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1.
The increasing focus on the chronology of environmental and climatic changes of the last glacial-interglacial transition has led to several independent attempts to try to calibrate the 14C time-scale beyond the Holocene. The Late Weichselian Gotiglacial varved clays of the Swedish Time Scale could potentially be used for this purpose. The reliability of the Swedish Time Scale is discussed as well as different ways of using the Swedish varved clays for calibrating the 14C chronology. The strategy and initial results from an ongoing calibration project are presented. They show clearly that, if the right strategy is adopted, varved clay may be dated by accelerator mass spectrometry (AMS) 14C measurement of terrestrial macrofossils. A Late Weichselian 'event stratigraphy', including the Vedde Ash fall-out, is established for south Scandinavia using three dating categories: clay varve measurements, terrestrial macrofossil measurement, and lake sediment (including aquatic mosses) measurements. It suggests that a 14C chronology based on terrestrial organic remains is not consistent with the traditional Late Weichselian chronostratigraphy based on lake-sediment samples, and that 'clay varve years' exceed 'terrestrial 14C years' by c. 900 years at the end of, and by 1100–1200 years at the beginning of the Younger Dryas Chronozone. Further back in time, the time-scales appear to converge. These results are compared with other recently published calibration studies.  相似文献   

2.
Expanded sedimentary records from the Tethys reveal unique faunal and isotopic changes across the Palaeocene-Eocene (P-E) transition. Unlike in the open oceans, the Tethys exhibits a gradual decrease of 1.5% in δ13C values prior to the rapid δ13C excursion. Associated with the 613C excursion is a decrease in calcite burial, increase in detrital content and appearance of a unique opportunistic planktic foraminifera1 assemblage (e.g. compressed acarininids). The existence of a prelude decrease in δ13C values in the Tethys suggests that the P-E δ13C excursion may have occurred in two steps and over a few hundred thousand years, rather than as one step over a few thousand years as previously suggested. This slower excursion rate is readily explained by changing organic carbon weathering or burial rates and avoids the need of invoking ad hoc scenarios.  相似文献   

3.
Carbon isotope measurements carried out on 201 carbonate samples from the early Proterozoic of the Kola Peninsula, N. Karelia and Norway yield δ13C (PDB) spanning - 20.5% to + 11%. A general δ13C secular trend shows that prior to 2.33 Ga values are typically 'normal' marine, averaging around - 3%0. Between 2.33 and 2.06 Ga, in Jatulian time, there follows a rapid excursion to positive δ13C of around + 6%. Post-Jatulian time is characterized by δ13C of sedimentary carbonates fluctuating between - 5% and +3%; also it is remarkable for the first pronounced development of diagenetic carbonates, which have δ13C between - 14 % and - 6% . The c. 6% positive δ13C shift with a duration of about 270 Myr coincides with a maximum in the diversity and abundance of stromatolites, and with widespread development of 'red beds', but does not coincide with the maximum of buried Corg mass. The Fennoscandian Shield represents the largest isotoically anomalous carbonate province yet reported, and the positive δ13C excursion together with a series of major global palaeoenviromental changes seems to be more intense than the Precambrian/Cambrian transition events. However, it is still not clear what kind of mechanism this phenomenon could be attributed to. An increase of the 'Ronov ratio', and/or 'Broecker ratio' and other possible models are discussed as the target for future investigations.  相似文献   

