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1.
武汉城市湖泊汞的环境地球化学评价 总被引：13，自引：0，他引：13
汞由于其在环境中的持久性、生物地球化学可循环性以及潜在的生态威胁性而受到格外关注。对武汉远郊、城乡结合部和市区三种环境中6个湖泊的水、沉积物和生物(鱼)中汞污染特征进行了调查采样,用原子荧光光谱仪进行了汞含量的测定。采用Hakanson提出的潜在生态危害指数法直接评价了武汉湖泊汞的生态效应。结果表明,与国家食品卫生标准鱼肉中汞含量(≤300ng/g)相比,除梁子湖乌鱼(汞含量为676ng/g)外,6个湖泊3种鱼肉中汞含量均未超标,表明武汉城市湖泊汞元素尚未造成明显的生态效应;与国家Ⅲ类水质汞含量标准(0.1μg/L)相比,除金银湖水汞含量(0.137μg/L)略有超标外,其他湖水汞含量分布在0.048～0.081μg/L之间,均在合格标准线以下,武汉地区湖水中重金属汞污染不严重,不会构成严重的环境问题;应用Hakanson评价模型,据单个金属的潜在生态危害系数,排出所研究湖泊沉积物汞污染程度的序列为:东湖>墨水湖>金银湖>梁子湖>汤逊湖>鲁湖。 相似文献
2.
乌梁素海和岱海沉积磷形态分布的差异性研究 总被引：3，自引：0，他引：3
湖泊沉积物中磷的含量及形态分布等地球化学信息可以用来反演湖泊流域的古环境及污染历史。本文以乌梁素海和岱海两个不同类型的湖泊为研究对象,对两个湖泊沉积柱芯中磷形态分布的差异性进行了研究。结果表明,乌梁素海和岱海沉积柱芯中沉积磷的主导形态均为ACa P、De P和 Or P,但乌梁素海表层沉积物和沉积柱芯中Al P和 ACa P的含量水平明显高于岱海,而Ex P、De P和 Or P的含量水平明显低于岱海。两个湖泊沉积磷形态分布的差异性能较好地揭示出湖泊流域的地理环境、化学风化程度以及湖泊富营养化类型的差异性,沉积柱芯中ACa P含量及其分布特征能很好的指示湖泊自身发展过程中的富营养化水平,而De P含量及其分布特征则能较好的揭示出整个湖泊流域的古环境古气候信息。 相似文献
3.
晚第四纪湖泊沉积物盐类与碎屑矿物反相关关系的沉积学解释 总被引：1，自引：0，他引：1
湖泊沉积物中矿物组合是古气候环境研究的敏感性指标之一, 充分认识湖泊沉积物中各类矿物组合类型、沉积过程, 对正确解释矿物学指标有重要意义. 我国晚第四纪湖泊沉积记录中, 盐类矿物与碎屑矿物含量普遍存在反相关关系, 影响了矿物组合作为气候指标的解释和应用. 从地球科学的角度正确理解这种关系, 可以为湖泊动力学以及古气候环境定量研究提供重要的科学依据. 选择甘肃民勤盆地石羊河下游终端湖猪野泽不同位置5个全新世剖面, 在明确湖泊沉积物来源、搬运方式和沉积动力机制的基础上, 研究了以碳酸盐矿物为主的盐类矿物含量与粒度指标之间的关系. 结果表明:猪野泽各剖面砂层富含的中砂、细砂沉积物主要是来自于巴丹吉林沙漠和腾格里沙漠的风成砂; 水动力作用主导了湖相沉积层200 μm以下沉积物的沉积, 风力作用对20~70 μm粉砂组分沉积也有所贡献. 同时, 猪野泽湖相沉积层中高含量的碳酸盐主要来自于流水搬运, 湖相沉积层位200 μm以下的粉砂和极细砂是碳酸盐的主要富集区. 综上所述, 干旱区湖泊沉积物中盐类矿物含量与其沉积过程密切相关, 盐类矿物在全球变化研究中的应用要建立在充分研究其沉积动力机制的基础上. 相似文献
4.
南岭山地湖泊多环芳烃的大气沉降历史记录 总被引：1，自引：0，他引：1
高大山脉对大气环流具有阻挡或屏障作用.通过分析测定南岭山地湖泊沉积物中多环芳烃(PAHs)的垂直分布,结合210Pb定年,探讨了大气PAHs污染在南岭山地的沉积历史.结果显示,沉积物中的PAHs主要以低环数化合物为主,其中尤以菲的含量为最高.在剖面深度0～28 cm范围内,总多环芳烃的含量范围为86～778 ng/g.自1970年开始,PAHs含量持续增加,其中20世纪80、90年代中后期PAHs含量略有降低;在2000年后,沉积柱中的PAHs含量呈急剧增加之势态.多环芳烃在大气迁移过程中发生了组成分异,沉积物中相对富集轻组分(低环数)PAHs,与颗粒物结合的大气干湿沉降是PAHs向偏远山地积的主要途径. 相似文献
5.
