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1.
The weathering products present in igneous terrestrial Antarctic samples were analyzed, and compared with those found in the four Miller Range nakhlite Martian meteorites. The aim of these comparisons was to determine which of the alteration phases in the Miller Range nakhlites are produced by terrestrial weathering, and what effect rock composition has on these phases. Antarctic terrestrial samples MIL 05031 and EET 96400, along with the Miller Range nakhlites MIL 03346 and 090032, were found to contain secondary alteration assemblages at their externally exposed surfaces. Despite the difference in primary mineralogy, the assemblages of these rocks consist mostly of sulfates (jarosite in MIL 05031, jarosite and gypsum in EET 96400) and iddingsite‐like Fe‐clay. As neither of the terrestrial samples contains sulfur‐bearing primary minerals, and these minerals are rare in the Miller Range nakhlites, it appears that SO42?, possibly along with some of the Na+, K+, and Ca+ in these phases, was sourced from wind‐blown sea spray and biogenic emissions from the southern ocean. Cl enrichment in the terrestrially derived “iddingsite” of MIL 05031 and MIL 03346, and the presence of halite at the exterior edge of MIL 090032, can also be explained by this process. However, jarosite within and around the olivine‐bound melt inclusions of MIL 090136 is present in the interior of the meteorite and, therefore, is probably the product of preterrestrial weathering on Mars.  相似文献   

2.
Abstract— Antarctic meteorite Miller Range (MIL) 03346 is a nakhlite composed of 79% clinopyroxene, ?1% olivine, and 20% vitrophyric intercumulus material. We have performed a petrological and geochemical study of MIL 03346, demonstrating a petrogenetic history similar to previously discovered nakhlites. Quantitative textural study of MIL 03346 indicates long (>1 × 101 yr) residence times for the cumulus augite, whereas the skeletal Fe‐Ti oxide, fayalite, and sulfide in the vitrophyric intercumulus matrix suggest rapid cooling, probably as a lava flow. From the relatively high forsterite contents of olivine (up to Fo43) compared with other nakhlites and compositions of augite cores (Wo38–42En35–40Fs22–28) and their hedenbergite rims, we suggest that MIL 03346 is part of the same or a similar Martian cumulate‐rich lava flow as other nakhlites. However, MIL 03346 has experienced less equilibration and faster cooling than other nakhlites discovered to date. Calculated trace element concentrations based upon modal abundances of MIL 03346 and its constituent minerals are identical to whole rock trace element abundances. Parental melts for augite have REE patterns that are approximately parallel with whole rock and intercumulus melt using experimentally defined partition coefficients. This parallelism reflects closed‐system crystallization for MIL 03346, where the only significant petrogenetic process between formation of augite and eruption and emplacement of the nakhlite flow has been fractional crystallization. A model for the petrogenesis of MIL 03346 and the nakhlites (Nakhla, Governador Valadares, Lafayette, Yamato‐000593, Northwest Africa (NWA) 817, NWA 998) would include: 1) partial melting and ascent of melt generated from a long‐term LREE depleted mantle source, 2) crystallization of cumulus augite (± olivine, ± magnetite) in a shallow‐level Martian magma chamber, 3) eruption of the crystal‐laden nakhlite magma onto the surface of Mars, 4) cooling, crystal settling, overgrowth, and partial equilibration to different extents within the flow, 5) secondary alteration through hydrothermal processes, possibly immediately succeeding or during emplacement of the flow. This model might apply to single—or multiple—flow models for the nakhlites. Ultimately, MIL 03346 and the other nakhlites preserve a record of magmatic processes in volcanic rocks on Mars with analogous petrogenetic histories to pyroxene‐rich terrestrial lava flows and to komatiites.  相似文献   

