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1.
内助剂型固硫剂在渭北高硫煤固硫中的应用   总被引:3,自引:0,他引:3  
定义了内助剂型固硫剂,并在此基础上对两种内助剂型固硫剂的固硫效果进行了对比研究。结果表明,内助剂型固硫剂因助剂的助固硫作用得以充分发挥,因而固硫率明显高于同类对比固硫剂,尤其是 1200℃的高温固硫率仍可达到25.7%~35.5%,是同类对比固硫剂的5~6倍。   相似文献   

2.
CaO/MgO比对固硫剂固硫率的影响   总被引:1,自引:1,他引:0  
通过对不同燃烧温度和固硫剂添加量下CaO/MgO之比与固硫率之间关系的研究发现,燃烧温度相同而CaO/MgO之比不同时,固硫率不同;燃烧温度不同时,最佳CaO/MgO之比也不同,而且随温度升高而向CaO增多、MgO减少的方向变化。最佳固硫温度以及固硫剂添加量均和CaO/MgO之比与固硫率之间的关系无关。   相似文献   

3.
蛭石尾砂在燃煤固硫除尘中的利用   总被引:8,自引:1,他引:8       下载免费PDF全文
在对新疆且干布拉克蛭石矿尾矿进行矿物学研究的基础上,进行了高温膨胀实验、结果表明,蛭石尾砂的膨胀倍数因粒度的增大、时间的延长而提高,较为理想的膨胀温度在950~1050℃之间,利用碳酸钙为固硫剂、膨胀土为粘结剂,蛭石尾矿为膨胀添加剂对肥城烟煤进行高温燃煤固硫实验。结果表明,蛭石尾砂能较大幅度地提高肥城烟煤的固硫率,经XRD、SEM和EDX等分析表明,燃煤灰渣的主要固硫物相为硫酸钙,且因燃烧条件、添加剂和燃煤种类的差异而以不同的形态存在。蛭石尾砂对燃煤固硫促进机理可解释为营造型煤内部氧化气氛,抑制新物相硫酸钙的分解。  相似文献   

4.
陕西韩城寒武系白云岩和石灰岩固硫试验   总被引:3,自引:1,他引:2  
选用韩城7个分别采自于寒武系白云岩和石灰岩的样品,以10%和25%为基准,加入韩城的高硫煤中,进行固硫试验。研究表明:中、下寒武系白云岩固硫率为10%~15%,石灰岩的固硫率为15%~26%,上寒武统下部白云岩的固硫率为30%~47%。上寒武统中上部的白云岩固硫率为10%~20%。岩石中白云石和方解石的含量相当时,白云岩的固硫率高于石灰岩5~10个百分点。   相似文献   

5.
韩城石炭——二叠系原煤的自身固硫率和硫的烧失率   总被引:1,自引:0,他引:1  
对陕西韩城矿区的石炭--二叠系4个主采煤层的原煤自身固硫率和硫的烧失率进行了研究,其中11号煤96%的煤,5号煤98%,3号煤92%和2号煤94%的硫在800-850℃温度下的灼烧2h已分解释放。其燃渣中的硫主要以硫酸盐的形式存在。煤自身的固硫率和灰分含量密切相关,特别是与煤灰分中的氧化钙关第最为密切,原煤中硫的烧失率与煤中全硫、有机硫和无机硫的含量关系密切。  相似文献   

