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1.
河北平原地下水氦氩同位素特征   总被引：1，自引：1，他引：1  
通过对河北平原地下水氦同位素进行分析比较，根据过剩He(4He exc)、3He/4He比值、δ3He和36Ar/38Ar及40Ar/36Ar值分析认为，河北平源地下水氦氩同位素有7个特征；①地下水中过剩He浓度沿地下水的流向而增高；②地下水中过剩He浓度随着地下水埋深加大而增高；③满城-沧州剖面上过剩He浓度大于石家庄-衡水剖面上的过剩He浓度；④河北平原地下水主要是由大气隆重水补给的；⑤衡水热水过剩He浓度很高（>674.83×10-8cm3STPg-1水）；⑥地下水的36Ar/38Ar比值平均值为5.37，非常接近地球大气的比值（5.35）；⑦地下水的40Ar/36Ar比值从296-412，均比大气氩的40Ar/36Ar比值（295.6）大，这表明40Ar都是放射成因的，且具有“年代积累效应”。  相似文献   

2.
河北平原地下水锶同位素形成机理   总被引：5，自引：0，他引：5  
为了研究河北平原地下水锶同位素的来源与形成机理, 对所采水样进行了分析.研究了87Sr/86Sr比值“时间积累效应”: 随着地下水年龄和埋深的增大而增大; 与地下水中过剩4Heexc呈正相关关系, 与δ18O和δD呈负相关关系.探讨了Sr2+与87Sr/86Sr比值的关系, 将地下水分为3类: (1) 中等Sr2+含量与高87Sr/86Sr比值水(Ⅰ类水); (2) 低Sr2+含量与高87Sr/86Sr比值水(Ⅱ类水); (3) 高Sr2+含量与低87Sr/86Sr比值水(Ⅲ类水), 即热水.通过综合分析认为: (1) 河北平原第四系地下水中的放射成因Sr是由富含Na和Rb的硅酸盐矿物风化作用提供的, 主要矿物为斜长石; (2) 黄骅港热水中的放射成因Sr是由碳酸盐溶解形成的, 87Sr/86Sr比值低, Sr/Na比值大; (3) 补给区地下水是由流经火成岩和变质岩区地下水的侧向补给的, 87Sr/86Sr比值中等.第三系地下水放射成因Sr的来源及形成机理尚须进一步研究.   相似文献   

3.
河北平原地下水锶同位素特征   总被引：3，自引：1，他引：3  
本文根据28个样品的测试结果，介绍了河北平原地下水的87Sr/86Sr比值。水的87Sr/86Sr比值变化很大。这些Sr同位素组成的差别反映了平原中水流受区域地质条件控制。文中讨论了Sr同位素的6个分布特征。河北平原地下水的87Sr/86Sr比值均大于现代海水的平均值（0.709073）。平原内第四系地下水（Q4-Q1）从补给区到排泄区的87Sr/86Sr比值随着距离（年龄）增大而系统增大。水文学上年轻的水显示非放射性成因的（初始的）87Sr/86Sr比值，而较老的水则具有明显的放射成因，可达0.71527(δ87Sr为8.74‰)这很可能是通过溶解含水层硅酸盐而增加大陆Sr的结果。  相似文献   

4.
河北平原地下水氘过量参数特征   总被引：11，自引：0，他引：11  
氘过量参数是由Dansg aar d提出的一个新概念,它被定义为:d= δD-8δ18O。河北平原地下水氘过量参数有三个特征: ( 1)地下热水的氢和氧同位素组成显示出热交换的态势,d 值随地下水年龄增大而减少。( 2)在同一地区,d 值随着地下水埋深加大而增大。( 3)在同一含水层内,沿着地下水的路径,从补给区到承压区, d 值随着地下水年龄增大而增大。我们认为, d 值虽然是地下水年龄的函数,但最好和3 H、3H- 3He、14 C、36 Cl和4 He测年结果结合使用。   相似文献   

