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1.
曲家金矿位于我国重要的蚀变岩型金矿矿集区之焦家金矿带的中段,矿床赋存标高为-726~-1 334 m。为研究黄铁矿的演化及其对金成矿过程的指示,运用LA-ICP-MS分析黄铁矿原位微量元素含量,结合岩相学观察和点群分析对黄铁矿进行了分类。发现黄铁矿中Co、Ni、As等微量元素主要以类质同像形式赋存,而Au、Ag、Cu、Zn、Pb、Bi等元素主要以纳米级、微米级矿物包裹体形式赋存。黄铁矿主要分为5种类型:富Co型Py1,富Ni型Py2,富Au、As型Py3,富Au、Ag、Pb、Bi型Py4及“干净”型Py5。黄铁矿微量元素特征指示成矿物质可能主要来源于前寒武纪变质基底岩石和中生代岩浆岩,少量来源于地幔,成矿热液可能属变质热液、岩浆热液和浅部大气降水的混合成因。不同类型黄铁矿反映成矿热液由富Co、Ni经富As、Au向富Pb、Bi、Au、Ag演化。Py1和Py2形成后受构造活动影响发生强烈破碎,裂隙表面对热液中金络合物增强的吸附作用促使金在裂隙中沉淀,对金的富集成矿可能起重要作用。Co、Ni含量较低,同时Au、Ag、As、Pb、Bi等元素含量较高的黄铁矿与成矿作用有密切关系。另外,黄铁矿中C...  相似文献   

2.
激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)是一种固体微区分析新技术。用该技术来分析矿床中硫化物的微量元素组成可以为研究成矿流体特征、矿床成因及找矿勘探提供有关的科学信息。文中以安徽铜陵矿集区内新桥Cu-Au-S矿床中的黄铁矿为研究对象,在详细的野外观察和室内鉴定的基础上,将矿床中的黄铁矿分为具有沉积特征的胶状黄铁矿(PyⅠ)、具有变形重结晶和热液叠加作用特征的细粒他形黄铁矿(PyⅡ)和具热液成因特征的中—粗粒自形黄铁矿(PyⅢ)3种类型。LA-ICP-MS原位微量元素测定结果显示,PyⅠ中相对富含Ti、Co、Ni、As、Se、Te;PyⅡ继承了PyⅠ中富含Ti、Co、Ni、As、Se、Te、Bi的特征,同时还含有不均匀分布的少量成矿元素(Cu、Pb、Zn、Au、Ag);PyⅢ中成矿元素Cu、Pb、Zn、Ag、Au以及Bi元素的含量较高,Co、Ni、As的含量较低。在元素赋存状态方面,Co、Ni、As、Se和Te均以类质同象的形式进入到了黄铁矿的晶格中;Bi在PyⅡ中主要以含Bi矿物的微细包裹体形式存在,而在PyⅢ中的Bi还部分取代了Fe而占据了晶格;Cu、Pb、Zn、Au、Ag这些成矿元素中,Cu和Zn分别以黄铜矿和闪锌矿的矿物包裹体存在于黄铁矿中;PyⅡ中所含的少量Au、Ag,可能分别以自然金和自然银的形式存在,而在PyⅢ中Au可能主要以银金矿的形式存在,Ag除了以银金矿的形式存在以外还可能赋存于黄铁矿中含铋的矿物包裹体内;Pb主要赋存于黄铁矿中的方铅矿或含铋矿物的包裹体中。在综合分析黄铁矿的结构形态和微量元素组成特征的基础上认为,PyⅠ型黄铁矿可能形成于前人提出的晚古生代海底沉积或喷流沉积环境,PyⅡ和PyⅢ型黄铁矿分别形成于中生代区域构造变形-热液叠加改造的过渡环境和热液环境,PyⅡ和PyⅢ的形成时间相近。新桥矿床的形成可能经历了晚古生代海底沉积或喷流沉积期和燕山期热液期,胶黄铁矿主要形成于沉积成矿期,而矿床中成矿物质Cu、Pb、Zn、Au、Ag等主要来自燕山期岩浆侵入作用形成的热液成矿系统。  相似文献   

