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1.
In the present study sediment and water samples collected from Kowsar Dam reservoir in Kohkiluye and Boyerahmad Province, southwest of Iran, are subjected to bulk digestion and chemical partitioning. The concentrations of nickel, lead, zinc, copper, cobalt, cadmium, manganese and iron in water and bed sediment were determined by atomic absorption spectrometry. The concentrations of metals bounded to five sedimentary phases were estimated. On this basis, the proportions of natural and anthropogenic elements were calculated.The anthropogenic portion of elements are as follows: zinc (96 %)> cobalt (88 %)> iron (78 %)> magnesium (78 %)> nickel (78 %)> copper (66 %)> lead (63 %)> cadmium (59 %). The results show sediment contamination by nickel, cadmium and lead, according to the world aquatic sediments and mean earth crust values. Manganese and copper have strong association with organic matter and are of high portion of sulfide bounded ions. Finally, The degree of sediment contamination was evaluated using enrichment factor, geo-accumulation index (Igeo) and pollution index (IPoll). The sediments were identified to be of high cadmium and lead pollution index. The pattern of pollution intensity according to enrichment factor is as follows; manganese (1.25) < copper (1.63) < zinc (1.93) < cobalt (2.35) < nickel (3.83) < lead (12.63) < cadmium (78.32). Cluster analysis was performed in order to assess heavy metal interactions between water and sediment. Accordingly, nickel, cadmium and copper are earth originated. Zinc, copper and manganese are dominated by pH. All the elemental concentrations in water and sediment are correlated except for sedimental copper.  相似文献   

2.
Five sediment cores from the fresh water region of the Vembanad wetland system were studied for the trace element contents The average concentration of iron, manganese, nickel, copper, zinc, cadmium, lead, mercury and chromium were determined. The core samples were collected using gravity type corer, digested with a mixture of nitric acid and perchloric acid and analyzed by atomic absorption spectrophotometry. Heavy metals such as iron, copper, nickel and zinc reported enrichment towards the surface of the core sediment sample collected from the centre of the lake. Lead, cadmium and mercury showed uniform distribution through out the core. Quality of the sediments were evaluated based on sediment quality guidelines, pollution load index, sum of toxic units and with effect range low/effect range median and threshold effect level/probable effect level values of Environmental Protection Agency guidelines. The degree of contamination for each station was determined. The concentration of different heavy metals has been compared with the world average concentration of shale values. Results of the analysis showed that Vembanad lake is facing serious metal pollution with increased rate of deposition.  相似文献   

3.
Groundwater outflows (springs and seeps) from porous sediments on European lowlands play a significant role in the surface water balance. It is therefore important to document these outflows’ water quality and spatial and temporal changes. The present study focused on changes in iron, manganese, and heavy metals in waters of groundwater outflows in an area of low anthropogenic impact—the Gryżyna-Grabin Tunnel Valley in western Poland. Eleven outflows were studied for a period of 2 years. Most of the samples analyzed revealed low element contents and little variation in time and space. Only values of iron and lead were above World Health Organization limits for drinking water. The concentrations of these elements were also variable in time and space. The seasonal changes in iron content are probably due to natural, temperature- and pH-controlled reactions of shallow groundwater with aquifer sediments. On the other hand, the elevated lead content points to regional water contamination.  相似文献   

4.
Ferromanganese nodules from the floors of the Chukchi and East Siberian seas were examined by means of analytical electron microscopy and plasmic and chemical analysis. It was found that the nodules consisted of aggregates of colloform and poorly crystallized matter of globular and irregular shapes, in which the minerals of iron and manganese were mainly presented by hematite, vernadite, and asbolane. The samples from the Chukchi Sea contained single micrograins of native gold. The tested nodules were comparable to oceanic ones in iron content. The contents of manganese, ore elements, and most of microelements are well below those of the ocean. The comparison of the composition of bottom sediments and considered nodules showed that the latter were enriched during their formation by factors of 100–200 in manganese, of 10–18 in cobalt, and of 4–8 in iron, nickel, and zinc. However, the process of diagenetic accumulation of metals by nodules in the marine environment is less effective than in the open ocean with the sediments of higher con-tent of mobile element forms and of higher exposure time compared to marine sediments.  相似文献   

