共查询到20条相似文献，搜索用时 15 毫秒
1.
A detailed petrological and geochemical study of low-temperatureperidotite xenoliths from Kimberley and northern Lesotho ispresented to constrain the processes that led to the magmaphileelement depletion of the Kaapvaal cratonic lithospheric mantleand its subsequent re-enrichment in Si and incompatible traceelements. Whole-rocks and minerals have been characterized forRe–Os isotope compositions, and major and trace elementconcentrations, and garnet and clinopyroxene for Lu–Hfand Sm–Nd isotope compositions. Most samples are characterizedby Archaean Os model ages, low Al, Fe and Ca contents, highMg/Fe, low Re/Os, very low (< 0·1 x chondrite) heavyrare earth element (HREE) concentrations and a decoupling betweenNd and Hf isotope ratios. These features are most consistentwith initial melting at 3·2 Ga followed by metasomatismby hydrous fluids, which may have also caused additional meltingto produce a harzburgitic residue. The low HREE abundances ofthe peridotites require that extensive melting occurred in thespinel stability field, possibly preceded by some melting inthe presence of garnet. Fractional melting models suggest that30% melting in the spinel field or 20% melting in the garnetfield followed by 20% spinel-facies melting are required toexplain the most melt-depleted samples. Garnet Nd–Hf isotopecharacteristics indicate metasomatic trace element enrichmentduring the Archaean. We therefore suggest a model includingshallow ridge melting, followed by metasomatism of the Kaapvaalupper mantle in subduction zones surrounding cratonic nuclei,probably during amalgamation of smaller pre-existing terranesin the Late Archaean (2·9 Ga). The fluid-metasomatizedresidua have subsequently undergone localized silicate meltinfiltration that led to clinopyroxene ± garnet enrichment.Calculated equilibrium liquids for clinopyroxene and their Hf–Ndisotope compositions suggest that most diopside in the xenolithscrystallized from an infiltrating kimberlite-like melt, eitherduring Group II kimberlite magmatism at 200–110 Ma (Kimberley),or shortly prior to eruption of the host kimberlite around 90Ma (northern Lesotho). KEY WORDS: Kaapvaal craton; lithospheric mantle; metasomatism; Nd–Hf isotopes; Re–Os isotopes 相似文献
2.
The Uintjiesberg kimberlite diatreme occurs within the Proterozoic Namaqua–Natal Belt, South Africa, approximately 60 km to the southwest of the Kaapvaal craton boundary. It is a group I, calcite kimberlite that has an emplacement age of 100 Ma. Major and trace element data, in combination with petrography, are used to evaluate its petrogenesis and the nature of its source region. Macrocryst phases are predominantly olivine with lesser phlogopite, with very rare garnet and Cr-rich clinopyroxene. Geochemical variation amongst the macrocrystic samples (Mg# 0.85–0.87, SiO 2=27.0–29.3%, MgO=26.1–30.5%, CaO=10.9–13.5%) is shown to result from 10% to 40% entrainment and partial assimilation of peridotite xenoliths, whereas that shown by the aphanitic samples (Mg# 0.80–0.83, SiO 2=19.1–23.0%, MgO=17.9–23.9%, CaO=16.5–23.7%) is consistent with 7–25% crystal fractionation of olivine and minor phlogopite. Changing trajectories on chemical variation diagrams allow postulation of a primary magma composition with 25% SiO 2, 26% MgO, 2.3% Al 2O 3, 5%H 2O, 8.6% CO 2 and Mg#=0.85. Forward melting models, assuming 0.5% melting, indicate derivation of the primary Uintjiesberg kimberlite magma from a source enriched in light rare earth elements (LREE) by 10× chondrite and heavy REE (HREE) by 0.8–2× chondrite, the latter being dependent on the proportion of residual garnet. Significant negative Rb, K, Sr, Hf and Ti anomalies present in the inferred primary magma composition are superimposed on otherwise generally smooth primitive mantle-normalized trace element patterns, and are inferred to be a characteristic of the primary magma composition. The further requirement for a source with chondritic or lower HREE abundances, residual olivine with high Fo content (Fo94) suggests derivation from a mantle previously depleted in mafic melt but subsequently enriched in highly incompatible elements prior to kimberlite genesis. These requirements are interpreted in the context of melting of continental lithospheric mantle previously enriched by metasomatic fluids derived from a sublithospheric (plume?) source. 相似文献
3.