泸沽湖沉积物α纤维素的提取及其稳定碳同位素研究初探 总被引：6，自引：0，他引：6
湖泊沉积是环境的气候变化的敏感指示器,在沉积过程中有机大分子α纤维素发生降解,其碳链上的Ｃ、Ｈ、Ｏ原子也不会与外界发生交换,故沉积物α纤维素的碳同位素能真实直反映原始环境信息。湖泊沉积物中的α纤维素含量少,笔者经过反复条件试验,得出了从湖泊沉积物提取α纤维素的简便可行的方法,泸沽湖是云贵高原上一半封闭湖泊,湖区人为活动干扰较微弱,该湖对环境变化敏感。笔者提取了沪沽湖沉积物柱的α纤维素,并研究了其碳 相似文献
6.
用137Cs计年法确定湖泊沉积物沉积速率研究进展 总被引：15，自引：0，他引：15
137Cs计年法利用137Cs固有的理化和沉降特性,在湖泊沉积物的137Cs垂直分布与大气137Cs沉降间确立对应关系,找出有异常137Cs含量的沉积层作为时标,但需注意137Cs从水体表面至湖底的时间和粘粒含量对各层137Cs含量的影响,并用其它方法校验时标的可靠性。再求取不同时标层间的年均沉积厚度,或因克服了压实效应而更能反映真实沉积速率的年均沉积通量,且结合GIS等手段进一步估算湖泊各区域的沉积总量;还可延伸研究湖泊内源污染负荷及相关环境演变和湖泊演化。但是,沉积柱样的分割厚度取多少才能既满足计年精度要求又不使工作量过大,137Cs的大气沉降时间与进入沉积物时间还与泥沙的陆地迁移时间有关,沉积物中究竟是否发生137Cs下渗及其机理等都还是此法应用中有待解决的问题。 相似文献
7.
137Cs和210Pbex是湖泊沉积物断代常用的两种核素,沉积物中核素的深度分布,不但随核素的大气沉降量变化,也与流域环境变化和沉积后核素的再分布有关.我国环境复杂,人类活动强烈,137Cs和210Pbex深度分布的非理想曲线常见于我国一些湖泊的沉积物.本文简要介绍了湖泊沉积物137Cs和210Pbex深度分布理想曲线和断代基本原理,在参阅大量有关中国湖泊沉积物137Cs和210Pbex断代文献的基础上,讨论了137Cs和210Pbex非理想深度分布曲线的解泽和沉积物断代的几个常见问题.主要观点如下:1)我国湖泊沉积物不存在所谓的1974年和1986年蓄积峰;2)一些湖泊沉积出现的非单峰型137Cs深度分布曲线,可能与人类活动或湖流扰动湖泊底泥、流域侵蚀产沙环境变化和137Cs主要来源于冰川融水补给等因素有关;3)沉积物中的核素垂向运移,不改变剖面中1963年137Cs蓄积峰的位置,不影响其断代标志意义;4)流域环境突发事件引起的沉积剖面中的137Cs和210Pbex明显异常,是断代的可靠标志等.最后介绍了根据沉积剖面137Cs和210Pbex总量与本底值对比,求算沉积速率的核素质量平衡法. 相似文献
8.
沉积物污染和环境沉积学 总被引：44，自引：2，他引：44
环境沉积学着重研究人类活动与沉积循环（包括风化作用、侵蚀作用、沉积作用和早期成岩作用）相互间的影响,寻求人类与自然协调发展的更佳方式。现在,全球河流、湖泊和海洋中沉积物污染严重,沉积学家应予以关注并为解决由此所产生的环境问题做出贡献。实际上,为了对沉积物环境质量进行评估和治理被污染的环境,需要沉积学家去研究污染物的时空分布与岩相、沉积相和沉积体系之间的相互关系,研究污染物在沉积作用和早期成岩作用中的行为,研究沉积物中污染物的存在形式等重要课题。 相似文献
9.
