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1.
Dew samples were collected between October 2007 and February 2008 from a suburban site in Agra. pH, conductivity, major inorganic ions (F?, Cl?, NO 3 ? , SO 4 2? , Na+, K+, Ca2+, Mg2+, and NH 4 + ), and some trace metals (Cr, Sn, Zn, Pb, Cd, Ni, Mn, Fe, Si, Al, V, and Cu) were determined to study the chemistry of dew water. The mean pH was 7.3, and the samples exhibited high ionic concentrations. Dew chemistry suggested both natural and anthropogenic influences, with acidity being neutralized by atmospheric ammonia and soil constituents. Ion deposition flux varied from 0.25 to 3.0?neq?m?2?s?1, with maximum values for Ca2+ followed by NH 4 + , Mg2+, SO 4 2? , Cl?, NO 3 ? , Na+, K+, and F?. Concentrations of trace metals varied from 0.13 to 48?μg?l?1 with maximum concentrations of Si and minimum concentration of Cd. Correlation analysis suggested their contributions from both crustal and anthropogenic sources.  相似文献   

2.
Changes in the chemical composition of the hot springs of Mendeleev Volcano (Kunashir Island) as for Cl?, SO 4 2? , CO2, NH 4 + and Cl?/SO 4 2? are given in function of the 1965–66 and 1973 (in part) seismic activity in the South Kurile islands.  相似文献   

3.
Rock masses contain ubiquitous multiscale heterogeneities, which (or whose boundaries) serve as the surfaces of discontinuity for some characteristics of the stress state, e.g., for the orientation of principal stress axes. Revealing the regularities that control these discontinuities is a key to understanding the processes taking place at the boundaries of the heterogeneities and for designing the correct procedures for reconstructing and theoretical modeling of tectonic stresses. In the present study, the local laws describing the refraction of the axes of extreme principal stresses T 1 (maximal tension in the deviatoric sense) and T 3 (maximal compression) of the Cauchy stress tensor at the transition over the elementary area n of discontinuity whose orientation is specified by the unit normal n are derived. It is assumed that on the area n of discontinuity, frictional contact takes place. No hypotheses are made on the constitutive equations, and a priori constraints are not posed on the orientation on the stress axes. Two domains, which adjoin area n on the opposite sides and are conventionally marked + and ?, are distinguished. In the case of the two-dimensional (2D) stress state, any principal stress axis on passing from domain ? to domain + remains in the same quadrant of the plane as the continuation of this axis in domain +. The sign and size of the refraction angle depend on the sign and amplitude of the jump of the normal stress, which is tangential to the surface of discontinuity. In the three-dimensional (3D) case, the refraction of axes T 1 and T 3 should be analyzed simultaneously. For each side, + and ?, the projections of the T 1 and T 3 axes on the generally oriented plane n form the shear sectors S + and S ?, which are determined unambiguously and to whose angular domains the possible directions p + and p ? of the shear stress vectors belong. In order for the extreme stress axes T 1 + ,T 3 + and T 1 ? , T 3 ? to be statically compatible on the generally oriented plane n, it is required that sectors S + and S ? had a nonempty intersection. The direction vectors p + and p ? are determined uniquely if, besides axes T 1 ? , T 3 ? and T 1 + , T 3 + , also the ratios of differential stresses R + and R ? (0 ≤ R ± ≤ 1) are known. This is equivalent to specifying the reduced stress tensors T R + and T R ? The necessary condition for tensors T R + and T R ? being statically compatible on plane n is the equality p + = p ?. In this paper, simple methods are suggested for solving the inverse problem of constructing the set of the orientations of the extreme stress axes from the known direction p of the shear stress vector on plane n and from the data on the shear sector. Based on these methods and using the necessary conditions of local equilibrium on plane n formulated above, all the possible orientations of axes T 1 + , T 3 + are determined if the projections of axes T 1 ? , T 3 ? axes on side — are given. The angle between the projections of axes T 1 + , T 1 ? and/or T 3 + , T 3 ? on the plane can attain 90°. Besides the general case, also the particular cases of the contact between the degenerate stress states and the special position of plane n relative to the principal stress axes are thoroughly examined. Generalization of the obtained results makes it possible to plot the local diagram of the orientations of axes T 1 + , T 3 + for a given sector S ?. This diagram is a so-called stress orientation sphere, which is subdivided into three pairs of areas (compression, tension, and compression-extension). The tension and compression zones cannot contain the poles of T 3 + and T 1 + axes, respectively. The compression-extension zones can contain the poles of either T 1 + or T 3 + axis but not both poles simultaneously. In the particular case when the shear stress vector has a unique direction p ? on side ?, the areas of compression-extension disappear and the diagram is reduced to a beach-ball plot, which visualizes the focal mechanism solution of an earthquake. If area n is a generally oriented plane and if the orientation of the pairs of the statically compatible axes T 1 ? , T 3 ? and T 1 + , T 3 + is specified, then, the stress values on side + are uniquely determined from the known stress values on side ?. From the value of differential stress ratio R ?, one can calculate the value of R +, and using the values of the principal stresses on side ?, determine the total stress tensor T + on side +. The obtained results are supported by the laboratory experiments and drilling data. In particular, these results disclose the drawbacks of some established notions and methods in which the possible refraction of the stress axes is unreasonably ignored or taken into account improperly. For example, it is generally misleading to associate the slip on the preexisting fault with the orientation of any particular trihedron of the principal stress axes. The reconstruction should address the potentially statically compatible principal stress axes, which are differently oriented on opposite sides of the fault plane. The fact that, based on the orientation of the intraplate principal stresses at the base of the lithosphere, one cannot make a conclusion on the active or passive influence of the mantle flows on the lithospheric plate motion is another example. The present relationships linking the stress values on the opposite sides of the fault plane on which the orientations of the principal stress axes are known demonstrate the incorrectness of the existing methods, in which the reduced stress tensors within the material domains are reconstructed without allowance for the dynamic interaction of these domains with their neighbors. In addition, using the obtained results, one can generalize the notion of the zone of dynamical control of a fault onto the case of the existence of discontinuities in this region and analyze the stress transfer across the system of the faults.  相似文献   