3.
Caleta el Cobre (CeC) 022 is a Martian meteorite of the nakhlite group, showing an unbrecciated cumulate texture, composed mainly of clinopyroxene and olivine. Augite shows irregular core zoning, euhedral rims, and thin overgrowths enriched in Fe relative to the core. Low‐Ca pyroxene is found adjacent to olivine. Phenocrysts of Fe‐Ti oxides are titanomagnetite with exsolutions of ilmenite/ulvöspinel. Intercumulus material consists of both coarse plagioclase and fine‐grained mesostasis, comprising K‐feldspars, pyroxene, apatite, ilmenite, Fe‐Ti oxides, and silica. CeC 022 shows a high proportion of Martian aqueous alteration products (iddingsite) in olivine (45.1 vol% of olivine) and mesostasis. This meteorite is the youngest nakhlite with a distinct Sm/Nd crystallization age of 1.215 ± 0.067 Ga. Its ejection age of 11.8 ± 1.8 Ma is similar to other nakhlites. CeC 022 reveals contrasted cooling rates with similarities with faster cooled nakhlites, such as Northwest Africa (NWA) 817, NWA 5790, or Miller Range 03346 nakhlites: augite irregular cores, Fe‐rich overgrowths, fine‐grained K‐feldspars, quenched oxides, and high rare earth element content. CeC 022 also shares similarities with slower cooled nakhlites, including Nakhla and NWA 10153: pyroxene modal abundance, pyroxenes crystal size distribution, average pyroxene size, phenocryst mineral compositions, unzoned olivine, and abundant coarse plagioclase. Moreover, CeC 022 is the most magnetic nakhlite and represents an analog source lithology for the strong magnetization of the Martian crust. With its particular features, CeC 022 must originate from a previously unsampled sill or flow in the same volcanic system as the other nakhlites, increasing Martian sample diversity and our knowledge of nakhlites.  相似文献   

4.
Abstract– Miller Range (MIL) 03346 is the most oxidized and least equilibrated nakhlite known and displays the highest amount of intercumulus phase. The discovery of three new nakhlites, MIL 090030, MIL 090032, and MIL 090136, in the Miller Range, Antarctica, geographically close to the location of MIL 03346, suggests that they may come from the same parent meteorite. In this study, we investigate the mineralogy and texture of cumulus and intercumulus phases, in situ major and trace element compositions for the cumulus phases, as well as pyroxene crystal size distribution patterns and spatial distribution patterns of MIL 090030, 090032, and 090136. Using these combined results, we conclude that the three nakhlites studied here are paired with MIL 03346. However, modal mineral abundances of MIL 090030, 090032, 090136, and 03346 exhibit variations indicating that a single sample of a Miller Range nakhlite is not modally representative of the parent meteorite and that analyses of multiple samples for a single nakhlite may be necessary to obtain representative modal data for placement in the cumulate pile. Our calculated parental melt composition based on all the paired samples confirms a previous study suggesting that the nakhlite parent melt crystallized as a closed system.  相似文献   

5.
Abstract— We petrologically examined the Miller Range (MIL) 03346 nakhlite. The main‐phase modal abundances are 67.7 vol% augite, 0.8 vol% olivine, and 31.5 vol% mesostasis. Among all known nakhlites, MIL 03346's modal abundance of olivine is the smallest and of mesostasis is the largest. Augite occurs as cumulus phenocrysts having a homogeneous core composition (En36–38Fs24–22Wo40), which is identical with other nakhlites. They accompany thin ferroan rims divided into inner and outer rims with a compositional gap at the boundary between the two rims. Olivine grains have magnesian cores (Fa ≥ 55) and show normal zoning toward ferroan rims (Fa ≤ 84). Mesostasis consists mostly of glass (26.0 vol%) with minor skeletal fayalites, skeletal titanomagnetites, acicular phosphate, massive cristobalite, and sulfides. We conclude that MIL 03346 is the most rapidly cooled nakhlite among all known nakhlites based on the petrography. We obtain the intercumulus melt composition for MIL 03346 from the mass balance calculation using the modal abundances and discuss the crystallization sequence of MIL 03346 in comparison with that of Yamato (Y‐) 000593. Although magnesian olivines of Y‐000593 are phenocrystic, magnesian olivine grains of MIL 03346 seem to have texturally crystallized from the intercumulus melt. After the MIL 03346 magma intruded upward to the Martian surficial zone, the magnesian olivine crystallized, and then the ferroan inner rim formed on phenocrystic core augite. The outer rim of phenocrystic augites formed after the crystallization of skeletal fayalites and skeletal titanomagnetites, resulting in a compositional gap between the inner and outer rims. Finally, glassy mesostasis formed from the residual melt. This crystallization sequence of MIL 03346 is different from those of other nakhlites, including Y‐000593.  相似文献   