贵阳百花湖长期受汞法生产醋酸企业含汞废水的污染,沉积物及其孔隙水均受到严重的汞污染,总汞含量远远高于背景区.我们研究了汞污染企业停排后,百花湖沉积物剖面中汞污染程度、水平和垂直分布特征.研究显示,汞的垂直分布呈现表层和底层含量较低,中层出现峰值的分布趋势,沉积物中总汞的最高含量达到38 mg/kg(干重),且这种分布趋势恰好与贵州有机化工厂的生产历史相对应,反映了百花湖汞污染主要来源于该厂.百花湖表层沉积物中总汞的含量逐步下降,但在上游沉积物中总汞含量仍约为背景区总汞含量的40倍左右,离污染源较远的下游逐渐减少到背景区的3倍左右.这表明百花湖的汞污染在逐渐减轻,沉积物中大量的汞的扩散和再悬浮对上覆水体、鱼类和其他水生物具潜在的危害性. 相似文献
10.
西藏错鄂湖和羊卓雍湖水体及沉积物中有机氯农药的初步研究 总被引：32，自引：0，他引：32
对2002年5月采集的西藏错鄂湖和羊卓雍湖的水和沉积物样品进行了实验及分析。结果表明，这2个高原湖泊均不同程度地受到有机氯农药的污染，并具有多种有机氯农药的同时存在、在沉积柱上近表层没有含量下降趋势以及南部的羊卓雍湖污染程度高于藏北的错鄂湖等特点，反映出湖泊中的有机氯农药有可能是随孟加拉湾洋暖流由南向北带人的。两个湖泊的水与沉积物中滴滴涕(DDTs)和六六六(HCHs)含量甚至与我国东部地区的一些淡水水体相近，这种现象很可能表明，大气沉降的有机氯农药可在青藏高原湖泊水体与沉积物中发生一定程度的累积。长远地看，这一过程将可能对青藏高原野生动物产生负面影响。 相似文献
11.
12.
长江中下游不同类型湖泊沉积物营养盐 蓄积变化过程及其原因分析* 总被引：7，自引：10，他引：7
在长江中下游的洪湖、太湖、巢湖采集了沉积柱样,测定了总有机碳、总氮、磷,并采用210 Pb和137 Cs定年。洪湖1950年以来沉积物中营养元素急剧增加,巢湖在20世纪70年代以来营养元素开始增加,而在太湖中则为80年代。结果表明草型湖中有机质增加比藻型湖迅速,洪湖湖泊沉积物有机质迅速增加与围垦活动开始时间一致。沉积物中总磷的变化不如总有机碳、总氮的变化规律性明显。洪湖两钻孔总磷背景值为0.7~0.8g/kg,太湖钻孔其总磷本底为0.6g/kg,梅梁湾大量钻孔表明总磷本底在0.5g/kg;巢湖的则更低。对比湖泊类型来看,目前为藻型湖的沉积本底磷偏低,而目前为草型湖的沉积本底磷偏高,这可能与不同生态类型湖泊营养元素的生物地球化学循环与积累的方式有关。 相似文献
13.
长江中下游地区浅水湖泊密布,全新世该区湖泊沉积的模式还不清晰。本研究在长江中下游的南漪湖、升金湖和菜子湖这3个湖泊开展了多钻孔AMS^14C测年工作,测年结果显示这些湖泊沉积地层中广泛出现长时间尺度的沉积物缺失。南漪湖湖泊钻孔的沉积物14C年龄介于5668~7828cal.aB.P.,菜子湖湖泊钻孔的沉积物^14C年龄介于6221~7929cal.aB.P.,升金湖围垦区钻孔14C年龄介于6302~7049cal.aB.P.。结合该地区以往湖泊钻孔研究资料,发现全新世长江中下游两岸洼地湖泊存在较广泛的6~3ka的沉积间断。结合长江水位重建资料,笔者提出关于全新世湖泊沉积存有长期间断的新认识:即6~3ka,长江水位相对平稳,湖泊沉积物虽有堆积,但易于被侵蚀搬运造成沉积间断;与此对应的是,在约8~7ka,海面上升造成长江水位较快上升,由于顶托作用,湖泊沉积物持续堆积;在约3ka以来,由于人类活动的影响,以及长江水位的进一步上升,湖泊沉积物也易于堆积,但在一些湖区沉积物也会被侵蚀。在6~3ka之间湖泊沉积物易于被侵蚀的一个可能原因是该时段长江上游来沙来水减少,自然堤易被破坏,对两岸湖泊洼地的封堵作用减少,使得湖泊泥沙易被侵蚀入江。 相似文献
14.
