共查询到20条相似文献，搜索用时 31 毫秒
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Şahset İrdemez Nazmi Topçu Yalçın Şevki Yıldız Nuhi Demircioğlu 《Stochastic Environmental Research and Risk Assessment (SERRA)》2006,21(2):175-181
In this study, the removal of nitrate ions from aqueous solutions with liquid membrane technique has been investigated for different organic solvent types in which solubilized tetradecyl trimethyl ammonium bromide (TDTMABr) as carrier. n-butyl alcohol, chloroform, and mixture of chloroform + n-hexane (n-hexane 85% + chloroform 15%) were used as organic solvent. Kinetic parameters (k
1d, k
2m, k
2a, t
max, R
mmax, J
mmax, J
amax) were calculated from obtained data. time R
a values of mixture, butyl alcohol, and chloroform are 0.81, 0.78, and 0.55, respectively. Similarly R
d, R
m, and t
max values of the mixture equal to 0.14, 0.04, and 87.92 min, respectively. This behavior of the system shows the organic solvent type is an effective parameter on separation yield. It can be concluded that the mixture is the most effective organic solvent type among the investigated ones, because liquid membrane systems should be operated within the range of having the R
m, R
d, and t
max values are minimum while R
a values are maximum. 相似文献
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Feasibility of grain-size analysis methods for determination of vertical hydraulic conductivity of streambeds 总被引：4，自引：0，他引：4
Jinxi Song Xunhong Chen Cheng Cheng Deming Wang Susan Lackey Zongxue Xu 《Journal of Hydrology》2009,375(3-4):428-437
Accurate estimation of streambed vertical hydraulic conductivity (Kv) is of great importance in the analysis of water quantity exchange and solute transfer between a stream and its sediments. The paper analyzed the inaccuracy of hydraulic conductivity values of sediments derived from grain-size distribution (Kg), which were determined from eight empirical grain-size methods to represent streambed Kv. In this study, the values of Kv for a streambed were derived using falling-head standpipe permeameter tests conducted at eight study sites in the Elkhorn River, Nebraska, and the tested streambed columns were then collected for grain-size analysis by sieving. These empirical methods were used to calculate the Kg values of the streambed from grain-size distribution data of sediments. Unlike many other studies, this study verifies Kg from grain-size distribution with Kv from permeameter tests on the basis of the same samples of streambed sediments. The Kg values derived from the eight empirical methods were larger than the Kv from permeameter tests; there are five methods that give Kg values of about 3–6 times larger than these Kv. The Kg values from the Kozeny formula followed by the Hazen formula give the largest overestimation error if they are used to represent the Kv of the streambed. The USBR and Shepherd formulas generated Kg values close to Kv, but these Kg values are still larger in general than the Kv values. Moreover, the new values of coefficient C for the empirical formulas were revised so that they can be used to calculate the approximate Kv of a streambed. Among the eight methods, the ratios of the original C values to the average new C range from 1.3 to 5.9. It can be hypothesized that smaller C values must be used in the estimation of Kv for general soil samples if these empirical formulas are used to calculate Kv. 相似文献
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滆湖水体光学性质初步研究 总被引：3，自引：1，他引：2
基于2009年7月至2010年6月滆湖全湖15个采样点的水体光学参数及相关水质理化因子数据,分析滆湖水体周年光合有效辐射(PAR)衰减特性,以期为滆湖沉水植物生态修复提供相关水体光学资料.结果表明,滆湖水体PAR衰减系数(Kd)周年变化范围为1.32～17.42 m-1.秋季Kd相对最小,平均值为2.35 m-1,变化范围为1.32 ～3.70 m-1;夏季Kd相对最大,平均值为6.23 m-1,变化范围为3.68～17.42 m-1.春、秋、冬季,滆湖水体真光层平均深度均满足沉水植物的生长需求,而在夏季滆湖水体真光层平均深度仅为0.84m,小于全湖平均水深(1.20 m),因此夏季PAR是限制沉水植物恢复的因子之一.滆湖水体Kd与透明度(SD)在秋、冬季的关系为:Kd =2.089 +0.705/SD.叶绿素a浓度和悬浮物浓度是影响滆湖水体Kd的重要因子之一. 相似文献