A suite of metasomatised xenoliths from the Letlhakane kimberlite (Botswana) forms a metasomatic sequence from garnet peridotite to garnet phlogopite peridotite to phlogopite peridotite. Before the modal metasomatism, most of the Letlhakane xenoliths were depleted harzburgites that had been subjected to an earlier cryptic metasomatic event. Modal phlogopite and clinopyroxene - Cr-spinel increase at the expense of garnet and orthopyroxene with increasing degrees of metasomatism. The most metasomatised xenolith is a wehrlite. With progressive modal metasomatism, the clinopyroxene becomes enriched in Sr, Sc and the LREE, orthopyroxene becomes depleted in Ca and Ni, but enriched in Al and Mn, and olivine becomes depleted in Al and V. Garnet chemical composition largely remains unchanged. The garnet replacement reaction seen in most xenoliths allows the measurement of the flux of trace elements through detailed modal analysis of the pseudomorphs. Mass balance calculations show that the modally metasomatised rocks became enriched in incompatible elements such as Sr, Na, K, the LREE and the HFSE (Ti, Zr and Nb). Major elements (Al, Cr and Fe) and garnet-compatible trace elements (V, Y, Sc, and the HREE) were removed during this metasomatic process. The modal metasomatism caused a strong depletion in Al, and the results challenge previous suggestions that this metasomatic process merely occurred within an Al-poor environment. The data suggest that the xenoliths represent the mantle wallrock adjacent to a major conduit for an alkaline basic silicate melt (with high contents of volatile and incompatible elements). The volatile and incompatible element-enriched component of this melt percolated into the wallrock along a strong temperature gradient and caused the observed range of metasomatism. 相似文献
4.
Orthopyroxene-rich olivine websterite xenoliths (OWB 2) in Palaeogene basanites in East Serbia are mostly composed of tabular low-Al 2O 3 orthopyroxene (> 70 vol.%, Mg# 85–87) containing tiny Cr spinel inclusions. Orthopyroxene shows a slightly U-shaped primitive mantle-normalized trace element pattern with strong peaks at U and Pb, similar to that of orthopyroxene from normal regional peridotitic mantle. In between the orthopyroxenes are interstitial spaces composed of partially altered olivine (Mg# 85–87), clinopyroxene, Ti-rich spinel, Mg-bearing calcite, K-feldspar, apatite, ilmenite and relicts of a hydrous mineral. Clinopyroxene appears as selvages around orthopyroxene and as coarser euhedral crystals. Trace element patterns of the clinopyroxene selvages resemble those of adjacent orthopyroxene, whereas the coarser ones have flatter and more LREE- and LILE-enriched patterns, similar to that of metasomatic clinopyroxene. The OWB 2 xenoliths are interpreted as having formed in two stages. During Stage I orthopyroxene crystallized, along with some spinel, olivine and probably hydrous phase(s). This original OWB 2 lithology was a hydrous olivine-bearing orthopyroxenite that crystallised from subduction-related SiO 2-saturated, boninite-like magmas. During Stage II the interstitial minerals formed due to infiltration of a low-SiO 2, high-CaO and CO 2-rich external melt, accompanied by decomposition of original H 2O-bearing minerals. The calculated composition of the infiltrating liquid corresponds to a mafic alkaline melt similar to the basanitic host but more enriched in CO 2, LREE and LILE. Metasomatism is interpreted in terms of small degree melts related to the Palaeogene mafic alkaline magmatism. 相似文献
5.
Kimberlites from the Kaapvaal craton have sampled numerous mantlegarnet lherzolites in addition to garnet harzburgites. Traceelement characteristics of constituent clinopyroxenes allowtwo groups of garnet lherzolites to be distinguished. Traceelement compositions of all clinopyroxenes are characterizedby enrichment in light rare earth elements (LREE) and largeion lithophile elements and by a relative depletion in Ti, Nb,Ta, and to a lesser extent Zr and Hf. However, the LREE enrichmentand the depletion in Nb and Zr (Hf) are less in the Type 1 clinopyroxenesthan in the Type 2 clinopyroxenes. Our study suggests that thetwo melts responsible for the metasomatic imprints observedin the two garnet lherzolite groups are highly alkaline maficsilicate melts. Type 1 clinopyroxenes that have trace elementsimilarities to those of PIC (Phlogopite–Ilmenite–Clinopyroxene)rocks appear to have crystallized from, or been completely equilibratedwith, the same melt related to Group I kimberlite magma. TheType 2 clinopyroxenes have trace element similarities to thoseof MARID (Mica– Amphibole–Rutile–Ilmenite–Diopside)rocks and are therefore probably linked to melt related to GroupII kimberlite magma. KEY WORDS: garnet lherzolites; Kaapvaal craton; mantle xenoliths; mantle metasomatism; trace elements 相似文献
6.
Coarse-grained, granular spinel lherzolites xenoliths from the Premier kimberlite show evidence of melt extraction and metasomatic enrichment, documenting a complex history for the shallow mantle beneath the Bushveld complex. Compositions of orthopyroxene, clinopyroxene and spinel indicate equilibration within the spinel–peridotite facies of the upper mantle, at depths from 80 to 100 km and temperatures from 720 to 850 °C. Bulk compositions have lower Mg-number [atomic 100 Mg/(Mg + Fe*)] than previously studied spinel peridotites from Premier, and have higher Mg/Si than low-temperature coarse grained garnet lherzolites, suggesting shallower melting conditions or metasomatic enrichment. Clinopyroxene in one sample is highly LREE-depleted indicating very minor modification of a residue of 20% melt extraction, whereas the calculated REE pattern for a melt in equilibrium with a mildly LREE-depleted sample is similar to MORB or late Archean basalt, possibly related to the Bushveld Complex. Bulk and mineral compositions suggest minimal refertilization by silicate melts in four out of six samples, but REE patterns indicate introduction of a LIL-enriched component that may be related to kimberlite. 相似文献
7.
