共查询到20条相似文献，搜索用时 15 毫秒
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Sanjay Kumar Shukla 《Geotechnical and Geological Engineering》2010,28(6):929-930
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David A. Burton 《Natural Hazards》2012,63(2):1219-1221
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A thermodynamic model for the Gibbs free energy of igneous pyroxenes with the general formula [Na, Ca, Fe2+, Mg]M2[Fe2+, Mg, Ti, Al, Fe3+]M1[Al, Fe3+, Si]TetSiO6 is calibrated from experimentally determined compositions of coexisting pyroxene and silicate melt. The model is based upon the general formulation, and relies upon the calibration of the “quadrilateral” subsystem, previously published by the present authors. The calibration database of pyroxene-liquid equilibria spans a broad spectrum of temperature, pressure and oxygen fugacity conditions, ranging from 1000°–1600°C, 0.001–30 kbar and iron-wüstite to air. Chemical potentials of endmember pyroxene components as well as exchange potentials between pyroxenes and coexisting liquids are defined utilizing the present authors' thermodynamic melt model. Model parameters are extracted from these relations by regression analysis. The resulting model and derivative endmember properties are internally consistent with an existing standard state thermodynamic database. The success of the model and its applicability to igneous petrogenesis are demonstrated by comparing calculated and experimentally determined liquidus compositions, temperatures and symmetry states for pyroxenes crystallizing from a variety of silicate melts, ranging in composition from tholeiites and angrites through rhyolites to potash ankaratrites. 相似文献
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Giorgio Hadi Curti 《GeoJournal》2009,74(3):201-208
Ostensibly, subtitles in films serve as linguistic approximations of meaning. Expectedly then, much of the debate surrounding
subtitling has been concerned with representational accuracy, fidelity and authenticity. In this article I argue that by encountering
subtitles as affective bodily expressions, as opposed to approximate representations of pre-existent meanings or intentions,
filmic experiences may be(come) transformed and differently transformational. As a result, meaning and accuracy in subtitles
as superimposed signifiers or static representations become secondary to subtitles as spatially affective- and expressive-movements
intimately part of filmic scapes. The creative use of subtitling in Bekmambetov’s Russian language film Night Watch (Nochnoy dozor; 2006 [2004]) is discussed.
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| Giorgio Hadi CurtiEmail: |
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Jacques Roux 《Geochimica et cosmochimica acta》1974,38(8):1213-1224
Ion exchange equilibrium of nepheline solid solutions (Na, K)AlSiO4 and (Na, Rb)AlSiO4 with hydrothermal solutions has been studied at 600°C and 2000 bars. The behaviour of dilute solid solutions was specially investigated.Na-Rb ion exchange data can be represented satisfactorily by a model taking into account the existence of two different sites in the structure of nepheline. At 600°C Rb atoms substitute almost exclusively for Na atoms situated in the larger sites. On the other hand, this model only partially applies to Na-K ion exchange equilibrium.Finally, the importance of the ion exchange data concerning extremely dilute solutions to calculate activity-composition diagrams is emphasized with special reference to the nepheline solid solutions. 相似文献
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Mathematical Geosciences - 相似文献
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A series of high structural state plagioclases (Ab-An) was crystallized from glasses. By exchanging Na for K in KCl melts, metastable K-plagioclases (Or-An) were prepared which possess the same structural state as the starting plagioclases. Both series were investigated at 980 K by lead borate solution calorimetry. Continuing the ideas of Carpenter and McConnell (1984) and Carpenter (1992a), the results can be interpreted as follows. In the high plagioclase series, the enthalpies of solution, jHsol, reflect the schemes of Al,Si ordering: (1) analbite-like (C2/m) ordering in the An-poor region 0hXAnА.2, (2) high albite-like (C1¥) ordering in intermediate plagioclases, and (3) anorthite-like (I1¥) ordering in the An-rich region 0.7AnБ. In regions 1 and 2, jHsol decreases as a function of XAn, but increases in region 3 as a consequence of the C1¥MI1¥ ordering reaction. Therefore, it is not a mixing effect but a compositionally restricted ordering effect which causes the excess enthalpies, jHex, to be positive in the plagioclase binary as a whole. Neglecting the existence of phase transitions at XAn=0.2 and XAn=0.7, jHex can be approximated by a two-parameter Margules model yielding WHAnAb=14Dž kJ/mol and WHAbAn=40Dž kJ/mol. jHsol values of I1¥ plagioclases (XAn>0.7) can be "corrected" for the C1¥MI1¥ ordering effect (Carpenter 1992a). When combining the corrected values with the jHsol data which were actually measured on the C1¥ plagioclases (XAn<0.7), negative excess enthalpies are generated in the plagioclase binary. This may be expected when C1¥ ordering occurs relative to topochemically monoclinic reference states of analbite and hypothetical anorthite devoid of I1¥ order. The solution experiments on the K-plagioclases resulted in similar characteristics as those found for the plagioclases. However, in addition to the ordering effects observed in the plagioclase binary, volume mismatch effects contribute to jHex in the K-plagioclase series. jHex can be represented by a Margules model with WHAnOr=60ᆞ kJ/mol and WHOrAn=91ᆢ kJ/mol when the phase transitions at XAn=0.2 and XAn=0.7 are again neglected. The contribution of the volume mismatch effect to jHex is considerable, as appears from the large difference between the K-plagioclase and the plagioclase Margules parameters. Their difference corresponds to a practically symmetrical dependence of jHexvolmism on composition, with WHvolmism=48ᆡ kJ/mol. 相似文献
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