3.
烧锅营子金矿床的黄铁矿形成于早、中、晚3期,是主要的矿石矿物和载金矿物,其中以中期黄铁矿为最主要的载金者.黄铁矿的化学成分为:TFe43.34%~45.52%,S46.58%~48.86%,与标准黄铁矿相比显示亏铁、亏硫特点.黄铁矿内含丰富的微量元素,有Au、Ag、As、Sb、Bi、Cu、Zn、Pb、Co、Ni、W、Mo、Se等.其中Au、Ag、Cu、Pb、Zn、Bi含量较高,而As、Sb低,Se极低.其Au/Ag(多大于0.5)、(Cu+Pb+Zn)/(Co+Ni+As)(4.26)、Co/Ni(>> 1)比值表明其属中温岩浆热液矿床.  相似文献   

4.
大庙子—菜抢子金矿区主要矿石类型有含金黄铁矿型和含金多金属型,对两类矿石研究表明金赋存于黄铁矿和交代、穿切黄铁矿的黄铜矿中,主要与黄铁矿有关。采用相关系数法、距离系数法及离差平方和法对38件矿石样品中的Au、Ag、Cu、Pb、Zn、Co、Ni、Bi元素进行R型聚类分群,结果为Au Bi、Ag Zn Cu Co Pb Ni二群。本矿区中金主要形成于金-黄铁矿阶段,少量形成于金-多金属阶段。  相似文献   

5.
胶东是我国最重要的金矿集中区, 焦家金矿带是区内最主要的金矿床分布区, 黄铁矿是焦家金矿成矿作用的贯通性矿物, 是主要的载金矿物之一。本次工作采集了焦家断裂带深部2700~3000 m内的矿体及矿化体样品, 对黄铁矿进行了晶体形态、主量元素、微量元素、EMPA面扫等研究工作。各个成矿阶段的黄铁矿晶体形态标型研究表明, 成矿I阶段黄铁矿自形-半自形, 颗粒较细小, 以细粒的立方体、五角十二面体为主; 成矿Ⅱ、Ⅲ阶段黄铁矿自形-半自形, 颗粒较粗大, 以立方体为主, 含少量五角十二面体, 具有较多的立方体、五角十二面体聚形晶; 成矿Ⅳ阶段黄铁矿主要以继承性的细粒立方体黄铁矿为主。各个成矿阶段的主、微量元素有显著的差异, 焦家深部成矿流体成矿早期Ⅰ阶段富Co、Ni, 贫Au, 成矿温度较高, 随着成矿作用的进行, 温度逐渐降低, 成矿Ⅱ阶段的成矿流体中含有一定量的伴生中温金属元素Ag、As、Te、Cu等, 成矿Ⅲ阶段中, 成矿温度进一步降低, 成矿流体逐渐转化为贫Co、Ni, 富Au及其伴生金属元素Ag、As、Te、Cu、Zn、Pb、Sb等。根据电子探针(EMPA)面扫描, 区分两种黄铁矿类型, Py1型黄铁矿, 富Co、Ni, 贫As、Pb等元素; Py2型黄铁矿, 主要为富As, 包裹部分被溶蚀的Py1型黄铁矿; 通过对焦家金矿带黄铁矿的晶体形态、主量元素、微量元素、EMPA面扫等标型特征进行详细研究, 对于深部找矿预测具有十分重要的意义。  相似文献   

6.
黄铁矿中的微量元素含量既可提供元素赋存状态的信息,又可示踪热液成矿过程。利用电子探针对龙山金锑矿赋矿地层新鲜板岩、蚀变围岩以及矿石中黄铁矿的多种微量元素进行了分析,研究结果表明:沉积黄铁矿中Au主要以纳米颗粒形式存在;热液黄铁矿中既有固溶体金,也有纳米金。沉积黄铁矿中Co、Ni、Sb、Mn、Te可能以固溶体形式存在,As、Pb、Zn、Cu、Ag以包裹体形式存在;热液黄铁矿中As、Sb、Mn、Te可能以固溶体的形式存在,Co、Ni、Pb、Zn、Cu、Ag以矿物包裹体形式存在。龙山金锑矿至少经历了两个成矿期:早期是由深部的富Ni岩浆流体引发的金、铅、铜、钨矿化,该期矿化强度不大;晚期是以大气降水循环引起的金、锑矿化,是龙山金锑矿的主要成矿期,并大致可分为显微金阶段、次显微金辉锑矿阶段、可见金辉锑矿阶段和辉锑矿阶段4个成矿阶段。  相似文献   