A suite of spinel lherzolite and wehrlite xenoliths from a Devonian kimberlite dyke near Kandalaksha, Kola Peninsula, Russia, has been studied to determine the nature of the lithospheric mantle beneath the northern Baltic Shield. Olivine modal estimates and Fo content in the spinel lherzolite xenoliths reveal that the lithosphere beneath the Archaean–Proterozoic crust has some similarities to Phanerozoic lithospheric mantle elsewhere. Modal metasomatism is indicated by the presence of Ti-rich and Ti-poor phlogopite, pargasite, apatite and picroilmenite in the xenoliths. Wehrlite xenoliths are considered to represent localised high-pressure cumulates from mafic–ultramafic melts trapped within the mantle as veins or lenses. Equilibration temperatures range from 775 to 969 °C for the spinel lherzolite xenoliths and from 817 to 904 °C for the wehrlites. Laser ablation ICP-MS data for incompatible trace elements in primary clinopyroxenes and metasomatic amphiboles from the spinel lherzolites show moderate levels of LREE enrichment. Replacement clinopyroxenes in the wehrlites are less enriched in LREE but richer in TiO2. Fractional melt modelling for Y and Yb concentrations in clinopyroxenes from the spinel lherzolites indicates 7–8% partial melting of a primitive source. Such a volume of partial melt could be related to the 2.4–2.5 Ga intrusion of basaltic magmas (now metamorphosed to garnet granulites) in the lower crust of the northern Baltic Shield. The lithosphere beneath the Kola Peninsula has undergone several episodes of metasomatism. Both the spinel lherzolites and wehrlites were subjected to an incomplete carbonatitic metasomatic event, probably related to an early carbonatitic phase associated with the 360–380 Ma Devonian alkaline magmatism. This resulted in crystallisation of secondary clinopyroxene rims at the expense of primary orthopyroxenes, with development of secondary forsteritic olivine and apatite. Two separate metasomatic events resulted in the crystallisation of the Ti–Fe-rich amphibole, phlogopite and ilmenite in the wehrlites and the low Ti–Fe amphibole and phlogopite in the spinel lherzolites. Alternatively, a single metasomatic event with a chemically evolving melt may have produced the significant compositional differences seen in the amphibole and phlogopite between the spinel lherzolites and wehrlites. The calculated REE pattern of a melt in equilibrium with clinopyroxenes from a cpx-rich pocket is identical to that of the kimberlite host, indicating a close petrological relationship. 相似文献
8.
The petrography and mineral composition of a mantle-derived garnet peridotite xenolith from the V. Grib kimberlite pipe (Arkhangelsk Diamond Province, Russia) was studied. Based on petrographic characteristics, the peridotite xenolith reflects a sheared peridotite. The sheared peridotite experienced a complex evolution with formation of three main mineral assemblages: (1) a relict harzburgite assemblage consist of olivine and orthopyroxene porphyroclasts and cores of garnet grains (Gar1) with sinusoidal rare earth elements (REE) chondrite C1 normalized patterns; (2) a neoblastic olivine and orthopyroxene assemblage; (3) the last assemblage associated with the formation of clinopyroxene and garnet marginal zones (Gar2). Major and trace element compositions of olivine, orthopyroxene, clinopyroxene and garnet indicate that both the neoblast and clinopyroxene-Gar2 mineral assemblages were in equilibrium with a high Fe-Ti carbonate-silicate metasomatic agent. The nature of the metasomatic agent was estimated based on high field strength elements (HFSE) composition of olivine neoblasts, the garnet-clinopyroxene equilibrium condition and calculated by REE-composition of Gar2 and clinopyroxene. All these evidences indicate that the agent was a high temperature carbonate-silicate melt that is geochemically linked to the formation of the protokimberlite melt. 相似文献
9.
The megacryst suite of the Grib kimberlite pipe (Arkhangelsk province, Russia) comprises garnet, clinopyroxene, magnesian ilmenite, phlogopite and garnet-clinopyroxene intergrowths. Crystalline inclusions, mainly of clinopyroxene and picroilmenite, occur in garnet megacrysts. Ilmenite is characterized by a wide range in the contents of MgO (10.6–15.5 wt.%) and Cr 2O 3 (0.7–8.3 wt.%). Megacryst garnets show wide variations in Cr 2O 3 (1.3–9.6 wt.%) and CaO (3.6–11.0 wt.%) but relatively constant MgO (15.4–22.3 wt.%) and FeO (5.2–9.9 wt.%). The pyroxenes also show wide variations in such oxides as Cr 2O 3, Al 2O 3 and Na 2O (0.56–2.95; 0.86–3.25; 1.3–3.0 wt.%, respectively). The high magnesium and chromium content of all these minerals puts them together in one paragenetic group. This conclusion was confirmed by studies of the crystalline inclusions in megacrysts, which demonstrate similar variations in composition. Low concentration of hematite in ilmenite suggests reducing conditions during crystallization. P– T estimates based on the clinopyroxene geothermobarometer (Contrib. Mineral. Petrol. 139 (2000) 541) show wide variations (624–1208 °C and 28.8–68.0 kbars), corresponding to a 40–45 mW/m 2 conductive geotherm. The majority of Gar-Cpx intergrowths differ from the corresponding monomineralic megacrysts in having higher Mg contents and relatively low TiO 2. The minerals from the megacryst association, as a rule, differ from the minerals of mantle xenoliths, but garnets in ilmenite-bearing peridotite xenoliths are compositionally similar to garnet megacrysts. The common features of trace element composition of megacryst minerals and kimberlite (they are poor in Zr group elements) suggest a genetic relationship. The origin of the megacrysts is proposed to be genetically connected with kimberlite magma-chamber evolution on the one hand and with associated mantle metasomatism on the other. We suggest that, depending on the primary melt composition, different paragenetic associations of macro/megacrysts can be crystallized in kimberlites. They include: (1) Fe–Ti (Mir, Udachnaya pipes); (2) high-Mg, Cr (Zagadochna, Kusova pipes); (3) high-Mg, Cr, Ti (Grib pipe). 相似文献
10.