6.
Secondary mineral assemblages in the nakhlite meteorites, Lafayette, Governador Valadares (GV), Nakhla, Yamato (Y)‐000593/Y‐000749 have been studied using scanning electron microscopy, transmission electron microscopy, and electron probe micro analysis. The different nakhlites have distinctive secondary assemblages in their olivine grains and mesostases, showing compositional fractionation correlated with their relative depths below the Martian surface. Fracture‐filled veins in Lafayette at the bottom of the pile consist of a siderite‐phyllosilicate‐Fe oxide‐hydrated silicate gel assemblage. Corresponding veins in Nakhla and GV further up the pile are predominantly a siderite‐gel assemblage, with additional evaporites including gypsum. Y‐000593/Y‐000749 veins are dominated by gel. The gel’s Mg/(Mg + Fe) ratio decreases from Lafayette (0.37) to GV (0.32), Nakhla (0.24), and Y‐000593 (0.15). We suggest that hydrothermal fluid flowed up this depth profile, initiated by melting of buried H2O–CO2 ice. Our results show a complex mix of Fe‐rich phyllosilicate within the veins and mesostasis of Lafayette with d‐spacings of 0.7–1.1 nm suggesting a mixture of smectite and serpentine. The phyllosilicate formed at close to neutral pH, ≤150 °C. We also suggest that water rock ratios (W/R) of 1–10 occurred in Lafayette with smaller values for the other nakhlites. This is reflected in the volume of alteration minerals: 10% of olivine in Lafayette to 3% in Nakhla. Textural evidence of rapid cooling, together with the W/R and likely fluid velocities, suggest that the secondary assemblages formed quickly, e.g., within months. A model is proposed in which the secondary assemblages formed in an impact‐induced hydrothermal system terminated by precipitation of the gel and evaporation of soluble salts.  相似文献   

7.
We present a geochemical study of recently discovered Martian meteorite Northwest Africa (NWA) 5790 and use our results to constrain its origin and relationship with the other nakhlites. This nakhlite is a clinopyroxene cumulate composed of phenocrysts of augite, olivine, and rare oxides surrounded by a mesostasis composed of vitrophyric glass, feldspars, oxides, phosphates, and fine‐grained olivines and augite. Petrography, and major and trace element compositions of the phases present are consistent with derivation of NWA 5790 from a parental magma common to all the nakhlites. Olivine cores grew from a distinct, incompatible‐element enriched magma and are surrounded by rims containing augite inclusions that grew from the nakhlite parental liquid, supporting previous arguments for xenocrystic olivine cores in nakhlites. Rare earth element microdistributions suggest derivation of NWA 5790 augites from an evolved, relatively oxidized magma, produced by augite fractionation from the common nakhlite parental liquid. Augite grain shapes and CSD patterns are consistent with rapid cooling and derivation near the top of the nakhlite cumulate pile, but patterns are distinct from other nakhlites thought to have formed near the stratigraphic top. The high mesostasis abundance (~44 vol%) indicates solidification near the top of the nakhlite pile close to locations suggested for nakhlites NWA 817 and Miller Range (MIL) 03346. However, the geochemical and petrographic characteristics of these three samples do not permit their placement in a simple stratigraphic order as would occur in a single lava flow. This lack of simple ordering suggests that the nakhlite lava flow split into multiple sections as would occur during breakouts from a single lava flow. Finally we note that NWA 5790 is unique among currently available nakhlites in having phenocryst abundances low enough to allow it to flow.  相似文献   

8.
Nakhlites, clinopyroxenite meteorites from Mars, share common crystallization and ejection ages, suggesting that they might have been ejected from the same place on Mars by the same ejection event (impact) and are different samples of the same thick volcanic flow unit or shallow sill. Mean modal abundances and abundance ranges of pyroxene, olivine, and mesostasis vary widely among different thin‐sections of an individual nakhlite. Lithologic heterogeneity is the main factor contributing to the observed modal‐abundance variations measured in thin‐sections prepared from different fragments of the same stone. Two groups of nakhlites are distinguished from one another by which major constituent varies the least and the abundance of that constituent. The group consisting of Nakhla, Lafayette, Governador Valadares, and the Yamato nakhlite pairing group is characterized by low modal mesostasis and pyroxene‐olivine covariance, whereas the group consisting of the Miller Range nakhlite pairing group and Northwest Africa 5790 is characterized by low modal olivine and pyroxene‐mesostasis covariance. These two groups sample the slowest‐cooled interior portion and the chilled margin, respectively, of the nakhlite emplacement body as presently understood, and appear to be also related to recently proposed nakhlite groups independently established using compositional rather than petrographic observations. Phenocryst modal abundances vary with inferred depth in the nakhlite igneous body in a manner consistent with solidification of the nakhlite stack from dynamically sorted phenocryst‐rich magmatic crystal‐liquid mush.  相似文献   