7.
为探讨黑龙江省东宁县金厂特大型金矿床角砾筒型和蚀变岩(石英脉)型两种矿化类型的关系,系统采集样品,利用LA-ICPMS方法对4个成矿阶段黄铁矿微量元素进行了原位点分析和面扫描。结果表明,金厂金矿黄铁矿富含As、Co、Ni、Cu、Pb、Zn、Au、Ag、Sb、Se、Te、Bi,含少量W、Mo、Sn。两种类型金矿化,从第一成矿阶段到第四成矿阶段,黄铁矿微量金属元素成分及其变化具有相对一致的脉动演化规律,总体表现为从高Co、Ni低As向高As低Co、Ni演化,Au、Ag、Cu、Pb、Zn集中在第二、第三成矿阶段。研究认为,金厂金矿区不同矿化类型、不同金矿体属同一斑岩系统、不同空间位置产物;黄铁矿中As、Au+Ag、Cu、Pb+Zn含量,微量元素总量以及成分环带发育情况是评价金(多金属)矿化强度、伴生成矿元素以及富矿部位的有效指标。LA-ICPMS方法对黄铁矿微量元素的面扫描能高效经济地识别不同阶段黄铁矿,并简单量化其微量元素变化特征。  相似文献   

8.
该文以山东招远大尹格庄金矿床中微量元素为研究对象,通过对矿床围岩、矿石等微量元素的研究,表明大尹格庄金矿围岩中微量元素以富含 Bi,Au,Pb,W,Ag,Sn 为特点,矿体和矿化体中元素组合为 Au,Ag,As,Sb,Hg,B, Cu,Zn,Bi,Mo,Mn,Co,Ni,W。在5个成矿阶段中,第二阶段与第三阶段微量元素的富集程度较明显,表现为 Au, Ag,As,Co,Bi,Cu,Pb,Zn 等的富集,成矿元素可分为2个分带序列,主成矿元素为 Au Ag Cu Pb Zn Bi 组合、头晕元素 As Sb Hg 组合和尾晕元素 Co Ni 组合。  相似文献   

9.
赵子欧  乔东海  赵元艺 《岩石学报》2020,36(9):2785-2798
位于西藏多龙矿集区的荣那铜金矿床是班公湖-怒江成矿带首例斑岩型-浅成低温热液型矿床,它的发现对于班公湖-怒江成矿带找矿模型的构建以及资源潜力评估有着重要意义。本文以荣那矿床ZK3204岩芯钻孔为研究对象,针对其蚀变矿物,运用短波红外光谱测试技术,并结合金属矿物组合以及黄铁矿LA-ICP-MS原位微量元素特征,以期查明其矿床成因,并为深部资源勘查提供理论依据。短波红外光谱测试显示出ZK3204钻孔蚀变矿物垂向分带组合为:高岭石+(地开石)→高岭石+伊利石→高岭石+(地开石+石膏)→高岭石+绢云母+伊利石→高岭石+伊利石+(叶腊石)+(地开石),金属矿物也从Cu-S体系逐渐转变为Cu-Fe-S体系。通过黄铁矿LA-ICP-MS原位微量元素分析发现,黄铁矿可分为四类,分别对应荣那矿床四个成矿阶段:(1) Py I:Co、Ni、Cu、Ag、Au含量较低,Co/Ni显示为沉积成因,代表成岩期黄铁矿;(2) PyⅡ:Co、Ni含量较低,Cu、Ag、Au含量较高,Co/Ni显示为沉积成因,代表第一期斑岩型矿床成矿期黄铁矿;(3) PyⅢ:Co含量较低,Ni、Cu、Ag、Au含量较高,Co/Ni显示为沉积成因,代表第二期斑岩型矿床成矿期黄铁矿;(4) PyⅣ:Cu、Ag、Au含量较低,Co、Ni含量较高,Co/Ni显示为热液成因,代表浅成低温热液矿床成矿期黄铁矿。风化作用也是荣那矿床重要地质过程,贯穿于各成矿阶段,反映为早白垩世班公湖-怒江洋盆向北俯冲消减大背景下的多龙矿集区隆升事件,导致矿床被大量剥蚀,也使黄铁矿显示沉积成因。荣那矿床目前仍有较大找矿潜力,在钻孔深部(815m以下),黄铁矿Cu、Ag、Au含量,钻孔中Cu、Pb、Zn、Cr、Hg等含量,绢云母、伊利石含量以及铜金矿的矿石品位均有向下升高的趋势,说明在ZK3204钻孔下部仍有巨大的找矿潜力,可作为未来深部资源探测的重点对象。  相似文献   

