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1.
An understanding of surface and subsurface water contributions to streamflow is essential for accurate predictions of water supply from mountain watersheds that often serve as water towers for downstream communities. As such, this study used the end‐member mixing analysis technique to investigate source water contributions and hydrologic flow paths of the 264 km2 Boulder Creek Watershed, which drains the Colorado Front Range, USA. Four conservative hydrochemical tracers were used to describe this watershed as a 3 end‐member system, and tracer concentration reconstruction suggested that the application of end‐member mixing analysis was robust. On average from 2009 to 2011, snowmelt and rainwater from the subalpine zone and groundwater sampled from the upper montane zone contributed 54%, 22%, and 24% of the annual streamflow, respectively. These values demonstrate increased rainwater and decreased snow water contributions to streamflow relative to area‐weighted mean values derived from previous work at the headwater scale. Young water (2.3 ± 0.8 months) fractions of streamflow decreased from 18–22% in the alpine catchment to 8–10% in the lower elevation catchments and the watershed outlet with implications for subsurface storage and hydrological connectivity. These results contribute to a process‐based understanding of the seasonal source water composition of a mesoscale watershed that can be used to extrapolate headwater streamflow generation predictions to larger spatial scales.  相似文献   

2.
Quantifying the relative contributions of different sources of water to a stream hydrograph is important for understanding the hydrology and water quality dynamics of a given watershed. To compare the performance of two methods of hydrograph separation, a graphical program [baseflow index (BFI)] and an end‐member mixing analysis that used high‐resolution specific conductance measurements (SC‐EMMA) were used to estimate daily and average long‐term slowflow additions of water to four small, primarily agricultural streams with different dominant sources of water (natural groundwater, overland flow, subsurface drain outflow, and groundwater from irrigation). Because the result of hydrograph separation by SC‐EMMA is strongly related to the choice of slowflow and fastflow end‐member values, a sensitivity analysis was conducted based on the various approaches reported in the literature to inform the selection of end‐members. There were substantial discrepancies among the BFI and SC‐EMMA, and neither method produced reasonable results for all four streams. Streams that had a small difference in the SC of slowflow compared with fastflow or did not have a monotonic relationship between streamflow and stream SC posed a challenge to the SC‐EMMA method. The utility of the graphical BFI program was limited in the stream that had only gradual changes in streamflow. The results of this comparison suggest that the two methods may be quantifying different sources of water. Even though both methods are easy to apply, they should be applied with consideration of the streamflow and/or SC characteristics of a stream, especially where anthropogenic water sources (irrigation and subsurface drainage) are present. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

3.
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4.
Critical zone influences on hydrologic partitioning, subsurface flow paths and reactions along these flow paths dictate the timing and magnitude of groundwater and solute flux to streams. To isolate first‐order controls on seasonal streamflow generation within highly heterogeneous, snow‐dominated basins of the Colorado River, we employ a multivariate statistical approach of end‐member mixing analysis using a suite of daily chemical and isotopic observations. Mixing models are developed across 11 nested basins (0.4 to 85 km2) spanning a gradient of climatological, physical, and geological characteristics. Hydrograph separation using rain, snow, and groundwater as end‐members indicates that seasonal contributions of groundwater to streams is significant. Mean annual groundwater flux ranges from 12% to 33% whereas maximum groundwater contributions of 17% to 50% occur during baseflow. The direct relationship between snow water equivalent and groundwater flux to streams is scale dependent with a trend toward self‐similarity when basins exceed 5.5 km2. We find groundwater recharge increases in basins of high relief and within the upper subalpine where maximum snow accumulation is coincident with reduced conifer cover and lower canopy densities. The mixing model developed for the furthest downstream site did not transfer to upstream basins. The resulting error in predicted stream concentrations points toward weathering reactions as a function of source rock and seasonal shifts in flow path. Additionally, the potential for microbial sulfate reduction in floodplain sediments along a low‐gradient, meandering portion of the river is sufficient to modify hillslope contributions and alter mixing ratios in the analysis. Soil flushing in response to snowmelt is not included as an end‐member but is identified as an important mechanism for release of solutes from these mountainous watersheds. End‐member mixing analysis used in combination with high‐frequency observations reveals important aspects of catchment hydrodynamics across scale.  相似文献   

