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1.
We investigated several mineral phases and their replacement products which occur as inclusions in garnets from felsic and mafic granulites of the Gföhl Unit in the Moldanubian Zone. The most important mineral inclusions, Ti-rich muscovite and omphacite, were used for the reconstruction of the metamorphic history of granulites. Some inclusions were transformed during high-temperature granulite facies metamorphism, partial melting and decompression to other phases, and so the original mineral can only be deduced from the inclusion morphology and reaction products. These inclusions have columnar shapes and consist of K-feldspar + kaolinite, albite + Fe-oxide, plagioclase + Fe-oxide, or albite + K-feldspar, respectively. The pseudomorphs with albite/plagioclase occur in a Ca-rich garnet that shows prograde zoning. Pressure–temperature (PT) evolution, derived from mineral assemblages in granulite and based on the inclusions, suggests a prograde metamorphism from amphibolite through eclogite to granulite facies conditions with subsequent amphibolite facies overprint during exhumation. The estimated PT trajectory for the studied granulites, which also host lenses or boudins of eclogites and garnet peridotites, allows reconstruction of the complete clockwise metamorphic path that is consistent with subduction geotherm prior to the tectonic amalgamation within the continental collisional root.  相似文献   

2.
Several metamorphic complexes in Southeast Asia have been interpreted as Precambrian basement, characterized by amphibolite to granulite facies metamorphism. In this paper, we re-evaluate the timing of this thermal event based on the large-scale geochronology and compositional variation of monazites from amphibolite to granulite facies metamorphic terranes in central Vietnam. Most of the samples in this study are from metamorphic rocks (n = 38) and granitoids (n = 11) in the Kontum Massif. Gneisses (n = 6) and granitoids (n = 5) from the Hai Van Migmatite Complex and the Truong Son Belt, located to the north of the massif, were also studied. Two distinct thermal episodes (245–230 Ma and 460–430 Ma) affected Kontum Massif gneisses, while a single dominant event at 240–220 Ma is recorded in the gneisses from the Hai Van Complex and the Truong Son Belt. Monazites from granitoids commonly yield an age of 240–220 Ma. Mesoproterozoic ages (1530–1340 Ma) were obtained only from monazite cores that are surrounded by c. 440 Ma overgrowths. Thermobarometric results, combined with concentrations of Y2O3, Ce2O3, and heavy rare earth elements in monazite, and recently reported pressure–temperature paths suggest that Triassic ages correspond to retrograde metamorphism following decompression from high- to medium-pressure/temperature conditions. Ordovician–Silurian ages reflect low-pressure/temperature metamorphism accompanied by isobaric heating during prograde metamorphism. Some samples were affected by both metamorphic events. We conclude that high-grade metamorphism observed in so-called Precambrian basement terranes in central Vietnam occurred during both the Permian–Triassic and the Ordovician–Silurian, while peraluminous granitoid magmatism is Triassic. Additionally, our preliminary analyses for U–Pb zircon age and whole-rock chemistry of granitic gneisses from the Truong Song Belt suggests the presence of the Ordovician–Silurian volcanic arc magmatism in the region. Based on the pressure–temperature–time–protolith evolutions, metamorphic rocks from central Vietnam provide a continuous record of subduction–accretion–collision tectonics between the South China and Indochina blocks: in the Ordovician–Silurian, the region was characterized by active continental margin tectonics, followed by continental collision during the Late Permian to Early Triassic and subsequent exhumation during the Late Triassic. The results also suggest that the timing of metamorphism and protolith formation as well as the geochemical features in other Southeast Asian terranes should be verified to achieve a better understanding of the Precambrian to Early Mesozoic tectonic history in Asia.  相似文献   

3.
The high-grade metamorphic terrane in the Badu region along the northeastern Cathaysia Block in South China preserves retrograded eclogites and mafic granulites. Here we present the petrology, mineral phase equilibria and P-T conditions based on pseudosection computations, as well as zircon U-Pb ages of these rocks. Mineral textures and reaction relationships suggest four metamorphic stages for the retrograded eclogite as follows: (1) eclogite facies stage (M1), (2) clinopyroxene retrograde stage (M2), (3) amphibole retrograde stage (M3), and (4) chlorite retrograde stage (M4). For the mafic granulite, three stages are identified as: (1) plagioclase-absent stage (M1), (2) granulite facies stage (M2) and (3) amphibolite facies stage (M3). Metamorphic evolution of both of the rock types follows clockwise P-T path. Conventional geothermometers and geobarometers in combination with phase equilibria modelling yield metamorphic P-T conditions for each metamorphic stage for the eclogite as 500–560 °C, 23–24 kbar (M1), 640–660 °C, 14–16 kbar (M2), 730–750 °C, and 11–13 kbar (M3). The chlorite retrograde stage (M4) is inferred to have occurred at lower amphibolite to greenschist facies conditions. Phase equilibria modelling of the mafic granulite shows P-T conditions for each metamorphic stage as 600–720 °C, > 13 kbar (M1) and 860–890 °C, 5–6 kbar (M2) and M3 at amphibolite facies conditions. LA-ICPMS zircon U-Pb dating and trace element analysis show that the high pressure metamorphism occurred at 245–251 Ma. Protolith age of the mafic granulite is 997 Ma, similar to that of the mafic to ultramafic rocks widely distributed in the Cathaysia Block and also along the Jiangnan belt. Subduction of ancient oceanic lithospheric materials (or crustal thickening) during Mesozoic and formation of eclogites suggest that the Cathaysia Block was perhaps in the Tethyan oceanic domain at this time. The granulite formation might have been aided by Mesozoic mafic magma underplating associated with lithospheric delamination, heating and retrogression of the eclogite accompanied by rapid uplift.  相似文献   

