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1.
The anodic stripping voltammetry with physically-coating mercury film electrode was used to investigate the complexing action of trace heavy metals in seawater with organic ligands. The apparent copper complexing capacity of seawater was determined by titrating the organic ligands in natural seawater with standard ionic copper solution. The complexing actions of copper in seawater with humic acid (HA) or fulvic acid (FA) were investigated by titrating copper in seawater with HA or FA solution. The equilibrium time, electrodeposition potential, and effect of pH etc. were investigated respectively. The results show that the interaction of copper in seawater with organic matter is a fast process. At natural pH, HA or FA tend to act with copper in seawater to form nonlabile complexes. During experimental electrode process, these complexes did not significantly dissociate. The experimental results were calculated according to 1∶1 complex formation.  相似文献   

2.
伏牛山是河南省的著名山脉 ,是我国亚热带向北暖温带的过渡带 ,是长江、黄河、淮河三大水系的分水岭 ,是华北地台和扬子地台的结合部。这里动、植物资源丰富 ,自然景观优美迷人 ,开发以旅游观光 ,生态示范 ,休闲度假、科普探险为一体的生态旅游区非常理想 ,是河南省近期重点开发的两条旅游线之一。文章从地质资源等方面详细介绍了伏牛山的概况 ,全面分析了伏牛山特殊的旅游价值和开发优势 ,提出了伏牛山生态旅游开发的基本思路 ,为伏牛山的系列开发提供了较好的科学依据。  相似文献   

3.
Global and local climate changes could disturb carbon sequestration and carbon stocks in forest soils. Thus, it is important to characterize the stability of soil organic matter and the dynamics of soil organic carbon (SOC) fractions in forest ecosystems. This study had two aims: (1) to evaluate the effects of altitude and vegetation on the content of labile and stabile forms of organic carbon in the mountain soils; and (2) to assess the impact of the properties of soil organic matter on the SOC pools under changing environmental conditions. The studies were conducted in the Karkonosze Mountains (SW Poland, Central Europe). The content of the most labile fraction of carbon (dissolved organic carbon, DOC) decreases with altitude, but the content of fulvic acids (FA), clearly increases in the zone above 1000 m asl, while the stabile fraction (humins, non-hydrolyzing carbon) significantly decreases. A higher contribution of stabile forms was found in soils under coniferous forests (Norway spruce), while a smaller - under deciduous forests (European beech) and on grasslands. The expected climate change and the ongoing land use transformations in the zone above 1000 m asl may lead to a substantial increase in the stable humus fraction (mainly of a non-hydrolyzing carbon) and an increase in the SOC pools, even if humus acids are characterized by a lower maturity and greater mobility favorable to soil podzolization. In the lower zone (below 1000 m asl), a decrease in the most stable humus forms can be expected, accompanied by an increase of DOC contribution, which will result in a reduction in SOC pools. Overall, the expected prevailing (spatial) effect is a decreasing contribution of the most stable humus fractions, which will be associated with a reduction in the SOC pools in medium-high mountains of temperate zone of Central Europe.  相似文献   

4.
砂岩型铀矿成矿过程中腐殖酸的化学作用   总被引:1,自引:0,他引:1  
研究表明,腐殖酸在铀成矿过程中的化学作用受多种因素制约,如pH值、温度和离子强度等。由于腐殖酸和富啡酸结构中的一些单元与一些小分子的芳香有机酸相似,因此,利用小分子的芳香有机酸来代替腐殖酸,研究不同条件下腐殖酸对铀成矿的影响,并获得了不同形式铀的配合物,证明了铀在含腐殖酸环境中的赋存状态。  相似文献   