4.
The apparent equilibrium constant, K 1 ′ , for the first acidity constant of carbonic acid has been determined in a lake water of 1.6 mM ionic strength in the temperature interval 4–18°C. The experimental method used comprises pH measurements in situ (NBS scale) with a probe and an IR-method for the selective determination of [H2CO3] and [HCO 3 ? ] in water samples. In the temperature interval studied the results can be described by the equation logK 1 ′ =126.39?6320.81/T?19.5682 ln T and are in agreement with the values of K 1 ′ obtained by the empirical equation presented by Millero [15]. This experimental agreement justifies thermodynamic calculations in the carbonate system based on field data. Also the experimental method described can be used to evaluate the acid-base balance of organic rich natural waters.  相似文献   

5.
Concentrations of major ions in surface waters of the rivers of Khara-Murin and Snezhnaya are compared based on data of many-year observations carried out in the 1950s and 2000s. The concentrations of HCO 3 ? , Cl?, Ca2+, Mg2+, Na+ + K+ are shown to be stable. A considerable increase in SO 4 ?2 concentration was revealed.  相似文献   

6.
The relative rate constants of O2(b1Σ g + , v= 1–4) production at an inelastic interaction between electronically excited N(2D) atoms and O2(X3Σ g ? , v = 0) oxygen molecules have been calculated. It was shown that an increase in equilibrium distances between oxygen atoms in NO2 quasi-molecule, produced during the interaction, substantially increases the calculated relative production rates of O2(b1Σ g + , v > 1). The obtained coefficients are used to calculate the O2(b1Σ g + , v= 1–4) relative populations at 110 km (T = 250 K) and 150 km (T = 500 K) altitudes of the polar ionosphere. The calculated populations have been compared with the results of the published measurements of the Atmospheric system band luminosity intensities, and satisfactory agreement has been obtained for low altitudes.  相似文献   