5.
本文根据河北平原地下水锶同位素比值等测试结果讨论了其演变特征：除个别水点外，地下水锶同位素比值均大于现代海水的均值（0.709073），第四系地下水的锶同位素比值均大于热水点值，且随着埋深的增大、沿迳流途径从补给区到排泄区系统增大，这同锶同位素比值与碳-14年水分三类进行了分析。在平原中部，呈NE—SW方向，出现了一个锶同龄呈正相关关系是一致的。本文根据锶同位素比值及锶离子浓度特点将该区地下位素比值的高值带，大致与子牙河的流向一致．即献县-青县-线．该咨料为河北平原第四第地下水演化提供了新的证据．  相似文献   

6.
雅鲁藏布江蛇绿岩的氦、氩同位素组成分别是：蛇绿岩中变质橄榄岩的^3He/^4He比值为1．104-3．384Ra，平均为2．383Ra；玄武岩的He同位素组成比较均一，^3He/^4He平均值为5．359 Ra；辉绿岩的^3He／^4He比值变化较大，为1—5Ra。由于各岩石样品有不同程度的蚀变，造成放射性成因He的加入，因此大多数样品He同位素组成比低于亏损地幔大洋中脊玄武岩的值(MORB≈8Ra)，不能真实反映源区特征。而采自吉定的辉绿岩样品^3He/^4He比值平均高达31．57Ra，与夏威夷发现的热点地幔源区的样品比值接近；分步加热法进一步测试，其高比值的He是在低温区段释放的。这种高^3He/^4He比值He的捕获，表明雅鲁藏布江蛇绿岩形成时存在地幔柱型富集地幔岩浆作用。  相似文献   

7.
河北平原北依燕山、西踞太行,东临渤海,海拔不超过00米。多年平均降雨450—600毫米,蒸发量为降雨量2—3倍;旱涝碱咸灾害严重。多年来有关部门围绕着自然灾害综合治理做了大量工作,水文地质研究程度较高。水文地质上,为一半干旱区滨海型的山前自流斜地;地下水形成规律有一定代表性。为探讨本区第四系地下水年龄、水流系统和咸水成因等问题,沿石家庄—衡水—沧州—渤海湾一线做了一条同位素水文地质剖面,取得了较为满意的成果。本文拟将这些初步结果介绍出来供大家参考。  相似文献   

8.
广东三水盆地非烃天然气同位素地球化学   总被引：7，自引：0，他引：7  
本文根据广东省三水盆地天然气中He,Ar,CO_2和N_2的稳定同位素地球化学特征,探讨了该区非烃天然气组分的成因以及大地热流。天然气中~3He/~4He值为(1.60—6.39)×10~(-6),~(40)Ar/~(36)Ar值为450—841,δ~(13)C_(Co_2)的变化范围为-20—-2‰,δ~(15)N在-58—+95‰之间。天然气同位素地球化学特征表明三水盆地有较强的地球深部流体(物质和热)向上溢出。富含非烃组分的气藏中,大部分He,Ar,N_2来自地球深部,CO_2则主要由岩石化学反应生成。烃类天然气藏中非烃组分主要来自地壳中放射性成因的~4He、~(40)Ar和有机质热分解产生的CO_2、N_(20)根据~3He/~4He值估算大地热流值(Q)为72—82mWm~(-2),其中一半以上可能来自上地幔。  相似文献   

9.
4He是测定地下水年龄理想的示踪剂之一,由于测年时间尺度及多成因等问题,其测年结果通常与14C测年结果缺乏一致性。通过采集河北平原第四系承压水中的惰性气体（He、Ne、Ar、Kr、Xe）及14C样品,利用CE（封闭系统平衡）模型分离出地下水中的放射性成因4Herad浓度为（5.43～8 994）×10-8 cm3·STP/g,进而得到地下水的4He年龄为8.8～55.9 ka;相应样品的14C测年结果为7.7～35.2 ka。结果表明,2种测年结果在河北平原具有很好的一致性。  相似文献   

