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Abstract— We measured nickel isotopes via multicollector inductively coupled plasma mass spectrometry (MC‐ICPMS) in the bulk metal from 36 meteorites, including chondrites, pallasites, and irons (magmatic and non‐magmatic). The Ni isotopes in these meteorites are mass fractionated; the fractionation spans an overall range of ~0.4‰ amu?1. The ranges of Ni isotopic compositions (relative to the SRM 986 Ni isotopic standard) in metal from iron meteorites (~0.0 to ~0.3‰ amu?1) and chondrites (~0.0 to ~0.2‰ amu?1) are similar, whereas the range in pallasite metal (~–0.1 to 0.0‰ amu?1) appears distinct. The fractionation of Ni isotopes within a suite of fourteen IIIAB irons (~0.0 to ~0.3‰ amu?1) spans the entire range measured in all magmatic irons. However, the degree of Ni isotopic fractionation in these samples does not correlate with their Ni content, suggesting that core crystallization did not fractionate Ni isotopes in a systematic way. We also measured the Ni and Fe isotopes in adjacent kamacite and taenite from the Toluca IAB iron meteorite. Nickel isotopes show clearly resolvable fractionation between these two phases; kamacite is heavier relative to taenite by ~0.4‰ amu?1. In contrast, the Fe isotopes do not show a resolvable fractionation between kamacite and taenite. The observed isotopic compositions of kamacite and taenite can be understood in terms of kinetic fractionation due to diffusion of Ni during cooling of the Fe‐Ni alloy and the development of the Widmanstätten pattern.  相似文献   
3.
The fall and recovery of the Tissint meteorite in 2011 created a rare opportunity to examine a Martian sample with a known, short residence time on Earth. Tissint is an olivine‐phyric shergottite that accumulated olivine antecrysts within a single magmatic system. Coarse olivine grains with nearly homogeneous cores of Mg# >80 suggest slow re‐equilibration. Many macroscopic features of this sample resemble those of LAR 06319, including the olivine crystal size distribution and the presence of evolved oxide and olivine compositions. Unlike LAR 06319, however, no magmatic hydrous phases were found in the analyzed samples of Tissint. Minor and trace element compositions indicate that the meteorite is the product of closed‐system crystallization from a parent melt derived from a depleted source, with no obvious addition of a LREE‐rich (crustal?) component prior to or during crystallization. The whole‐rock REE pattern is similar to that of intermediate olivine‐phyric shergottite EETA 79001 lithology A, and could also be approximated by a more olivine‐rich version of depleted basaltic shergottite QUE 94201. Magmatic oxygen fugacities are at the low end of the shergottite range, with log fO2 of QFM‐3.5 to ‐4.0 estimated based on early‐crystallized minerals and QFM‐2.4 estimated based on the Eu in pyroxene oxybarometer. These values are similarly comparable to other depleted shergottites, including SaU 005 and QUE 94201. Tissint occupies a previously unsampled niche in shergottite chemistry: containing olivines with Mg# >80, resembling the enriched olivine‐phyric shergottite LAR 06319 in its crystallization path, and comparable to intermediate olivine‐phyric shergottite EETA 79001A, depleted olivine‐phyric shergottite DaG 476, and depleted basaltic shergottite QUE 94201 in its trace element abundances and oxygen fugacity. The apparent absence of evidence for terrestrial alteration in Tissint (particularly in trace element abundances in the whole‐rock and individual minerals) confirms that exposure to the arid desert environment results in only minimal weathering of samples, provided the exposure times are brief.  相似文献   
4.
Spectral analysis is used to determine the wave force characteristics on structures exposed to random waves. Considerable work has been carried out to determine the magnitude of random wave forces acting on a single cylinder, but little information is available in the case of a group of cylinders in random waves. Such situations arise when structures comprise multiple tubular members which are in close proximity, and wave forces cannot be calculated precisely by analytical methods due to complicated flow conditions past the group. Experimental studies are also required for proper understanding and analysis. An experimental scheme was carried out to study the wave force characteristics on a single cylinder and on a group of cylinders in response to two different wave spectra with the same significant wave height, and the results are compared.  相似文献   
5.
