex h-ave distinctive difference,the relative positions of them are different in the eastern and western hemispheres,and exept they have periods of 4 months,quasi half year,quasi year,4-5 years and 10 years commonly,and each of them has its own respective variation as well.The sea ice area is decreasing apparently since 1980's,so is the polar vortex area,but their abrupt changge time are different totally.The area of sea ice and polar vortex has prominent positive correlation,but the relationship of sea ice intensity,polar vortex intensity,polar vortex area is complicated. 相似文献
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《中国海洋大学学报(英文版)》2014,(3):I0001-I0001
<正>The Journal of Ocean University of China(Oceanic and Coastal Sea Research)is a comprehensive academic quarterly sponsored by the Ocean University of China,published one volume per year.This journal is devoted to the publication of the theoretical and applied research 相似文献