4.
The Salvador–Curaçá Belt, located in São Francisco Craton, Brazil, was subjected to granulite facies metamorphism during the Paleoproterozoic orogeny (c. 2.0 Ga). Well preserved in enclaves of silica-undersaturated sapphirine-bearing granulite occur in a charnockite outcrop located along a kilometric-scale shear zone. The sapphirine-bearing granulite preserves domains with distinct mineral assemblages that record interactions between melt and peritectic phases (orthopyroxene1 + spinel1 + biotite1). Sapphirine was crystallized in the Si-poor cores of the enclaves, sillimanite and spinel–cordierite symplectites in the intermediate Si-rich domains between cores and margins, and garnet and quartz-bearing cordierite/biotite symplectites in Si-rich margins of the enclaves. Melt-rock interactions and metamorphism occurred at ultrahigh temperatures of 900–950 °C at 7.0–8.0 kbar pressures. The mineralogical evolution of the domains reflects not only the influence of changes in bulk composition in the equilibrium volume of the reactions but also P–T changes during orogeny evolution. Electron microprobe dating of monazite both in the sapphirine-bearing granulite and charnockite indicates UHT metamorphism timing at c. 2.08–2.05 Ga that is related to global Paleoproterozoic UHT metamorphic events that occurred during the Columbia supercontinent assembly.  相似文献   

5.
A typical Algoma-type banded iron formation (BIF) occurs in Orvilliers, Montgolfier, and Aloigny townships in the Abitibi Greenstone belt, Quebec, Canada. The BIF is composed of millimeter to decimeter thick beds of alternating fine-grained, dark gray to black, well laminated, magnetite-rich (and/or hematite) beds and quartz–feldspar metasedimentary (graywacke) beds. The BIF is well defined by magnetic anomalies. These BIF layers are commonly associated with decimeter to meter thick horizons of metasedimentary rocks and mafic to intermediate volcanic rocks, which are locally crosscut by dikes of felsic or mafic intrusive rocks and, as well, narrow dikes of lamprophyre. The upper and lower contacts of the BIF are gradational with the adjacent graywacke. All geological units in the area are metamorphosed to the greenschist facies of regional metamorphism. Magnetite is mainly associated with subordinate amounts of hematite, quartz, Na-rich plagioclase, and muscovite. The fine-grained magnetite content is composed of 77% to 89% of the principal iron oxide minerals present. The magnetite occurs as disseminated idiomorphic to sub-idiomorphic small crystals, which average 20 μm ± 5 μm in size. Hematite is the second most abundant iron oxide mineral. Although less abundant, red jasper occurs in cherty horizons with strongly folded fragments and within fault zones. This particular Algoma-type iron formation stratigraphically extends more than 36 km along strike. It dips sub-vertically with a true width from 120 m to 600 m. The origin of the BIF is closely linked to regionally extensive submarine hydrothermal activity associated with the emplacement of volcanic and related subvolcanic rocks in an Archean greenstone belt.  相似文献   

6.
Following ultrahigh temperature granulite metamorphism at ∼1 Ga, the Eastern Ghats Province of India was intruded by the Koraput Alkaline Complex, and was subsequently re-metamorphosed in the granulite facies in the mid-Neoproterozoic time. Fluid inclusion studies were conducted on silica undersaturated alkali gabbro and syenites in the complex, and a pre-metamorphic pegmatitic granite dyke that intrudes it. High density (1.02–1.05 g/cc), pseudo-secondary pure CO2 inclusions are restricted to metamorphic garnets within the gabbro and quartz within the granite, whereas moderate (∼0.92–0.95 g/cc) and low density (∼0.75 g/cc) secondary inclusions occur in garnet, magmatic clinopyroxene, plagioclase, hornblende and quartz. The isochores calculated for high density pseudo-secondary inclusions pass very close to the peak metamorphic window (∼8 kbar, 750 °C), and are interpreted to represent the fluid present during peak metamorphism that was entrapped by the growing garnet. Microscopic round inclusions of undigested, relict calcite in garnet suggest that the CO2 present during metamorphism of the complex was internally derived through carbonate breakdown. Pure to low salinity (0.00–10.1 wt% NaCl equivalent) aqueous intra-/intergranular inclusions showing unimodal normal distribution of final ice-melting temperature (Tm) and temperature of homogenization (Th) are present only in quartz within the granite. These represent re-equilibrated inclusions within the quartz host that were entrapped at the metamorphic peak. Rare, chemically precipitated graphite along the walls of carbonic inclusions is interpreted as a post-entrapment reaction product formed during decompression. The fluid inclusion evidence is consistent with rapid exhumation of a thickened lower crust following the mid-Neoproterozoic granulite facies metamorphic event. The study suggests that mantle CO2, transported by alkaline magma into the crust, was locked up within carbonates and released during granulite metamorphism.  相似文献   