10.
从赣中马鞍坪地区采集了 11个水样分析了温泉及冷泉的氢、氧同位素组成 ,得出温泉水起源于大气降水补给。在此基础上 ,对 4个温泉采集了气样 ,测定了气体组成的含量和氦同位素组成 ,以及二氧化碳的碳同位素 ,结果表明 :马鞍坪地区地热气体为二氧化碳型 ,温泉气的二氧化碳含量很高 ,占总体积的 97%以上 ,二氧化碳气体的δ1 3C值变化于 -4 18‰～ -7 0‰ ,平均为 -5 .63‰ ,为变质无机成因和幔源无机成因的混合物 ;其3He/4He比值变化于 (1.72± 0 .15 )×10 7～ (2 .5 5± 0 .19)× 10 - 7之间 ,R/Ra值均小于 1,属壳源成因  相似文献   

11.
Dissolved helium concentrations and 3He/4He ratios were measured for 18 groundwater samples collected from the Quaternary confined aquifers in the North China Plain (NCP). The dissolved helium concentrations ranged from 1 × 10−7 to 1 × 10−6 cm3STP·g−1 in the 14 samples from the central plain, but was approximately two orders of magnitude higher, between 6 × 10−6 and 9 × 10−5 cm3STP·g−1, in 4 samples from the coastal plain. Based on these concentrations and the corresponding 3He/4He ratios varying from 0.09 to 0.55 Ra (where Ra is the 3He/4He ratio of air), the dissolved helium in groundwater in the central plain was identified to be primarily a mixture of atmospheric helium with radiogenic helium and a representative radiogenic helium ratio was estimated to be 0.035 Ra. Despite the high fraction of terrigenic 4He in the samples from the coastal plain, their 3He/4He ratios were found to be significantly above this radiogenic value, ranging between 0.20 and 0.37 Ra, indicating the presence of a mantle-derived He component in this area. About 2–4% mantle helium was estimated to be present in the groundwater of the coastal plain, which probably is associated with the regional Cangdong fault and tectonic activities. Based on the radiogenic He component, 4He ages of the groundwater in the central plain were calculated by assuming either pure in situ production or an external helium flux J0 of 4.7 × 10−8 cm3STPcm−2a−1. The estimated 4He ages fall between 9.5 and 51.4 ka and are comparable to the 14C ages, suggesting that the results of 4He dating are reasonable and can be an effective tool to estimate groundwater residence times under suitable conditions.  相似文献   

12.
This study Investigates a tracing method using dissolved noble gases to survey the groundwater flow in a large groundwater basin. The tracing method is based on measuring the concentrations of noble gases and the ratio of helium isotopes in groundwater samples. Since it is very difficult to detect trace amounts of noble gases and helium with high accuracy in a 15-ml groundwater sample, dissolved gases were extracted and purified, then a high-resolution mass spectrometer was used for measurement and comparison with standard samples. We used this method with samples from a confined aquifer formed by the deposition of pyroclastic flow in the Kumamoto Plain on the west side of Mt. Aso in central Kyushu, Japan. The groundwater basin under the plain is divided into four small basins, based on the helium concentrations and isotope ratios, with two major groundwater flows. One flow is buried by the Aso pyroclastic flow along the old Kase River; the other is along the Tsuboi River Valley. These two groundwater flows were identified from the different helium isotope-ratios. The helium component from the deep mantle is mixed into the groundwater under the Kumamoto Plain. Finally, data on the concentrations and ratios of3He to4He in groundwater samples were used to determine the location of faults in the volcanic aquifer.  相似文献   

13.
西藏羊八井热田地热流体成因及演化的惰性气体制约   总被引：4，自引：5，他引：4  
赵平  Mack  KENNEDY 《岩石学报》2001,17(3):497-503
地热流体中惰性气体的相对丰度和同位素组成，不仅可以揭露热田的热源性质，而且还能够揭示深，浅层地热流体的内在联系和演化过程等。在西藏羊八井热田的地热气体中，已检测出大量的^4He组分，3He/^4He值是大气的0．087－0．259倍，表明深部地壳物质的局部熔融为热田提供能量，浅层地热流体的3He/4He 值自西北向东南呈降低趋势，与热储温度的变化相一致，反映出侧向运移时补充了更多的壳源氦，热田北区深层地热流体具有稍高的3He/4He值，是浅层地热流体的母源，气体中氪和氙的相对丰度具有大气降水成因的特征，结合现有的实际资料，建立了热田地热流体的概念模型。  相似文献   