4.
An exhaustive 14C dating programme of molluscs from the Fossvogur sediments in Reykjavik. Iceland is presented. For the first time all the fossiliferous units of the sediments are dated. The results confirm earlier conclusions of a widespread occurrence of marine sediments of Allerød age in Reykjavik. The set of dates from the Fossvogur sediments shows a narrow 14C age distribution (standard deviation of ±235 years) of molluscs from all localities and from successive marine units in vertical sections. The weighted mean conventional 14C age is 11,400 BP. Assuming a reservoir effect of 400 years. this corresponds to a reservoir-corrected age of I1,000 BP. i.e. the Allerød- Younger Dryas transition for the sampled units, These new 14C dates from Fossvogur confirm the need for a revision of the Upper Pleistocene chronology of the Reykjavik region. They also have a bearing on the Late Weichselian record of glacier readvances and sea-level changes in the area. The dates suggest that the marine units in Fossvogur accumulated within a restricted time-span of a few hundred years. The sediments in Fossvogur are of volcaniclastic origin and are extremely lithified, indicating local geothermal activity soon after their deposition. This may explain anomalously high D/L amino acid ratios measured in molluscs from the Fossvogur sediments. δ13C and δ18O results suggest that temperatures may have ranged up to 60°C.  相似文献   

5.
In this paper we address the question of how to determine the period of activity (sedimentation) of fossil (Holocene) fluvial systems in vertically aggrading environments. Our data base consists of almost 100 14C ages (partly AMS) from the Rhine–Meuse delta in the central Netherlands. Radiocarbon samples from the tops of lithostratigraphically correlative organic beds underneath overbank deposits (sample type 1) yield consistent ages, indicating a synchronous onset of overbank deposition over distances of at least up to 20 km along channel belts. Similarly, 14C ages from the base of organic residual channel fills (sample type 3) generally indicate a clear termination of within-channel sedimentation. In contrast, 14C ages from the base of organic beds overlying overbank deposits (sample type 2), commonly assumed to represent the end of fluvial sedimentation, show a large scatter reaching up to 1000 14C years. This setting usually produces 14C ages significantly younger than residual channels of the same fluvial system, indicating the presence of non-depositional unconformities. These usually occur on top of slightly elevated sediment bodies (especially natural levee deposits), which often contain palaeosols. Such hiatuses appear to be much more abundant than hitherto supposed. We conclude that a combination of sample types 1 and 3 generally yields a satisfactory delimitation of the period of activity of a fossil fluvial system. The problems associated with 14C samples of type 2 may also be present in coastal areas with an alternation of tidal deposits and organic beds.  相似文献   

6.
Analysis of 2D and 3D seismic records from the continental shelf off western Norway, in combination with chronological constraints from 14C dates, has led to a model for the glacial development in these shelf areas between c. 15 and 13 14C ka BP. On the shallow Måløy Plateau adjacent to the Norwegian Channel, iceberg scours are preserved below a prominent moraine ridge, which by correlation to the Norwegian Channel indicate ice retreat at c. 15 14C ka BP. Subsequently, the ice advanced across the scoured surface and deposited a till sheet before stabilizing to deposit a prominent moraine, termed the Bremanger Moraine. Based on location on the shelf, seismic stratigraphy, morphology and C dates the Bremanger Moraine is correlated with a significant moraine on the continental shelf off Trøndelag. We suggest that these features are products of a regional glacial event, the Bremanger Event, dated to <15–13.3 14C ka BP. The Bremanger Event is probably a result of the deteriorating climatic conditions in the NE Atlantic during Heinrich event 1.  相似文献   

7.
A Barremian to Albian succession on Mount Kanala, part of a Tethyan isolated carbonate platform, was investigated for its δ13C variations. The limestone sequence is composed of a series of peritidal shallowing-upward cycles with clear petrographic evidence for strong early diagenetic overprinting related to repeated subaerial exposure. Despite significant impact of diagenesis, the observed changes in δ13C can be very well correlated with deep-water sections from different ocean basins and shallow water carbonate platforms in the Middle East. This lends further support to the applicability of δ13C variations for stratigraphic purposes in shallow-water limestones. Using the δ13C signal, time resolution in Lower Cretaceous platform carbonates can be significantly increased, independent of bio-zonations often hampered by ecological variability.
Cyclostratigraphic analysis of the Aptian part of the section shows that strong positive excursions of the cumulative departure from mean cycle thickness of the peritidal shallowing-upward cycles coincide with global positive δ13C excursions. This, and the fact that positive shifts in the δ13C record are preserved within shallow water limestones, provide evidence that black-shale accumulation in the ocean basins occurred during sea-level rise and flooding of platform tops. Integration of carbon-isotope-, cyclo- and sequence-stratigraphic results from different carbonate platforms indicate that strong positive global δ13C shifts and concurrent organic-carbon burial during black-shale deposition are ultimately caused by rapid rises of eustatic sea level. Hence, the rate of change of eustatic sea level is considered to play a crucial role in black-shale accumulation in the global ocean basins during the Cretaceous.  相似文献   