Mantle xenoliths and xenocrysts were retrieved from three of the 88–86 Ma Buffalo Hills kimberlites (K6, K11, K14) for a reconnaissance study of the subcontinental lithospheric mantle (SCLM) beneath the Buffalo Head Terrane (Alberta, Canada). The xenoliths include spinel lherzolites, one garnet spinel lherzolite, garnet harzburgites, one sheared garnet lherzolite and pyroxenites. Pyroxenitic and wehrlitic garnet xenocrysts are derived primarily from the shallow mantle and lherzolitic garnet xenocrysts from the deep mantle. Harzburgite with Ca-saturated garnets is concentrated in a layer between 135–165 km depth. Garnet xenocrysts define a model conductive paleogeotherm corresponding to a heat flow of 38–39 mW/m 2. The sheared garnet lherzolite lies on an inflection of this geotherm and may constrain the depth of the lithosphere–asthenosphere boundary (LAB) beneath this region to ca 180 km depth. A loss of >20% partial melt is recorded by spinel lherzolites and up to 60% by the garnet harzburgites, which may be related to lithosphere formation. The mantle was subsequently modified during at least two metasomatic events. An older metasomatic event is evident in incompatible-element enrichments in homogeneous equilibrated garnet and clinopyroxene. Silicate melt metasomatism predominated in the deep lithosphere and led to enrichments in the HFSE with minor enrichments in LREE. Metasomatism by small-volume volatile-rich melts, such as carbonatite, appears to have been more important in the shallow lithosphere and led to enrichments in LREE with minor enrichments in HFSE. An intermediate metasomatic style, possibly a signature of volatile-rich silicate melts, is also recognised. These metasomatic styles may be related through modification of a single melt during progressive interaction with the mantle. This metasomatism is suggested to have occurred during Paleoproterozoic rifting of the Buffalo Head Terrane from the neighbouring Rae Province and may be responsible for the evolution of some samples toward unradiogenic Nd and Hf isotopic compositions. Disturbed Re–Os isotope systematics, evident in implausible model ages, were obtained in situ for sulfides in several spinel lherzolites and suggest that many sulfides are secondary (metasomatic) or mixtures of primary and secondary sulfides. Sulfide in one peridotite has unradiogenic 187Os/188Os and gives a model age of 1.89±0.38 Ga. This age coincides with the inferred emplacement of mafic sheets in the crust and suggests that the melts parental to the intrusions interacted with the lithospheric mantle. A younger metasomatic event is indicated by the occurrence of sulfide-rich melt patches, unequilibrated mineral compositions and overgrowths on spinel that are Ti-, Cr- and Fe-rich but Zn-poor. Subsequent cooling is recorded by fine exsolution lamellae in the pyroxenes and by arrested mineral reactions. If the lithosphere beneath the Buffalo Head Terrane was formed in the Archaean, any unambiguous signatures of this ancient origin may have been obliterated during these multiple events. 相似文献
11.
The diamondiferous Letlhakane kimberlites are intruded into the Proterozoic Magondi Belt of Botswana. Given the general correlation
of diamondiferous kimberlites with Archaean cratons, the apparent tectonic setting of these kimberlites is somewhat anomalous.
Xenoliths in kimberlite diatremes provide a window into the underlying crust and upper mantle and, with the aid of detailed
petrological and geochemical study, can help unravel problems of tectonic setting. To provide relevant data on the deep mantle
under eastern Botswana we have studied peridotite xenoliths from the Letlhakane kimberlites. The mantle-derived xenolith suite
at Letlhakane includes peridotites, pyroxenites, eclogites, megacrysts, MARID and glimmerite xenoliths. Peridotite xenoliths
are represented by garnet-bearing harzburgites and lherzolites as well as spinel-bearing lherzolite xenoliths. Most peridotites
are coarse, but some are intensely deformed. Both garnet harzburgites and garnet lherzolites are in many cases variably metasomatised
and show the introduction of metasomatic phlogopite, clinopyroxene and ilmenite. The petrography and mineral chemistry of
these xenoliths are comparable to that of peridotite xenoliths from the Kaapvaal craton. Calculated temperature-depth relations
show a well-developed correlation between the textures of xenoliths and P-T conditions, with the highest temperatures and pressures calculated for the deformed xenoliths. This is comparable to xenoliths
from the Kaapvaal craton. However, the P-T gap evident between low- T coarse peridotites and high- T deformed peridotites from the Kaapvaal craton is not seen in the Letlhakane xenoliths. The P-T data indicate the presence of lithospheric mantle beneath Letlhakane, which is at least 150 km thick and which had a 40mW/m 2 continental geotherm at the time of pipe emplacement. The peridotite xenoliths were in internal Nd isotopic equilibrium at
the time of pipe emplacement but a lherzolite xenolith with a relatively low calculated temperature of equilibration shows
evidence for remnant isotopic disequilibrium. Both harzburgite and lherzolite xenoliths bear trace element and isotopic signatures
of variously enriched mantle (low Sm/Nd, high Rb/Sr), stabilised in subcontinental lithosphere since the Archaean. It is therefore
apparent that the Letlhakane kimberlites are underlain by old, cold and very thick lithosphere, probably related to the Zimbabwe
craton. The eastern extremity of the Proterozoic Magondi Belt into which the kimberlites intrude is interpreted as a superficial
feature not rooted in the mantle.