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Streambed hydraulic conductivity (K) and vertical K (K v) are key controls on groundwater and surface water exchange and biogeochemical fluxes through the hyporheic zone, but drivers of transient hydraulic properties in different fluvial environments are poorly understood. This study combines hydrogeology, geophysics, and sedimentology to reveal mechanisms of K and K v transience in the upper 0.5 m of a sandy streambed during low discharge. Hydraulic tests (44 slug tests, 130 falling-head permeameter tests) and 130 grain-size analyses were repeated three times over 8 weeks on a 1,200 m2 grid spanning: (a) a channel with continuously flowing water and mobile bed load; (b) an adjacent mid-channel bar that was stationary and infrequently submerged. Aerial photographs and ground-penetrating radar show scour and complete reworking of fluvial sediments in the channel. Bar sediments below the water table remained immobile, but infrequent flows of moderate discharge reworked the uppermost few centimetres of the bar top. Despite differences in sediment mobility and stream flow characteristics across environments, K and K v exhibited order-of-magnitude differences in spatial heterogeneity and temporal variability in both the channel and bar. Mean K and K v values in the channel were comparatively stable over time. In the immobile bar, mean K declined 20% and K v declined 26% after increased discharge temporarily inundated the bar. Grain-size distributions were steady across both environments over time, but repeat geophysical surveys of the bar show a decrease in electrical conductivity, likely from porosity reduction. These findings suggest that sediment dynamics and stream flow characteristics in different streambed environments are important drivers of K transience during low discharge conditions. Specifically, pore clogging can be an important mechanism of transience over short durations (weeks to months) in immobile sediments subject to infrequent flows and minor reworking. 相似文献
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浮游植物对氮的吸收与其生长繁殖密切相关,太湖梅梁湾湖区蓝藻水华频频暴发,对该水域浮游植物氮吸收进行研究具有重要意义.本文分别在冬、春、夏、秋4个季节于梅梁湾采样,对水体常规理化指标和浮游植物群落结构进行分析,并利用15N稳定同位素示踪技术研究了浮游植物对铵态氮（NH4+-N）、硝态氮（NO3--N）和尿素态氮（Urea-N）吸收的动力学特征.结果表明,太湖梅梁湾浮游植物群落除了秋季对NH4+-N的吸收不符合米氏方程外,其余均符合.冬季和春季3种形态氮最大吸收速率（Vmax）的大小依次为：NH4+-N > NO3--N > Urea-N,而夏季为：NH4+-N > Urea-N > NO3--N.3种形态氮Vmax的季节变化规律为夏季 > 秋季 > 春季 > 冬季.Vmax在不同季节以及不同形态氮之间的差异性可能与浮游植物群落组成以及水体中NH4+-N浓度不同有关.浮游植物对NH4+-N吸收的KS值在冬、春季高于夏季,对Urea-N吸收的Ks值则在夏、秋季高于冬、春季,而对NO3--N吸收的Ks值则在夏季显著高于其他3个季节.冬季和春季梅梁湾浮游植物群落最容易受到NO3--N限制,而最不容易受到Urea-N的限制;而夏季,则最容易受到NO3--N限制,而最不容易受到NH4+-N的限制,且浮游植物群落对NH4+-N的亲和力最高.与NO3--N相比,秋季浮游植物更容易受到Urea-N的限制.不同季节,容易对浮游植物产生限制作用的氮的形态不同. 相似文献
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Ten reaction vessels containing 1 m3 were used as the experimental arrangement. They were filled with coarse sand or fine gravel and installed 60 cm below the floor. The pore volume (water saturation) was 227… 260 l. Anaerobic conditions were established by the addition of 6 g glucose at storage. The reactors were given tap water with 50 and 200 mg/l NO from KNO3 in such a way that a volumetric rate of flow of 0.2, 0.4 and 0.8 l/d was created. The volumetric rates of flow corresponded to the natural recharge of groundwater, the recharge of groundwater under the conditions of irrigation and the conditions of an intensive wastewater ground treatment. In the effluent from the reaction vessels the nitrate concentration was determined every month. It was stationary from the 7th to the 55th month after the beginning of the experiment. The experiments are evaluated by means of a model which takes into account the diffusion, convection and kinetics of the nitrate degradation according to Michaelis-Menten. A simple method for solving homogeneous non-linear differential equations of the second order is proposed. The experimental and model results show a good agreement and prove the very slow nitrate degradation in the groundwater with kM = 210 mg/l, vmax = 1.5 mg/l · d or k1 = 0.005 d?1. 相似文献
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Nitrogen uptake and denitrification in restored and unrestored streams in urban Maryland, USA 总被引：2，自引：0，他引：2
Carolyn A. Klocker Sujay S. Kaushal Peter M. Groffman Paul M. Mayer Raymond P. Morgan 《Aquatic Sciences - Research Across Boundaries》2009,71(4):411-424
There is growing interest in rates of nitrate uptake and denitrification in restored streams to better understand the effects
of restoration on nitrogen processing. This study quantified nitrate uptake in two restored and two unrestored streams in
Baltimore, Maryland, USA using nitrate additions, denitrification enzyme assays, and a 15N isotope tracer addition in one of the urban restored streams, Minebank Run. Restoration included either incorporation of