8.
For studies of mass-dependent fractionation of calcium isotopes in natural materials, the 48Ca/42Ca ratio is a superior choice to the conventionally measured 44Ca/40Ca ratio for two important reasons. These are (1) mass-dependent fractionation can be determined free from the effects of inherited or ingrown radiogenic 40Ca and (2) this ratio increases the spread of measured isotopic masses by 50%, resulting in statistically better resolution of fractionation, assuming similar precision. A third, though strictly technical, advantage is the inherent ability of a mass spectrometer to measure ratios close to unity (48Ca/42Ca) more precisely than very small or large ratios (44Ca/40Ca). However, because of the very low natural abundance of both 48Ca and 42Ca, their ratio has been very difficult to measure, the only attempt so far being on a high mass resolution MC-ICP-MS with a precision of 0.33%. We report here determination of the 48Ca/42Ca ratio by the more commonly available and user-friendly multi-collector TIMS using a 43Ca-46Ca double-spike, with a significantly better precision of 0.18% (2s). The 48Ca/40Ca or 44Ca/40Ca ratio can also be measured in the same mass spectrometer run to provide complementary information on any radiogenic component.  相似文献   

9.
Two sections of the Upper Cenomanian and Lower Turonian in central and south-east Poland were investigated for foraminifers, CaCO3content, carbon content insoluble in HCl (Corg) and in the carbonates (Ccarb), carbon and oxygen isotopic composition of bulk-rock carbonates and elemental abundances. The Cenomanian/Turonian boundary interval is characterized by the appearance of more marly facies, a δ13C and δ18O stable isotope anomaly, a considerable increase in Corg content and decrease in Ccarb content and substantial changes in the foraminiferal assemblages. A major carbon stable isotope excursion with a shift of +2 (PDB) occurs in the lowermost Whiteinella archaeocretacea Zone. The late Cenomanian δ13C anomaly is associated with heavy δ18O values. The peak value of δ13C corresponds to the minima in P/B ratio and in diversity of foraminiferal assemblages. A late Cenomanian anoxic event is thought to be responsible for changes in foraminiferal assemblages. However, elemental abundance analyses do not show changes in the concentrations of trace elements. This may be explained by the long distance between studied area and a source of enrichment which was probably located in the western hemisphere.  相似文献   

10.
New pollen-analytical investigations and two 14C series indicate that, at the Bedrina on Mount Piottino (Tessin, Switzerland), the post-Allerød NAP phase (Piottino oscillation) represents the well-marked Younger Dryas at least for the most part. The late-glacial part of the profile is re-classified, and the term Piottino oscillation is rejected, as it is largely identical with the Younger Dryas. Individual 14C dates from the transition between the Younger Dryas and the Preboreal should be considered critically. Considerable fluctuations in the 14C level are supposed for this period.  相似文献   