7.
The use of submersed macrophyte tissue δ 15N to quantify the level of WWTP effluent use in a highly urbanized and agricultural river was evaluated using several methods. Macrophytes, NH4 + and NO3 ? were collected by canoe along two 10 km reaches of river, upstream and downstream of two major municipal WWTPs over 3 years. NH4 + decreased in concentration while δ 15N–NH4 + increased as a function of distance downstream of both WWTPs, changing in one survey from 13 to 31 ‰ over 1 km. This increase is attributed to the combined effects of volatilization, nitrification and uptake. While NO 3 ? concentrations increased downstream of the WWTP over one of the survey reaches, δ 15N–NO 3 ? showed no prominent trend with distance at either. Macrophyte tissue δ 15N increased with distance downstream of both WWTPs, with a slope not significantly different from that of δ 15N–NH4 + suggesting that macrophytes incorporate effluent NH4 + as their main N source in those areas. However, mixing models suggest that towards the end of the reach, where source separation is distinct, macrophytes may utilize background NO 3 ? . Our study indicates the difficulty of deriving precise estimates of effluent use by macrophytes in a system where the δ 15N of the effluent changes rapidly. It also illustrates the utility of macrophytes in describing those changes where the effluent is too attenuated to allow for direct isotopic analysis.  相似文献   

8.
Nutrients are important building blocks for healthy aquatic ecosystems and are generally nontoxic; but they can change with alteration in environmental parameters. The main objective of this study was to consider the seasonal variability of NO 3 – , PO 4 3– and total suspended solids (TSS) concentrations in water. The study sites, stream crossings (L30, L15) and river (R), are located in the hyrcanian forests, district 1 of Darabkola forest. The sampling was conducted in winter and spring. Water samples were taken into plastic bottles, labeled, and carried out to the laboratory for NO 3 – , PO 4 3– and TSS analysis. T-test results showed that there was a seasonal change in nutrient concentrations (p < 0.05) except for NO 3 – concentration at L30. Also, there was no significant seasonal change in TSS concentrations at all stations. Pearson correlation analysis did not reveal the same trend. Further analysis showed that the effect of road age on water quality parameters was statistically significant for PO 4 3– in spring and winter. Atmospheric precipitation plays vital role in nutrient loss and increasing concentration of suspended sediment. To prevent soil erosion from activities and discharge of wastes in the vicinity of river and stream an effective management should be planned and enforced.  相似文献   

9.
Presently available data on the reaction of SO2 with OH radicals (OH + SO2 + \(M\xrightarrow[{k_1 }]{}\) HSO3 +M) are critically reviewed in light of recent stratospheric sulfur budget calculations. These calculations impose that the net oxidation ratek of SO2 within the stratosphere should fall within the range 10?7≤k≤10?9, if the SO2 oxidation model for the stratospheric sulfate layer is assumed to be correct. The effective reaction rate constantk 1 * =k 1[M] at the stratospheric temperature is estimated as $$k_1^* = \frac{{(8.2 \pm 2.2) \times 10^{ - 13} \times [M]}}{{(0.79 \mp 0.34) \times 10^{ - 13} + [M]}}cm^3 /molecules sec$$ where [M] refers to the total number density (molecules/cm3). Using the above limiting values ofk 1 * , and the estimated OH density concentrations, the net oxidation rate is calculated as 3.6×10?7≤k≤1.3×10?8 at 17 km altitude. This indicates that the upper limit of thesek values exceeds the tolerable range imposed by the model by a factor of about four. Obviously the uncertainty of thek 1 * values and of the OH concentrations in the stratosphere is still too large to make definite conclusions on the validity of the SO2 model.  相似文献   