6.
民用燃煤烟尘特征及环境矿物材料固硫剂开发   总被引:9,自引:0,他引:9  
通过对北京某地区居民炊事用型煤和散装烟煤煤岩和元素分析 ,表明烟煤和型煤含碳量分别为 70 %和 5 9% ,烟煤中可燃性高变质活性组分为 87% ,而型煤有较高的粘土成分 ,约达 2 0 %。对它们燃烧产生的烟尘进行物相分析、组分定量、粒度测试、显微形貌和微观结构等矿物学研究 ,表明型煤和烟煤的烟尘均含有较高碳质组分 ,分别占 2 5 %和 2 8% ;烟煤烟尘只有型煤烟尘含更高的烧蚀残渣 ,两者的粘土 (包括石英等矿物 )类组分均相当多 ,约占 5 0 % ;烟尘平均粒径都很小 ,型煤烟尘只有烟煤烟尘的 1/ 4左右 ,约为 6 5 μm ,而比表面积大 2倍多 ;烟煤烟尘呈碎屑状 ,型煤烟尘为粉末状 ;烟尘中均含有较多的均质体 ,并有铁质侵染现象 ;石英小颗粒在烟尘中大量存在。为促使燃煤充分燃烧 ,达到固硫、助燃和降尘的目的 ,本实验室开发研制了效果良好的民用燃煤环境矿物材料固硫添加剂 ,并对山东肥城高硫烟煤进行了型煤固硫实验 ,在 85 0℃ ,95 0℃和 10 5 0℃燃烧条件下固硫率高于目前国内同类水平 ,固硫率达 70 % 80 %。  相似文献   

7.
氧化物及复合添加剂对硫酸钙高温稳定性的影响   总被引:2,自引:0,他引:2  
在硫酸钙高温分解行为的研究基础上,探讨了氧化物SiO_2、Fe_2O_3、ZnO和SiO_2_Fe_2O_3、CaCO_3-Al_2O_3复合添加剂对硫酸钙分解的影响。结果表明ZnO、SiO_2、SiO_2-Fe_2O_3均有利于固硫,这分别与反应过程中形成能起包覆作用的Ca_2SiO_4和耐热含硫物相Ca2Fe2S2O3有关;复合添加剂CaCO3_Al2O3固硫效果更佳,当CaCO3∶Al2O3∶CaSO4摩尔比为3∶3∶1时,固硫作用最理想,1400℃时CaSO4的分解率从87.5%降低到21.2%,这与形成大量高温耐热物相硫铝酸钙有关。  相似文献   

8.
地下浅层地温和近地表空气温度存在着必然的内在联系,地面温度变化的信息随着时间推移向下传播并叠加到稳态地温场上,因此通过对现今地温剖面的分析可以重建过去地面温度变化的历史。为了研究西安地区地下和地上的温度变化,本文在西安开展了钻孔温度测量,获得了16个钻孔的地温剖面,同时收集整理了西安气象站1951~2010年气温数据。对1951~2010年气温数据进行回归分析得到西安地区年平均气温、年平均最高气温和最低气温增温率分别为3.71 ℃/100a、2.03 ℃/100a和5.14 ℃/100a,均高于全国和全球平均水平,其中1986~2010年间平均气温增温更是显著,达到9.01 ℃/100a。从钻孔测温曲线中筛选出西安城郊6个传导型地温剖面进行分析,结果表明西安地区钻孔温度记录的地面温度变化趋势与气象台记录的气温变化趋势基本吻合。根据利用钻孔温度剖面下段回归分析得到的地表稳态温度和地温梯度以及25年间西安地区平均气温增温率推算得到钻孔理论地温剖面与实测地温数据总体上具有较好的一致性。对实测地温数据的进一步精确拟合分析显示,西安城郊6个选定的钻孔所在区域地面温度变暖分别起始于20年、24年、26年、28年、30年和30年前,对应的地表增温幅度分别为0.4 ℃、0.72 ℃、2.18 ℃、4.2 ℃、2.4 ℃和2.4 ℃。市区和周边郊区钻孔所在区域在增温幅度上存在明显的差异,市区增温强度明显高于郊区,而城郊结合部介于两者之间。  相似文献   

9.
从不同标高、不同矿化带的流体包襄体研究入手,系统地论述了七宝山铜多金属矿床成矿流体的性质、演化过程及其与成矿的关系。黄铁矿爆裂测温表明:成矿流体温度变化在平面上以岩体为中心向四周依次为291℃~287℃~279℃,在剖面上由下往上依次为312℃~286℃~228℃。成矿流体成分主要为H2O,其次为CO2,H^ ,浓度由早期到后期呈递减趋势,表明成矿热液为酸性—弱碱性的演化过程。  相似文献   