5.
This study aimed to investigate the seasonal variability of runoff generation processes, the sources of stream water, and the controls on the contribution of event water to streamflow for a small forested catchment in the Italian pre‐Alps. Hydrometric, isotopic, and electrical conductivity data collected between August 2012 and August 2013 revealed a marked seasonal variability in runoff responses. Noticeable differences in runoff coefficients and hydrological dynamics between summer and fall/spring rainfall events were related to antecedent moisture conditions and event size. Two‐component and three‐component hydrograph separation and end‐member mixing analysis showed an increase in event water contributions to streamflow with event size and average rainfall intensity. Event water fractions were larger during dry conditions in the summer, suggesting that stormflow generation in the summer consisted predominantly of direct channel precipitation and some saturated overland flow from the riparian zone. On the contrary, groundwater and hillslope soil water contributions dominated the streamflow response during wet conditions in fall. Seasonal differences were also noted between event water fractions computed based on isotopic and electrical conductivity data, likely because of the dilution effect during the wetter months. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

6.
High‐elevation mountain catchments are often subject to large climatic and topographic gradients. Therefore, high‐density hydrogeochemical observations are needed to understand water sources to streamflow and the temporal and spatial behaviour of flow paths. These sources and flow paths vary seasonally, which dictates short‐term storage and the flux of water in the critical zone (CZ) and affect long‐term CZ evolution. This study utilizes multiyear observations of chemical compositions and water residence times from the Santa Catalina Mountains Critical Zone Observatory, Tucson, Arizona to develop and evaluate competing conceptual models of seasonal streamflow generation. These models were tested using endmember mixing analysis, baseflow recession analysis, and tritium model “ages” of various catchment water sources. A conceptual model involving four endmembers (precipitation, soil water, shallow, and deep groundwater) provided the best match to observations. On average, precipitation contributes 39–69% (55 ± 16%), soil water contributes 25–56% (41 ± 16%), shallow groundwater contributes 1–5% (3 ± 2%), and deep groundwater contributes ~0–3% (1 ± 1%) towards annual streamflow. The mixing space comprised two principal planes formed by (a) precipitation‐soil water‐deep groundwater (dry and summer monsoon season samples) and (b) precipitation‐soil water‐shallow groundwater (winter season samples). Groundwater contribution was most important during the wet winter season. During periods of high dynamic groundwater storage and increased hydrologic connectivity (i.e., spring snowmelt), stream water was more geochemically heterogeneous, that is, geochemical heterogeneity of stream water is storage‐dependent. Endmember mixing analysis and 3H model age results indicate that only 1.4 ± 0.3% of the long‐term annual precipitation becomes deep CZ groundwater flux that influences long‐term deep CZ development through both intercatchment and intracatchment deep groundwater flows.  相似文献   

7.
The Wind River Range (WRR) of Wyoming has the largest concentration of alpine glaciers in the American Rockies and contributes to several major river systems in the western United States. Declines in the areal extent and volume of these glaciers are well documented, and eventual loss of alpine glaciers will reduce the amount of water available for agricultural and domestic use. The contribution of glacial melt to streamflow remains largely unquantified in Wyoming. We used isotope measurements and Bayesian modeling to estimate the fractional contribution of glacier meltwater to Dinwoody Creek (DC) in the WRR on bi‐weekly and seasonal (spring, summer, and fall) time scales over 2 years. In 2007 and 2008, we made temporally intensive measurements of the stable isotope composition of water from the DC watershed. Samples of the primary sources of streamflow (snowmelt, glacier melt, rain, and baseflow) were collected during field campaigns, and automated collection of stream samples occurred over the melt season. Isotope data (D and 18O) were analyzed within a hierarchical Bayesian framework that incorporated temporal and spatial correlations. Glacial melt contributed a significant proportion (～53–59%) to streamflow in a low‐flow year (2007) or when streamflow was low during a high‐flow year (2008). In 2008, a large and persistent snowpack contributed significantly (～0·42–51%) to streamflow in mid‐summer. The large contribution of glacial melt to streamflow suggests that the loss of glaciers may impact riparian ecosystems and human water supplies in the late summer and in years with low snowpack. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