10.
The hydrochemical analyses of twenty-three springs were used to determine the properties and types of groundwater of the Tertiary-Quaternary Aquifer of northern Jordan. The result shows that the geological formation influences the quality of the investigated groundwater more than the anthropogenic factors. The water of the Quaternary-Tertiary aquifer is enriched in Ca++ due to the dissolution of the nearby carbonate rocks. The investigated water has a low EC values with Ca(Na)-HCO3 water type. Most springs belong to this hydrochemical facies except Malka. Groundwater in the Malka wells has high salinity with NaCl waters and a strong Ca(Mg)-HCO3 facies (900 to 1000 mg/l TDS). The area long-term hydrochemical data have been also evaluated; general trend of increase of the analyzed ion was observed. Bicarbonate represents the most abundant anion in the studied water, which exceeds the permissible limits. Nitrates (NO 3 ? ) also exceed the permissible limit and are the most common contaminant in the investigated water. Data on dissolved major and trace elements (K+, Na+, Mg2+, Ca2+, Cl?, SO 4 2? , Fe, Zn, Cu and Pb) in the investigated water revealed that the concentrations lie within the natural background range. The positive correlation values between various ions indicate that most of ions come from same lithological sources. According to the residual sodium carbonate, and EC values, the studied springs are suitable for agricultural purposes.  相似文献   

11.
In the present study, a digital waveform dataset of 216 local earthquakes recorded by the Egyptian National Seismic Network (ENSN) was used to estimate the attenuation of seismic wave energy in the greater Cairo region. The quality factor and the frequency dependence for Coda waves and S-waves were estimated and clarified. The Coda waves (Q c) and S-waves (Q d) quality factor were estimated by applying the single scattering model and Coda Normalization method, respectively, to bandpass-filtered seismograms of frequency bands centering at 1.5, 3, 6, 12, 18 and 24?Hz. Lapse time dependence was also studied for the area, with the Coda waves analyzed through four lapse time windows (10, 20, 30 and 40?s). The average quality factor as function of frequency is found to be Q c?=?35?±?9f 0.9±0.02 and Q d?=?10?±?2f 0.9±0.02 for Coda and S-waves, respectively. This behavior is usually correlated with the degree of tectonic complexity and the presence of heterogeneities at several scales. The variation of Q c with frequency and lapse time shows that the lithosphere becomes more homogeneous with depth. In fact, by using the Coda Normalization method we obtained low Q d values as expected for a heterogeneous and active zone. The intrinsic quality factor (Q i ?1 ) was separated from the scattering quality factor (Q s ?1 ) by applying the Multiple Lapse Time Domain Window Analysis (MLTWA) method under the assumption of multiple isotropic scattering with uniform distribution of scatters. The obtained results suggest that the contribution of the intrinsic attenuation (Q i ?1 ) prevails on the scattering attenuation (Q s ?1 ) at frequencies higher than 3?Hz.  相似文献   

12.
Multivariate analysis methods have been applied to studying variations in the concentrations of Ag, Al, As, B, Ba, Br, Ca, Cd, Co, Cr, Cs, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, P, Pb, Rb, S, Sb, Si, Sn, Sr, Th, Tl, U, V, Zn, Cl?, NO 3 ? , SO 4 2? as components of precipitation at 11 rural stations under project “Ecogeochemistry of Barents Region”. Hierarchic factor analysis revealed the structure and space-time distribution of seven first-order factors and two second-order factors. The combinations of ingredients that determine the composition of first-order factors characterize the sources of precipitation composition, which have been found to be specific and volatile products of fuel oil and coal combustion, marine and earth aerosols, and biogenic processes. Second-order factors showed two independent sets of components, which are typical of the chemistry of precipitation at the examined stations in winter and summer. Step-by-step discriminant and cluster analysis made it possible to classify the observational stations by precipitation chemistry and demonstrate the extent of difference between them.  相似文献   

13.
This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): 1O2, O 2 ·? /HOO·, H2O2, HO·, and CO 3 ·? in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.  相似文献   