5.
The Liangshui Natural Reserve in Heilongjiang Province of China was selected as the study area. The authors collected the samples of forest litter (Tilia amurensis, Fraxinus mandshurica, Pinus koraiensis, Acer mono, Betula costata, and mixed litter), soil in humus horizon (0--5cm) and soil horizon (5-20cm), and soil macrofauna (Oligochaeta, Geophiloporpha and Juliformia) from 2001 to 2002. The role of soil macrofauna in the material cycle was analyzed through comparing the macro-element contents among various parts of the subsystems and using enrichment index (El). The results indicate that dynamic changes of various litters are very complicated. The contents of Fe in each kind of litter increase firstly, and then decrease in the study period. The changes of macro-element contents are greater in the broad-leaf litter than in the coniferous litter, and the mixed litter is in the middle level, but the differences among them are not significant. The contents of Mg and Fe in humus are higher than those in soil, but the contents of Ca in soil are higher than that in humus. The dynamic changes of macro-element contents in soil and soil fauna are not consistent with those in litter. The diplopod presented obvious enrichment of Ca and Mg (E1〉1), but it does not significantly enrich Fe. Earthworm has a stronger enrichment ability of Fe than diplopod and scolopendra, but E1〈1. Soil fauna can make great influences on the material cycle of the subsystems.  相似文献   

6.
Alpine grassland soils on Qinghai-Tibet Plateau store approximately 33.5 Pg of organic carbon(C) at 0–0.75 m depth and play an important role in the global carbon cycle.We investigated soil organic C(SOC),water-soluble organic C(WSOC),easily oxidizable organic C(EOC),humic C fractions,aggregate-associated C,aggregate stability,and humic acid(HA) composition along an east-west transect across Qinghai-Tibet Plateau,and explored their spatial patterns and controlling factors.The contents of SOC,WSOC,EOC,humic C fractions and aggregate-associated C,the proportions of macroaggregates(2-0.25) and micro-aggregates(0.25-0.053 mm),and the aggregate stability indices all increased in the order alpine desert alpine steppe alpine meadow.The alkyl C,O-alkyl C,and aliphatic C/aromatic C ratio of HA increased as alpine desert alpine meadow alpine steppe,and the trends were reverse for the aromatic C and HB/HI ratio.Mean annual precipitation and aboveground biomass weresignificantly correlated with the contents of SOC and its fractions,the proportions of macro- and microaggregates,and the aggregate stability indices along this transect.Among all these C fractions,SOC content and aggregate stability were more closely associated with humic C and silt and clay sized C in comparison with WSOC,EOC,and macro- and microaggregate C.The results suggested that alpine meadow soils containing higher SOC exhibited high soil aggregation and aggregate stability.Mean annual precipitation should be the main climate factor controlling the spatial patterns of SOC,soil aggregation,and aggregate stability in this region.The resistant and stable C fractions rather than labile C fractions are the major determinant of SOC stocks and aggregate stability.  相似文献   

7.
Application of swat model in the upstream watershed of the Luohe River   总被引:6,自引:0,他引:6  
1INTRODUCTIONIntheHuanghe(Yellow) Riverbasin, soilerosionisaseriousproblem,whilerunoffandsedimentyieldsim-ulation hasnotbeenextensivelystudiedonthebasisofGIS(GeographicInformationSystem) and dis-tributedhydrologicalmodel.Inthisstudy,theLushiwatershed,whichislocatedattheupstreamoftheLushiHydrologicalStationintheLuoheRiver—thebiggesttributary oftheHuanghe Riveranddown-streamofXiaolangdiDam,isselectedasthestudyarea.ThelevelofsoilerosioninLushiwatershedismoderatein theHuangheRiverbas…  相似文献   

8.
Based on the spatial organizational structures of the provincial border-regions (a border-region is one which borders two or more independent administrative regions), we build a spatial economic model for N-provincial border-regions (a N-p border-region is one which is under the jurisdiction of N provincial governments) and find that, for a given region with same geographical condition and resources endowment, the largest output of a N-p border-regional system will not exceed that of a (N-1)-p border-regional system, i.e., F1*>F2*...>FN−1*>Fn*. Using the model in this paper, we present a quantitative method to calculate the economic impacts of "provincial borders" and apply it to the border-region of Shanxi, Hebei, Shangdong, and Henan provinces. The results shows that the economic potential in the border-region has not been efficiently exploited and that the annual gross agricultural products have decreased by 10.4% due to the 4-p borders. Financial supports from China National Science Foundation and National Social Science Foundation are graterfully acknowledged.  相似文献   