14.
河北平原地下水14C年龄新认识   总被引：4，自引：0，他引：4  
本文对河北平原第四系地下水14C年龄最新的结果进行了分析,得出如下认识:(1)垂向上,地下水的14C年龄随深度的增加而增大,或者沿地下水的流向而增大。但是,在同一孔组中,地下水埋深大于300m时出现了混乱现象。地下水14C年龄不但不增大,反而减小,其原因复杂;(2)水平方向上,第三含水组Q2地下水较老的年龄出现在河北平原中部,大致与子牙河方向一致,而第四含水组Q1地下水较老的年龄则呈北东东方向展布,即沧州—歧口一线分布,可能是地质结构影响所致。  相似文献   

15.
Chemical and C–He isotopic compositions have been measured for N2-rich hydrothermal gases from the Liaodong (abbreviation of East Liaoning Province) Peninsula from which the oldest crustal rocks in China with ⩾3.8 Ga outcrop. With the exception of one sample containing tritogenic 3He and atmospheric 4He in Liaoyang, the observed 3He/4He ratios from 0.1 Ra to 0.7 Ra indicate 1–8% helium from mantle, 92–98% from crust and 0.1–0.8% from atmosphere. Despite the lack of Quaternary volcanism, such 3He/4He ratios suggest, together with geophysical evidences, the existence of intrusive magmas that contain mantle helium and heat within the Liaodong middle-lower crust. The 3He/4He ratios are high along the NE-trending Jinzhou faults and gradually decrease with the increase of distance from the faults. Such a spatial distribution suggests that the mantle helium exsolves from magmatic reservoir in the middle-lower crust, becomes focused into the root zones of Jinzhou faults, and subsequently traverses the crust via permeable fault zones. When transversely migrated by groundwater circulation in near surface, mantle helium with high 3He/4He ratio may have been further diluted to the observed values by addition of radiogenic helium produced in the crust. This pattern shows strong evidence that the major faults played an important role on mantle-derived components transport from mantle upwards.  相似文献   

16.
江西省横迳温泉区地热气体地球化学   总被引：2，自引：0，他引：2  
孙占学  高柏  刘金辉 《现代地质》2004,18(1):116-120
从赣南横迳温泉区采集10个水样并分析了温泉及冷泉的水化学成分,认为热水起源于大气降水补给。在此基础上,还在温泉区采集了4个气样,测定了气体组分的含量及氦同位素．以及CO2和CH4的碳同位素。研究结果表明：横迳地区温泉气中CO2的含量很高(>96％),δCCO2较重(-4.43‰～-5.50‰),属幔源CO2;He同位素特征值(R/Ra)变化于1.36～2.11之问．均大于1,有幔源He的加入;本区温泉气的的组合类型为二氧化碳幔源温泉气,从整体上来说属于幔源无机成因气,是地幔脱气的产物。  相似文献   