11.
Values of δ13C obtained from conventional bulk sediment radiocarbon dates encompassing the Pleistocene Holocene boundary have been compiled and plotted against 14C age. In all. 286 lake sediment dates from southern Sweden in the range 8.000 to 13.000 BP have been evaluated. A significant decrease in δ13C values, initiated shortly before 10.000 RP and amounting to 5%, is distinguished. This change is accompanied by increased limnic productivity. decreased erosive input and increased organic carbon content of the sediments. A probable explanation for the δ13C decline in organic material is decreased importance of dissolution of silicates at the transition to the Holocene. During the Late Weichselian. extensive weathering of exposed minerogenic material with subsequent input of bicarbonate to the lake water may have caused a relative enrichment of 13C in dissolved inorganic carbon. Furthermore, the early Holocene increase in terrestrial vegetation cover probably led to an increased supply of 13C depleted carbon dioxide to the lake water by root respiration. Altered limnic vegetation, presumably towards increased production of phytoplankton. could also have contributed to the observed decreasing δ13C trend. The importance of these processes compared to other possible influencing factors. mainly endogenic carbonate production and changes in the global carbon cycle. is discussed.  相似文献   

12.
Nine stratigraphic sections, each ≈5 m thick, were sampled from the Alamogordo Member limestones of the Lake Valley Formation, Sacramento Mountains, New Mexico, USA. Four stratigraphic sections consist entirely of lime mudstone and wackestone, whereas the other five sections have a prominent layer of crinoidal packstone about 1 m thick at their base. Stable isotopic analyses reveal that the lime muds in the sections with basal packstone layers show a downward decrease in δ18O and constant δ13C values, whereas those in the sections solely composed of lime mudstone and wackestone have, in general, relatively uniform δ18O and δ13C values. The diagenesis of the Alamogordo Member limestones was previously believed to have been governed by the downward percolation of meteoric water from a regional pre-Pennsylvanian exposure surface ≈100 m above this unit. However, the uniform δ13C and downward decrease in δ18O values in the lime muds in the sections with basal packstones indicate that the meteoric water ascended within the Alamogordo Member, rather than descended from the overlying exposure surface. This indicates that the basal packstones were probably a conduit for meteoric water. This is further supported indirectly by the relatively uniform δ18O and δ13C values of the lime mud in the sections without basal packstones. The implications are that the oxygen isotopic gradients may be used to identify palaeoaquifers, flow directions within these aquifers and that meteoric diagenesis below an exposure surface could be governed by flow through a palaeoaquifer.  相似文献   

13.
Abstract. Carboniferous-Permian limestones of the Akiyoshi Plateau, in the Inner Zone of southwestern Japan, are composed of essentially pure calcium carbonate containing only small amounts of other elements, and they are accompanied by marble and copper skarn deposits near the contact with late Cretaceous granitoids. The δ18O values of the Akiyoshi limestones range widely from 7.6 to 28.3% and are mostly lower than those of other areas of the same age (23–29%), whereas the differences among the δ13C values are small. The δ18O values are negatively correlated with Mn and Fe contents. Samples with high δ18O (>25%) and δ13C (>2%) values do not contain Fe, Zn, or Pb, but those with low δ18O values tend to be rich in these elements, indicating that these elements were introduced by interaction with H2O dominant fluids, possibly of magmatic origin. Potential scores for evaluating the degree of interaction with hydro thermal fluids were calculated for δ18O, δ13C, Fe, Mn, Zn, Pb, and Sr. Higher scores implying much hydrothermal interaction were evident in the Mt. Hananoyama area, where there are many skarn deposits, and along faults oriented mainly NNW-SSE. Therefore, these are promising areas for exploring for blind deposits. It is likely that the hydrothermal fluid traveled through the limestones along fractures at the time of the granitic intrusions. However, the potential scores here are much smaller than those in the Pb-Zn mineralized area of the Kamioka mine, so more detailed petrological and mineralogical investigations are necessary.  相似文献   