14.
In the strip limestone mine in Guiding county, Guizhou Province the shear and frictionin situ tests of rock body were made for the three typical inclined weak bands C 3 1 /C 3 1 , C 3 1 /C 2 2 and C 2 2 /C 2 1 . The tests were made according to the second scheme of cuneate sample of the standards on rock mechanics test of Water Conservancy and Electricity Ministry. The changes of the resistivity in the weak band and the acoustic speed across the weak band were measured in the same time. The apparent resistivity data, obtained for 8 samples on 27 measure lines in 38 cycle tests, show that the apparent resistivity changes have rather obvious characters as follows: 1. At shear and friction stage, the change of the apparent resistivity accelerates after the yield point, and reaches the maximum of change rate and change amplitude near fracture point (except the lines with resistivity invariant); 2. On the same sample, the resistivity changes are different on the various lines and related to the location settled the lines, there are some “sensitive” location; 3. At the stage of preloading normal stress before shearing, the resistivity decreases on most lines, but on a few lines the resistivity does not changes; 4. After unloading shear stress, the resistivity could not recover completely and the hysteresis of resistiviity takes place on a few lines.  相似文献   

15.
Seismic coda wave attenuation ( $ Q_{\text{c}}^{ - 1} $ ) characteristics in the Garhwal region, northwestern Himalaya is studied using 113 short-period, vertical component seismic observations from local events with hypocentral distance less than 250?km and magnitude range between 1.0 to 4.0. They are located mainly in the vicinity of the Main Boundary Thrust (MBT) and the Main Central Thrust (MCT), which are well-defined tectonic discontinuities in the Himalayas. Coda wave attenuation ( $ Q_{\text{c}}^{ - 1} $ ) is estimated using the single isotropic scattering method at central frequencies 1.5, 3, 5, 7, 9, 12, 16, 20, 24 and 28?Hz using several starting lapse times and coda window lengths for the analysis. Results show that the ( $ Q_{\text{c}}^{ - 1} $ ) values are frequency dependent in the considered frequency range, and they fit the frequency power law ( $ Q_{\text{c}}^{ - 1} \left( f \right) = Q_{0}^{ - 1} f^{ - n} $ ). The Q 0 (Q c at 1?Hz) estimates vary from about 50 for a 10?s lapse time and 10?s window length, to about 350 for a 60?s lapse time and 60?s window length combination. The exponent of the frequency dependence law, n ranges from 1.2 to 0.7; however, it is greater than 0.8, in general, which correlates well with the values obtained in other seismically and tectonically active and highly heterogeneous regions. The attenuation in the Garhwal region is found to be lower than the Q c ?1 values obtained for other seismically active regions of the world; however, it is comparable to other regions of India. The spatial variation of coda attenuation indicates that the level of heterogeneity decreases with increasing depth. The variation of coda attenuation has been estimated for different lapse time and window length combinations to observe the effect with depth and it indicates that the upper lithosphere is more active seismically as compared to the lower lithosphere and the heterogeneity decreases with increasing depth.  相似文献   

16.
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17.
The accumulation of data sets of past tsunamis is the most basic but reliable way to prepare for future tsunamis because the frequency of tsunami occurrence and their magnitude can be estimated by historical records of tsunamis. Investigation of tsunami deposits preserved in geological layers is an effective measure to understand ancient tsunamis that occurred before historical records began. However, the areas containing tsunami deposits can be narrower than the area of tsunami inundation, thus resulting in underestimation of the magnitude of past tsunamis. A field survey was conducted after the 2010 Chile tsunami and 2011 Japan tsunami to investigate the chemical properties of the tsunami-inundated soil to examine the applicability of tsunami inundation surveys considering water-soluble salts in soil. The soil and tsunami deposits collected in the tsunami-inundated areas are rich in water-soluble ions (Na+, Mg2+, Cl?, Br? and SO 4 2? ) compared with the samples collected in the non-inundated areas. The analytical result that the ratios of Na+, Mg2+, Br? and SO 4 2? to Cl? are nearly the same in the tsunami deposits and in the tsunami-inundated soil suggests that the deposition of these ions resulting from the tsunami inundation does not depend on whether or not tsunami deposits exist. Discriminant analysis of the tsunami-inundated areas using the ion contents shows the high applicability of these ions to the detection of tsunami inundation during periods when the amount of rainfall is limited. To examine the applicability of this method to palaeotsunamis, the continuous monitoring of water-soluble ions in tsunami-inundated soil is needed as a future study.  相似文献   