17.
Numerous iron cosmic micro-spherules have been discovered from Mesoproterozoic strata including the Changzhougou Formation(1.8 Ga) and the Dahongyu Formation(1.6 Ga) of the Ming Tombs district,Beijing.There are 1 to 30 grains of cosmic spherules per 2 kg of a sandstone sample taken from the bottom of a coarse sandstone bed of the Changzhougou Formation and 56 grains per 3.69 kg of a rock sample from silicified carbonate rocks of the Dahongyu Formation.The surface textures of cosmic spherules analyzed by means of the secondary electron imagery are identical with those reported from references either domestic or abroad.So far the geo-ages of 1.8 Ga and 1.6 Ga of cosmic spherules from the Changzhougou and Dahongyu formations might be older than those reported in the world.Table 1 gives the electron probe analysis data of cosmic spherules for 30 spherule grains and 44 testing points as follows(%):FeO,80-95;Cr_2O_3;0-9.56;NiO,0-0.78;CoO,0-0.46; indicating that the Cr_2O_3 content is higher and FeO content lower in the Changzhougou Formation than in the Dahongyu Formation.The helium isotopic data of cosmic spherules as well as their host rocks vary greatly between the Changzhougou and the Dahongyu formations as shown in Table 2.The data of cosmic spherules of the Changzhougou Formation vs the Dahongyu Formation are 57.5/1.23 in ~3He/~4He(10~(-8));and 55.54/809.60 in ~4He(10~(-6)cm~3STP/g);those of coarse sandstone of the Changzhougou Formation vs silicified carbonate of the Dahongyu Formation are 3.39/2.59 in ~3He/~4He(10~(-8)) and 4.56/2.34 in ~3He(10~(-6)cm~3STP/g).The ratio of analytic data of helium isotopes are different for cosmic spherules and their host rocks;for example,the ~3He/~4He(10~(-8)) values are 16.96 and 0.48,and the ~4He (10~(-6)cm~3STP/g) are 12.18 and 345.98 for the Changzhougou and Dahongyu formations respectively.It was reported that the world's oldest micrometeorites had been found in the Meso-Proterozoic Satakunta Formation,Finland.However,the cosmic spherules from the Meso-Proterozoic Changzhougou and Dahongyu formations are 200 to 400 Ma older than those from the Satakunta Formation.Besides,one carbonaceous chondrite grain was discovered for the first time as the earliest remain formed in the solar nebula from the Dahongyu Formation.  相似文献   

18.
Stable isotopes (δ18O, δ2H), tritium (3H), and helium isotopes (3He, 4He) were used for evaluating groundwater recharge sources, flow paths, and residence times of three watersheds in the Cape Verde Islands (West Africa). Stable isotopes indicate the predominance of high-elevation precipitation that undergoes little evaporation prior to groundwater recharge. In contrast to other active oceanic hotspots, environmental tracers show that deep geothermal circulation does not strongly affect groundwater. Low tritium concentrations at seven groundwater sites indicate groundwater residence times of more than 50 years. Higher tritium values at other sites suggest some recent recharge. High 4He and 3He/4He ratios precluded 3H/3He dating at six sites. These high 3He/4He ratios (R/Ra values of up to 8.3) are consistent with reported mantle derived helium of oceanic island basalts in Cape Verde and provided end-member constraints for improved dating at seven other locations. Tritium and 3H/3He dating shows that São Nicolau Island’s Ribeira Fajã Basin has groundwater residence times of more than 50 years, whereas Fogo Island’s Mosteiros Basin and Santo Antão Island’s Ribeira Paul Basin contain a mixture of young and old groundwater. Young ages at selected sites within these two basins indicate local recharge and potential groundwater susceptibility to surface contamination and/or salt-water intrusion.  相似文献   

19.
渭河盆地地热水水溶氦气成因与来源研究   总被引：2，自引：0，他引：2  
渭河盆地地热水中含有丰富的水溶氦气,通过采集分析渭河盆地地热水水溶氦气成分和He同位素研究了氦气的成因与来源。分析结果表明,渭河盆地地热水水溶氦气体积分数普遍超过0.1%,最高达到3.395%。地热水水溶氦气的3He/4He比值介于(3.61±0.29)×10-8～(7.80±0.23)×10-7之间,氦气的R/Ra值小于1.00。天然气的4He/20Ne比值研究一致表明,渭河盆地地热水水溶氦气主要为壳源成因,混有微量的幔源氦。区域地质资料分析表明,富铀花岗岩放射性成因的氦气是渭河盆地地热水水溶氦气的主要来源,大面积出露于秦岭造山带以及隐伏于渭河盆地南缘新生代沉积层下的富铀花岗岩体为渭河盆地地热水水溶氦气的主要气源岩。  相似文献   

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