5.
Study on contamination of tsunami sediments deposited on 26 December 2004 conducted shortly after the tsunami in coastal zone of Thailand revealed elevated contents of salts in water-soluble and some heavy metals and arsenic in bioavailable fractions (Szczuciński et al. in Env Geol 49:321–331, 2005). Few months later rainy season started and effected in total rainfall of over 3,300 mm. This paper presents results of survey repeated 1 year after the tsunami. To assess the effects of rainy season on mobilization of previously determined potential contaminants, the same locations were sampled again and analysed with the same methods. The tsunami deposit layer was well preserved but in many locations the sediments were coarser than just after tsunami due to washing out of finer fractions. The water-soluble salts contents were strongly reduced after the rainy season. However, the concentrations of acid leachable heavy metals and metalloids were still elevated in comparison to reference sample from an area not impacted by tsunami. It is possible that the metals and metalloids are successively moved to more bioavailable fraction from forms which were more resistant to mobilization.  相似文献   

6.
The heavy metal burden of Akkulam–Veli Lake, a shallow lake in southern part of India, is investigated through the analysis of surface sediments. The average concentrations of heavy metals such as lead, chromium, nickel, copper, zinc, cobalt, iron, and manganese were determined at selected stations. The degree of contamination of selected stations was evaluated using indices such as enrichment factor, contamination factor, and pollution load index and compared with sediment quality guidelines. Statistical analysis is carried out by correlation analysis and hierarchical clustering analysis to identify relatively homogeneous groups of cases. The results of this study indicate severe contamination at most of the stations selected. The degree of contamination of the lake could be rated as ‘moderate’ to ‘strong’. The average pollution load index shows progressive deterioration of sediment quality indicating ‘risk’ on the aquatic environment and ecosystems of the lake.  相似文献   

7.
Globally, aquatic ecosystems are highly polluted with heavy metals arising from anthropogenic and terrigenous sources. The objective of this study was to investigate the pollution of stream sediments and possible sources of pollutants in Nakivubo Channel Kampala, Uganda. Stream sediments were collected and analysed for heavy metal concentration using flame atomic absorption spectrophotometer. The degree of pollution in Nakivubo channelized stream sediments for lead, cadmium, copper, zinc, manganese and iron was assessed using enrichment factor, geo-accumulation index and pollution load index. The results indicated that (1) the sediments have been polluted with lead, cadmium and zinc and have high anthropogenic influences; (2) the calculation of geo-accumulation index suggest that Nakivubo stream sediments have background concentration for copper, manganese and Fe (I geo ≤ 0); (3) factor analysis results reveal three sources of pollutants as explained by three factors (75.0 %); (i) mixed origin or retention phenomena of industrial and vehicular emissions; (ii) terrigenous and (iii) dual origin of zinc (vehicular and industrial). In conclusion, the co-precipitation (inclusion, occlusion and adsorption) of lead, cadmium and zinc with manganese and iron hydroxides, scavenging ability of other metals, very low dissolved oxygen and slightly acidic to slightly alkaline pH in stream water could account for the active accumulation of heavy metals in Nakivubo stream sediments. These phenomena may pose a risk of secondary water pollution under sediment disturbance and/or changes in the geo-chemistry of sediments.  相似文献   

8.
In the “Sea Diamond” shipwreck, it is estimated that almost 1.7 tons of batteries/accumulators and approximately 150 cathode ray tube technology televisions have gone to the bottom of the sea. Under these circumstances, all the aforementioned materials will eventually undergo severe accelerated corrosion. Consequently, a variety of heavy metals will either be released in seawater or precipitate in the form of salts resulting in contamination of the sea sediments. According to the ship data, and the aforementioned quantities of batteries and televisions, it is estimated that approximately 75–80 g of mercury, 630–1,050 g of cadmium and 1.14–1.26 tons of lead exist in the wreck only due to the electrical and electronic equipment present in the ship, not to mention the significant amount of heavy metals such as copper, nickel, ferrous and chromium that exist in the hulk. Four series of seawater sampling (n = 85) were conducted in different stations surrounding the wreck area in order to assess the overall impact from the release of heavy metals in the surrounding aquatic environment. The analysis indicated that there were stations where lead, zinc and cadmium were present in concentrations higher than the permissible limits set by the Unites States Environmental Protection Agency for seawater. Furthermore, the analysis of three series of sediment sampling (n = 31) from the wreck area showed elevated but expected concentration values for ferrous and manganese, considering the geological background of the area and contamination with lead, copper and cadmium.  相似文献   