10.
半宽金矿床有两类矿石:石英-黄铁矿型和石英-多金属硫化物型。微量元素研究表明元素组合为Bi、Pb、Au、Ag、Zn、Sb、W、Cu、As、Mo。矿石中铅含量是区分黄铁矿型矿石和多金属硫化物矿石的重要指际。金矿化与Co/Ni、Cu+Pb、Rb/Sr值密切相关。1号脉和9号脉矿石微量元素的对比研究表明9号脉Au与Mo、Ag、Hg,As、Pb具显著正相关;1号脉Au与其他元素相关性不明显。9号脉经历三次金矿化,1号脉仅有一次金矿化。从矿石微量元素地球化学研究结果分析,9号脉下部仍有延伸。  相似文献   

11.
山西堡子湾金矿床黄铁矿标型特征   总被引:6,自引:1,他引:6  
从成因矿物学及找矿矿物学观点出发,系统研究了堡子湾金矿床黄铁矿的产状,形态,化学成分,热电性质和热爆特征,该矿床黄铁矿富含Co,Ni,As,Ag,Au与W,Cu,Hg,Ag,As,Bi,Ni,Co,Pb相关性较好,构成特征元素组合,与通常认为的与火山-次火山热液有关的明矾石-高岭土型浅成中低温热液型金矿床特征元素及其组合基本一致。黄铁矿空穴型导电性与明矾,石-高岭土型浅成中低温热液型金矿床特征元素圾其组合基本一致。黄铁矿空穴型导电性与As,Au正相关,与Co,Ni呈明显的负相关,P型和N型导电性是由As/(Co Ni)值决定的。利用黄铁矿热电性及热爆特征空间分带与赋矿空间的对应关系进行成矿预测,效果明显。  相似文献   

12.
The Xiaoqinling district, the second largest gold producing district in China, is located on the southern margin of the North China Craton. It consists of three ore belts, namely, the northern ore belt, the middle ore belt and the southern ore belt. Pyrite from the Dahu gold deposit in the northern ore belt and Wenyu and Yinxin gold deposits in the southern ore belt were investigated using a combination of ore microscopy and in-situ laser-ablation inductively-coupled plasma-mass spectrometry (LA-ICP-MS). A range of trace elements was analyzed, including Au, Te, Ag, Pb, Bi, Cu, Co, Ni, Zn, Mo, Hg, As and Si. The results show that there are no systematic differences between the trace element compositions of pyrite in the three deposits from different ore belts. In general, Au concentrations in pyrite are low (from < 0.01 ppm to 2.2 ppm) but Ni concentrations are rather high (up to 8425 ppm). A four-stage mineralization process is indicated by microscopic and field observations and this can be related to the systematic trace element differences between distinct generations of pyrite. Stage I precedes the main gold mineralization stage; pyrite of this stage has the lowest Au concentrations. Stages II and III contributed most of the gold to the ore-forming system. The corresponding pyrite yielded the highest concentrations of Au and Ni. Our microscopic observations suggest that pyrite in the main gold mineralization stage precipitated simultaneously with molybdenite that has been previously dated as Indosinian (~ 218 Ma by Re–Os molybdenite dating), indicating the Indosinian as the main gold mineralization stage. The Indosinian mineralization age and the geological and geochemical features of these gold deposits (e.g., low salinity, CO2-rich ore fluids; spatial association with large-scale compressional structures of the Qinling orogen; δ18O and δD data suggestive of mixing between metamorphic and meteoric waters; δ34S and Pb-isotopic data that point to a mixed crustal-mantle source) all point to typical orogenic-type gold deposits. High Ni concentrations (up to 8425 ppm) of pyrite possibly linked to deep-seated mafic/ultramafic metamorphic rocks provide further evidence on the orogenic gold deposit affinity, but against the model of a granitic derivation of the mineralizing fluid as previously suggested by some workers. Generally low Au concentration in pyrite is also consistent with those from worldwide orogenic gold deposits. Therefore, the gold mineralization in the Xiaoqinling district is described as orogenic type, and is probably related to Indosinian collision between the North China Craton and the Yangtze Craton.  相似文献   