Comparison of metal(loid) concentrations in water, sediments and fish from two large shallow lakes 总被引：2，自引：0，他引：2
J. Zeng L. Y. Yang X. M. Chuai X. F. Chen H. Y. Zhao Q. L. Wu 《International Journal of Environmental Science and Technology》2013,10(6):1209-1218
Hulun Lake and Taihu Lake are both large shallow lakes in China. In summer and winter of 2009, water, sediments and fish samples were collected from the two lakes and the concentrations of metal(loids) were analyzed. The results demonstrated that aqueous concentrations of arsenic (As), chromium (Cr), cadmium (Cd), nickel (Ni) and copper (Cu) in Hulun Lake were significantly higher than those in Taihu Lake. Especially, the As concentrations (about 130 μg/L) in Hulun Lake dramatically exceeded the permissible level of drinking water. Compared with Taihu Lake, metal(loid) concentrations in the sediments of Hulun Lake were significantly lower, which might have less impacts on the metal exchanges between water and sediments. In contrast, concentrations of the measured metal(loids) (including As) in fish from Hulun Lake and Taihu Lake were comparable, suggesting that the dramatic difference in aqueous and sediment metal(loid) concentrations had less influence on the metal(loid) bioavailability. The higher concentrations of dissolved organic carbon (DOC) and cations (e.g., Na+, K+ and Mg2+) in lake water might contribute to the reduced metal(loid) bioavailability to fish in Hulun Lake. 相似文献
15.
论成油和成煤的若干基本条件--以云南三个湖泊为例 总被引：1，自引：0，他引：1
本文以云南三个湖泊水生生物的数量和质量、沉积环境与有机质的关系、有机质埋藏初期和成岩早期的演化趋势等方面,着重讨论了成油和成煤的基本条件,并联系我国新生代成油成煤的有关条件,提出六点主要认识:1.成油、成煤必须具有构造条件;2.湖泊所处气候带必须适中;3.湖水须属富营养型;4.成煤与成油要求湖水深度不同;5.湖水的氧化还原状况;6.成煤还需没有陆源碎屑物质的补入。 相似文献
16.
The water, pore water, sediment, and fish samples were collected from the Hongfeng Reservoir in November 2003 and February 2004 in accordance with trace metal protocols. The average concentrations of total mercury （THg）, dissolved mercury （DHg）, reactive mercury, dissolved gaseous mercury, total methylmercury, and dissolved methylmercury in the water columns were 8.00, 5.70, 0.63, 0.05, 0.16, and 0.07 ng/L, respectively. THg and DHg in the water columns, THg in pore water and THg in lake sediments of the Hongfeng Reservoir showed the level of mercury in the Hongfeng Reservoir was higher than in other natural waters in the world due to the loading of a lot of waste water with relatively high concentrations of mercury, whereas methylmercury concentrations in fish （wet weight） varied from 1.73-51.00 ng/g, much lower than in most remote lakes and reservoirs reported in northern Europe and North America. Methylmercury distributions in pore water and sediments showed methylation occurred mainly in the upper several centimeters of sediment cores in the Hongfeng Reservoir. The concentrations of dissolved organic carbon, total suspended particles, total Hg, and methylmercury were higher at Houwu than those at Daba in November 2003. It is suggested that other pollutants such as N and P from fishing farm and other waste water at Houwu, which resulted in deterioration of water quality, affected the concentrations and distributions of mercury species in the reservoir. 相似文献
17.
Uranium geochemistry has been investigated in three acid lakes located on the Canadian Shield and one circumneutral lake in the Appalachian Region of Eastern Canada. In all Shield lakes, dissolved U concentrations were higher in the porewater than in the overlying water. In one of them, whose hypolimnion is perennially oxic, U released to porewater at depths of Fe remobilization was removed from the porewater at depths of Fe oxyhydroxides precipitation; these similarities in the U and Fe profiles indicate that part of the U becomes associated to Fe oxyhydroxides. The dissolved U and Fe profiles in the other two Shield lakes, whose hypolimnions were anoxic when sampled, did not show any significant recycling of these elements in the vicinity of the sediment-water interface and both elements diffused from the sediment to the overlying water. In contrast, in the Appalachian Lake, dissolved U concentrations were higher in the overlying water than in porewater, strongly decreased at the vicinity of the sediment-water interface and then remained relatively constant with sediment depth. Diagenetic modeling of the porewater U profiles, assuming steady-state, reveals that authigenic U always represented ?3% of the total U concentration in the sediments of all lakes. This observation indicates that diagenetic reactions involving U are not quantitatively important and that most of the U was delivered to the sediments at our study sites as particulate U and not through diffusion across the sediment-water interface, as is seen in continental margin sediments. Comparison of the U:Corg and U:Fe molar ratios in diagenetic material collected across the sediment-water interface with Teflon sheets and in surface sediments (0-0.5 cm) of the lake having a perennially oxic hypolimnion suggest that solid phase U was mainly bound to organic matter originating from the watershed; a strong statistical correlation between sediment non-lithogenic U and Corg in the Appalachian Lake supports this contention. Thermodynamic calculations of saturation states suggest that dissolved U was not removed from porewater through precipitation of UO2(s), U3O7(s) and U3O8(s) as previously proposed in the literature. 相似文献
18.