9.
In order to assess pollutants and impact of environmental changes along the Egyptian Red Sea coast, seven recent and Pleistocene coral species have been analyzed for Zn, Pb, Mn, Fe, Cr, Co, Ni, and Cu. Results show that the concentration of trace elements in recent coral skeletons is higher than those of Pleistocene counterpart except for Mn and Ni. In comparison with recent worldwide reefs, the present values are less than those of Central America coast (iron), Gulf of Aqaba, Jordan (lead, copper), Gulf of Mannar, India (chromium, zinc, manganese), Costa Rica, Panama (chromium, nickel), North-west coast of Venezuela and Saudi Arabia (copper). The present values are higher than those of Gulf of Aqaba, Jordan (iron, zinc, manganese), Gulf of Mannar, India (lead, cobalt, nickel), North-west coast of Venezuela (lead, zinc, chromium, manganese), Australia (copper, nickel, zinc, manganese). The highest values were recorded in Stylophora pistillata (iron, lead and copper), Acropora cytherea (cobalt), Pocillopora verrucosa (zinc) and the lowest concentrations were recorded in Goniastrea pectinata (iron, chromium, copper and nickel), Favites pentagona (lead, zinc and manganese), and Porites lutea (cobalt). The differences in metals content among the studied species are attributed to differences in microstructure and microarchitecture.  相似文献   

10.
A study was conducted to investigate the trace metal pollution of water and sediments of downstream of Tsurumi River, Yokohama, Japan. Twenty samples of water and sediments were collected from the river starting from Tokyo bay side up to the junction point of the Yagami River. Results show that the mean concentrations of chromium, cupper and nickel in water greatly exceed (>100 times) the surface water standard. The concentration of molybdenum and lead was also higher than standard values while iron and manganese was lower than that of surface water standard. The mean concentration of zinc, cupper, cadmium, lead, chromium, vanadium, bromine and iodine was 381.1, 133.0, 1.0, 40.8, 102.9, 162.0, 71.5 and 10.6 μg/g sediments, respectively and was greatly exceed the average worldwide shale concentrations and average Japanese river sediment values. However, mean concentration of arsenic, nickel and strontium was 11.0, 36.6 and 164.6 μg/g sediments, respectively which was lower than the average shale value. Other analyzed trace metals, including barium, zirconium, rubidium, yttrium, tin, antimony, cesium, lanthanum, cerium, praseodymium and neodymium were detected in river sediments; the concentration of which was close to the Japan’s river sediment average values. Pollution load index values of the sites of the studied area ranged from 1.24 to 7.65 which testify that the river sediments are polluted. The PLI value of the area was, however, high (6.53) as the concentration of trace metals like zinc, cupper, cadmium, lead and chromium were very high and were the major pollutants.  相似文献   

11.
 The areal distribution of oil products and various trace metals have been studied in bottom surface deposits from the harbors of Neva Bay. The data of contents were normalized to natural background concentrations. Also the size and biomass of benthos groups were analyzed. The results show clearly that industrial discharges have elevated levels of contamination in the sediments. Few efficient measures against environmental contamination have been taken. The sediments contain very high concentrations of oil products and such heavy metals as Hg, Pb, Cu, and Zn. The benthic organisms most sensitive to heavy metal contamination are Chironomidae. The dredging and dumping of the contaminated deposits can lead to secondary contamination of the Gulf of Finland and the Baltic proper. Received: 18 November 1996 · Accepted: 17 March 1997  相似文献   

12.
Sediments from the Mackenzie Valley — two suspended and one river bottom — were analyzed for major and minor elements, mineralogy, particle size, and ability to release trace metals when subjected to mild leaching. Copper and zinc in suspended sediments and cadmium in bottom sediment occurred largely (70 to 84 percent for Cu, 72 to 98 percent for Zn, 75 to 81 percent for Cd) in a form that could not easily be separated from the sediments by 0.1M HC1 and EDTA solutions. Cadmium was present in suspended sediments in low concentrations, and was present totally in sorbed leachable form. Iron, manganese, cobalt and chromium were separable from the particulate phase by mild leaching. It was found that approximately 70 hours were required for an apparent steady state concentration to be attained in such leachings. Reaction of these sediments with Beaufort Sea water (salinity 22.3 parts per thousand) indicated that both iron and manganese were released from sediments to sea water to a very small degree. Copper, lead, and zinc, however, were absorbed by sediments from sea water.  相似文献   