The study reports estimates of above ground phytomass carbon pools in Indian forests for 1992 and 2002 using two different methodologies. The first estimate was derived from remote sensing based forest area and crown density estimates, and growing stock data for 1992 and 2002 and the estimated pool size was in the range 2,626–3,071 Tg C (41 to 48 Mg C ha???1) and 2,660–3,180 Tg C (39 to 47 Mg C ha???1) for 1992 and 2002, respectively. The second methodology followed IPCC 2006 guidelines and using an initial 1992 pool of carbon, the carbon pool for 2002 was estimated to be in the range of 2,668–3,112 Tg C (39 to 46 Mg C ha???1), accounting for biomass increment and removals for the period concerned. The estimated total biomass increment was about 458 Tg over the period 1992–2002. Removals from forests include mainly timber and fuel wood, whereby the latter includes large uncertainty as reported extraction is lower than actual consumption. For the purpose of this study, the annual extraction values of 23 million m3 for timber and 126 million m3 for fuel wood were used. Out of the total area, 10 million ha are plantation forests with an average productivity (3.2 Mg ha???1 year???1) that is higher than natural forests, a correction of 408 Tg C for the 10 year period was incorporated in total estimated phytomass carbon pool of Indian forests. This results in an estimate for the net sink of 4 Tg C year???1. Both approaches indicate Indian forests to be sequestering carbon and both the estimates are in agreement with recent studies. A major uncertainty in Indian phytomass carbon pool dynamics is associated with trees outside forests and with soil organic carbon dynamics. Using recent remote-sensing based estimates of tree cover and growing stock outside forests, the estimated phytomass carbon pool for trees outside forests for the year 2002, is 934 Tg C with a national average tree carbon density of 4 Mg C ha???1 in non-forest area, in contrast to an average density of 43 Mg C ha???1 in forests. Future studies will have to consider dynamics in both trees outside forests and soil for total terrestrial carbon dynamics.  相似文献   
6.
About half of the lunar meteorites in our collections are feldspathic breccias. Acquiring geochronologic information from these breccias is challenging due to their low radioactive-element contents and their often polymict nature. We used high-spatial-resolution (5 μm) NanoSIMS (nanoscale secondary ion mass spectrometry) U-Pb dating technique to date micro-zircons in the lunar feldspathic meteorites Dhofar 1528 and Dhofar 1627. Three NanoSIMS dating spots of two zircon grains from Dhofar 1528 show a discordia with an upper intercept at 4354 ± 76 Ma and a lower intercept at 332 ± 1407 Ma (2σ, MSWD = 0.01, p = 0.91). Three spots of two zircon grains in Dhofar 1627 define a discordia with an upper intercept at 3948 ± 30 Ma and a lower intercept at 691 ± 831 Ma (2σ, MSWD = 0.40, p = 0.53). Both samples likely experienced shock metamorphism caused by impacts. Based on the clastic nature, lack of recrystallization and the consistent U-Pb and Pb-Pb dates of the zircons in Dhofar 1528, the U-Pb date of 4354 Ma is interpreted as the crystallization age of its Mg-suite igneous precursor. Some of the Dhofar 1627 zircons show poikilitic texture, a crystallization from the matrix impact melt, so the U-Pb date of 3948 Ma corresponds to an impact event, likely the Imbrium basin-forming event. These data are the first radiometric ages for these two meteorites and demonstrate that in situ (high spatial resolution) U-Pb dating has potential for extracting geochronological information about igneous activities and impact events from lunar feldspathic and polymict breccias.  相似文献   
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In this work, the deposition of clay-sized fine particles (d50 = 0.006 mm) and its subsequent influence on the dune-induced hyporheic exchange are investigated. Fine sand (D50 = 0.28 mm), coarse sand (D50 = 1.7 mm), and gravel (D50 = 5.5 mm) grains were used to form homogenous model streambeds; one control - no clay input, and two treatments - increasing clay inputs for each grain type. The results indicate that the clogging profiles of clay-sized sediments may not be predicted accurately using the previously proposed metric based on the relative sizes of infiltrating and substrate sediments. Further, the depositional patterns vary with the initial concentration of clay particles in the surface water. The assessment of clogging profiles in coarse-grained model streambeds also reveals a preferential infiltration of the clay particles in the hyporheic downwelling regions. The results from the dye tracer test suggest that the accumulation of clay particles altered the exchange characteristics in the treatment flumes. For each grain size, the treatment flumes exhibit lower hyporheic flux and higher median residence times compared to their respective control flumes. The dye penetration depths were lower in treatment flumes with fine and coarse sand compared to their respective control flumes. Interestingly, higher penetration depths were observed in treatment flumes with gravel compared to their respective control flume potentially due to the generation of preferential flow paths in the partially clogged gravel beds. The clogging altered the hyporheic fluxes and residence times in the coarse-grained model beds to a greater degree in comparison to the fine sand beds. Overall, our findings indicate that the properties of both fine and substrate sediments influence the clogging patterns in streambeds, and the subsequent influence of fine sediment clogging on hyporheic exchange and associated processes may vary across stream ecosystems.  相似文献   
9.