7.
The Eastern Ghats Frontal Thrust (EGFT) demarcates the boundary between the Archaean/Paleoproterozoic cratonic rocks to the west, and the Meso/Neoproterozoic granulites of the Eastern Ghats Mobile Belt (EGMB) to the east. At Jeypore (Orissa, India), mafic schists and granites of the cratonic domain document a spatial increase in the metamorphic grade from greenschist facies (garnet, clinozoisite – absent varieties) in the foreland to amphibolite facies (clinozoisite- and garnet-bearing variants) progressively closer to the EGFT. Across the EGFT, the enderbite–charnockite gneisses and mafic granulites of EGMB preserves a high-grade granulite facies history; amphibolite facies overprinting in the enderbite–charnockite gneisses at the cratonic fringe is restricted to multi-layered growth of progressively Al, Ti – poor hornblende at the expense of pyroxene and plagioclase. In associated mafic granulites, the granulite facies gneissic layering is truncated by sub-centimeter wide shear bands defined by synkinematic hornblende + quartz intergrowth, with post-kinematic garnet stabilized at the expense of hornblende and plagioclase. Proximal to the contact, these granulites of the Eastern Ghats rocks are intruded by dolerite dykes. In the metadolerites, the igneous assemblage of pyroxene–plagioclase is replaced by intergrown hornblende + quartz ± calcite that define the thrust-related fabric and are in turn mantled by coronal garnet overgrowth, while scapolite is stabilized at the expense of recrystallized plagioclase and calcite. Petrogenetic grid considerations and thermobarometry of the metamorphic assemblages in metadolerites intrusive into granulites and mafic schists within the craton confirm that the rocks across the EGFT experienced prograde heating (Tmax value ∼650–700 °C at P ∼ 6–8 kbar) along the prograde arm of a seemingly clockwise P–T path. Since the dolerites were emplaced post-dating the granulite facies metamorphism, the prograde heating is correlated with renewed metamorphism of the granulites proximal to the EGFT. A review of available age data from rocks neighboring the EGFT suggests that the prograde heating of the cratonic granites and the re-heating of the Eastern Ghats granulites are Pan – African in age. The re-heating may relate to an Early Paleozoic Pan-Gondwanic crustal amalgamation of older terrains or reactivation along an old suture.  相似文献   

8.
Much of the exposed Archean crust is composed of composite gneiss which includes a large proportion of intermediate to tonalitic material. These gneiss terranes were typically metamorphosed to amphibolite to granulite facies conditions, with evidence for substantial partial melting at higher grade. Recently published activity–composition (a?x) models for partial melting of metabasic to intermediate compositions allows calculation of the stable metamorphic minerals, melt production and melt composition in such rocks for the first time. Calculated P?T pseudosections are presented for six bulk rock compositions taken from the literature, comprising two metabasic compositions, two intermediate/dioritic compositions and two tonalitic compositions. This range of bulk compositions captures much of the diversity of rock types found in Archean banded gneiss terranes, enabling us to present an overview of metamorphism and partial melting in such terranes. If such rocks are fluid saturated at the solidus, they first begin to melt in the upper amphibolite facies. However, at such conditions, very little (< 5%) melt is produced and this melt is granitic in composition for all rocks. The production of greater proportions of melt requires temperatures ～800–850 °C and is associated with the first appearance of orthopyroxene at pressures below 8–9 kbar or with the appearance and growth of garnet at higher pressures. The temperature at which orthopyroxene appears varies little with composition providing a robust estimate of the amphibolite–granulite facies boundary. Across this boundary, melt production is coincident with the breakdown of hornblende and/or biotite. Melts produced at granulite facies range from tonalite–trondhjemite–granodiorite for the metabasic protoliths, granodiorite to granite for the intermediate protoliths and granite for the tonalitic protoliths. Under fluid‐absent conditions the melt fertility of the different protoliths is largely controlled by the relative proportions of hornblende and quartz at high grade, with the intermediate compositions being the most fertile. The least fertile rocks are the most leucocratic tonalites due to their relatively small proportions of hydrous mafic phases such as hornblende or biotite. In the metabasic rocks, melt production becomes limited by the complete consumption of quartz to higher temperatures. The use of phase equilibrium forward‐modelling provides a thermodynamic framework for understanding melt production, melt loss and intracrustal differentiation during the Archean.  相似文献   