Received: 19 March 1996 / Accepted: 16 October 1996 相似文献
12.
The concentrations of platinum-group elements (PGE; Os, Ir, Ru, Pd and Pt) and Re, and the Os isotopic compositions were determined for 33 lithospheric mantle peridotite xenoliths from the Somerset Island kimberlite field. The Os isotopic compositions are exclusively less radiogenic than estimates of bulk-earth ( 187Os/ 188Os as low as 0.1084) and require a long-term evolution in a low Re–Os environment. Re depletion model ages ( TRD) indicate that the cratonic lithosphere of Somerset Island stabilised by at least 2.8 Ga, i.e. in the Neoarchean and survived into the Mesozoic to be sampled by Cretaceous kimberlite magmatism. An Archean origin also is supported by thermobarometry (Archean lithospheric keels are characterised by >150 km thick lithosphere), modal mineralogy and mineral chemistry observations. The oldest ages recorded in the lithospheric mantle beneath Somerset Island are younger than the Mesoarchean (>3 Ga) ages recorded in the Slave craton lithospheric mantle to the southwest [Irvine, G.J., et al., 1999. Age of the lithospheric mantle beneath and around the Slave craton: a Rhenium–Osmium isotopic study of peridotite xenoliths from the Jericho and Somerset Island kimberlites. Ninth Annual V.M. Goldschmidt Conf., LPI Cont., 971: 134–135; Irvine, G.J., et al., 2001. The age of two cratons: a PGE and Os-Isotopic study of peridotite xenoliths from the Jericho kimberlite (Slave craton) and the Somerset Island kimberlite field (Churchill Province). The Slave–Kaapvaal Workshop, Merrickville, Ontario, Canada]. Younger, Paleoproterozoic, TRD model ages for Somerset Island samples are generally interpreted as the result of open system behaviour during metasomatic and/or magmatic processes, with possibly the addition of new lithospheric material during tectono-thermal events related to the Taltson–Thelon orogen. PGE patterns highly depleted in Pt and Pd generally correspond to older Archean TRD model ages indicating closed system behaviour since the time of initial melt extraction. Younger Proterozoic TRD model ages generally correspond to more complex PGE patterns, indicating open system behaviour with possible sulfide or melt addition. There is no correlation between the age of the lithosphere and depth, at Somerset Island. 相似文献
13.
Dunite, wehrlite and websterite are rare members of the mantle xenolith suite in the Kimberley kimberlites of the Kaapvaal Craton in southern Africa. All three types were originally residues of extensive melt extraction and experienced varying amounts and types of melt re-enrichment. The melt depletion event, dated by Re-Os isotope systematics at 2.9 Ga or older, is evidenced by the high Mg# (Mg/(Mg + Fe)) of silicate minerals (olivine (0.89-0.93); pyroxene (0.88-0.93); garnet (0.72-0.85)), high Cr# (Cr/(Cr + Al)) of spinel (0.53-0.84) and mostly low whole-rock SiO 2, CaO and Al 2O 3 contents. Shortly after melt depletion, websterites were formed by reaction between depleted peridotites and silica-rich melt (>60 wt% SiO 2) derived by partial melting of eclogite before or during cratonization. The melt-peridotite interaction converted olivine into orthopyroxene.All three xenolith types have secondary metasomatic clinopyroxene and garnet, which occur along olivine grain boundaries and have an amoeboid texture. As indicated by the preservation of oxygen isotope disequilibrium in the minerals and trace-element concentrations in clinopyroxene and garnet, this metasomatic event is probably of Mesozoic age and was caused by percolating alkaline basaltic melts. This melt metasomatism enriched the xenoliths in CaO, Al 2O 3, FeO and high-field-strength-elements, and might correspond to the Karoo magmatism at 200 Ma. The websterite xenoliths experienced both the orthoyproxene-enrichment and clinopyroxene-garnet metasomatic events, whereas dunite and wehrlite xenoliths only saw the later basaltic melt event, and may have been situated further away from the source of melt migration channels. 相似文献
14.