9.
Abstract— Crystallization of parent melts for nakhlites was experimentally studied under QFM ± 2 at one bar. Isothermal experiments suggest that melts having parent magma composition for nakhlites crystallize both augites and titanomagnetites at liquidus temperatures of 1144–1154 °C. Compositions of the augites are identical to those of phenocrystic core augites (En36–38Fs22–25Wo39–40) in nakhlites. No olivines crystallize from the isothermal runs, and solidus temperature is about 1000 °C. Linear‐cooling experiments were carried out at various cooling rates (1–17 °C/h) ranging from liquidus to solidus temperatures under similar pressure conditions to the isothermal runs. Augites, titanomagnetites, and fayalites crystallized in the cooling runs, but magnesian olivines never crystallized there. Magnesian core augite in the cooling runs has the same composition as those of nakhlites. Rims of augite crystals from the cooling runs of 1–4 °C/h consist of two layers, ferroan augite inner rim and hedenbergite outer rim, which are very similar to those in the Miller Range (MIL) 03346 nakhlite. Small amounts of pyroxferroite crystallized in mesostasis and augite rims from two cooling runs. Titanomagnetites from cooling runs never accompany ilmenite lamellae as seen in nakhlites, suggesting that the subsolidus cooling rate of the cooling runs was much more rapid than those of nakhlite intercumulus melts. The cooling experiments reproduce the crystallization processes of pyroxenes and the compositional change of residual melt for a rapidly cooled magma such as MIL 03346.  相似文献   

10.
Recently it has been shown that the relatively low closure temperature (Tc) of 500 (100)°C calculated for augite from Miller Range nakhlite (MIL 03346,13) using the available geothermometers would correspond to a slow cooling rate inconsistent with the petrologic evidence for an origin from a fast‐cooled lava flow. Moreover, previous annealing experiments combined with HR‐SC‐XRD on an augite crystal from MIL 03346 clearly showed that at 600 °C, the Fe2+‐Mg degree of order remained unchanged, thus suggesting that the actual Tc is close to this temperature. In order to clarify this discrepancy, we undertook an ex situ annealing experimental study at 700, 800, and 900 °C, until the equilibrium in the intracrystalline Fe2+‐Mg exchange is reached, using an augite crystal from Miller Range nakhlite (MIL 03346,13) with a composition of about En36Fs24Wo40. These data allowed us to calculate the following new geothermometer calibration for Martian nakhlites: where The application of this new equation to other Martian nakhlites (NWA 988 and Nakhla) suggests that for augite with composition close to that of MIL 03346, the Tc is up to 170 °C higher with respect to the one calculated using the previous available geothermometer equation, thus suggesting a significantly faster cooling in agreement with petrologic evidence.  相似文献   

11.
Abstract— Experimentally rehomogenized melt inclusions from the nakhlite Miller Range 03346 (MIL 03346) and the lherzolitic shergottite Allan Hills 77005 (ALH 77005) have been analyzed for their rare earth element (REE) concentrations in order to characterize the early melt compositions of these Martian meteorites and to calculate the oxygen fugacity conditions they crystallized under. D(Eu/Sm)pyroxene/melt values were measured at 0.77 and 1.05 for ALH 77005 and MIL 03346, respectively. These melts and their associated whole rock compositions have similar REE patterns, suggesting that whole rock REE values are representative of those of the early melts and can be used as input into the pyroxene Eu‐oxybarometer for the nakhlites and lherzolitic shergottites. Crystallization fO2 values of IW + 1.1 (ALH 77005) and IW + 3.2 (MIL 03346) were calculated. Whole rock data from other nakhlites and lherzolitic shergottites was input into the Eu‐oxybarometer to determine their crystallization fO2 values. The lherzolitic shergottites and nakhlites have fO2 values that range from IW + 0.4 to 1.6 and from IW + 1.1 to 3.2, respectively. These values are consistent with some previously determined fO2 estimates and expand the known range of fO2 values of the Martian interior to four orders of magnitude. The origins of this range are not well constrained. Possible mechanisms for producing this spread in fO2 values include mineral/melt fractionation, assimilation, shock effects, and magma ocean crystallization processes. Mineral/melt partitioning can result in changes in fO2 from the start to the finish of crystallization of 2 orders of magnitude. In addition, crystallization of a Martian magma ocean with reasonable initial water content results in oxidized, water‐rich, late‐stage cumulates. Sampling of these oxidized cumulates or interactions between reduced melts and the oxidized material can potentially account for the range of fO2 values observed in the Martian meteorites.  相似文献   