9.
The Urals VMS province comprises a broad spectrum of variably metamorphosed deposits, from unmetamorphosed to those without any primary ore textures, which are the results of high-grade metamorphic processes. Contact metamorphism near large granite and granodiorite plutons caused the most significant changes of ores, with coarse-grained to pegmatoidal ores with magnetite closest to its contact with the intrusion, followed by pyrrhotite-enriched copper ores, and more distal zinc (± Pb ± Ag) mineralisation. Koktau, Tarnyer and Vesenneye deposits are metamorphosed to the hornblende-hornfels and pyroxene-hornfels facies (t = 400–800 °C, P = 1–6 kbar). Metamorphism of Tash-Yar, Dzhusinskoe and Krasnogvardeiskoe deposits corresponds to the greenschist and albite-epidote-hornfels facies (t = 250–450 °C, P = 1–4 kbar).The regional metamorphism of VMS ores varies from prehnite-pumpellyite facies (t = 150–300 °C, P = 0.5–4 kbar) in the South Urals to the epidote-amphibolite and amphibolite facies (t = 400–600 °C (up to 700 °C), P = 1–6 kbar) in the Karabash area in the Middle Urals. In the Magnitogorsk zone, the metamorphism of host rocks and VMS bodies increases to the north, reaching its peak near the Ufa promontory of the East European platform. With increased metamorphism, the morphology of orebodies evolves from gently dipping thick lenses (Alexandrinskoe and Uzelga fields), to subvertical and folded (Uchaly and Novo-Uchaly deposits) and pseudomonoclinal steeply-dipping vein-like bodies (Karabash district).The massive sulphide transformation in PTX-gradient fields led to partial redistribution of ore material. An enrichment in Cu, Zn, Ag and Au, ± Pb occur in the uppermost parts of large steeply-dipping massive sulphide lenses in wide tectonic zones (e.g., Gai deposit) or as gold-sulphide disseminated bodies near large metamorphosed VMS lenses, distal to a granite pluton (Tarnyer deposit). Partial melting probably occurred in some highly metamorphosed deposits (Tarnyer, Koktau and Mauk). Redeposition of base metals sulphides (chalcopyrite, tennantite, sphalerite, ± bornite, galena), as well as the presence of “visible” gold and tellurides, took place during retrograde metamorphism, which produced a transfer of ore matter towards the low stress areas, such as the outer parts of shear zones, the uppermost parts of steeply-dipping ore lenses, pressure shadows, hinge zones of small folds, and small extension fractures (i.e., Alpine-type veins) in deformed ore body or its immediate surroundings.  相似文献   

10.
Oxide–sulphide–Fe–Mg–silicate and titanite–ilmenite textures as well as their mineral compositions have been studied in felsic and intermediate orthogneisses across an amphibolite (north) to granulite facies (south) traverse of lower Archean crust, Tamil Nadu, south India. Titanite is limited to the amphibolite facies terrane where it rims ilmenite or occurs as independent grains. Pyrite is widespread throughout the traverse increasing in abundance with increasing metamorphic grade. Pyrrhotite is confined to the high‐grade granulites. Ilmenite is widespread throughout the traverse increasing in abundance with increasing metamorphic grade and occurring primarily as hemo‐ilmenite in the high‐grade granulite facies rocks. Magnetite is widespread throughout the traverse and is commonly associated with ilmenite. It decreases in abundance with increasing metamorphic grade. In the granulite facies zone, reaction rims of magnetite + quartz occur along Fe–Mg silicate grain boundaries. Magnetite also commonly rims or is associated with pyrite. Both types of reaction rims represent an oxidation effect resulting from the partial subsolidus reduction of the hematite component in ilmenite to magnetite. This is confirmed by the presence of composite three oxide grains consisting of hematite, magnetite and ilmenite. Magnetite and magnetite–pyrite micro‐veins along silicate grain boundaries formed over a wide range of post‐peak metamorphic temperatures and pressures ranging from high‐grade SO2 to low‐grade H2S‐dominated conditions. Oxygen fugacities estimated from the orthopyroxene–magnetite–quartz, orthopyroxene–hematite–quartz, and magnetite–hematite buffers average 2.5 log units above QFM. It is proposed that the trends in mineral assemblages, textures and composition are the result of an external, infiltrating concentrated brine containing an oxidizing component such as CaSO4 during high‐grade metamorphism later acted upon by prograde and retrograde mineral reactions that do not involve an externally derived fluid phase.  相似文献   

11.
《Gondwana Research》2014,25(2):585-613
The Belomorian eclogite province was repeatedly affected by multiple deformation episodes and metamorphism under moderate to high pressure. Within the Gridino area, high pressure processes developed in a continental crust of tonalite–trondhjemite–granodiorite (TTG) affinity that contains mafic pods and dykes, in which products of these processes are most clearly evident. New petrological, geochemical and geochronological data on mafic and felsic rocks, including PT-estimates, mineral chemistry, bulk rock chemistries, REE composition of the rocks and zircons and U–Pb and Lu–Hf geochronology presented in the paper make it possible to reproduce the magmatic and high-grade metamorphic evolution in the study area. In the framework of the extremely long-lasting geologic history recorded in the Belomorian province (3–1.7 Ga), new geochronological data enabled us to define the succession of events that includes mafic dyke emplacement between 2.87 and 2.82 Ga and eclogite facies metamorphism of the mafic dykes between ~ 2.82 and ~ 2.72 Ga (most probably in the time span of 2.79–2.73 Ga). The clockwise PT path of the Gridino association crosses the granulite- and amphibolite-facies PT fields during the time period of 2.72 Ga to 2.64 Ga. A special aspect of this work concerns the superposed subisobaric heating (thermal impact) with an increase in the temperature to granulite facies conditions at 2.4 Ga. Later amphibolite facies metamorphism occurred at 2.0–1.9 Ga. Our detailed geochronological and petrological studies reveal a complicated Mesoarchaean–Palaeoproterozoic history that involved deep subduction of the continental crust and a succession of plume-related events.  相似文献   