14.
The timing of the extinction of the Australian Megafauna and whether it was simultaneous and widespread has been a much researched topic in Quaternary geoscience. The Black Creek Swamp Megafauna site on Kangaroo Island was thought to be a refugium for Megafauna; however, recent and multidiscipline age determinations have established that the fossils are considerably older than the well-quoted extinction age of 45 kyr. Further radiocarbon age determinations, δ13C isotope analysis and 13C-NMR spectroscopy of the fossil containing organic matter demonstrates that it is highly soluble and accumulated as recently as 31–18 cal. kyr BP. These radiocarbon ages are much younger than the 100–50 kyr age bracket ascertained for the fossil material itself, implying separate episodes of death, deposition and burial. The soluble nature of the organic matter and increasing radiocarbon ages with depth suggests lateral accumulation, probably transported by subsurface waters from elevated areas proximal to the low-lying swamp. Such depositional conditions and 14C age range implies that the site may have experienced an unusually wet Last Glacial Maximum, due maybe to its proximity to the continental shelf and thus to maritime conditions. C3 vegetation dominates the Black Creek Swamp and its organic matter (δ13C; −30‰ and −23‰); however, variations in δ13C may indicate climatic shifts. 13C-enrichment and an abundance of salt-tolerant gastropods within the site's final phase of sediment accumulation (<6 cal. kyr BP) suggest that conditions during this most recent period were not as wet as those of the Last Glacial Maximum.  相似文献   

15.
Foraminifera, sedimentology, and tephra geochemistry in core 93030-006 LCF from the southwestern Iceland shelf were used to reconstruct paleoenvironments between 12.7 and 9.4 14C ka BP. Seismic-reflection profiles place the core in glacial-marine and marine sediments within one meter of the underlying glacial till. Foraminifers in the earliest glacial-marine sediments provide a record of ice-distal conditions and immigration of slope species onto the shelf in association with warm Atlantic water. Meltwater increased during the Allerød under a weakened Atlantic water influence. Arctic conditions began by 11.14 14C ka BP with an abrupt increase in meltwater and near exclusion of boreal fauna from the shelf. Meltwater diminished in the early Younger Dryas, coinciding with sea-surface cooling between 11.14 and 10.5 14C ka BP. A slight warming recorded in the uppermost glacial-marine sediments was interrupted by an inferred jökulhlaup event emanating from glacier ice on the Western Volcanic Zone. Retreat of the ice margin from the sea sometime between c. 10.3 and 9.94 14C ka BP coincided with this event. The onset of postglacial marine sedimentation occurred along with increasing evidence of Atlantic water c. 9.94 14C ka BP and was interrupted by a short-lived Pre-boreal cooling of the Irminger Current c. 9.91 14C ka BP. Conditions similar to those today were established by 9.7 14C ka BP.  相似文献   

16.
Data from a series of extended analytical sessions using a range of different zircon reference samples have been used to investigate the periodic derivation of abnormal 207Pb/206Pb ages during microbeam analysis%For the Canberra SHRIMP II, this phenomenon probably results from the presence of a signal at mass 204 that is alien to the Pb spectrum; isotopic fractionation is unlikely to be a significant contributor. In contrast, abnormal 207Pb/206Pb ages obtained from SHRIMP I at the same research centre require a different, but as yet unknown explanation. Assessment of the reasons for atypical 207Pb/206Pb measurements and the means of correcting for them should therefore be independently assessed for individual analytical instruments. The use of reference samples with very different ages is an effective way of doing this, because older reference samples are more useful for documenting isotopic fractionation, whereas younger ones are more sensitive indicators of isobaric interference.  相似文献   

17.
BOREAS Griffey, N. J. & Worsley, P. 1978 03 01: The pattern of Neoglacial glacier variations in the Okstindan region of northern Norway during the last three millennia (Okstindan Research Project Report 26). Boreas, Vol. 7, pp. 1–17. Oslo. ISSN 0300–9483.
Historical, lichenometrical and stratigraphical evidence is combined to establish a provisional history of Neoglacial glacier variation in a mountainous environment approx. 66oN. Attention is focussed on end moraine chronology. At five sites, derived organic materials have been located within end moraines and at two others in situ palaeosols occur buried beneath distal slopes. Organic rich samples from all the sites have been radiocarbon dated and the results permit the recognition of three major glacier expansion episodes, each of which contributes to the diachronous nature of the Okstindan outer Neoglacial limit. A widespread 'Little Ice Age' event with a maximum extent of probable eighteenth century age is confirmed. Limited areas of older moraine ridges peripheral to the 'Little Ice Age' maximal limit appear to date from about 3000-2500 14C years B.P. and a younger period tentatively dated as about 1250-1000 14C years B. P. which agrees with recent data from Engabreen in northwest Svartisen. No evidence for any extensive glacial activity after the inlandice wastage approx. 9000 14C years B. P. and prior to 3000 14C years B.P. was forthcoming.  相似文献   