12.
Abstract— Dynamic crystallization experiments performed on Fe‐rich, Al‐poor basalt are employed as a textural calibration set to quantify the late‐stage igneous history of nakhlite Miller Range (MIL) 03346. The ratio of crystal‐melt surface area to volume typifying morphologically distinct populations of Ca‐pyroxene has been shown to vary as a strong function of cooling rate (Hammer 2006). Furthermore, a texture of phenocrysts surrounded by finer‐grained groundmass crystals arises by sequential nucleation events during constant‐rate cooling, but multiple populations nucleate only if the cooling rate is 72 °C h?1. Textural analysis of meteorite MIL 03346 reveals at least two distinct populations. The Ca‐pyroxene phenocryst and microphenocryst three dimensional (3D) aspect ratios are 112 ± 8.3 and 1530 ± 160 mm?1, respectively. By comparison with the calibration set, the range of cooling rates consistent with 3D aspect ratios of both populations in MIL 03346 is ?20 °C h?1An additional experiment was performed approximating a conductive heat transfer profile in order to interpret and apply results of constant‐rate cooling experiments to the natural cooling of magma. Results suggest that the textures of constant‐rate experiments parallel the initial period of rapid cooling in natural magma. Initial cooling rates of ?20 °C h?1in the lava hosting MIL 03346 occur in conductively solidifying lava at depths of?0.4 m, constraining the minimum total thickness to 0.8 m. Crystal accumulation beginning in a subsurface reservoir and continuing after lava emplacement as an inflated pahoehoe sheet satisfies all textural constraints on the late‐stage igneous history of MIL 03346.  相似文献   

13.
Abstract— Pyroxene structural data, along with analyses of titanomagnetite, fayalite and mesostasis of the new nakhlite Miller Range (MIL) 03346, define equilibration near 1 bar, 1100 °C, and oxygen fugacity near the FMQ buffer. There is a clear progression of oxygen fugacity (fO2) in Martian meteorites from reduced Allan Hills (ALH) 84001 to intermediate shergottites to oxidized nakhlites. This trend can be explained by polybaric graphite‐CO‐CO2 equilibria in the Martian mantle. Shergottites would have formed at pressures between 1.2 and 3.0 GPa, and nakhlite parent liquids formed at pressures >3.0 GPa, consistent with geochemical and petrologic data for the shergottites and nahklites. Carbon buffering in the Martian mantle could be responsible for variation in fO2 in Martian meteorites (rather than assimilation or crustal interaction), as well as C‐H‐O fluids that could be the source of ˜30 ppb CH4 detected by recent spacecraft missions. The conundrum of an oxidized current mantle and basalts, but reduced early mantle during core‐mantle equilibrium exists for both the Earth and Mars. A polybaric buffering role for graphite can explain this discrepancy for Mars, and thus it may not be necessary to have an oxidation mechanism like the dissociation of MgFe‐perovskite to account for the oxidized terrestrial mantle.  相似文献   