武汉市位于长江中游,长江与汉江在此交汇,城区河网纵横,湖泊众多,素有"江城"和"百湖之市"之称.湖泊对于武汉城市的可持续发展及宜居城市建设有着特别重要的意义.关于武汉市的湖泊前人曾开展了大量的研究,但对于湖泊的成因则研究较少.湖泊的成因不仅对武汉市近代地质环境演化具有重要意义,同时也是湖泊保护的基础科学问题.在地质地貌调查上,通过江湖古地理演变分析,结合历史文献记录等综合研究,认为武汉湖泊的形成与河流地质作用过程密切相关,据此将武汉市湖泊的成因类型划分为:河道遗迹湖（又分河道废弃湖和河道洲滩夹湖）、河堤溃口湖、河间洼地湖和沟谷壅塞湖四种类型.分析了各类湖泊的特征、地貌分布及形成过程.其中沟谷壅塞湖是现存湖泊的主要类型,其形成演化与区域气候变化背景下的河海相互作用密切相关,分别经历了湖盆形成期（20~14 ka）、湖泊形成期（14~7 ka）和湖泊发展期（7 ka以来）3个阶段.此外,武汉的城市与湖泊经历了由"湖中城"到"城中湖"的发展历程,围湖造地是武汉市最重要人为改造自然工程,依湖泊类型的不同采取了不同的围湖发展方式,汉口地区以河间洼地湖为主,主要以"筑堤-排水-造地"填湖发展;武昌和汉阳地区以沟谷壅塞湖为主,采取的是"堵塞湖汊造地"的环湖发展方式.在未来的城市建设中,有计划地实施湖-湖连通和河-湖连通工程是十分必要的. 相似文献
19.
Mercury contribution to an adirondack lake 总被引：1，自引：0，他引：1
Elevated copper, lead, and zinc concentrations in the upper 10 to 20 cm of sediment sampled from Cranberry Lake, a large Adirondack
lake, are attributed to atmospheric contributions. Pb-210 and pollen core data, however, suggest Cranberry Lake also received
mercury discharges during the turn of the century when the area was the center of extensive lumbering and related activities.
Elevated mercury concentrations in Cranberry Lake smallmouth bass derived from remobilization from mercury-contaminated bottom
sediments which increased the bioavailability to Cranberry Lake organisms. Mercury remobilization and accumulation by fish
are promoted by fluctuating pH values resulting from acid precipilation. 相似文献
20.
Characterizing vertical profiles of water columns is important to understanding the biochemical cycles and nutrient dynamics of an aquatic ecosystem. Physical and chemical properties of surface water in Mongolian saline lakes have been studied over the past decade, but chemical composition along a vertical profile of the water column has not been well documented. Four major saline lakes (Lakes Telmen, Oigon, Tsegeen and Khag) in northwestern Mongolia were studied to determine geochemical behavior of microelements and to assess major ionic components and trace elements associated with vertical profile of various water samples and sediments. Water samples were vertically collected from each sampling depth with a vacuum deep-water sampler in July 2013. Physical–chemical parameters, major ionic components and trace elements were analyzed by conventional methods and inductively coupled plasma-mass spectrometry. Concentrations of microelements and mineralogical composition of sediment samples from near shore were characterized by X-ray fluorescence spectrometry and X-ray diffraction. This study was apparently the first to characterize chemical composition along vertical profiles of these lakes. Sodium, chloride and sulfate ions were largely conserved in all water samples except Lake Oigon. Depending on salinity type, these lakes were divided into sodium-sulfate lake (Lake Khag) or chloride lakes. Due to geomorphological characteristics, strontium (≤3.18 mg/l) was the only ion in the highest concentration across all depths of water and sediment samples among the lakes. Sediments were comprised mainly of quartz, anorthite, albite and orthoclase. In conclusion, physical and chemical properties in Lake Oigon were highly variable and dissimilar among lakes. Furthermore, we inferred that vertical profiles of water columns were intimately linked to variations in chemical composition of salt lakes in the western Mongolia. 相似文献