12.
The crystalline basement of the Sierra de San Luis, which belongs to the Eastern Sierras Pampeanas in central Argentina, consists of three main units: (1) Conlara, (2) Pringles, and (3) Nogolí metamorphic complexes. In the Pringles Metamorphic Complex, mafic–ultramafic bodies occur as discontinuous lenses along a narrow central belt concordant with the general NNE–SSW structural trend. A metamorphic gradient from granulite to greenschist facies is apparent on both sides of the mafic–ultramafic bodies. This work focuses on the characteristics of the mylonitization overprinted on the mafic–ultramafic intrusives in the Pringles Metamorphic Complex and their gneissic–migmatitic surroundings, both previously metamorphosed within the granulite facies. Petrogenetic grid and geothermobarometry applied to the paragenesis equilibrated during the mylonitic event, together with mineral deformation mechanisms, indicate that mafic and adjacent basement mylonites developed under upper amphibolite transitional to granulite facies metamorphic conditions at intermediate pressures (668–764 °C, 6.3–6.9 kbar, 0.3 < XCO2 < 0.7). However, the following mylonitic assemblages can be distinguished from the external limits of the Pringles Metamorphic Complex to its center: lower amphibolite facies ⇒ middle amphibolite facies ⇒ upper amphibolite transitional to granulite facies. Geothermobarometry applied to mylonitic assemblages indicate a temperature gradient from 555 °C to 764 °C and pressures of 6–7 kbar for the mylonitic event. This event is considered to have developed on a preexisting temperature gradient attributed to the intrusion of mafic–ultramafic bodies. The concentration of sulfides in mylonitic bands and textural relationships provide evidence of remobilization of primary magmatic sulfides of the mafic–ultramafic rocks (+PGM) during the mylonitic event. A lower-temperature final overprint produced brittle fracturing and localized retrogression on mafic–ultramafic minerals and ores by means of a water-rich fluid phase, which gave rise to a serpentine + magnetite ± actinolite association. Concordantly in the adjacent country rocks, fluids channeled along preexisting mylonitic foliation planes produced local obliteration of the mylonitic texture by a randomly oriented replacement of the mylonite mineralogy by a chlorite + sericite/muscovite + magnetite assemblage. Observed mineral reactions combined with structural data and geothermobarometry suggest a succession of tectonometamorphic events for the evolution of the Pringles Metamorphic Complex of Sierra de San Luis, developed in association with a counterclockwise P–T–d path. The most likely geological setting for this type of evolution is a backarc basin, associated with east-directed Famatinian subduction initiated in Mid-Cambrian times and closed during the collision of the allochthonous Precordillera terrane in Mid-Ordovician times.  相似文献   

13.
The Guelb Moghrein copper–gold deposit in the Islamic Republic of Mauritania reopened in 2006 and has produced copper concentrate and gold since then. The deposit is hosted in Neoarchaean–Palaeoproterozoic Fe–Mg carbonate-dominated metamorphic rocks interpreted as carbonate-facies iron formation. It forms tabular orebodies controlled by shear zones in the hanging wall and footwall of this meta-iron formation. Copper and gold are hosted in a complex sulfide ore in tectonic breccia replacing Fe–Mg carbonate and magnetite. Hydrothermal monazite dates the mineralization at 2492 ± 9 Ma. Two types of aqueous fluid inclusions suggest fluid mixing at 0.75–1.80 kbar and ~ 410 °C as the mineralization and precipitation mechanism, which is temporally coincident with regional retrograde metamorphism at 410 ± 30 °C (garnet-biotite). Distal alteration zones are enriched in K, Rb and Cu, whereas orebodies are depleted in K, Rb, Sr and Ba. The copper–gold mineralization at Guelb Moghrein formed during retrograde shearing in metamorphic rocks and contemporaneous hydrothermal alteration. The stable isotope signature of alteration and ore minerals suggest an external crustal fluid source. Fluids were focused in the reactive and competent meta-iron formation. Potassium alteration, magnetite and copper–gold mineralization suggest an IOCG mineral system akin similar deposits in Australia and Brazil.  相似文献   

14.
This paper investigates the age, P–T conditions and kinematics of Karakorum Fault (KF) zone rocks in the NW part of the Himalaya–Karakorum belt. Granulite to greenschist facies assemblages were developed within the KF zone during strike-slip shearing. The granulites were formed at high temperature (800 °C, 5.5 kbar), were subsequently retromorphosed into the amphibolite facies (700–750 °C, 4–5 kbar) and the greenschist facies (350–400 °C, 3–4 kbar). The Tangtse granite emplaced syn-kinematically at the contact between a LT and the HT granulite facies. Intrusion occurred during the juxtaposition of the two units under amphibolite conditions. Microstructures observed within the Tangtse granite exhibit a syn-magmatic dextral S–C fabric. Compiled U–Pb and Ar–Ar data show that in the central KF segment, granulite facies metamorphism occurred at a minimum age of 32 Ma, subsequent amphibolite facies metamorphism at 20–18 Ma. Further shearing under amphibolite facies (650–500 °C) was recorded at 13.6 ± 0.9 Ma, and greenschist-facies mica growth at 11 Ma. These data give further constrains to the age of initiation and depth of the Karakorum Fault. The granulite-facies conditions suggest that the KF, accommodating the lateral extrusion of Tibet, could be at least a crustal or even a Lithosphere-scale shear zone comparable to other peri-Himalayan faults.  相似文献   