14.
The nakhlite meteorites are clinopyroxenites that are derived from a ~1300 million year old sill or lava flow on Mars. Most members of the group contain veins of iddingsite whose main component is a fine‐grained and hydrous Fe‐ and Mg‐rich silicate. Siderite is present in the majority of veins, where it straddles or cross‐cuts the Fe‐Mg silicate. This carbonate also contains patches of ferric (oxy)hydroxide. Despite 40 years of investigation, the mineralogy and origins of the Fe‐Mg silicate is poorly understood, as is the paragenesis of the iddingsite veins. Nanometer‐scale analysis of Fe‐Mg silicate in the Nakhla meteorite by electron and X‐ray imaging and spectroscopy reveals that its principal constituents are nanoparticles of opal‐A. This hydrous and amorphous phase precipitated from acidic solutions that had become supersaturated with respect to silica by dissolution of olivine. Each opal‐A nanoparticle is enclosed within a ferrihydrite shell that formed by oxidation of iron that had also been liberated from the olivine. Siderite crystallized subsequently and from solutions that were alkaline and reducing, and replaced both the nanoparticles and olivine. The fluids that formed both the opal‐A/ferrihydrite and the siderite were sourced from one or more reservoirs in contact with the Martian atmosphere. The last event recorded by the veins was alteration of the carbonate to a ferric (oxy)hydroxide that probably took place on Mars, although a terrestrial origin remains possible. These results support findings from orbiter‐ and rover‐based spectroscopy that opaline silica was a common product of aqueous alteration of the Martian crust.  相似文献   

15.
Northwest Africa (NWA) 6112, Miller Range (MIL) 090206 (plus its pairs: MIL 090340 and MIL 090405), and Divnoe are olivine‐rich ungrouped achondrites. We investigated and compared their petrography, mineralogy, and olivine fabrics. We additionally measured the oxygen isotopic compositions of NWA 6112. They show similar petrography, mineralogy, and oxygen isotopic compositions and we concluded that these five meteorites are brachinite clan meteorites. We found that NWA 6112 and Divnoe had a c axis concentration pattern of olivine fabrics using electron backscattered diffraction (EBSD). NWA 6112 and Divnoe are suggested to have been exposed to magmatic melt flows during their crystallization on their parent body. On the other hand, the three MIL meteorites have b axis concentration patterns of olivine fabrics. This indicates that the three MIL meteorites may be cumulates where compaction of olivine grains was dominant. Alternatively, they formed as residues and were exposed to olivine compaction. The presence of two different olivine fabric patterns implies that the parent body(s) of brachinite clan meteorites experienced diverse igneous processes.  相似文献   

16.
Miller Range (MIL) 090340 and MIL 090206 are olivine‐rich achondrites originally classified as ureilites. We investigate their petrography, mineral compositions, olivine Cr valences, equilibration temperatures, and (for MIL 090340) oxygen isotope compositions, and compare them with ureilites and other olivine‐rich achondrites. We conclude that they are brachinite‐like achondrites that provide new insights into the petrogenesis of brachinite clan meteorites. MIL 090340,6 has a granoblastic texture and consists of ~97 modal % by area olivine (Fo = molar Mg/[Mg+Fe] = 71.3 ± 0.6). It also contains minor to trace augite, chromite, chlorapatite, orthopyroxene, metal, troilite, and terrestrial Fe‐oxides. Approximately 80% by area of MIL 090206,5 has a granoblastic texture of olivine (Fo 72.3 ± 0.1) plus minor augite and chromite, similar to MIL 090340 but also containing minor plagioclase. The rest of the section consists of a single crystal of orthopyroxene (~11 × 3 mm), poikilitically enclosing rounded grains of olivine (Fo = 76.1 ± 0.6), augite, chromite, metal, and sulfide. Equilibration temperatures for MIL 090340 and MIL 090206, calculated from olivine‐spinel, olivine‐augite, and two‐pyroxene thermometry range from ~800 to 930 °C. In both samples, symplectic intergrowths of Ca‐poor orthopyroxene + opaque phases (Fe‐oxides, sulfide, metal) occur as rims on and veins/patches within olivine. Before terrestrial weathering, the opaques were probably mostly sulfide, with minor metal. All petrologic properties of MIL 090340 and MIL 090206 are consistent with those of brachinite clan meteorites, and largely distinct from those of ureilites. Oxygen isotope compositions of olivine in MIL 090340 (δ18O = 5.08 ± 0.30‰, δ17O = 2.44 ± 0.21‰, and Δ17O = ?0.20 ± 0.12‰) are also within the range of brachinite clan meteorites, and well distinguished from ureilites. Olivine Cr valences in MIL 090340 and the granoblastic area of MIL 090206 are 2.57 ± 0.06 and 2.59 ± 0.07, respectively, similar to those of three brachinites also analyzed here (Brachina, Hughes 026, Nova 003). They are higher than those of olivine in ureilites, even those containing chromite. The valence systematics of MIL 090340, MIL 090206, and the three analyzed brachinites (lower Fo = more oxidized Cr) are consistent with previous evidence that brachinite‐like parent bodies were inherently more oxidized than the ureilite parent body. The symplectic orthopyroxene + sulfide/metal assemblages in MIL 090340, MIL 090206, and many brachinite clan meteorites have superficial similarities to characteristic “reduction rims” in ureilites. However, they differ significantly in detail. They likely formed by reaction of olivine with S‐rich fluids, with only minor reduction. MIL 090340 and the granoblastic area of MIL 090206 are similar in modal mineralogy and texture to most brachinites, but have higher Fo values typical of brachinite‐like achondrites. The poikilitic pyroxene area of MIL 090206 is more typical of brachinite‐like achondrites. The majority of their properties suggest that MIL 090340 and MIL 090206 are residues of low‐degree partial melting. The poikilitic area of MIL 090206 could be a result of limited melt migration, with trapping and recrystallization of a small volume of melt in the residual matrix. These two samples are so similar in mineral compositions, Cr valence, and cosmic ray exposure ages that they could be derived from the same lithologic unit on a common parent body.  相似文献   

