首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到17条相似文献,搜索用时 140 毫秒
1.
大庙子—菜抢子金矿区主要矿石类型有含金黄铁矿型和含金多金属型,对两类矿石研究表明金赋存于黄铁矿和交代、穿切黄铁矿的黄铜矿中,主要与黄铁矿有关。采用相关系数法、距离系数法及离差平方和法对38件矿石样品中的Au、Ag、Cu、Pb、Zn、Co、Ni、Bi元素进行R型聚类分群,结果为Au Bi、Ag Zn Cu Co Pb Ni二群。本矿区中金主要形成于金-黄铁矿阶段,少量形成于金-多金属阶段。  相似文献   

2.
在胶东莱州吴一村地区完成的3266.06 m深钻,是目前焦家金成矿带最深见矿钻孔,研究钻孔揭露的深部矿石中金矿物及黄铁矿微量元素特征,对探讨深部成矿作用演化具有重要意义。笔者采取深钻中2420~3206 m垂深的岩(矿)芯样品进行了详细的岩相学和矿相学研究,结合扫描电镜和电子探针微区分析,研究了矿石中金矿物的赋存状态和成分。对不同成矿阶段形成的黄铁矿进行了LA-ICPMS微量元素分析。研究结果表明,深部矿石中载金矿物主要为黄铁矿,其次为石英、黄铜矿、方铅矿,可见金主要以自然金和银金矿的形式存在,以晶隙金和裂隙金为主,其次为包体金。与浅部金矿床比较,深部金的成色较高。黄铁矿分为6种类型,第Ⅰ成矿阶段形成富Co型黄铁矿Py1,第Ⅱ成矿阶段形成富Ni型黄铁矿Py2a和Py2b,第Ⅲ成矿阶段形成富Au、As型黄铁矿Py3a和富Au、Ag、Pb、Bi型黄铁矿Py3b,第Ⅳ成矿阶段形成贫微量元素黄铁矿Py4。其中,Py1和Py2a发生强烈破碎,裂隙表面对热液中的Au络合物产生吸附作用,对金沉淀富集起重要作用。黄铁矿中Co、Ni、As等微量元素主要以类质同象形式赋存,而Au、Ag、Cu、Pb、Zn、Bi等主要以纳米级、微米级矿物包体形式赋存。Pb+Bi、Cu+Pb+Zn、Te+Bi与Au+Ag呈明显正相关,而Au与As相关性较差。黄铁矿中Co、Ni含量较低,而Au+Ag+As或Au+Ag+Pb+Bi+Cu含量较高指示成矿有利。另外,黄铁矿中Co、Ni含量较高,并且破碎强烈,成矿相关元素含量较高也指示成矿有利。  相似文献   

3.
老挝中部、北部热带雨林地区的大地构造位置大致处于北西向长山岩浆—构造带和北东向琅布拉邦岩浆—构造带的交汇部位。该区域地表土壤测量分析表明,Cu与Pb、Zn、Ag、Sn、Mo、Sb、Hg、As、Cd、Co、B i总体呈共消长关系,为最佳元素组合。本区Cu、Pb、Zn等主要成矿元素沿花岗岩与灰岩接触带分布,Cu、Pb、Zn相关性不大并具有明显的分带性,Cu分布于接触带靠近花岗岩一侧,Pb、Zn分布于接触带靠近灰岩一侧,共伴生组分Mo、Sn、B i、Ag、Cd等异常明显。本区的元素组合可划分为5类:①Cu与Ag;②Pb与B i;③Zn与Cd;④Sn与Mo;⑤Sb与Hg、As。从元素分布特征看,本区具有矽卡岩的成矿特征,同时又可能有斑岩成矿的潜力。  相似文献   

4.
烧锅营子金矿床的黄铁矿形成于早、中、晚3期,是主要的矿石矿物和载金矿物,其中以中期黄铁矿为最主要的载金者.黄铁矿的化学成分为:TFe43.34%~45.52%,S46.58%~48.86%,与标准黄铁矿相比显示亏铁、亏硫特点.黄铁矿内含丰富的微量元素,有Au、Ag、As、Sb、Bi、Cu、Zn、Pb、Co、Ni、W、Mo、Se等.其中Au、Ag、Cu、Pb、Zn、Bi含量较高,而As、Sb低,Se极低.其Au/Ag(多大于0.5)、(Cu+Pb+Zn)/(Co+Ni+As)(4.26)、Co/Ni(>> 1)比值表明其属中温岩浆热液矿床.  相似文献   