9.
At present, approximately 36% of coasts are experiencing net erosion in the Changjiang River delta and the north Jiangsu coastal plain. Future sea level rise will accelerate the process of coastal erosion. According to the ratio of the calculated value of coast retreat by Bruun rule to the estimated value by using measured data, the proportion affected by sea level rise in total coastal erosion has been estimated in this paper. When sea level rises by 20cm, the proportion determined by sea level rise will increase from 1.0% at present to 2.2% in the future in the coasts of abandoned Huanghe River delta and from 8.5%–9.6% to 13.5%–15.2% in the north and south banks of the Changjiang River delta. This result is lower than that from the similar research in the world, and this phenomenon is related with the special development process of the coasts in this area. The mechanism of accelerating coastal erosion by sea level rise is that sea level is will increase the intensity of tidal current, wave and storm surge and decrease the ability to reduce the force of waves on the tidal flat and coastal wetland due to the loss of their areas. Therefore, the length of erosion coasts will increase, the sedimentation rate of accretion coasts will decrease or even turn accretion into erosion, the width of tidal flat will reduce and coastal slope will increase. So the project of coastal protection of this area must be reinforced. Project funded by the National Natural Science Foundation of China and the Chinese Academy of Sciences.  相似文献   

10.
TheQuaternalypaleo--environmentoftheLushan,HuangshanandTianmumountainsisasignificantacademicproblemtowhichmuchattentionhasbeenpaidbymanyresearchersingeosciencecircle.Manyscholarshavestudiedtheproblemandgotalotofachivementsoverthepastyears(Lee,1933;Lee,1936;Lee,1947;Ren,1953;Huang,1963;Li,1974;Shi,1989).HOWever,identicalviewsandconclusionshavenotbeenreachedyetuptillnow,especiallylackingofcomprehensivestudyforsedimentsintheseregions.Inrecentyears,applyingsedimentalcomprehensiveindexgotfromv…  相似文献   

11.
Understanding the effects of elevation and related factors (climate, vegetation) on the physical and chemical soil properties can help to predict changes in response to future climate or afforestation forcings. This work aims to contribute to the knowledge of soil evolution and the classification of forest soils in relation to elevation in the montane stage, with special attention to podzolization and humus forms. The northern flank of the Moncayo Massif (Iberian Range, SW Europe) provides a unique opportunity to study a forest soils catena within a consistent quartzitic parent material over a relatively steep elevation gradient. With increasing elevation, pH, base saturation, exchangeable potassium, and fine silt-sized particles decrease significantly, while organic matter, the C/N ratio, soil aggregate stability, water repellency and coarse sand-sized particles increase significantly. The soil profiles shared a set of properties in all horizons: loamy-skeletal particle-size, extreme acidity (pH-H2O<5.6) and low base saturation (<50%). The most prevalent soil forming processes in the catena include topsoil organic matter accumulation and even podzolization, which increases with elevation. From the upper to lower landscape positions of wooded montane stage of the Moncayo Massif, mull-moder-mor humus and an Umbrisol-Cambisol-Podzol soil unit sequences were found.  相似文献   

12.
There are 463 species of woody plant, belonging to 166 genera and 70 families in Shanxi, North China. The floristic composition types of genera and species are abundant, in which the compositions distributed in temperate zones (including North Temperate, Old World Temperate and Temperate Asia), having 62 genera, are dominant and account for 38.27% in total genera (except for Cosmopolitan), and they are major constructive or dominant species of vegetation in Shanxi. The floristic compositions of woody plants of Shanxi, Hebei, Beijing, Shandong, Henan, Jiangxi and Inner Mongolia were studied comparatively by using diversity index, principal component analysis (PCA) and group-average clustering, respectively. The floristic composition of Shanxi was considerably similar to that of Hebei, Beijing and Shandong because they shared a lot of genera, specially genera distributed in temperate regions, such as Rosa, Quercus, Populus, Salix, Acer, Ulmus, Pinus etc. and their eco-environment were considerably similar. However, the flora of Shanxi was comparatively different from that of Henan, Jiangxi and Inner Mongolia by reason that there were distinct differences among their eco-geographic conditions, floristic compositions and constructive or dominant species of dominant vegetation types. Supported by Shanxi Returned Oversea Scholar Foundation, China  相似文献   