8.
Stream temperatures in urban watersheds are influenced to a high degree by changes in landscape and climate, which can occur at small temporal and spatial scales. Here, we describe a modelling system that integrates the distributed hydrologic soil vegetation model with the semi‐Lagrangian stream temperature model RBM. It has the capability to simulate spatially distributed hydrology and water temperature over the entire network at high time and space resolutions, as well as to represent riparian shading effects on stream temperatures. We demonstrate the modelling system through application to the Mercer Creek watershed, a small urban catchment near Bellevue, Washington. The results suggest that the model was able to produce realistic streamflow and water temperature predictions that are consistent with observations. We use the modelling construct to characterize impacts of land use change and near‐stream vegetation change on stream temperatures and explore the sensitivity of stream temperature to changes in land use and riparian vegetation. The results suggest that, notwithstanding general warming as a result of climate change over the last century, there have been concurrent increases in low flows as a result of urbanization and deforestation, which more or less offset the effects of a warmer climate on stream temperatures. On the other hand, loss of riparian vegetation plays a more important role in modulating water temperatures, in particular, on annual maximum temperature (around 4 °C), which could be mostly reversed by restoring riparian vegetation in a fairly narrow corridor – a finding that has important implications for management of the riparian corridor. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

9.
Diel fluctuations can comprise a significant portion of summer discharge in small to medium catchments. The source of these signals and the manner in which they are propagated to stream gauging sites is poorly understood. In this work, we analysed stream discharge from 15 subcatchments in Dry Creek, Idaho, Reynolds Creek, Idaho, and HJ Andrews, Oregon. We identified diel signals in summer low flow, determined the lag between diel signals and evapotranspiration demand and identified seasonal trends in the evolution of the lag at each site. The lag between vegetation water use and streamflow response increases throughout summer at each subcatchment, with the rate of increase as a function of catchment stream length and other catchment characteristics such as geology, vegetation and stream geomorphology. These findings support the hypothesis that variations in stream velocity are the key control on the seasonal evolution of the observed lags. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

10.
Climate change threatens water resources in snowmelt‐dependent regions by altering the fraction of snow and rain and spurring an earlier snowmelt season. The bulk of hydrological research has focused on forecasting response in streamflow volumes and timing to a shrinking snowpack; however, the degree to which subsurface storage offsets the loss of snow storage in various alpine geologic settings, i.e. the hydrogeologic buffering capacity, is still largely unknown. We address this research need by assessing the affects of climate change on storage and runoff generation for two distinct hydrogeologic settings present in alpine systems: a low storage granitic and a greater storage volcanic hillslope. We use a physically based integrated hydrologic model fully coupled to a land surface model to run a base scenario and then three progressive warming scenarios, and account for the shifts in each component of the water budget. For hillslopes with greater water retention, the larger storage volcanic hillslope buffered streamflow volumes and timing, but at the cost of greater reductions in groundwater storage relative to the low storage granite hillslope. We found that the results were highly sensitive to the unsaturated zone retention parameters, which in the case of alpine systems can be a mix of matrix or fracture flow. The presence of fractures and thus less retention in the unsaturated zone significantly decreased the reduction in recharge and runoff for the volcanic hillslope in climate warming scenarios. This approach highlights the importance of incorporating physically based subsurface flow in to alpine hydrology models, and our findings provide ways forward to arrive at a conceptual model that is both consistent with geology and hydrologic principles. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

11.
The spatial and temporal characterization of geochemical tracers over Alpine glacierized catchments is particularly difficult, but fundamental to quantify groundwater, glacier melt, and rain water contribution to stream runoff. In this study, we analysed the spatial and temporal variability of δ2H and electrical conductivity (EC) in various water sources during three ablation seasons in an 8.4‐km2 glacierized catchment in the Italian Alps, in relation to snow cover and hydro‐meteorological conditions. Variations in the daily streamflow range due to melt‐induced runoff events were controlled by maximum daily air temperature and snow covered area in the catchment. Maximum daily streamflow decreased with increasing snow cover, and a threshold relation was found between maximum daily temperature and daily streamflow range. During melt‐induced runoff events, stream water EC decreased due to the contribution of glacier melt water to stream runoff. In this catchment, EC could be used to distinguish the contribution of subglacial flow (identified as an end member, enriched in EC) from glacier melt water to stream runoff, whereas spring water in the study area could not be considered as an end member. The isotopic composition of snow, glacier ice, and melt water was not significantly correlated with the sampling point elevation, and the spatial variability was more likely affected by postdepositional processes. The high spatial and temporal variability in the tracer signature of the end members (subglacial flow, rain water, glacier melt water, and residual winter snow), together with small daily variability in stream water δ2H dynamics, are problematic for the quantification of the contribution of the identified end members to stream runoff, and call for further research, possibly integrated with other natural or artificial tracers.  相似文献   