13.
The Woxi Au-Sb-W deposit is one of the largest polymetallic ore deposits in the Xuefengshan Range, southern China, hosted in low-grade metamorphosed Neoproterozoic volcaniclastic rocks. The orebodies of the deposit are predominantly composed of banded quartz veins, which are strictly controlled by bedding and faults. Petrographic observations and geochemical results are reported on the occurrence of Au and properties of the ore-forming processes for different stages in the deposit. The veins extend vertically up to 2 km without obvious vertical metal zoning. The ore-forming process can be subdivided into four mineralization stages: Pre-ore stage; Early stage (scheelite-quartz stage); Middle stage (pyrite-stibnite-quartz stage); and Late stage (stibnite-quartz sage). Four types of pyrite (Py0, Py1, Py2, and Py3) were identified in the ores and host-rock: Py0 occurs as euhedral grains with voids in the core, ranging in size from 50 to 100 μm and formed mainly in the Pre-ore stage and Early stage; Py1 occurs as subhedral grains. Small grains (around 10 μm) of Py1 form irregularly shaped clusters of variable size ranging from tens to hundreds of μm and mainly formed in the Middle stage; Euhedral-subhedral fine-grained Py2 formed in the Late stage; Minor subhedral fine-grained Py3 was deposited in the Late-stage. Stibnite is widely distributed in the Middle and Late stage ore veins. No systemic difference was recognized in mineralogical features among stibnite formed in different stages. In addition to native gold, the lattice bound Au+1 widely exists in Py1 and Py2 in the deposit, and widespread Py1 is considered as the main Au-bearing mineral with the highest Au contents. Most elements (such as Co, Ni, Cu, As, Sb, Ba, and Pb) are considered to occur as solid solution within the crystal lattice and/or invisible nanoparticles in sulfides minerals. The Co/Ni ratio of most pyrite is lower than 1, suggesting that the metals in the ore-forming fluid are sourced from sedimentary rocks. The coupled behavior between Au and As; Au and Sb suggests that the substitution of As and Sb in pyrite can enhance the incorporation of Au. Variation of trace elements in pyrites of different stages suggests some information on the mineralization processes: Large ion lithophile elements (such as Ba and Pb) are enriched in Py0 indicating that water-rock reaction occurred in the Early stage; Fine-grained Py1 with a heterogeneous distribution of elements suggests fast crystallization of pyrite in the Middle stage.  相似文献   

14.
三山岛金矿床是位于胶东金矿集区西北部的超大型破碎带蚀变岩型金矿床.该矿床细致的矿相学及元素地球化学研究尚有不足,限制了对其金富集机制及过程的理解.基于野外地质调查和室内矿相学研究将该矿床划分为4个成矿阶段:石英?绢云母?黄铁矿阶段(I)、石英?金?黄铁矿阶段(I I)、石英?金?多金属硫化物阶段(I I I)和碳酸盐?...  相似文献   

15.
对胶东西北部望儿山金矿床中的黄铁矿进行了系统的采样和热电系数、热电导型、晶胞参数、化学成分等特征的分析,在此基础上探讨了黄铁矿的找矿意义。研究表明,望儿山金矿床中的黄铁矿化学成分亏S,特征元素为Au、Ag、Cu、Pb、Zn、As、Co、Ni、Se;黄铁矿热电导型P型的出现率为29.4%,热电性各项参数的变化在时间和空间上都与矿石金品位有明显的相关性;黄铁矿热电系数-温度标尺显示成矿温度集中在130.3~339.8℃之间;黄铁矿晶胞参数a0、v0值及X射线衍射峰半高宽都偏低,具有深部黄铁矿特征。黄铁矿δFe-δS图和晶胞参数a0图均显示望儿山金矿床为中低温热液成因,矿体的剥蚀程度较深,向下可能转化为蚀变岩型。  相似文献   