13.
Soil types, humus types and vegetation as well as their hypsometric variation were analysed in terms of sequences in the northern part of the high mountains of the Pirin National Park at altitudes between looo and 2400 m a.s.1. The study area is characterised by a large variety of natural parameters like petrology (mainly marble and granite), morphology (different slope deposits, exposition) and the orographic climate gradient. Statistical analyses using these parameters provided a basis for the soil group classification of the sites. Based on a Digital Terrain Model (DTM) and a geological map of the Pirin National Park, the results of these statistical analyses were used to generate a "map of potential soil groups" (regionalisation using GIS). Six potential soil groups could be determined. The resulting map exhibits a confidence level of 68 % on 74.4 % of the covered area. Rendzic Leptosols, in combination with Folic Histosols and Histi-lithic Leptosols occur in the alpine and subalpine regions on calcareous substrates. With decreasing altitude they are replaced by a mosaic of Rendzic Leptosols, Phaeozems and an increasing occurrence of Cambic Umbrisols. Umbrisols found on silicatic substrates in the alpine region are replaced by Cambic Umbrisols with decreasing altitude as well. Hence, pedogenesis is characterised by increasing browning and depth of the soil profiles with decreasing altitude. The pH-level is slightly acidic to neutral in lower zones and on calcareous rocky bases. Acidification increases in the subalpine zone. Soil pH decreases down to 4 on silicate subtrates. Typical humic values in mineral topsoils are 10 to 12 %, and in organic layers of the soils above 2000 m a.s.1, they are even more. The C:N ratio closely ranges around 20 (median).  相似文献   

14.
ECOLOGICAL SERIES OF SOIL ANIMALS IN DARLIDAI MOUNTAIN   总被引:1,自引:0,他引:1  
The ecological series of soil animals under the broad-leaved and pine mixed forest in Darlidai Mountainwas studied. Seven sample plots were selected according to different altitude gradients, which belong to different vegeta-tion types. By investigating and analyzing soil animals in every sample plot it is found that there are 45 groups and 1956individuals, which axe involved in 3 phylums, 7 classes, 16 orders, respectively. The altitude is a key factor which af-fects ecological series of soil animals. Both the groups and individuals of soil animals increase with altitude increasingunder certain conditions, which contrastes with ordinary cases, resulting from special micro-climate in studied area. Thegroups and individuls of soil animals are the most under the broad-leaved and pine forest on the top of the mountain, andthe least under Picea-Abies forest in the foot of the mountain.  相似文献   

15.
Marine sediment microbial fuel cell(MSMFCs)can be utilized as a long lasting power source to drive small instruments to work for long time on ocean floor and its higher power has a significant meaning for practical application.Anode modification can greatly improve the performance of MSMFCs.Herein,humic acid(HA)and humic acid-iron ion complex(HA-Fe)were used to modify the anode for constructing a better MSMFCs.The results indicated that HA-Fe modified anode,better than HA modification,significantly improved the MSMFCs cell power output.The maximum power density of HA-Fe modified MSMFCs is 165.3 mW m?2,which are 6.5-folds of blank MSMFCs.The number of microorganisms on anode,redox activity,and relative kinetic activity were 1.8-,6.1-,and 13.1-folds of blank MSMFCs,respectively.The MSMFCs improvement would be attributed to the electron transfer media of HA and the valence conversion of Fe ions.A synergistic interaction between the naturally occurring HA and Fe ions on the anodic surface in marine sediments would make the modified anodes have‘renewable’characteristics,which is beneficial for the MSMFCs to maintain its long-term higher power.  相似文献   

16.
In this study,the fatty acids(FAs) of the organs and tissues of sea cucumber(Apostichopus japonicus) were profiled in order to compare the FA composition of sea cucumber collected from natural habitat(wild) and cages(cultured).The differences in FA contents in dermomuscular tube,peripharyngeal annulus,gonad and intestine(with or without content) between the wild and the cultured were determined.The main fatty acids in all organs and tissues were 20:5n-3,16:1n-7,20:4n-6,22:6n-3,18:0,and 18:1n-7.The basically different FAs of body wall and digestive tube were 16:1n-7,18:1n-9 and 20:1n-11.The ratio of saturated to mono-and polyunsaturated FAs in digestive tube was independent on inside content while there was a redistribution of the total amount of n-3 and n-6 fatty acids.The comparison of FA composition of the wild and the cultured sea cucumber showed that 20:5n-3,16:1n-7 and 18:1n-7 predominated the wild while 20:4n-6 predominated the cultured.The content of branched-chain fatty acids in the wild was 3%–4% and about 9% in the cultured.The possible FAs for identifying the wild and the cultured sea cucumbers were selected.It was suggested that the indexes such as the ratio of either(n-3:n-6) to(n-7:n-6) or(n-3) +(n-7) to(n-6) may serve as the biomarkers distinguishing the wild and the cultured sea cucumber.  相似文献   