10.
徐州——宿州地区平衡剖面研究   总被引:6,自引:0,他引:6  
通过对横贯全区的3条构造平衡剖面的制作与分析,在徐宿地区推覆构造细结构及深部结构特征等问题上获得了新认识,确证了台阶状逆断层和断层相关褶皱普遍存在。复原剖面研究表明,其变形缩短率为40.5% ̄62.4%,说明研究区的推覆变形具有显著的地壳缩短与增厚作用。  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414.  相似文献   

13.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

14.
Some olistolites reworked in a Tertiary flysch of Mount Parnon (Peloponnesus, Greece) exhibit a Late Permian assemblage, dominated by Paradunbarula (Shindella) shindensis, Hemigordiopsis cf. luquensis and Colaniella aff. minima. This association corresponds to the Late Wuchiapingian (=Late Dzhulfian), a substage whose algae and foraminifera are generally little known. Contemporaneous limestones crop out in the middle part of the Episkopi Formation in Hydra, but they are rather commonly reworked in Mesozoic and Cainozoic sequences. The palaeobiogeographical affinities shared by the foraminiferal markers of Greece, southeastern Pamir, and southern China, are very strong (up to the specific level), and are congruent with the Pangea B reconstructions. To cite this article: E. Skourtsos et al., C. R. Geoscience 334 (2002) 925–931.  相似文献   

15.
PALEONTOLOGY     
正20141596 Liu Yunhuan(School of Earth Sciences and Resources,Chang’an University,Xi’an 710054,China);Shao Tiequan Early Cambrian Quadrapyrgites Fossils of Xixiang Boita in Southern Shaanxi Province(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,35(3),2013,p.39-43,3 illus.,20 refs.)  相似文献   

16.
正20141719 Chen Zhijun(State Key Laboratory of Geological Processes and Mineral Resources,China University of Geosciences,Wuhan 430074,China);Chen Jianguo Automated Batch Mapping Solution for Serial Maps:A Case Study of Exploration Geochemistry Maps(Journal of Geology,ISSN1674-3636,CN32-1796/P,37(3),2013,p.456-464,2 illus.,2 tables,10 refs.)  相似文献   

17.
正20140962 Chen Fenning(Xi’an Institute of Geology and Mineral Resources,Xi’an710054,China);Chen Ruiming Late Miocene-Early Pleistocene Ostracoda Fauna of Gyirong Basin,Southern Tibet(Acta Geologica Sinica,ISSN0001-5717,CN11-1951/P,87(6),2013,p.872-886,6illus.,56refs.)  相似文献   

18.
PETROLOGY     
正1.IGNEOUS PETROLOGY20142008Cai Jinhui(Wuhan Center,China Geological Survey,Wuhan 430205,China);Liu Wei Zircon U-Pb Geochronology and Mineralization Significance of Granodiorites from Fuzichong Pb-Zn Deposit,Guangxi,South China(Geology and Mineral Resources of South China,ISSN1007-3701,CN42-1417/P,29(4),2013,p.271-281,7illus.,  相似文献   

19.
正20141205Cheng Weiming(State Key Laboratory of Resources and Environmental Information System,Institute of Geographic Sciences and Natural Resources Research,CAS,Beijing 100101,China);Xia Yao Regional Hazard Assessment of Disaster Environment for Debris Flows:Taking Jundu Mountain,Beijing as an  相似文献   

20.
正20141266Fan Chaoyan(Guangdong Provincial Key Laboratory of Mineral Resources and Geological Processes,Guangzhou 510275,China);Wang Zhenghai On Error Analysis and Correction Method of Measured Strata Section with Wire Projection Method(Journal of  相似文献   

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