16.
小秦岭-熊耳山金矿集区位于华北克拉通南缘,发育众多伴生铅锌银等金属的金矿,成为揭示克拉通破坏型金矿成因的天然实验室。产于小秦岭-熊耳山金矿集区内的康山金多金属矿床受控于北东向的中生代脆性断裂,赋存于新太古代变质岩和中元古代火山岩中。成矿过程可分为4个热液阶段:石英±黄铁矿阶段、石英-黄铁矿-黄铜矿-自然金阶段、多金属硫化物-自然金-石英-铁白云石阶段、石英-方解石±萤石阶段。本文获得康山金多金属矿床金成矿阶段热液独居石LA-ICP-MS U-Pb年龄为131.7±4.6Ma,与晚中生代华北克拉通破坏有关的岩浆热液成矿作用时代一致。本次研究开展的各阶段黄铁矿原位微量元素单点和扫面分析,发现第2阶段Au与Co、Ni、As呈正相关关系,且有明显的振荡环带,Cu、Ag、Sb、Pb、Bi这几种元素从黄铁矿颗粒的核部向边缘含量逐渐降低,且黄铁矿颗粒中出现富含这些元素的矿物包裹体,说明该阶段发生流体沸腾作用;而第3阶段黄铁矿中各微量元素含量为所有阶段中最低,黄铁矿无振荡环带且裂隙中有富含各微量元素的硫化物充填,说明各种元素在该阶段均得到充分卸载,且成矿流体的化学性质较稳定。结合前人关于该矿床各阶段流体包裹体分析结果,表明流体沸腾是Au的主要沉淀机制,而流体混合是Pb、Zn、Ag的主要沉淀机制。黄铁矿中微量元素含量指示,从第1阶段到第3阶段流体温度依次降低;第2和第3阶段流体fO2比第1阶段高且后两者相差不大。根据黄铁矿Co、Ni含量及比值的计算,认为第1和第2阶段黄铁矿为岩浆热液成因,第3阶段黄铁矿受围岩物质影响。黄铁矿原位S同位素分析得到第1至第3阶段黄铁矿δ34S分别为+6.6‰-+8.9‰、+5.0‰-+7.2‰和+6.0‰-+8.7‰,均与区域花岗岩类的S同位素值类似。综上所述,本文得出康山金多金属矿床形成于早白垩世与华北克拉通破坏有关的岩浆热液成矿作用。  相似文献   

17.
也金嘎波金矿位于冈底斯成矿带上,是对区域化探发现的Au、As多元素组合异常进行追踪发现的,属于热液型金矿床。矿区各类岩石Au、As、Sb、W、Hg、Ag、Bi、Pb元素平均值高于中国丰度值数倍以上,表明矿区具有丰富的物质来源基础。岩石地球化学研究证明,矿床地表发育Au、As、Sb等10多个元素组合异常。其中Au是成矿指示元素,As、Sb、W是密切伴生元素,Bi、Ag、Pb、Hg是一般的伴生元素。多元素组合异常浓度带发育,浓集中心互相套合叠置部位指示金矿(化)体位置。矿体指示元素(Au、As、Sb、W、Hg、Bi、Ag、Pb)异常分布在岩体、地层接触带和构造交汇处,显示金矿与岩浆活动、热液作用和断裂构造相关,属多次构造作用、岩浆热液叠加富集而成。该金矿床处在冈底斯成矿带内,此研究对该成矿带金异常的识别和查证,寻找新的金矿具有借鉴意义。  相似文献   

18.
There are controversies about the genesis of the lode gold deposits in Jiaodong area. The Sanshandao gold deposit is the largest one in Jiaodong area. To better understand the genesis of the gold deposit, it is necessary to know the evolution of ore-forming fluid and the source of ore-forming material for the Sanshandao gold deposit. In this paper, the trace element composition of pyrite at different metallogenic stages in the Sanshandao gold deposit was analyzed by using LA-ICP-MS. Based on geological characteristics and petrography observation and SEM analysis, pyrite can be divided into three stages and six classes, including porous Py1-a and smooth Py1-b in pyrite-sericite-quartz alteration (Py1), many mineral inclusions in the Py2-a and smooth Py2-b associated with carbonate in the quartz-pyrite ± siderite veins (Py2), a lot of polymetallic sulfide inclusions hosted Py3-a and Py3-b with smooth and oscillation band in the quartz-polymetallic sulfide vein (Py3). The experimental results show that the gold content is very low in the lattice of pyrite, most of which is less than 1×10-6, and gold mainly occurs in the form of visible gold. The contents of Au, Ag, Cu, Pb and Sb of pyrite gradually increase from early stage to late stage. The high content of Co+Ni in the earliest stage (up to 9268×10-6) reflects that pyrite in the early stage is likely derived from magma, and the Co/Ni ratio gradually decreases, suggesting the decrease of ore forming fluid temperature. Combined with the geological observations and trace elements component of pyrite, the study shows that the genesis of the Sanshandao gold deposit is related to the evolution of magmatic hydrothermal reservoir. The ore-forming fluid is transported several times along the fault by seismic pumping.  相似文献   

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