15.
The original ore-fluid of the Huogeqi Cu–Pb–Zn deposit in Inner Mongolia, northern China, was enriched in heavy oxygen isotopes with δ18O values ranging from 9.9 to 11.4 per mil, which is characteristic of the metamorphic devolatilization of pelitic rocks. The δD values determined by direct measurement of syn-ore hydrothermal tremolite range from − 116 to − 82 per mil, lying between the domains of typical metamorphic fluid and meteoric water, which is in equilibrium with organic matter. Oxygen and hydrogen isotope ratios indicate that the ore-fluid was derived from deep-sourced metamorphic fluid and interacted with organic-rich shale during fluid migration, which is consistent with the fluid evolution history revealed by a previous fluid inclusion study. Sulfides in the deposit are characteristically enriched in heavy S isotopes, with an average δ34S value of 13.4 ± 6.2 per mil (1σ, n = 103). The S-isotope ratios are identical to stratabound sulfides generated through the non-bacterial reduction of Neoproterozoic marine sulfate (with δ34S values of ~ 17 per mil). Previous studies on lead isotopes of sulfides revealed that the ore-forming metals (Cu, Pb, and Zn) at the Huogeqi deposit were also remobilized from a stratabound source. This source was syngenetically elevated in its Cu-, Pb-, and Zn-sulfide content as a result of submarine hydrothermal activities forming sulfide-rich layers within a rift tectonic setting. The Fe isotope ratios for sulfides are consistent with those of an intercalated iron-formation within the ore-hosting rocks, suggesting that the Fe in the sulfides was derived from local host rocks during sulfide precipitation and the Fe-rich rocks are favorable lithological units for high-grade mineralization. The heterogeneous sources of ore-fluid, S, ore-forming metals, and Fe are explained by a multistage genetic model, which is supported by the geological characteristic of the deposit. The enriched sulfides were subsequently remobilized and enriched by metamorphic devolatilization during the Permian and Triassic periods. The metamorphic ore-fluid ascended along a shear zone and interacted with organic-rich shale. Sulfides eventually precipitated within the shear zone at a shallower crustal level, especially where the shear zone intersected Fe-rich host rocks. This multistage genetic model has implications for mineral exploration. Greenschist to amphibolite facies terranes containing thick Neoproterozoic rift sequences are ideal regions for potential Cu–Pb–Zn mineralization. In particular, intercalated volcanic rocks within the rift sequences are indicative of high heat-flow and are ideal for the development of submarine hydrothermal systems. The primary structures hosting mineralization and ore shoots in the Huogeqi area are jogs in the shear zones. In addition, Fe-rich lithological units, such as iron-formations, are ideal hosts for high-grade ore.  相似文献   

16.
A high-grade metamorphic complex is exposed in Filchnerfjella (6–8°E), central Dronning Maud Land. The metamorphic evolution of the complex has been recovered through a study of textural relationships, conventional geothermobarometry and pseudosection modelling. Relicts of an early, high-P assemblage are preserved within low-strain mafic pods. Subsequent granulite facies metamorphism resulted in formation of orthopyroxene in rocks of mafic, intermediate to felsic compositions, whereas spinel + quartz were part of the peak assemblage in pelitic gneisses. Peak conditions were attained at temperatures between 850–885 °C and 0.55–0.70 GPa. Reaction textures, including the replacement of amphibole and garnet by symplectites of orthopyroxene + plagioclase and partial replacement of garnet + sillimanite + spinel bearing assemblages by cordierite, indicate that the granulite facies metamorphism was accompanied and followed by decompression. The observed assemblages define a clock-wise P-T path including near-isothermal decompression. During decompression, localized melting led to formation of post-kinematic cordierite-melt assemblages, whereas mafic rocks contain melt patches with euhedral orthopyroxene. The granulite facies metamorphism, decompression and partial crustal melting occurred during the Cambrian Pan-African tectonothermal event.  相似文献   

17.
The Garevka metamorphic complex (GMC), located at the junction of the Central Angara and Isakovka terranes (western part of the Transangarian Yenisei Ridge), was studied in terms of its tectonometamorphic evolution and geodynamic processes in the Neoproterozoic history of the region. Geological, structural, geochronological, and petrological data permitted the recognition of two stages in the GMC evolution, which differ in thermodynamic regimes and metamorphic field gradients. These stages were related to crustal contraction and extension within the Yenisei regional shear zone, a large lineament structure in the region. Stage 1 was marked by the formation of metamorphic complexes in the middle to upper amphibolite facies moderate-pressure regional metamorphic settings at ～ 960 Ma, P = 7.7–8.6 kbar, and T = 582–631 °C. This suggests subsidence of the area to the middle continental crust with dT/dH = 20–25 °C/km. During stage 2, the rocks experienced Late Riphean (～ 880 Ma, SHRIMP II U–Pb and 40Ar–39Ar dating) dynamic metamorphism under epidote-amphibolite facies conditions (P = 3.9–4.9 kbar; T = 461–547 °C), indicating a metamorphic field gradient of dT/dH no greater than 10 °C/km, with the formation of blastomylonites in narrow zones of ductile and brittle deformations. In these zones, high-grade GMC blocks were exhumed to the upper continental crust and underwent low-temperature metamorphism. Comparison of the structural, geologic, and other evolutionary features (nearly identical age constraints in view of exhumation rate, similar PT-paths, and different types of metamorphism associated with different geodynamic settings, etc.) of the Garevka and Teya complexes suggests that they constitute a single polymetamorphic complex.  相似文献   