Trace element partition coefficients ( D's) for up to 13 REE, Nb, Ta, Zr, Hf, Sr and Y have been determined by SIMS analysis of seven garnets, four clinopyroxenes, one orthopyroxene and one phlogopite crystallized from an undoped basanite and a lightly doped (200 ppm Nb, Ta and Hf) quartz tholeiite. Experiments were conducted at 2–7.5 GPa, achieving near-liquidus crystallization at relatively low temperatures of 1080–1200°C under strongly hydrous conditions (5–27 wt.% added water). Garnet and pyroxene DREE show a parabolic pattern when plotted against ionic radius, and conform closely to the lattice strain model of Blundy and Wood (Blundy, J.D., Wood, B.J., 1994. Prediction of crystal–melt partition coefficients from elastic moduli. Nature 372, 452–454). Comparison, at constant pressure, between hydrous and anhydrous values of the strain-free partition coefficient ( D0) for the large cation sites of garnet and clinopyroxene reveals the relative importance of temperature and melt water content on partitioning. In the case of garnet, the effect of lower temperature, which serves to increase D0, and higher water content, which serves to decrease D0, counteract each other to the extent that water has little effect on garnet–melt D0 values. In contrast, the effect of water on clinopyroxene–melt D0 overwhelms the effect of temperature, such that D0 is significantly lower under hydrous conditions. For both minerals, however, the lower temperature of the hydrous experiments tends to tighten the partitioning parabolas, increasing fractionation of light from heavy REE compared to anhydrous experiments. Three sets of near-liquidus clinopyroxene–garnet two-mineral D values increase the range of published experimental determinations, but show significant differences from natural two-mineral D's determined for subsolidus mineral pairs. Similar behaviour is observed for the first experimental data for orthopyroxene–clinopyroxene two-mineral D's when compared with natural data. These differences are in large part of a consequence of the subsolidus equilibration temperatures and compositions of natural mineral pairs. Great care should therefore be taken when using natural mineral–mineral partition coefficients to interpret magmatic processes. The new data for strongly hydrous compositions suggest that fractionation of Zr–Hf–Sm by garnet decreases with increasing depth. Thus, melts leaving a garnet-dominated residuum at depths of about 200 km or greater may preserve source Zr/Hf and Hf/Sm. This contrasts with melting at shallower depths where both garnet and clinopyroxene will cause Zr–Hf–Sm fractionation. Also, at shallower depths, clinopyroxene-dominated fractionation may produce a positive Sr spike in melts from spinel lherzolite, but for garnet lherzolite melting, no Sr spike will result. Conversely, clinopyroxene megacrysts with negative Sr spikes may crystallize from magmas without anomalous Sr contents when plotted on mantle compatibility diagrams. Because the characteristics of strongly hydrous silicate melt and solute-rich aqueous fluid converge at high pressure, the hydrous data presented here are particularly pertinent to modelling processes in subduction zones, where aqueous fluids may have an important metasomatic role. 相似文献
15.
Major, trace element and radiogenic isotope results are presented for a suite of hypabyssal kimberlites from a single pipe, at the Finsch Mine, South Africa. These are Group 2 kimberlites characterised by abundant phlogopite ± serpentine ± diopside; they are ultrabasic (SiO 2 < 42 wt.%%) and ultrapotassic (K 2O/Na 2O > 6.9) igneous rocks, they exhibit a wide range in major element chemistry with SiO 2 = 27.6−41.9 wt. % and MgO = 10.4−33.4 wt. %. ( 87Sr/ 86Sr) i=0.7089 to 0.7106, ε Nd is −6.2 to −9.7 and they have unradiogenic ( 207Pb/ 204Pb) i contents which ensure that they plot below the Pb-ore growth curve. They have high incompatible and compatible element contents, a striking positive array between Y and Nb which indicates that garnet was not involved in the within suite differentiation processes, and a negative trend between K/Nb and Nb contents which suggests that phlogopite was involved. In addition, some elements exhibit an unexpected order of relative incompatibility for different trace elements which suggests that the intra-kimberlite variations are not primarily due to variations in the degree of partial melting. The effects of fractional crystallization are difficult to establish because for the most part they have been masked by the entrainment of 50–60% mantle peridotite. Thus, the Finsch kimberlites are interpreted as mixtures of a melt component and entrained garnet peridotite, with no evidence for significant contamination with crustal material. The melt component was characterised by high incompatible element contents, which require both very small degrees of partial melting, and source regions with higher incompatible element contents than depleted or primitive mantle. Since the melt component was the principal source of incompatible elements in the kimberlite magma, the enriched Nd, Sr and Pb isotope ratios of the kimberlite are characteristic of the melt source region. The melt fractions were therefore derived from ancient, trace elements enriched portions of the upper mantle, most probably situated within the sub-continental mantle lithosphere, and different from the low 87Sr/ 86Sr garnet peridotite xenoliths found at Finsch. Within the sub-continental mantle lithosphere old, incompatible element enriched source regions for the kimberlite melt fraction are inferred to have been overlain by depleted mantle material which became entrained in the kimberlite magma. 相似文献
16.