5.
粤北大宝山铜多金属矿床一直存在燕山期岩浆热液成因和海西期火山喷流成因之争,争议的焦点在于块状、似层状硫化物矿体的成因。本文在全面开展矿区地质调查和钻探查证的基础上,对块状、似层状和脉状硫化物矿石中的黄铁矿和磁黄铁矿开展EPMA和LA-ICP-MS原位分析。测试结果表明,不同产状黄铁矿的平均分子式相似,分别为FeS_(1.98)、FeS_(1.99)和FeS_(1.98),似层状和脉状硫化物中磁黄铁矿的平均化学式为Fe_(0.886)S和Fe_(0.874)S,属形成温度相对较低单斜磁黄铁矿。与花岗岩岩浆热液标型黄铁矿相比,不同产状的黄铁矿和磁黄铁矿中Co、Ni、Mn、Se和Ge等元素以类质同象形式赋存,它们含量较低但稳定,Cu、Pb、Zn、Ag、Bi和Tl及Ga主要以微细矿物子晶形式存在,其含量丰富,但变化明显。从块状、似层状到脉状硫化物矿体,黄铁矿和磁黄铁矿中Co、Zn和Se的含量及Co/Ni值降低,而Cu、Pb、Ag、Bi等元素的含量明显升高。结合矿区次英安斑岩的产状和含矿性特征表明,大宝山矿床块状、似层状和脉状硫化物矿体都是次英安斑岩深部岩浆房产出的含矿流体在不同赋矿环境中的产物。  相似文献   

6.
浙江火山岩区金矿床黄铁矿的找矿矿物学研究   总被引:4,自引:0,他引:4       下载免费PDF全文
论文给出了中国浙江火山岩区金矿床中黄铁矿的微量元素、形态和物理性质找矿标型特征.例如.(在许多)浙江火山岩区重要金-银矿床中黄铁矿相对富含铅、锌、钼、锡、砷、锑、铋而贫钴,镍、硒、碲:并且S/Se、Ag/Au、Pb/Ni、Se/Te、(As+sb+Bi)/(Se+Te)比值较高,Co/Nj、Ag/Pb、Ag/Zn、Cu/Zn和(Co+Ni)/(Pb+Zn)比值较低,再如含金黄铁矿比不含金黄铁矿的反射率低.总之,黄铁矿的标型性研究对于寻找金矿具有重大的理论意义和实际意义.  相似文献   

7.
西藏谢通门县雄村铜金矿的成矿与含眼球状石英斑晶的角闪石英闪长玢岩有关,并至少受3个玢岩岩枝控制。主成矿元素为Cu,伴生元素为Au、Ag、Zn、Pb,其他微量元素Mo、As、Ba、Bi、Cd、Co、Mn、Ni、Sb含量较高。元素在垂向上具有分带特征,即从矿体中心向外可依次划分为Cu、Au、Ag、As、Sb、(Bi)→Co、Ni→Mo→Mn→Ba→Pb、Zn、Cd、Bi、(Sb),上述元素的异常和组合是寻找和评价该类矿床的重要地球化学标志。矿床的形成经历了早期Cu—Au—Ag成矿和晚期Zn—Pb—Cu—Au—Ag成矿两个阶段:早期成矿阶段形成了Cu—Au—Ag主矿体,晚期叠加Zn—Pb—Cu—Au—Ag矿化。Cu与Au、Ag呈显著的正相关,Cu主要呈独立矿物黄铜矿产出,Au、Ag主要赋存于黄铜矿中。矿石的K/Na值为6.9、Rb/Sr值为0.8,显示出矿床矿富K、Sr和贫Na、Rb的成矿环境;而Au(平均品位0.6×10-6)0.4×10-6、Au(0.6×10-6)/Cu(0.4%)1和n(Cu)/n(Au)(为20678)40000以及Mo(19.7×10-6),说明该矿床富金而贫钼。矿床所处的大地构造位置,成矿与偏中性的斑岩有关,元素组合特征,异常元素在垂向上的分带特征,主成矿阶段的Cu—Au—Ag矿化和晚期叠加的Zn—Pb—Cu—Au—Ag矿化,富Cu、Au、Ag和贫Mo的成矿元素组合及富K、Sr和贫Na、Rb的成矿环境,均表明矿床具有产于岛弧或类似岛弧环境的斑岩型铜金矿床的特征且叠加斑岩成矿系统晚期呈脉状产出的浅成低温热液型Zn—Pb—Cu—Au—Ag矿化。  相似文献   