12.
While the effects of land use change in urban areas have been widely examined, the combined effects of climate and land use change on the quality of urban and urbanizing streams have received much less attention. We describe a modelling framework that is applicable to the evaluation of potential changes in urban water quality and associated hydrologic changes in response to ongoing climate and landscape alteration. The grid‐based spatially distributed model, Distributed Hydrology Soil Vegetation Model‐Water Quality (DHSVM‐WQ), is an outgrowth of DHSVM that incorporates modules for assessing hydrology and water quality in urbanized watersheds at a high‐spatial and high‐temporal resolution. DHSVM‐WQ simulates surface run‐off quality and in‐stream processes that control the transport of non‐point source pollutants into urban streams. We configure DHSVM‐WQ for three partially urbanized catchments in the Puget Sound region to evaluate the water quality responses to current conditions and projected changes in climate and/or land use over the next century. Here, we focus on total suspended solids (TSS) and total phosphorus (TP) from non‐point sources (run‐off), as well as stream temperature. The projection of future land use is characterized by a combination of densification in existing urban or partially urban areas and expansion of the urban footprint. The climate change scenarios consist of individual and concurrent changes in temperature and precipitation. Future precipitation is projected to increase in winter and decrease in summer, while future temperature is projected to increase throughout the year. Our results show that urbanization has a much greater effect than climate change on both the magnitude and seasonal variability of streamflow, TSS and TP loads largely because of substantially increased streamflow and particularly winter flow peaks. Water temperature is more sensitive to climate warming scenarios than to urbanization and precipitation changes. Future urbanization and climate change together are predicted to significantly increase annual mean streamflow (up to 55%), water temperature (up to 1.9 °C), TSS load (up to 182%) and TP load (up to 74%). Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

13.
The lower coastal plain of the Southeast USA is undergoing rapid urbanisation as a result of population growth. Land use change has been shown to affect watershed hydrology by altering stream flow and, ultimately, impairing water quality and ecologic health. However, because few long‐term studies have focused on groundwater–surface water interactions in lowland watersheds, it is difficult to establish what the effect of development might be in the coastal plain region. The objective of this study was to use an innovative improvement to end‐member mixing analysis (EMMA) to identify time sequences of hydrologic processes affecting storm flow. Hydrologic and major ion chemical data from groundwater, soil water, precipitation and stream sites were collected over a 2‐year period at a watershed located in USDA Forest Service's Santee Experimental Forest near Charleston, South Carolina, USA. Stream flow was ephemeral and highly dependent on evapotranspiration rates and rainfall amount and intensity. Hydrograph separation for a series of storm events using EMMA allowed us to identify precipitation, riparian groundwater and streambed groundwater as main sources to stream flow, although source contribution varied as a function of antecedent soil moisture condition. Precipitation, as runoff, dominated stream flow during all storm events while riparian and streambed groundwater contributions varied and were mainly dependent on antecedent soil moisture condition. Sensitivity analyses examined the influence of 10% and 50% increases in analyte concentration on EMMA calculations and found that contribution estimates were very sensitive to changes in chemistry. This study has implications on the type of methodology used in traditional forms of EMMA research, particularly in the recognition and use of median end‐member water chemistry in hydrograph separation techniques. Potential effects of urban development on important hydrologic processes (groundwater recharge, interflow, runoff, etc.) that influence stream flow in these lowland watersheds were qualitatively examined. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

14.
Groundwater flow through coarse blocky landforms contributes to streamflow in mountain watersheds, yet its role in the alpine hydrologic cycle has received relatively little attention. This study examines the internal structure and hydrogeological characteristics of an inactive rock glacier in the Canadian Rockies using geophysical imaging techniques, analysis of the discharge hydrograph of the spring draining the rock glacier, and chemical and stable isotopic compositions of source waters. The results show that the coarse blocky sediments forming the rock glacier allow the rapid infiltration of snowmelt and rain water to an unconfined aquifer above the bedrock surface. The water flowing through the aquifer is eventually routed via an internal channel parallel to the front of the rock glacier to a spring, which provides baseflow to a headwater stream designated as a critical habitat for an at‐risk cold‐water fish species. Discharge from the rock glacier spring contributes up to 50% of basin streamflow during summer baseflow periods and up to 100% of basin streamflow over winter, despite draining less than 20% of the watershed area. The rock glacier contains patches of ground ice even though it may have been inactive for thousands of years, suggesting the resiliency of the ground thermal regime under a warming climate.  相似文献   