13.
We measured the amount of arsenic, chromium, copper, lead, nickel, vanadium, and zinc accumulated over a five-year period from 1997 to 2002 in surface sediments of seven salt marshes along the New Brunswick coast of the Bay of Fundy, Canada. Study sites extended from outer to inner Bay, spanning a gradient in tidal range (6–12 m) and mean sediment deposition rate (0.27–1.76 cm yr−1). In each study site, metal concentrations were measured in low and high marsh areas. Concentrations of chromium, nickel, and zinc appear to be within their natural range, while arsenic, lead, and vanadium are enriched in some sites. Calculated sediment metal loadings rates showed variability among marsh sites that closely followed sediment deposition patterns, suggesting sediment deposition rate is the driving factor of short-term metal accumulation in Fundy marshes. The value of salt marshes as a sink for metals may be enhanced by high sedimentation rates.  相似文献   

14.
 The focus of this research was to determine the impact of abandoned mines on surface water and groundwater in the historical mining districts of the Cerbat Mountains, Arizona. The surface water in the mining areas was found to be contaminated by various combinations and concentrations of heavy metals. Elevated arsenic, cadmium, and iron concentrations were detected in most surface-water samples, while lead, copper, and zinc contamination differed from region to region, depending on the ore mined. The groundwater was seriously polluted by arsenic, cadmium, lead, zinc, iron, and manganese in the immediate vicinity of mines that processed ore on the site, such as the Tennessee Mine near Chloride. Chloride's groundwater, however, showed no evidence of contamination. Three possible explanations are discussed: immobilization of the heavy metals in the soil by chemical reactions and adsorption, dilution effects due to the rainy season in spring, or the existence of different groundwater systems. Received: 17 September 1996 · Accepted: 14 May 1997  相似文献   

15.
In order to assess the pollution levels of selected heavy metals, 45 bottom sediment samples were collected from Al-Kharrar lagoon in central western Saudi Arabia. The concentrations of the heavy metals were recorded using inductively coupled plasma-mass spectrometer (ICP-MS). The results showed that the concentrations of Pb and Cd exceeded the environmental background values. However, the heavy metal contents were less than the threshold effect level (TEL) limit. The concentrations of heavy metals in lagoon bottom sediments varied spatially, but their variations showed similar trends. Elevated levels of metals were observed in the northern and southern parts of the lagoon. Evaluation of contamination levels by the sediment quality guidelines (SQG) of the US-EPA revealed that sediments were non-polluted-moderately to heavily polluted with Pb; non-polluted to moderately polluted with Cu; and non-polluted with Mn, Zn, Cd, and Cr. The geoaccumulation index showed that lagoon sediments were unpolluted with Cd, Mn, Fe, Hg, Mo, and Se; unpolluted to moderately polluted with Zn and Co; and moderately polluted with Pb, Cr, Cu, and As. The high enrichment factor values for Pb, As, Cu, Cr, Co, and Zn (>2) indicate their anthropogenic sources, whereas the remaining elements were of natural origins consistent with their low enrichment levels. The values of CF indicate that the bottom sediments of Al-Kharrar lagoon are moderately contaminated with Mn and Pb.  相似文献   

16.
The purpose of this study was to determine and assess the concentrations of trace metals in surface seawaters and sediments from different coastal habitats of the Red Sea coast of Yemen. Surface seawater and sediment samples were collected, treated and analyzed for cadmium, cobalt, manganese, chromium, lead, iron, nickel, copper, zinc and vanadium by the atomic absorption spectrometric analysis. The concentrations were high for cadmium, cobalt and lead and low or consistent with the natural background concentrations for the rest of the metals. However, the coastal habitats of the Red Sea coast of Yemen are still considered unpolluted, it is concluded that the cadmium cobalt and lead levels in surface seawaters are high and could have negative effects on marine life of the sites. Further studies are needed to characterize the sources fate, biogeochemical processes and impacts of these trace metals on coastal habitats and marine life of the region.  相似文献   