8.
铁格隆南斑岩-浅成低温热液型铜(金)矿床是班公湖—怒江成矿带上最重要的矿床之一。本文以矿床内发育的黄铁矿为主要研究对象, 对其开展微量元素、稀土元素和硫同位素分析。依据产出状态, 黄铁矿可以分为黄铁矿-1, 黄铁矿-2和黄铁矿-3, 其中黄铁矿-2与浅成低温热液型矿化相关, 黄铁矿-3与斑岩型矿化相关。黄铁矿-1的Au、Ag、Cu、Pb、Zn、Bi的含量最低, 黄铁矿-2的Au、Ag、Cu、Pb、Zn、Bi的含量最高。Cu和Ni、Ag和Cu、Cu和Pb、Ag和Pb、Pb和Zn的相关性可作为黄铁矿-2和黄铁矿-3的辨别标志。黄铁矿-1的δ34S值(1.9‰)最大; 黄铁矿-2和黄铁矿-3的δ34S值在–4.5‰~0.3‰之间。黄铁矿富集轻稀土, 亏损重稀土, 具有“右倾”式稀土配分模式, 浅部(200—450 m)黄铁矿的轻重稀土分异程度较大, 以正铕异常为主, 而深部(700—1000 m)黄铁矿轻重稀土分异相对较小, 以负铕异常为主。铁格隆南矿床含硫热液运移方向为横向上从ZK1604向东运移, 纵向以ZK1604的230—250 m为中心向深部和侧向运移。黄铁矿中高含量的Cu、Au、Ag以及Ag和Cu、Pb和Zn、Cu和Pb、Ag和Pb的正相关性是指示浅成低温热液型矿化的重要标志, 而黄铁矿内Cu和Ni的负相关性是指示斑岩型矿化的标志。  相似文献   

9.
青海卡而却卡铜多金属矿床矿石矿物化学成分特征研究   总被引:2,自引:0,他引:2  
卡而却卡铜多金属矿床是祁漫塔格成矿带最重要的一个矿床,该矿床分为A、B、C三个矿区,成矿以铜、铅、锌为主,伴有铁、钼、金、银等矿化。本文主要分析卡而却卡铜多金属矿床黄铜矿、黄铁矿、磁铁矿、闪锌矿与斑铜矿共5种主要矿石矿物的化学成分特征,利用A、B、C三个矿区黄铜矿S元素含量,黄铜矿(Fe+Cu)/S比值(平均值分别为1. 93、1. 82、1. 8),黄铁矿Co/Ni值(平均值分别为5. 43、3. 89、1. 06),闪锌矿中Fe含量以及Zn/Cd比值(B区和C区Zn/Cd比值在177. 84~488. 13之间),结合前人流体包裹体测温结果表明卡而却卡矿床成矿温度存在A区>B区>C区,其中B区7号脉>8号脉>4号脉的特征,A区成矿于中高温环境;B区、C区早期形成于中高温,晚期形成于中温环境。依据卡而却卡A、B、C三个矿区的成矿环境和矿床地质特征,通过黄铁矿Co、Ni、As元素含量特征、闪锌矿中Cd、Zn、Mn、Fe元素含量特征,认为卡而却卡矿床A区具有受岩浆热液控制的斑岩型铜矿床成因特征,B区和C区为矽卡岩型矿床成因特征。  相似文献   

10.
黑龙江地区金厂金矿床是以爆破角砾岩筒型矿化为主体的特大型岩金矿床,以矿区J0号爆破角砾岩筒型矿体为主要对象,通过对其6 个不同标高水平的岩、矿石微量元素地球化学分析,探讨了该类矿体地球化学特征。结果表明,在所分析的12 种元素中,Hg、As、Sb 异常多出现于金矿体顶部及上方; Ag、Pb、Zn、Cu 异常主要出现于金矿体中部; 而Ni、Mo、W、Co 异常主要发育于矿体尾部和下方。这些元素岩石地球化学异常分布特点可以用于金厂矿区爆破角砾岩筒的含矿性评价及深部找矿前景预测分析。  相似文献   