15.
The thermal regimes of alpine streams remain understudied and have important implications for cold‐water fish habitat, which is expected to decline due to climatic warming. Previous research has focused on the effects of distributed energy fluxes and meltwater from snowpacks and glaciers on the temperature of mountain streams. This study presents the effects of the groundwater spring discharge from an inactive rock glacier containing little ground ice on the temperature of an alpine stream. Rock glaciers are coarse blocky landforms that are ubiquitous in alpine environments and typically exhibit low groundwater discharge temperatures and resilience to climatic warming. Water temperature data indicate that the rock glacier spring cools the stream by an average of 3 °C during July and August and reduces maximum daily temperatures by an average of 5 °C during the peak temperature period of the first two weeks in August, producing a cold‐water refuge downstream of the spring. The distributed stream surface and streambed energy fluxes are calculated for the reach along the toe of the rock glacier, and solar radiation dominates the distributed stream energy budget. The lateral advective heat flux generated by the rock glacier spring is compared to the distributed energy fluxes over the study reach, and the spring advective heat flux is the dominant control on stream temperature at the reach scale. This study highlights the potential for coarse blocky landforms to generate climatically resilient cold‐water refuges in alpine streams.  相似文献   

16.
The US Department of Agriculture-Agricultural Research Service Southeast Watershed Research Laboratory (SEWRL) initiated a hydrologic research program on the Little River Experimental Watershed (LREW) in 1967. Long-term (52 years) streamflow data are available for nine sites, including rainfall-runoff relationships and hydrograph characteristics regularly used in research on interactive effects of climate, vegetation, soils, and land-use in low-gradient streams of the US EPA Level III Southeastern Plains ecoregion. A summary of prior research on the LREW illustrates the impact of the watershed on building a regional understanding of hydrology and water quality. Climatic and streamflow data were used to make comparisons of scale across the nine nested LREW watersheds (LRB, LRF, LRI, LRJ, LRK, LRO, LRN, LRM, and LRO3) and two regional watersheds (Alapaha and Little River at Adel). Annual rainfall for the largest LREW, LRB, was 1200 mm while average annual streamflow was 320 mm. Annual rainfall, streamflow, and the ratio between annual streamflow and rainfall (Sratio) were similar (α = 0.05) across LREWs LRB, LRF, LRI, LRJ, LRK, and LRO. While annual rainfall within the 275 ha LRO3 was found to be similar to LRO and LRM (α = 0.05), annual streamflow and Sratio were significantly different (α = 0.05). Comparisons of annual rainfall, streamflow, and Sratio between LRB and the regional watersheds indicated no differences (α = 0.05). Based upon this analysis, most regional watersheds shared similar hydrologic characteristics. LRO3 was an exception, where increases in row crops and decreases in forest coverage resulted in increased streamflow. LREW data have been instrumental in building considerable scientific understanding of flow and transport processes for these stream systems. Continued operation of the LREW hydrologic network will support hydrologic research as well as environmental quality and riparian research programs that address emerging and high priority natural resource and environmental issues.  相似文献   

17.
Streams in the McMurdo Dry Valleys (MDVs) of Antarctica moderate an important hydrologic and biogeochemical connection between upland alpine glaciers, valley‐bottom soils, and lowland closed‐basin lakes. Moreover, MDV streams are simple but dynamic systems ideal for studying interacting hydrologic and ecological dynamics. This work synthesizes 20 years of hydrologic data, collected as part of the MDVs Long‐Term Ecological Research project, to assess spatial and temporal dynamics of hydrologic connectivity between glaciers, streams, and lakes. Long‐term records of stream discharge (Q), specific electrical conductance (EC), and water temperature (T) from 18 streams were analysed in order to quantify the magnitude, duration, and frequency of hydrologic connections over daily, annual, and inter‐annual timescales. At a daily timescale, we observe predictable diurnal variations in Q, EC, and T. At an annual timescale, we observe longer streams to be more intermittent, warmer, and have higher median EC values, compared to shorter streams. Longer streams also behave chemostatically with respect to EC, whereas shorter streams are more strongly characterized by dilution. Inter‐annually, we observe significant variability in annual runoff volumes, likely because of climatic variability over the 20 record years considered. Hydrologic connections at all timescales are vital to stream ecosystem structure and function. This synthesis of hydrologic connectivity in the MDVs provides a useful end‐member template for assessing hydrologic connectivity in more structurally complex temperate watersheds. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