17.
Cu, Zn, Ni, Cr and Co pollution of El Melah lagoon waters near the city of Slimane in northwestern Tunisia was evaluated relative to identified human activity and waste repositories in the neighborhood. These metals were measured in lagoon waters and sediments, and in the potential pollutants, during two consecutive years for evaluation of their impact on the lagoon waters. A sequential extraction of the metals from sediments was designed to distinguish those potentially anthropogenic from those naturally scavenged by the sediments. This procedure allowed identification and quantification of the metals that are temporarily trapped, therefore contributing directly to the ecotoxicity of the lagoon waters, from those incorporated in the sediments. The highest supplies of Cr and Co to the lagoon waters come from El-Bey creek waters, while the wastewater treatment plant contributes for most of the Zn, and the urban garbage deposit for most of the Ni. Alternatively, the impact of the cultivated soils is minimal for the studied metals. In fact, Zn and Ni contents of the sediments amount 100 to 20 times less than in the present water, which is negligible. Cr is potentially the most polluting with contents up to ten times more in the sediments of the eastern lagoon pool and next to the outlet of the wastewater plant than in the waters. Potentially, contents of the anthropogenic Cu of the sediments amount 3–15 times less than in the lagoon waters.  相似文献   

18.
Metal fluxes to the sediments of the Moulay Bousselham lagoon,Morocco   总被引：2，自引：0，他引：2  
The metal content in surface sediments (0–2 cm, 26 samples), in a sediment core (120, 1 cm slices), taken from Moulay Bousselham (Morocco) was investigated. Concentrations of Al, Fe, Mn, Pb, Zn, Cu, Ni, Cr, Cd, As, and Hg were evaluated in surface and cored sediments of Moulay Bousselham lagoon. Significantly high concentrations in μg g−1 dw of Pb (31.7–6.2), Zn (758.9–167), Cu (310.7–22), Ni (96–10.5), Cr (113–18.9), Cd (0.84–0.02), As (1–0.1), and Hg (0.61–0.02) were found in sediment samples from Moulay Bousselham lagoon. Calculated enrichment factors [EFMe = (Me/Al)sample/(Me/Al)background], using Al as a normalizer, and correlation matrices showed that metal pollution in Merja Zerga of Moulay Bousselham lagoon was the product of anthropogenic sources, while the metal content in Merja Kehla was of natural origins. The results suggest that a major change in the sedimentary regime of the lagoon, associated with internal trapping and re-distribution of heavy metal, has been occurring in the past few decades. The cause would appear to be the construction of a Nador Canal at the lagoon. Probable effects concentrations (PEC) were often exceeded for heavy metals in the lagoon sediments, especially for Zn, Cu, Ni, and Cr, and four stations, stations MZ-11, MZ-12, MZ-13, MZ-14, MZ-16, and MZ-17, had multiple metals at presumptively toxic levels. These comparisons suggest that sediment metal levels in the river are clearly high and probably pose an environmental risk at some stations. The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake. Metal concentrations found in Moulay Bousselham lagoon were comparable to aquatic systems classified as contaminated from other regions of the world.  相似文献   

19.
Heavy metal contamination and its indexing approach for river water   总被引：9，自引：2，他引：7  
The objective of the study is to reveal the seasonal variations in the river water quality with respect to heavy metals contamination. To get the extend of trace metals contamination, water samples were collected from twelve different locations along the course of the river and its tributaries on summer and the winter seasons. The concentrations of trace metals such as cadmium, cromium, copper, cobalt, iron, manganese, nickel, lead, mercury and zinc were determined using atomic absorption spectrophotometer. Most of the samples were found within limit of Indian drinking water standard (IS: 10500). The data generated were used to calculate the heavy metal pollution index of river water. The mean values of HPI were 36.19 in summer and 32.37 for winter seasons and these values are well below the critical index limit of 100 because of the sufficient flow in river system. Mercury and chromium could not be traced in any of the samples in the study area.  相似文献   

20.
The studies presented explore post-depositional changes of zinc, cadmium, lead, manganese and 137Cs distribution in alluvial sediments accumulated in the upper Odra River valley in southern Poland. The rate of these changes was estimated by comparing metal and 137Cs distributions in four vertical alluvial profiles with a history of river pollution and sediment deposition. The untypical 137Cs distribution with peaks in the surface 40–60 cm and lower down, even at a depth of 2.5 m in strata deposited before the beginning of nuclear tests in 1954, indicates rapid post-depositional migration of this isotope from the surface and its retention in lower, less permeable layers. Moreover, the highest concentrations of lead, zinc and cadmium were found at a depth of 4 m in sediments accumulated in the mid-nineteenth century in spite of the growth of industrialization and the pollution of the Odra River with heavy metals until the end of the twentieth century. The post-depositional changes in heavy metals and 137Cs are rapid in comparison with the slow element migration usually observed in uninundated soils. This difference is explained by the frequent and easy infiltration of polluted river water into the gravelly and sandy sediments present in the profiles.  相似文献   

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