18.
We report field relationships, petrography and isotopic ages from two superposed basement units of the Kabul Block, the so called Lower Sherdarwaza and Upper Welayati formations. The Sherdarwaza Formation is represented mostly by migmatites and gneisses that are derived from pelitic and psammitic lithologies with lenses and layers of mafic and carbonate rocks. Several bodies of orthogneisses are also exposed in the Sherdarwaza Formation. The Upper Welayati Formation is characterized by micaschist, quartzite and amphibolites. SHRIMP U–Pb data on zircon from the orthogneiss in the Sherdarwaza Formation indicates a Neoarchean age of ca 2.5–2.8 Ga for their magmatic crystallization. The rocks exhibit granulite facies conditions of 5–7 kbar and 800 °C that are documented by the presence of orthopyroxene and Ti-rich biotite in the orthogneiss and by olivine and phlogopite in some calc-silicate rocks at contact with marble. A Paleoproterozoic age of ca. 1.85–1.80 Ga for this metamorphism was obtained using U-Pb SHRIMP dating on zircon and U-Th dating on monazite. Mineral textural relations also show a younger amphibolite facies metamorphism that is documented in both the Sherdarwaza and Welayati formations. This metamorphism occurred at relatively higher pressure conditions of up to 9 kbar at ca. 650 °C, compared to the granulite facies event. A Neoproterozoic age of ca 0.85–0.9 Ga, for this metamorphism is confirmed by Ar-Ar data on biotite and white mica as well as by U-Th data on monazite. By combining the presented results on the metamorphic petrology, geochronology and geochemistry, we conclude that: (1) The Kabul basement is a fragment of an Archean block (craton); (2) the ca. 1.85–1.8 and 0.9–0.85 Ga metamorphism marks an important orogenic events for the basement rocks of the Kabul Block which was stabilized during the early Precambrian; (3) the two metamorphic ages correlate well with global-scale orogenies related to the assembly of the Paleoproterozoic Columbia and Neoproterozoic Rodinia supercontinents; (4) based on metamorphic characteristics and ages, the Kabul basement rocks show an affinity to the Neoarchean rocks of the Tarim and/or South China cratons.  相似文献   

19.
The BIF-hosted iron ore system represents the world's largest and highest grade iron ore districts and deposits. BIF, the precursor to low- and high-grade BIF hosted iron ore, consists of Archean and Paleoproterozoic Algoma-type BIF (e.g., Serra Norte iron ore district in the Carajás Mineral Province), Proterozoic Lake Superior-type BIF (e.g., deposits in the Hamersley Province and craton), and Neoproterozoic Rapitan-type BIF (e.g., the Urucum iron ore district).The BIF-hosted iron ore system is structurally controlled, mostly via km-scale normal and strike-slips fault systems, which allow large volumes of ascending and descending hydrothermal fluids to circulate during Archean or Proterozoic deformation or early extensional events. Structures are also (passively) accessed via downward flowing supergene fluids during Cenozoic times.At the depositional site the transformation of BIF to low- and high-grade iron ore is controlled by: (1) structural permeability, (2) hypogene alteration caused by ascending deep fluids (largely magmatic or basinal brines), and descending ancient meteoric water, and (3) supergene enrichment via weathering processes. Hematite- and magnetite-based iron ores include a combination of microplaty hematite–martite, microplaty hematite with little or no goethite, martite–goethite, granoblastic hematite, specular hematite and magnetite, magnetite–martite, magnetite-specular hematite and magnetite–amphibole, respectively. Goethite ores with variable amounts of hematite and magnetite are mainly encountered in the weathering zone.In most large deposits, three major hypogene and one supergene ore stages are observed: (1) silica leaching and formation of magnetite and locally carbonate, (2) oxidation of magnetite to hematite (martitisation), further dissolution of quartz and formation of carbonate, (3) further martitisation, replacement of Fe silicates by hematite, new microplaty hematite and specular hematite formation and dissolution of carbonates, and (4) replacement of magnetite and any remaining carbonate by goethite and magnetite and formation of fibrous quartz and clay minerals.Hypogene alteration of BIF and surrounding country rocks is characterised by: (1) changes in the oxide mineralogy and textures, (2) development of distinct vertical and lateral distal, intermediate and proximal alteration zones defined by distinct oxide–silicate–carbonate assemblages, and (3) mass negative reactions such as de-silicification and de-carbonatisation, which significantly increase the porosity of high-grade iron ore, or lead to volume reduction by textural collapse or layer-compaction. Supergene alteration, up to depths of 200 m, is characterised by leaching of hypogene silica and carbonates, and dissolution precipitation of the iron oxyhydroxides.Carbonates in ore stages 2 and 3 are sourced from external fluids with respect to BIF. In the case of basin-related deposits, carbon is interpreted to be derived from deposits underlying carbonate sequences, whereas in the case of greenstone belt deposits carbonate is interpreted to be of magmatic origin. There is only limited mass balance analyses conducted, but those provide evidence for variable mobilization of Fe and depletion of SiO2. In the high-grade ore zone a volume reduction of up to 25% is observed.Mass balance calculations for proximal alteration zones in mafic wall rocks relative to least altered examples at Beebyn display enrichment in LOI, F, MgO, Ni, Fe2O3total, C, Zn, Cr and P2O5 and depletions of CaO, S, K2O, Rb, Ba, Sr and Na2O. The Y/Ho and Sm/Yb ratios of mineralised BIF at Windarling and Koolyanobbing reflect distinct carbonate generations derived from substantial fluid–rock reactions between hydrothermal fluids and igneous country rocks, and a chemical carbonate-inheritance preserved in supergene goethite.Hypogene and supergene fluids are paramount for the formation of high-grade BIF-hosted iron ore because of the enormous amount of: (1) warm (100–200 °C) silica-undersaturated alkaline fluids necessary to dissolve quartz in BIF, (2) oxidized fluids that cause the oxidation of magnetite to hematite, (3) weakly acid (with moderate CO2 content) to alkaline fluids that are necessary to form widespread metasomatic carbonate, (4) carbonate-undersaturated fluids that dissolve the diagenetic and metasomatic carbonates, and (5) oxidized fluids to form hematite species in the hypogene- and supergene-enriched zone and hydroxides in the supergene zone.Four discrete end-member models for Archean and Proterozoic hypogene and supergene-only BIF hosted iron ore are proposed: (1) granite–greenstone belt hosted, strike-slip fault zone controlled Carajás-type model, sourced by early magmatic (± metamorphic) fluids and ancient “warm” meteoric water; (2) sedimentary basin, normal fault zone controlled Hamersley-type model, sourced by early basinal (± evaporitic) brines and ancient “warm” meteoric water. A variation of the latter is the metamorphosed basin model, where BIF (ore) is significantly metamorphosed and deformed during distinct orogenic events (e.g., deposits in the Quadrilátero Ferrífero and Simandou Range). It is during the orogenic event that the upgrade of BIF to medium- and high-grade hypogene iron took place; (3) sedimentary basin hosted, early graben structure controlled Urucum-type model, where glaciomarine BIF and subsequent diagenesis to very low-grade metamorphism is responsible for variable gangue leaching and hematite mineralisation. All of these hypogene iron ore models do not preclude a stage of supergene modification, including iron hydroxide mineralisation, phosphorous, and additional gangue leaching during substantial weathering in ancient or Recent times; and (4) supergene enriched BIF Capanema-type model, which comprises goethitic iron ore deposits with no evidence for deep hypogene roots. A variation of this model is ancient supergene iron ores of the Sishen-type, where blocks of BIF slumped into underlying karstic carbonate units and subsequently experienced Fe upgrade during deep lateritic weathering.  相似文献   