17.
Abstract– The nakhlites, a subgroup of eight clinopyroxenites thought to come from a single geological unit at the Martian surface, show melt inclusions in augite and olivine. In contrast to olivine‐hosted melt inclusions, augite‐hosted melt inclusions are not surrounded by fractures, and are thus considered preferential candidates for reconstructing parent liquid compositions. Furthermore, two types of augite‐hosted melt inclusion have been defined and characterized in four different nakhlites (Northwest Africa [NWA] 817, Nakhla, Governador Valadares, and NWA 998): Type‐I isolated inclusions in augite cores that contain euhedral to subhedral augite, Ti‐magnetite, and pigeonite plus silica‐rich glass and a gas bubble; Type‐II microinclusions that form trails crosscutting host augite crystals. Fast‐heating experiments were performed on selected pristine primary augite‐hosted melt inclusions from these four samples. Of these, only data from Nakhla were considered robust for reconstruction of a nakhlite parental magma composition (NPM). Based upon careful petrographic selection and consideration of iron‐magnesium ratios, our data are used to propose an NPM, which is basaltic (49.1 wt% SiO2), of high Ca/Al (1.95), and K2O‐poor (0.32 wt%). Thermodynamic modeling at an oxygen fugacity one log unit below the QFM buffer using the MELTS and PETROLOG programs implies that Mg‐rich olivine was not a liquidus phase for this composition. Our analysis is used to suggest that olivine megacrysts found in the nakhlites are unlikely to have coprecipitated with augite, and thus may have been introduced during or subsequent to accumulation in the magma chamber, possibly from more evolved portions of the same chamber.  相似文献   

18.
MIL 11207 (R6) and LAP 04840 (R6) contain hornblende and phlogopite; MIL 07440 (R6) contains accessory titan‐phlogopite and no hornblende. All three meteorites have been shocked: MIL 11207 contains extensive sulfide veins, pyroxene that formed from dehydrated hornblende, and an extensive network of plagioclase glass; MIL 07440 contains chromite‐plagioclase assemblages, chromite veinlets and blebs, pincer‐shaped plagioclase patches, but no sulfide veins; LAP 04840 contains olivine grains with chromite‐bleb‐laden cores and opaque‐free rims, rare grains of pyroxene that formed from dehydrated hornblende, and no sulfide veins. These meteorites appear to have been heated to maximum temperatures of approximately 700–900 °C under conditions of moderately high PH2O (perhaps 250–500 bars). All three samples underwent postshock annealing. During this process, olivine crystal lattices healed (giving the rocks the appearance of shock‐stage S1), and diffusion of Fe and S from thin sulfide veins to coarse sulfide grains caused the veins to disappear in MIL 07440 and LAP 04840. This latter process apparently also occurred in most S1–S2 ordinary chondrites of high petrologic type. The pressure–temperature conditions responsible for forming the amphibole and mica in these rocks may have been present at depths of a few tens of kilometers (as suggested in the literature). A giant impact or a series of smaller impacts would then have been required to excavate the hornblende‐ and biotite‐bearing rocks and bring them closer to the surface. It was in that latter location where the samples were shocked, deposited in a hot ejecta blanket of low thermal diffusivity, and annealed.  相似文献   