18.
Seasonal water storage in high-elevation alpine catchments are critical sources of water for mountainous regions like the western U.S. The spatial distribution of snow in these topographically complex catchments is primarily governed by orography, solar radiation, and wind redistribution. While the effect of solar shading is relatively consistent from year-to-year, the redistribution of snow due to wind is more variable – capable of producing snowpacks that have varying degrees of uniformity across these hydrologically-important catchments. A reasonable hypothesis is that a warmer climate will cause snowfall to become more dense (i.e. wetter and heavier), possibly leading to less wind redistribution and thus produce a more uniformly distributed snowpack across the landscape. In this study, we investigate the role of increasingly uniform spatial snowpack distributions on streamflow generation in the Green Lakes Valley Niwot Ridge Long Term Ecological Research station, within the headwaters of the Boulder Creek watershed in Colorado. A set of idealized hydrologic simulation experiments driven by reconstructed snowpacks spanning 2001–2014 show that more a more uniform spatial snowpack distribution leads to an earlier melt-out of 31 days on average and tends to produce less total streamflow, with maximum decreases as large as 7.5%. Isolating the role of snowpack heterogeneity from melt-season precipitation, we find that snowpack uniformity reduces total streamflow by as much as 13.2%. Reductions in streamflow are largely explained by greater exposure to solar radiation in the uniformly distributed case relative to a more heterogeneous snowpack, with this exposure driving shifts towards earlier snowmelt and changes in soil water storage. Overall, we find that the runoff efficiency from shallower snowpacks is more sensitive to the effects of uniformity than deeper snowpacks, which has potential implications for a warming climate where shallower snowpacks and enhanced sensitivities may be present.  相似文献   

19.
Changes in hydrologic flowpaths have important impacts on the timing, magnitude and hydrochemistry of run‐off during snowmelt in forested catchments, but how flowpaths are affected by variation in winter climate and the irregular presence of soil frost remains poorly understood. The depth and extent of soil frost may be expected to increase as snowpack decreases or develops later because of climate change. In this study, we used end‐member mixing analysis to determine daily contributions of snow, forest floor soil water and groundwater to stream run‐off during snowmelt under different soil frost regimes resulting from interannual and elevational variation at the Hubbard Brook Experimental Forest in New Hampshire, USA. We observed greater routing of run‐off through forest floor flowpaths during early snowmelt in 2011, when the snowpack was deep and soil frost was minimal, compared with the early snowmelt in 2012 under conditions of deep and extensive soil frost. The results indicate that widespread soil frost that penetrated the depth of the forest floor decreased the flow signal through the shallowest subsurface flowpaths, but did not reduce overall infiltration of melt waters, as the contribution from the snow‐precipitation end‐member was similar under both conditions. These results are consistent with development of granular soil frost which permits vertical infiltration of melt waters, but either reduces lateral flow in the forest floor or prevents the solute exchange that would produce the typical chemical signature of shallow subsurface flowpaths in streamwater. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

20.
We introduce a new representation of coupled solute and water age dynamics at the catchment scale, which shows how the contributions of young runoff waters can be directly referenced to observed water quality patterns. The methodology stems from recent trends in hydrologic transport that acknowledge the dynamic nature of streamflow age and explores the use of water age fractions as an alternative to the mean age. The approach uses a travel time‐based transport model to compute the fractions of streamflow that are younger than some thresholds (e.g., younger than a few weeks) and compares them to observed solute concentration patterns. The method is here validated with data from the Hubbard Brook Experimental Forest during spring 2008, where we show that the presence of water younger than roughly 2 weeks, tracked using a hydrologic transport model and deuterium measurements, mimics the variation in dissolved silicon concentrations. Our approach suggests that an age–discharge relationship can be coupled to classic concentration–discharge relationship, to identify the links between transport timescales and solute concentration. Our results highlight that the younger streamflow components can be crucial for determining water quality variations and for characterizing the dominant hydrologic transport dynamics.  相似文献   

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