Garnet peridotite xenoliths from the Sloan kimberlite (Colorado) are variably depleted in their major magmaphile (Ca, Al) element compositions with whole rock Re-depletion model ages generally consistent with this depletion occurring in the mid-Proterozoic. Unlike many lithospheric peridotites, the Sloan samples are also depleted in incompatible trace elements, as shown by the composition of separated garnet and clinopyroxene. Most of the Sloan peridotites have intermineral Sm–Nd and Lu–Hf isotope systematics consistent with this depletion occurring in the mid-Proterozoic, though the precise age of this event is poorly defined. Thus, when sampled by the Devonian Sloan kimberlite, the compositional characteristics of the lithospheric mantle in this area primarily reflected the initial melt extraction event that presumably is associated with crust formation in the Proterozoic—a relatively simple history that may also explain the cold geotherm measured for the Sloan xenoliths. The Williams and Homestead kimberlites erupted through the Wyoming Craton in the Eocene, near the end of the Laramide Orogeny, the major tectonomagmatic event responsible for the formation of the Rocky Mountains in the late Cretaceous–early Tertiary. Rhenium-depletion model ages for the Homestead peridotites are mostly Archean, consistent with their origin in the Archean lithospheric mantle of the Wyoming Craton. Both the Williams and Homestead peridotites, however, clearly show the consequences of metasomatism by incompatible-element-rich melts. Intermineral isotope systematics in both the Homestead and Williams peridotites are highly disturbed with the Sr and Nd isotopic compositions of the minerals being dominated by the metasomatic component. Some Homestead samples preserve an incompatible element depleted signature in their radiogenic Hf isotopic compositions. Sm–Nd tie lines for garnet and clinopyroxene separates from most Homestead samples provide Mesozoic or younger “ages” suggesting that the metasomatism occurred during the Laramide. Highly variable Rb–Sr and Lu–Hf mineral “ages” for these same samples suggest that the Homestead peridotites did not achieve intermineral equilibrium during this metasomatism. This indicates that the metasomatic overprint likely was introduced shortly before kimberlite eruption through interaction of the peridotites with the host kimberlite, or petrogenetically similar magmas, in the Wyoming Craton lithosphere. 相似文献
17.
首次报道了来自东北地区岩石圈地幔水含量的数据。通过对吉林龙岗和汪清新生代玄武岩中的橄榄岩包体矿物进行电子探针(EMP)和激光熔蚀等离子体质谱(LA-ICPMS)的分析,得到了矿物的主量元素和微量元素的数据,结果显示这些橄榄岩是原始地幔经历了不同程度部分熔融的残余,大部分样品的熔融程度可能<10%。橄榄岩样品在后期还经历了地幔交代作用,大部分样品受到硅酸岩熔体的交代,少部分样品受到碳酸岩熔体的交代。显微傅里叶变换红外光谱(FTIR)的分析结果显示,橄榄岩样品中的单斜辉石、斜方辉石均含有以结构羟基形式存在的水,而橄榄石中没有明显的羟基吸收峰。龙岗样品中单斜辉石的水含量为(48~464)×10 -6(H 2O, 质量分数),斜方辉石水含量为(28~104)×10 -6;汪清样品中单斜辉石的水含量为(34~403)×10 -6,斜方辉石的水含量为(13~89)×10 -6;所有样品全岩水含量为(8~92)×10 -6。样品的水含量可以代表龙岗和汪清地区岩石圈地幔的水含量信息,并且水含量变化范围较大,造成这种变化的原因可能是由于地幔源区初始水含量的不均一,以及部分熔融和地幔交代作用叠加的结果。 相似文献
18.
On a global scale, peridotitic garnet inclusions in diamonds from the subcratonic lithosphere indicate an evolution from strongly sinusoidal REE N, typical for harzburgitic garnets, to mildly sinusoidal or “normal” patterns (positive slope from LREE N to MREE N, fairly flat MREE N–HREE N), typical for lherzolitic garnets. Using the Cr-number of garnet as a proxy for the bulk rock major element composition it becomes apparent that strong LREE enrichment in garnet is restricted to highly depleted lithologies, whereas flat or positive LREE–MREE slopes are limited to less depleted rocks. For lherzolitic garnet inclusions, there is a positive relation between equilibration temperature, enrichment in MREE, HREE and other HFSE (Ti, Zr, Y), and decreasing depletion in major elements. For harzburgitic garnets, relations are not linear, but it appears that lherzolite style enrichment in MREE–HREE only occurs at temperatures above 1150–1200 °C, whereas strong enrichment in Sr is absent at these high temperatures. These observations suggest a transition from melt metasomatism (typical for the lherzolitic sources) characterized by fairly unfractionated trace and major element compositions to metasomatism by CHO fluids carrying primarily incompatible trace elements. Melt and fluid metasomatism are viewed as a compositional continuum, with residual CHO fluids resulting from primary silicate or carbonate melts in the course of fractional crystallization and equilibration with lithospheric host rocks. Eclogitic garnet inclusions show “normal” REEN patterns, with LREE at about 1× and HREE at about 30× chondritic abundance. Clinopyroxenes approximately mirror the garnet patterns, being enriched in LREE and having chondritic HREE abundances. Positive and negative Eu anomalies are observed for both garnet and clinopyroxene inclusions. Such anomalies are strong evidence for crustal precursors for the eclogitic diamond sources. The trace element composition of an “average eclogitic diamond source” based on garnet and clinopyroxene inclusions is consistent with derivation from former oceanic crust that lost about 10% of a partial melt in the garnet stability field and that subsequently experienced only minor reenrichment in the most incompatible trace elements. Based on individual diamonds, this simplistic picture becomes more complex, with evidence for both strong enrichment and depletion in LREE. Trace element data for sublithospheric inclusions in diamonds are less abundant. REE in majoritic garnets indicate source compositions that range from being similar to lithospheric eclogitic sources to strongly LREE enriched. Lower mantle sources, assessed based on CaSi–perovskite as the principal host for REE, are not primitive in composition but show moderate to strong LREE enrichment. The bulk rock LREEN–HREEN slope cannot be determined from CaSi–perovskites alone, as garnet may be present in these shallow lower mantle sources and then would act as an important host for HREE. Positive and negative Eu anomalies are widespread in CaSi–perovskites and negative anomalies have also been observed for a majoritic garnet and a coexisting clinopyroxene inclusion. This suggests that sublithospheric diamond sources may be linked to old oceanic slabs, possibly because only former crustal rocks can provide the redox gradients necessary for diamond precipitation in an otherwise reduced sublithospheric mantle. 相似文献
19.