20.
Magnetite is common in many ore deposits and their host rocks, and is useful for petrogenetic studies. In the Khetri copper belt in Rajasthan Province, NW India, there are several Cu-(Au, Fe) deposits associated with extensive Cu ± Fe ± Au ± Ag ± Co ± REE ± U mineralization hosted in phyllites, schists and quartzites of the Paleoproterozoic Delhi Supergroup. Ore bodies of these deposits comprise dominantly disseminated and vein-type Cu-sulfide ores composed of chalcopyrite, pyrite, and pyrrhotite intergrown with minor magnetite. There are also Fe-oxide ores with minor or no Cu-sulfides, which are locally overprinted by the mineral assemblage of the Cu-sulfide ores. In addition to the Fe-oxide and Cu-sulfide ores, the protolith of the Delhi Supergroup includes banded iron formations (BIFs) with original magnetite preserved (i.e. magnetite-quartzites) and their sheared counterparts. In the sheared magnetite-quartzites, their magnetite and quartz are mobilized and redistributed to magnetite and quartz bands. Trace elemental compositions of magnetite from these types of ores/rocks were obtained by LA-ICP-MS. The dataset indicates that different types of magnetite have distinct concentrations of Ti, Al, Mg, Mn, V, Cr, Co, Ni, Zn, Cu, P, Ge and Ga, which are correlated to their forming environments. Magnetite grains in magnetite-quartzites have relatively high Al (800–8000 ppm), Ti (150–900 ppm) and V (300–600 ppm) contents compared to those of BIFs in other regions such as the Yilgarn Craton, Western Australia and Labrador, Canada. The high Al, Ti and V contents can be explained by precipitation of the magnetite from relatively reduced, Al–Ti-rich water possibly involving hotter, seafloor hydrothermal fluids derived from submarine mafic volcanic rocks. Magnetite in sheared magnetite-quartzites is generally irregular and re-crystallized, and has Ni, Mn, Al, Cu and P contents lower than the magnetite from the unsheared counterparts, suggesting that the shearing-related mobilization is able to extract these elements from original magnetite. However, elevated contents of Ti, V, Co, Cr, Ge and Mg of the magnetite in the sheared magnetite-quartzites can be ascribed to involvement of external hydrothermal fluids during the shearing, consistent with occurrence of some hydrothermal minerals in the samples.Compositions of magnetite from the Fe-oxide and Cu-sulfide ores are interpreted to be controlled mainly by fluid compositions and/or oxygen fugacity (fO2). Other potential controlling factors such as temperature, fluid–rock interaction and co-precipitating minerals have very limited impacts. Magnetite in the Cu-sulfide ores has higher V but lower Ni contents than that of the Fe-oxide ores, likely indicating its precipitation from relatively reduced, evolved fluids. However, it is also indicated that the two types of magnetite do not show large distinctions in terms of concentrations of most elements, suggesting that they may have precipitated from a common, evolving fluid. We propose a combination of Ge versus Ti/Al and Cr versus Co/Ni co-variation plots to discriminate different types of magnetite from the Khetri copper belt. Our work agrees well with previous studies that compositions of magnetite can be potentially useful for provenance studies, but also highlights that discrimination schemes would be more meaningful for deposits in a certain region if fluid/water chemistry and specific formation conditions reflected in compositions of magnetite are clearly understood.  相似文献   

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