Larkman Nunatak (LAR) 12095 and LAR 12240 are recent olivine‐phyric shergottite finds. We report the results of petrographic and chemical analyses of these two samples to understand their petrogenesis on Mars. Based on our analyses, we suggest that these samples are likely paired and are most similar to other depleted olivine‐phyric shergottites, particularly Dar al Gani (DaG) 476 and Sayh al Uhaymir (SaU) 005 (and samples paired with those). The olivine megacryst cores in LAR 12095 and LAR 12240 are not in equilibrium with the groundmass olivines. We infer that these megacrysts are phenocrysts and their major element compositions have been homogenized by diffusion (the cores of the olivine megacrysts have Mg# ~70, whereas megacryst rims and groundmass olivines typically have Mg# ~58–60). The rare earth element (REE) microdistributions in the various phases (olivine, low‐ and high‐Ca pyroxene, maskelynite, and merrillite) in both samples are similar and support the likelihood that these two shergottites are indeed paired. The calculated parent melt (i.e., in equilibrium with the low‐Ca pyroxene, which is one of the earliest formed REE‐bearing minerals) has an REE pattern parallel to that of melt in equilibrium with merrillite (i.e., one of the last‐formed minerals). This suggests that the LAR 12095/12240 paired shergottites represent the product of closed‐system fractional crystallization following magma emplacement and crystal accumulation. Utilizing the europium oxybarometer, we estimate that the magmatic oxygen fugacity early in the crystallization sequence was ~IW. Finally, petrographic evidence indicates that LAR 12095/12240 experienced extensive shock prior to being ejected from Mars.  相似文献   
10.
CK chondrites are the only group of carbonaceous chondrites with petrologic types ranging from 3 to 6. Although CKs are described as calcium‐aluminum‐rich inclusion (CAI)‐poor objects, the abundance of CAIs in the 18 CK3–6 we analyzed ranges from zero to approximately 16.4%. During thermal metamorphism, some of the fine‐grained CAIs recrystallized as irregular assemblages of plagioclase + Ca‐rich pyroxene ± olivine ± Ca‐poor pyroxene ± magnetite. Coarse‐grained CAIs display zoned spinel, fassaite destabilization, and secondary grossular and spinel. Secondary anorthite, grossular, Ca‐rich pyroxene, and spinel derive from the destabilization of melilite, which is lacking in all CAIs investigated. The Al‐Mg isotopic systematics measured in fine‐ and coarse‐grained CAIs from Tanezrouft (Tnz) 057 was affected by Mg redistribution. The partial equilibration of Al‐Mg isotopic signatures obtained in the core of a coarse‐grained CAI (CG1‐CAI) in Tnz 057 may indicate a lower peak temperature for Mg diffusion of approximately 540–580 °C, while grossular present in the core of this CAI indicates a higher temperature of around 800 °C for the metamorphic event on the parent body of Tnz 057. Excluding metamorphic features, the similarity in nature and abundance of CAIs in CK and CV chondrites confirms that CVs and CKs form a continuous metamorphic series from type 3 to 6.  相似文献   
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