19.
We used new analytical and theoretical methods to determine the major and minor element compositions of the primary trapped liquid (PTLs) represented by melt inclusions in olivine and augite in the Martian clinopyroxenite, Nakhla, for comparison with previously proposed compositions for the Nakhla (or nakhlite) parent magma. We particularly focused on obtaining accurate K2O contents, and on testing whether high K2O contents and K2O/Na2O ratios obtained in previous studies of melt inclusions in olivine in Nakhla could have been due to unrepresentative sampling, systematic errors arising from electron microprobe techniques, late alteration of the inclusions, and/or boundary layer effects. Based on analyses of 35 melt inclusions in olivine cores, the PTL in olivine, PTLoliv, contained (by wt) approximately 47% SiO2, 6.3% Al2O3, 9.6% CaO, 1.8% K2O, and 0.9% Na2O, with K2O/Na2O = 2.0. We infer that the high K2O content of PTLoliv is not due to boundary layer effects and represents a real property of the melt from which the host olivine crystallized. This melt was cosaturated with olivine and augite. Its mg# is model‐dependent and is constrained only to be ≥19 (equilibrium Fo = 40). Based on analyses of 91 melt inclusions in augite cores, the PTL in augite, PTLaug, contained (by wt) 53–54% SiO2, 7–8% Al2O3, 0.8–1.1% K2O, and 1.1–1.4% Na2O, with K2O/Na2O = 0.7–0.8. This K2O content and K2O/Na2O ratio are significantly higher than inferred in studies of melt inclusions in augite in Nakhla by experimental rehomogenization. PTLaug was saturated only with augite, and in equilibrium with augite cores of mg# 62. PTLaug represents the Nakhla parent magma, and does not evolve to PTLoliv by fractional crystallization. We therefore conclude that olivine cores in Nakhla (and, by extension, other nakhlites) are xenocrystic. We propose that PTLoliv and PTLaug were generated from the same source region. PTLoliv was generated first and emplaced to form olivine‐rich cumulate rocks. Shortly thereafter, PTLaug was generated and ascended through these olivine‐rich cumulates, incorporating fragments of wallrock that became the xenocrystic olivine cores in Nakhla. The Nakhla (nakhlite) mantle source region was pyroxenitic with some olivine, and could have become enriched in K relative to Na via metasomatism. A high degree of melting of this source produced the silica‐poor, alkali‐rich magma PTLoliv. Further ascension and decompression of the source led to generation of the silica‐rich, relatively alkali‐poor magma PTLaug. Potassium‐rich magmas like those involved in the formation of the nakhlites represent an important part of the diversity of Martian igneous rocks.  相似文献   

20.
Abstract— Nakhla contains crystallized melt inclusions that were trapped in augite and olivine when these phases originally formed on Mars. Our study involved rehomogenization (slow‐heating and fast‐heating) experiments on multiphase melt inclusions in Nakhla augite. We studied melt inclusions trapped in augite because this phase re‐equilibrated with the external melt to a lesser extent than olivine and results could be directly compared with previous Nakhla melt inclusion studies. Following heating and homogenization of encapsulated melt inclusions, single mineral grains were mounted and polished to expose inclusions. Major element chemistry was determined by electron microprobe. The most primitive melt inclusion analyzed in Nakhla NA03 is basaltic and closely matches previously reported nakhlite parent melt compositions. MELTS equilibrium and fractional crystallization models calculated for NA03 and previous Nakhla parent melt estimates at QFM and QFM‐1 produced phase assemblages and compositions that can be compared to Nakhla. Of these models, equilibrium crystallization of NA03 at QFM‐1 produced the best match to mineral phases and compositions in Nakhla. In all models, olivine and augite co‐crystallize, consistent with the hypothesis that olivine is not xenocrystic but has undergone subsolidus re‐equilibration. In addition, measured melt inclusion compositions plot along the MELTS‐calculated liquid line of descent and may represent pockets of melt trapped at various stages during crystallization. We attempt to resolve discrepancies between previous estimates of the Nakhla parental melt composition and to reinterpret the results of a previous study of rehomogenized melt inclusions in Nakhla. Melt inclusions demonstrate that Nakhla is an igneous rock whose parent melt composition and crystallization history reflect planetary igneous processes.  相似文献   

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