In situ trace element analyses of constituent minerals in mantle xenoliths occurring in an alnöite diatreme and in nephelinite plugs emplaced within the central zone of the Damara Belt have been determined by laser ablation ICP-MS. Primitive mantle-normalized trace element patterns of clinopyroxene and amphibole indicate the presence of both depleted MORB-like mantle and variably enriched mantle beneath this region. Clinopyroxenes showing geochemical depletion have low La/Sm n ratios (0.02–0.2), whereas those showing variable enrichment have La/Sm n ranging up to 3.8 and La/Yb n to 9.1. The most enriched clinopyroxenes coexist with amphibole showing similar REE patterns (La/Sm n = 1.3–4.1; La/Yb n = 4.5–9). Primitive mantle-normalized trace element patterns allow further groups to be distinguished amongst the variably enriched clinopyroxenes: one having strong relative depletion in Rb–Ba, Ta–Nb and relative enrichment in Th–U; another with similar characteristics but with additional strong relative depletion in Zr–Hf; and one showing no significant anomalies. Amphiboles show similar normalized trace element patterns to co-existing clinopyroxene. Clinopyroxene and amphiboles showing LREE N enrichment have high Sr and low Nd isotope ratios compared to clinopyroxene with LREE-depleted patterns. Numerical simulation of melt percolation through the mantle via reactive porous flow is used to show that the chromatographic affect associated with such a melt migration process is able to account for the fractionation seen in La–Ce–Nd in cryptically metasomatized clinopyroxenes in Type 1 xenoliths, where melt–matrix interactions occur near the percolation front, whereas REE patterns in clinopyroxenes proximal to the source of metasomatic melt/fluid match those found in modally metasomatized Type 2 xenoliths. The strong fractionation between Rb–Ba, Th–U and Ta–Nb shown by some cryptically metasomatized xenoliths can be also accounted for by reactive porous flow, provided amphibole crystallizes from the percolating melt/fluid close to its source. The presence of amphibole in vein-like structures in some xenoliths is consistent with this interpretation. The strong depletion in Zr–Hf in clinopyroxene and amphibole in some xenoliths cannot be accounted for by melt migration processes and requires metasomatism by a separate carbonate-rich melt/fluid. When taken together with published isotope data on these same xenoliths, the source of metasomatic enrichment of the previously depleted (MORB-like) sub-Damaran lithospheric mantle is attributed to the upwelling Tristan plume head at the time of continental breakup. 相似文献
20.
Xenoliths from the upper mantle and lower crust are abundant in Plio–Pleistocene alkali basalts of the Nógrád-Gömör Volcanic Field (NGVF; northern Pannonian Basin, northern Hungary/southern Slovakia), representing a valuable ‘probe’ of lithospheric structures and processes. Ultramafic xenoliths have been divided into two groups: (1) Type-I, composed mostly of olivine with subsidiary orthopyroxene, clinopyroxene and spinel, and (2) Type-II, containing mostly Al- and Ti-rich clinopyroxene with subordinate olivine, spinel and plagioclase. Both types often contain amphibole and, to a lesser extent, mica. The refractory character of Type-I xenoliths suggests they represent mantle depleted by prior episodes of partial melting. In contrast, Type-II series (wehrlites, olivine clinopyroxenites, clinopyroxenites and plagioclase-bearing ultramafic lithologies), on the basis of their textural features, thermobarometric histories and major and trace element variation, appear to have formed as magmatic cumulates. Petrologic and geochemical studies of Type-II xenoliths from Nógrád-Gömör suggest they crystallized from basaltic melts emplaced within the lithospheric mantle and lower crust, prior to the onset of Plio–Pleistocene volcanic activity. After their consolidation, metasomatic agents reacted with the anhydrous cumulate phases producing amphiboles and micas at the expense of olivine and clinopyroxene. The metasomatic agents appear to have been adakitic rather than basaltic in composition, possibly linked to a retreating arc–forearc system. Large-scale contamination of the lithospheric mantle can therefore be attributed to fluid and melt fractions related to subduction beneath the outer Carpathian arc. 相似文献
|