11.
赵善仁  吴悦斌 《现代地质》1996,10(4):478-484
五台山—恒山绿岩带Au、Ag、Cu矿床可分为二大类型:(1)再生型金银铜矿,产在包括岩浆岩在内的各类岩石断裂构造中,与岩浆期后热液有关;(2)变生型金银铜矿,产于各类变质岩中,具有层控特征(即绿岩型金矿)。在地球化学特征上,再生型矿床与变生型矿床相比,矿体及围岩中Mo、Ag、Pb、Zn、Cd等成矿及伴生元素明显富集;K2O、Rb、Sr、Ba、Th、U也明显富集,是后期岩浆热液作用的结果;Hg、F的明显富集则与后期构造活动有关;Zn/Cd比值较低,说明受到后期岩浆侵入影响;Th/U比值低,可能指示富钙的酸性岩环境。再生型Au矿化的元素组合为Cd、As、Ni、Ag、Sb、Au、Hg(Bi),再生型Ag矿化的元素组合为As、Sb、Ag、Cd、Cu、Ni(Mo、Pb、Zn、Bi),变生型Au矿化的元素组合较简单,只为Au、Hg、As或Au、Cu。上述地球化学特征不仅可以有效地区分矿化类型,而且可以作为地球化学找矿和评价的指标  相似文献   

12.
百里坪银、多金属矿化集中区白垩纪岩浆岩主要有花岗质与闪长质两个岩石系列。前者为富钾质钙碱性岩石,后者为富钠质碱钙性岩石,二者具有不同的变异曲线特征;花岗质岩石Co/N i值平均为2.644,闪长质岩石平均为0.498;花岗质岩石R b/S r值平均为0.223,闪长质岩石平均为0.020;在R b、S r、B a演化趋势上,花岗质岩石趋向富集R b,闪长质岩石趋向富集S r、B a,二者明显不同;两个岩系代表性岩石在稀土含量、稀土比值以及稀土模式上都不相同。两者的成矿专属性为:花岗质岩石对A g、Cu、P b、Zn矿化有利,闪长质岩石对A g、A u矿化有利。  相似文献   

13.
北山地区植被属戈壁荒漠植被类型,主要植物群落为红沙,红沙中多数元素特别是成矿元素及其伴生元素的含量和变化系数矿区大于背景区,元素含量背景区呈对数正态分布,矿区呈偏对数正态或多峰分布,红沙中的元素组合分类背景区为Au,Cu,Pb,Zn,As,Sb,Mo,V,Mn和Ag,Sn,Sr,Ba及Ti,Cr,Co,Ni,金矿区为Au,Ag,As,Sb,Mo,Mn,Sr和Cu,Pb,Zn,Sn,Ba及Co,Ni,Ti,V,Cr,铜矿区为Cu,Pb,Zn,Mo,Au,Ag,Ba和As,Sb,Sn,Mn及Ti,V,Cr,Co,Ni,Sr,矿区红沙中浓集系数较大的元素多数在矿区岩石中的浓集系统亦较大,金,铜矿床红沙和岩石中的特征元素分别都有Au,Ag,Ag,Sb,Mo,(Mn)和Cu,Pb,(Ba,Ti,Cr)。在金,铜矿床(体上方分别发育有良好的Au和Cu的生物地球化学异常和元素组合及分带,根据红沙的地球化学特征能,判断金或铜矿种类型,并能对掩埋,隐伏金,铜矿床(体)进行定位预测。  相似文献   

14.
锡铁山铅锌矿床为海底喷流沉积为主兼后期迭加改造的矿床.研究表明,矿体元素在纵向上从盆地边缘-近边缘-盆地中心-喷流口部位,出现由低温Hg、Sr、Ba、Cu-中低温Hg、Sr、Ba、B、Ag、Au、Mn、Cu、Pb、Zn-中高温Pb、Zn、Ag、Au、Cu、Sn、Bi、As-高温Cu、Bi(Pb、Zn)的分带,并且以喷流口为中心,两侧盆地呈对称状态.矿体垂向上晕的表现为Cu、Pb、Zn、Sn、Bi、As、Au等中高温元素紧裹着矿体,Co、Ni、Cr对称地分布在两侧,Ba(Hg)呈宽缘晕如帽式样分布在矿体前缘,为一种紧裹型镜相对称的帽式结构.元素轴向分带序列为(由上至下):B-Ba-Hg-(Sr-Cr)-Ni-Cu-Zn-Au-Mo-Bi-As-Pb-Mn-Sn-Co-Ag-Sb-(Ni),前缘晕元素为Ba、B、Hg、Sr,矿体尾部元素为Co、Ni、Cr.在此基础上建立了矿床综合地球化学异常模式及找矿评价指标.  相似文献   