18.
Unloaded natural rock masses are known to generate seismic signals (Green et al., 2006; Hainzl et al., 2006; Husen et al., 2007; Kraft et al., 2006). Following a 1,000 m3 mass failure into the Mediterranean Sea, centimeter-wide tensile cracks were observed to have developed on top of an unstable segment of the coastal cliff. Nanoseismic monitoring techniques (Wust-Bloch and Joswig, 2006; Joswig, 2008), which function as a seismic microscope for extremely weak seismic events, were applied to verify whether brittle failure is still generated within this unconsolidated sandstone mass and to determine whether it can be detected. Sixteen days after the initial mass failure, three small-aperture sparse arrays (Seismic Navigation Systems-SNS) were deployed on top of this 40-m high shoreline cliff. This paper analyzes dozens of spiky nanoseismic (?2.2 ≥ M L ≥ ?3.4) signals recorded over one night in continuous mode (at 200 Hz) at very short slant distances (3–67 m). Waveform characterization by sonogram analysis (Joswig, 2008) shows that these spiky signals are all short in duration (>0.5 s). Most of their signal energy is concentrated in the 10–75 Hz frequency range and the waveforms display high signal similarity. The detection threshold of the data set reaches M L ?3.4 at 15 m and M L ?2.7 at 67 m. The spatial distribution of source signals shows 3-D clustering within 10 m from the cliff edge. The time distribution of M L magnitude does not display any decay pattern of M L over time. This corroborates an unusual event decay over time (modified Omori’s law), whereby an initial quiet period is followed by regained activity, which then fades again. The polarization of maximal waveform amplitude was used to estimate spatial stress distribution. The orientation of ellipses displaying maximal signal energy is consistent with that of tensile cracks observed in the field and agrees with rock mechanics predictions. The M L– surface rupture length relationship displayed by our data fits a constant-slope extrapolation of empirical data collected by Wells and Coppersmith (1994) for normal fault features at much larger scale. Signal characterization and location as well as the absence of direct anthropogenic noise sources near the monitoring site, all indicate that these nanoseismic signals are generated by brittle failure within the top section of the cliff. The atypical event decay over time that was observed suggests that the cliff material is undergoing post-collapse bulk strain accommodation. This feasibility study demonstrates the potential of nanoseismic monitoring in rapidly detecting, locating and analyzing brittle failure generated within unconsolidated material before total collapse occurs.  相似文献   

19.
Retrospective data of monitoring under conditions of low seismic activity are used to identify free oscillations of the Earth, including the fundamental mode, the oscillation with a central period of 54 min (0 S 2 m multiplet), split into five lines with azimuthal numbers m = ?2, ?1, 0, 1, 2. It is shown that some lines of this oscillation are also recorded in atmospheric pressure variation spectra and group in ensembles of observations around frequencies predicted by the 0 S 2 m splitting theory. This phenomenon is discovered in data recorded both synchronously and in different time intervals. A causal relationship involved in the oscillation under study is determined on the basis of the examination of the direction of the acoustic energy flux. The energy flux in the region of the 0 S 2 m multiplet is shown to be directed from the Earth toward the atmosphere. This suggests that deep processes in the Earth are capable of exciting its upper shells.  相似文献   

20.
A mathematical model of the middle and high latitude ionosphere   总被引：5，自引：0，他引：5  
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