stormwater ponds below a storm drain and catch basins to attenuate flow or hydrologic “reconnection” of a stream channel to
its floodplain. Stream restoration was conducted for restoring aging sanitary and bridge infrastructure and introducing some
stormwater management in watersheds developed prior to current regulations. Denitrification potential in sediments was variable
across streams, whereas nitrate uptake length appeared to be significantly correlated to surface water velocity, which was
low in the restored streams during summer baseflow conditions. Uptake length of NO3
−–N in Minebank Run estimated by 15N tracer addition was 556 m. Whole stream denitrification rates in Minebank Run were 153 mg NO3
−–N m−2 day−1, and approximately 40% of the daily load of nitrate was estimated to be removed via denitrification over a distance of 220.5 m
in a stream reach designed to be hydrologically “connected” to its floodplain. Increased hydrologic residence time in Minebank
Run during baseflow likely influenced rates of whole stream denitrification, suggesting that hydrologic residence time may
be a key factor influencing N uptake and denitrification. Restoration approaches that increase hydrologic “connectivity” with
hyporheic sediments and increase hydrologic residence time may be useful for stimulating denitrification. More work is necessary,
however, to examine changes in denitrification rates in restored streams across different seasons, variable N loads, and in
response to the “flashy” hydrologic flow conditions during storms common in urban streams. 相似文献
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青藏高原地区分布的湖泊数量众多、面积较大、分布范围广泛.受制于恶劣的自然条件,对该地区湖泊的光学吸收特性以及光合有效辐射衰减系数(Kd(PAR))的研究鲜有成果.本文依据2014和2015年间采集的13个典型高海拔、湖泊面积较大的湖库的现场实测数据和实验室测定数据,分析了采样湖库各个采样点的Kd(PAR)特征以及有色可溶性有机物(CDOM)、藻类颗粒物吸收及非色素颗粒物吸收特性,计算并分析了Kd(PAR)与透明度以及光学活性物质的关系.研究结果表明:青藏高原地区各湖库平均各项颗粒物吸收系数均较低,总颗粒物吸收系数在400~700 nm波段内不超过0.14 m~(-1)、CDOM吸收系数在355 nm波长处最高,为1.23 m~(-1)、最低接近于0、藻类颗粒物吸收特性不明显;实验数据完整的巴木错、格仁错和班公错的主导吸收组分各异,其中巴木错为CDOM吸收主导,格仁错与班公错为非色素颗粒物吸收主导;青藏高原采样湖泊总体Kd(PAR)平均值较小,仅为0.26 m~(-1),样点最大值出现在可鲁克湖(1.17 m~(-1)),最小值出现在普莫雍错(0.10 m~(-1));在采样湖泊中Kd(PAR)与透明度呈显著相关;Kd(PAR)与CDOM的相关性最强,叶绿素a浓度次之,与总悬浮颗粒物浓度的相关性最不显著. 相似文献
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Xunhong Chen 《水文研究》2011,25(2):278-287
Characterization of streambed hydraulic conductivity from the channel surface to a great depth below the channel surface can provide needed information for the determination of stream‐aquifer hydrologic connectedness, and it is also important to river restoration. However, knowledge on the streambed hydraulic conductivity for sediments 1 m below the channel surface is scarce. This study describes a method that was used to determine the distribution patterns of streambed hydraulic conductivity for sediments from channel surface to a depth of 15 m below. The method includes Geoprobe's direct‐push techniques and Permeameter tests. Direct‐push techniques were used to generate the electrical conductivity (EC) logs and to collect sequences of continuous sediment cores from river channels, as well as from the alluvial aquifer connected to the river. Permeameter tests on these sediment cores give the profiles of vertical hydraulic conductivity (Kv) of the channel sediments and the aquifer materials. This method was applied to produce Kv profiles for a streambed and an alluvial aquifer in the Platte River Valley of Nebraska, USA. Comparison and statistical analysis of the Kv profiles from the river channel and from the proximate alluvial aquifer indicates a special pattern of Kv in the channel sediments. This depth‐dependent pattern of Kv distribution for the channel sediments is considered to be produced by hyporheic processes. This Kv‐distribution pattern implied that the effect of hyporheic processes on streambed hydraulic conductivity can reach the sediments about 9 m below the channel surface. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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为了研究抚仙湖紫外辐射(UVR)和光合有效辐射(PAR)衰减的时空特征及其与有色可溶性有机物(CDOM)、悬浮物(SS)、浮游植物(叶绿素a表征)等因子的关系,于2014年10月(秋季)、2015年1月(冬季)开展现场调查,结果显示:秋季不同波长(段)的漫射衰减系数Kd(305)、Kd(340)和Kd(PAR)分别为1.27±0.12、0.68±0.11和0.32±0.13 m-1,冬季分别为1.13±0.10、0.63±0.07和0.36±0.07 m-1;秋季CDOM的不同波长吸收系数ag(254)、ag(305)和ag(340)分别为4.09±0.26、1.18±0.09和0.57±0.05 m-1,冬季分别为2.95±0.24、0.61±0.11和0.11±0.07 m-1,秋季ag(254)、ag(305)和ag(340)显著高于冬季;秋季Kd(305)显著大于冬季,这与秋季(雨季)较高的CDOM丰度、浮游植物生物量(及SS浓度)有关.秋季ag(305)/Kd(305)、ag(340)/Kd(340)均显著高于冬季;秋季及秋冬季整体而言,ag(254)与Kd(305)、Kd(340)呈显著正相关,各多元逐步回归方程中均包含ag(254),说明CDOM吸收对UVR的衰减有重要贡献.空间差异方面,秋季北部的ag(254)、Kd(305)和Kd(340)显著高于南部,冬季南北部无明显差异,或与雨旱季北岸河流输入的CDOM和SS的情况有关.此外,浮游植物对UV-B衰减的影响和SS(与CDOM的交互作用)对UV-A衰减的影响更在于季节变化方面,而影响UVR、PAR衰减的各因子的相对贡献有待进一步量化. 相似文献