15.
The Xiaoqinling district, the second largest gold producing district in China, is located on the southern margin of the North China Craton. It consists of three ore belts, namely, the northern ore belt, the middle ore belt and the southern ore belt. Pyrite from the Dahu gold deposit in the northern ore belt and Wenyu and Yinxin gold deposits in the southern ore belt were investigated using a combination of ore microscopy and in-situ laser-ablation inductively-coupled plasma-mass spectrometry (LA-ICP-MS). A range of trace elements was analyzed, including Au, Te, Ag, Pb, Bi, Cu, Co, Ni, Zn, Mo, Hg, As and Si. The results show that there are no systematic differences between the trace element compositions of pyrite in the three deposits from different ore belts. In general, Au concentrations in pyrite are low (from < 0.01 ppm to 2.2 ppm) but Ni concentrations are rather high (up to 8425 ppm). A four-stage mineralization process is indicated by microscopic and field observations and this can be related to the systematic trace element differences between distinct generations of pyrite. Stage I precedes the main gold mineralization stage; pyrite of this stage has the lowest Au concentrations. Stages II and III contributed most of the gold to the ore-forming system. The corresponding pyrite yielded the highest concentrations of Au and Ni. Our microscopic observations suggest that pyrite in the main gold mineralization stage precipitated simultaneously with molybdenite that has been previously dated as Indosinian (~ 218 Ma by Re–Os molybdenite dating), indicating the Indosinian as the main gold mineralization stage. The Indosinian mineralization age and the geological and geochemical features of these gold deposits (e.g., low salinity, CO2-rich ore fluids; spatial association with large-scale compressional structures of the Qinling orogen; δ18O and δD data suggestive of mixing between metamorphic and meteoric waters; δ34S and Pb-isotopic data that point to a mixed crustal-mantle source) all point to typical orogenic-type gold deposits. High Ni concentrations (up to 8425 ppm) of pyrite possibly linked to deep-seated mafic/ultramafic metamorphic rocks provide further evidence on the orogenic gold deposit affinity, but against the model of a granitic derivation of the mineralizing fluid as previously suggested by some workers. Generally low Au concentration in pyrite is also consistent with those from worldwide orogenic gold deposits. Therefore, the gold mineralization in the Xiaoqinling district is described as orogenic type, and is probably related to Indosinian collision between the North China Craton and the Yangtze Craton.  相似文献   

16.
The structure and petrologic composition of new gold-ore provinces in southeastern East Sayan (Tissa-Sarkhoi cluster) are considered. Several morphogenetic types of gold mineralization have been established: quartz veins with beresitization zones, veinlet-disseminated ores in granitoids, and listwaenitization and sulfidation zones in effusions of the Sarkhoi Group and intrusive rocks of the Late Riphean Khorin-Gol complex. According to geochronological dates and some mineralogical and geochemical features, the gold mineralization is close in age to these Precambrian island-arc complexes. Parageneses of two stages of ore formation have been recognized: early high-temperature (250–460 °C) gold-pyrite and late low-temperature (110–280 °C) gold-telluride. The latter mineralization is widespread and is represented by tellurides of Au, Ag, Pb, Bi, and Ni — petzite, calaverite, hessite, tellurobismuthite, altaite, and melonite. Native gold associated with these tellurides is characterized by a fineness of 750–900‰. The intimate temporal and spatial relationships of the gold mineralization with island-arc volcanoplutonic complexes and the wide occurrence of its veinlet-disseminated type suggest that this is porphyry gold mineralization related to the Late Riphean-Vendian island-arc magmatism.  相似文献   

17.
The mineral composition and geochemical characteristics of the ores of the Malinovskoe gold-ore deposit are studied by the data from mining works (ditches, cleanings, and boreholes). It is found that the ore–magma system of the deposit was formed in several stages of mineralization characterized by two phases of magmatism differing in age. In terms of the set of features (the geological–structural position of the deposit, as well as the material composition and geochemical characteristics of the ores), the deposit is attributed to the gold–tourmaline type of mineralization associated spatially and genetically with the “raremetal” granitoid magmatism. This type has not previously been found in Primorskii Krai. The studies of the material composition and geochemical characteristics of the ores allow us to ascertain the correlations between the elements along with the reasons of their origination. By analogy with other gold-ore formations of the Russian Far East, the mineralogical and geochemical model of the deposit is developed (Be–Sn–Cr–Ba–Au–Cu–Mo–Pb–V–Ti–Co–W–Ag–Bi–Ni–Mn–Sr–Zn–Sb–As modeling element series of vertical zoning), which enables us to estimate the levels of the erosion section of the ore bodies and to evaluate their prospects. It is found that the most productive associations in the deposit are the gold–bismuth geochemical association (Au–Ag–Bi–Cu–As–Co) and, to a lesser degree, the gold–tungsten association (W–Au–Ag–Cu–Bi–As).  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号