17.
利用重磁资料正反演计算,获得了一系列的地壳深部资料。多种资料综合反映了河南省深部构造的主要特征。本文论述了我省地壳层状结构的特点和深断裂带的划分。首次提出黄河南断裂带、驻马店-桐柏断裂带为超壳断裂带;确山-固始断裂带、南阳断裂带为地壳断裂带。  相似文献   

18.
Mangrove-derived dissolved organic matter(DOM) has an important effect on estuarine and coastal area on a large scale.In order to improve the understanding of origin,composition,and fate of DOM in mangrove-fringed estuarine and coastal areas,dissolved humic substances(DHS) were isolated from one mangrove pore-water sample and one near-shore seawater sample downstream the mangrove pore-water site in the eastern coast of Hainan Island,South China.Fulvic acids,humic acids and XAD-4 fractions were obtained from the two water samples by using a two-column array of XAD-8 and XAD-4 resins.Chemical and spectroscopic methods were used to analyze the features of these DHS.Compared to the mangrove pore-water DHS,the near-shore seawater DHS were found rich in 13 C with lower C/N ratios and more aliphatic compounds and carbohydrates,but less aromatic structures and carboxyl groups.As for the three fractions of the two DHS,XAD-4 fractions contain more aliphatics,carbohydrates,carboxyl groups,and enrich in 13 C with respect to both fulvic and humic acids.Photo-oxidation transformation and contribution from marine-derived DOM were considered as the main reasons resulted in the difference in compositional features for these DHS in this study.  相似文献   

19.
Soil respiration is a main dynamic process of carbon cycle in wetland. It is important to contribute to global climate changes. Water table and nutritious availability are significant impact factors to influence responses of CO2 emission from wetland soil to climate changes. Twenty-four wetland soil monoliths at 4 water-table positions and in 3 nitrogen status have been incubated to measure rates of CO2 emission from wetland soils in this study. Three static water-table controls and a fluctuant water-table control, with 3 nitrogen additions in every water-table control, were carried out. In no nitrogen addition treatment, high CO2 emissions were found at a static low water table (I) and a fluctuant water table (IV), averaging 306.7mg/(m2·h) and 307.89mg/(m2·h), respectively, which were 51%–57% higher than that at static high water table (II and III). After nitrogen addition, however, highest CO2 emission was found at II and lowest emission at III. The results suggested that nutritious availability of wetland soil might be important to influence the effect of water table on the CO2 emission from the wetland soil. Nitrogen addition led to enhancing CO2 emissions from wetland soil, while the highest emission was found in 1N treatments other than in 2N treatments. In 3 nutritious treatments, low CO2 emissions at high water tables and high CO2 emissions at low water tables were also observed when water table fluctuated. Our results suggested that both water table changes and nutritious imports would effect the CO2 emission from wetland. Foundation item: Under the auspices of the National Natural Science Foundation of China (No. 90211003) and the Knowledge Innovation Program of Chinese Academy of Sciences (No. KACX3-SW-332) Biography: YANG Ji-song (1978-), male, a native of Chengwu of Shandong Province, Ph.D. candidate, specialized in environmental ecology and wetland biogeochemistry. E-mail: yangjisong@neigae.ac.cn  相似文献   

20.
CARBON DYNAMICS OF WETLAND IN THE SANJIANG PLAIN   总被引:2,自引:0,他引:2  
1INTRODUCTIONWetlandsplayanimportant roleintheprocessofcar-bonstorage.Thetotalcarbonstoredindifferentkindsofwetlandsisabout15%-35%ofthetotalcarboninthegloballandsoils(POSTetal.,1982;GORHAM,1991).Inaddition,wetlandsaresignificantnaturalsources fortheatmospheric CH4 (MOORE,1994).It isestimatedthatabout110×1012gCH4 originates fromanaerobicdecompositioninthenaturalwetlands,CH4 emission fromthenaturalwetlandsis15%-30%oftheglobalCH4 emission andtheCH4 emission from thepeat land at hi…  相似文献   

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