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Alessio Nicosia Costanza Di Stefano Vincenzo Palmeri Vincenzo Pampalone Vito Ferro 《水文研究》2021,35(10):e14407
Flow velocity is one of the most important hydrodynamic variables for both channelized (rill and gullies) and interrill erosive phenomena. The dye tracer technique to measure surface flow velocity Vs is based on the measurement of the travel time of a tracer needed to cover a known distance. The measured Vs must be corrected to obtain the mean flow velocity V using a factor αv = V/Vs which is generally empirically deduced. The Vs measurement can be influenced by the method applied to time the travel of the dye-tracer and αv can vary in different flow conditions. Experiments were performed by a fixed bed small flume simulating a rill channel for two roughness conditions (sieved soil, gravel). The comparison between a chronometer-based (CB) and video-based (VB) technique to measure Vs was carried out. For each slope-discharge combination, 20 measurements of Vs, characterized by a sample mean Vm, were carried out. For both techniques, the frequency distributions of Vs/Vm resulted independent of slope and discharge. For a given technique, all measurements resulted normally distributed, with a mean equal to one, and featured by a low variability. Therefore, Vm was considered representative of surface flow velocity. Regardless of roughness, the Vm values obtained by the two techniques were very close and characterized by a good measurement precision. The developed analysis on αv highlighted that it is not correlated with Reynolds number for turbulent flow regime. Moreover, αv is correlated neither with the Froude number nor with channel slope. However, the analysis of the empirical frequency distributions of the correction factor demonstrated a slope effect. For each technique (CB, VB)-roughness (soil, gravel) combination, a constant correction factor was statistically representative even if resulted in less accurate V estimations compared to those yielded by the slope-specific correction factor. 相似文献
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Spatial and depth variability of streambed vertical hydraulic conductivity under the regional flow regimes 
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下载免费PDF全文 Jinxi Song Liping Wang Xinyi Dou Fangjian Wang Hongtao Guo Junlong Zhang Guotao Zhang Qi Liu Bo Zhang 《水文研究》2018,32(19):3006-3018
This study investigated the influence of the regional flow on the streambed vertical hydraulic conductivity (Kv) within the hyporheic zone in three stream reaches of the Weihe River in July 2016. The streambed Kv with two connected depths was investigated at each test reach. Based on the sediment characteristics, the three test reaches could be divided into three categories: a sandy streambed without continuous silt and clay layer, a sandy streambed with continuous silt and clay layer, and a silt–clay streambed. The results demonstrate that the streambed Kv mainly decreases with the depth at the sandy streambed (without continuous silt and clay layer) and increases with the depth at the other two test reaches. At the sandy streambed (with continuous silt and clay layer) where streambed Kv mainly decreases with the depth, the regional upward flux can suspend fine particles and enhance the pore spacing, resulting in the elevated Kv in the upper sediment layers. At another sandy streambed, the continuous silt and clay layer is the main factor that influences the vertical distribution of fine particles and streambed Kv. An increase in streambed Kv with the depth at the silt/clay streambed is attributed to the regional downward movement of water within the sediments that may lead to more fine particles deposited in the pores in the upper sediment layers. The streambed Kv is very close to the bank in the sandy streambed without continuous silt and clay layer and the channel centre in the other two test reaches. Differences in grain size distribution of the sediments at each test reach exercise a strong controlling influence on the streambed Kv. This study promotes the understanding of dynamics influencing the interactions between groundwater and surface water and provides guidelines to scientific water resources management for rivers. 相似文献