18.
Late-Glacial radiocarbon- and palynostratigraphy on the Swiss Plateau   总被引:4,自引:0,他引:4  
A detailed late-glacial radiocarbon stratigraphy for the Swiss Plateau has been established on the basis of over 90 accelerator 14C dates on terrestrial plant macrofossils. Two plateaux of constant.,14C age were observed, occurring at 12,700 B.P. and at 10,000 B.P. The consequences of these plateaux for palaeo-ecological investigations are threefold: (1) a more refined 14C dating within the plateaux is not possible, (2) in teleconnections between different sites (if based on 14C dating and concerning the periods around 12,700 B.P. and 10,000 B.P.) events are considered synchronous which are only synchronous within a plateau of constant age, and (3) exact time-depth relationship and therefore influx calculations are made impossible during these plateau periods. A comparison of the radiocarbon ages derived from terrestrial, telmatic and limnic material at different sites on the Swiss Plateau yields a proposal for modifying the zonation system of Welten for the Late-Glacial. By retaining the limits of chronozones (at 13, 12, 11 and 10ka B.P.) and by refining the palynostratigraphic criteria for the limits of biozones, a separation between chrono- and biozonation at the beginning of the Belling and at the beginning of the Younger Dryas becomes obvious.  相似文献   

19.
A well-preserved moraine on the northern coast of County Donegal, Ireland, has played a critical role in our understanding of the glacial history of this sector of the Irish Ice Sheet (IIS). Because of a lack of numerical dating of the moraine, however, previous interpretations of its age and significance to the glacial history of this region have varied widely. Here we report eight in situ cosmogenic 10Be ages on boulders sampled from the moraine. Two of these ages are outliers, with the remaining six ranging from 18.8±1.0 10Be kyr to 20.9±1.3 10Be kyr, with an uncertainty-weighted mean age of 19.4±0.3 10Be kyr (19.4±1.2 kyr accounting for production rate uncertainty). Our results confirm one previous 10Be age obtained from the moraine, with the combined data ( n =7) constraining the age of initial deglaciation of the IIS from its LGM position on the continental shelf to be 19.3±0.3 10Be kyr (19.3±1.2 kyr accounting for production rate uncertainty). These ages are in excellent agreement with calibrated 14C ages that constrain retreat of the IIS margin from the continental shelf elsewhere in northwestern and western Ireland and the Irish Sea Basin associated with the start of the Cooley Point Interstadial (≥20–≤18.2 cal. kyr BP), suggesting widespread deglaciation of the IIS ∼19.5–20 kyr ago.  相似文献   

20.
The laminated sediments at Pudozh in eastern Karelia are generally assumed to have been deposited between 13 000 and 16 000 14C yr BP and have been used to date the recession of the active ice margin. However, 17 AMS 14C measurements performed on terrestrial plant macrofossils contained in these sediments show that deposition began during the late Allerφd, when the ice margin had already receded to the northern part of Lake Onega. Based on an age model, we assume that the 1933-year-long varved sequence covers the time period between c. 12 900 and 11 000 calendar years BP. During this period, which comprises the later part of the Late Weichselian and the early Holocene, the local vegetation consisted of open, tree-less dwarf shrub heaths. Increased soil erosion may have occurred before 12 550 calendar years BP.  相似文献   

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