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Deterministic Seismic Zoning of Eastern Cuba 总被引：1，自引：0，他引：1
—A deterministic seismic zoning of Cuba is performed by modelling, with modal summation, the complete P-SV and SH waves fields generated by point-source earthquakes buried in flat-layered anelastic media. The results of the computation, performed for periods greater than 1 second, are presented in two sets of maps of maximum displacement (d max), maximum velocity (v max) and design ground acceleration (DGA), obtained by using two different criteria in the definition of the input magnitude: (1) values reported in the earthquake catalogue (M obs) and (2) values determined from seismotectonic considerations (M max). A comparison with the results of a previous probabilistic seismic zoning is made to test the possibility of making intensity — ground motion conversion with the aid of log-linear regressions. 相似文献
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湖泊底泥疏浚环境效应:Ⅲ.对沉积物反硝化作用的影响 总被引：8，自引：1，他引：7
通过为期一年的疏浚模拟试验,在试验室培养疏浚与对照柱样,研究了底泥疏浚对沉积物反硝化过程的影响.沉积物反硝化速率的测定采用经典的乙炔抑制法.研究结果表明,在一年的试验周期内,疏浚和对照柱沉积物的反硝化速率分别为6.9-26.9nmol/(g·h)和21.6-102.7nmol/(g·h),除2006年的2月外的其他月份,疏浚沉积物的反硝化速率显著(P<0.05)低于未疏浚对照沉积物,同时还研究了环境因子对沉积物反硝化速率的影响,结果表明,疏浚和对照沉积物的反硝化速率都受温度的控制.硝态氟浓度是疏浚和对照沉积物反硝化速率的主要限制因子,有机碳对疏浚沉积物的反硝化速率有影响,但对未疏浚对照沉积物的反硝化速率没有影响.疏浚后短期内沉积物反硝化速率低于未疏浚对照沉积物,可看作是底泥疏浚在富营养华水体脱氮方面的一个负效应. 相似文献
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An Integrated Laboratory Method to Measure and Verify Directional Hydraulic Conductivity in Fine‐to‐Medium Sandy Sediments 下载免费PDF全文
下载免费PDF全文 The constant‐head permeameter test (CHPT) is widely used in sandy samples as a standard method in the laboratory to investigate hydraulic conductivity (K). However, it neither can be used to consistently determine directional hydraulic conductivity (DHC) nor guarantee the comparability of measured K values of samples with different sizes. Therefore, this paper proposes an integrated laboratory method, called modified CHPT (MCHPT), for the efficient determination and verification of consistent DHC values in fine‐to‐medium sandy sediments, based on a new methodological framework. A precise and standardized procedure for preparing the experimental setup of MCHPT was conducted, based on the integrated experimental setup of CHPT and tracer tests. Moreover, a formula was yielded for the time‐optimized sample saturation control. In comparison with grain size‐based methods, the validity of consistent Kh and Kv values determined by MCHPT was convincing. 相似文献
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This study evaluated the spatial variability of streambed vertical hydraulic conductivity (Kv) in different stream morphologies in the Frenchman Creek Watershed, Western Nebraska, using different variogram models. Streambed Kv values were determined in situ using permeameter tests at 10 sites in Frenchman, Stinking Water and Spring Creeks during the dry season at baseflow conditions. Measurements were taken both in straight and meandering stream channels during a 5 day period at similar flow conditions. Each test site comprised of at least three transects and each transect comprised of at least three Kv measurements. Linear, Gaussian, exponential and spherical variogram models were used with Kriging gridding method for the 10 sites. As a goodness-of-fit statistic for the variogram models, cross-validation results showed differences in the median absolute deviation and the standard deviation of the cross-validation residuals. Results show that using the geometric means of the 10 sites for gridding performs better than using either all the Kv values from the 93 permeameter tests or 10 Kv values from the middle transects and centre permeameters. Incorporating both the spatial variability and the uncertainty involved in the measurement at a reach segment can yield more accurate grid results that can be useful in calibrating Kv at watershed or sub-watershed scales in distributed hydrological models. 相似文献