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1.
Geochemical modeling was employed to estimate the chemistry of water infiltrating into abandoned underground flooded and unflooded coalmines of the Uniontown syncline, Fayette County, Pennsylvania. This was done to help evaluate factors governing the long-term evolution of coalmine discharge water quality in the Uniontown syncline area. The subsurface structure and lithology was delineated using borehole, mine shaft, and stratigraphic information. Hydrogeologic analyses indicated that most of the recharge to mine voids occurs in the zones of shallow overburden cover of less than 20 m in thickness. The water–rock contact period in the recharge areas of the overburden was estimated to be 5 days or greater for the flooded mines, and a day or less for the unflooded mines. Flow-through reaction-path models were applied to the topsoil and shale–sandstone lithological units identified in the recharge areas. The model predicted water entering the flooded mines at a pH of 6.65, alkalinity of 6.92 mequiv. l–1 and a total sulfate concentration of 7.33 mM, and the unflooded mines at a pH of 6.68, alkalinity of 6.99 mequiv. l–1 and a total sulfate concentration of 3.08 mM. The model predictions for the flooded and unflooded mines are consistent with groundwater data from the study site, indicating the usefulness of this approach in evaluating the contribution of overburden chemistry to the evolution of mine discharge quality.  相似文献   

2.
《Applied Geochemistry》1998,13(2):185-195
The occurrence and significance of aqueous flow through fractures in unsaturated tuff was investigated at the Apache Leap Research Site near Superior, Arizona. Water samples for geochemical and isotopic analysis were collected from water seeping from fractures in a mine haulage tunnel, from the saturated zone in a vertical borehole (USW UZP-4), and from both the unsaturated and saturated zones in an angled borehole (DSB). The geochemistry and14C activity of water samples from the DSB suggest that most of the recharge to the saturated zone has occurred through fractures, especially beneath the ephemeral streams. Evidence of substantial recent recharge through fractures was found in saturated-zone samples from the mine haulage tunnel using 3H, δ34S and SO42−/Cl− analyses. Evidence of partial imbibition of fracture flow into the rock matrix was found at multiple depths throughout the 147 m unsaturated zone at the DSB using geophysical measurements from the borehole, water-content analyses from core samples, and 14C and 3H analyses from pore water extracted from preserved core samples. Post-bomb 14C activity was measured in pore water near fractures just above the saturated zone.  相似文献   

3.
在对巷道导水裂隙详细调查量测的基础上, 通过对导水裂隙产状的归纳总结, 结合涌水水样的温度、矿化度及氢、氧同位素的动态监测结果, 分析了三山岛金矿两个矿区的渗流优势方位以及矿坑水与地表水体的连通性。研究表明:西山矿区的渗流优势方位与最大水平地应力平行, 而新立矿区的渗流优势方位与最大水平地应力近于垂直; 西山矿区存在海水、基岩咸水和第四系淡水的稳定补给, 新立矿区的咸水和淡水补给量不断减小, 海水补给量不断增大; 新构造断裂对矿区渗流优势方位的控制作用大于采动裂隙, 使得西山矿坑与地表水体存在良好的连通性, 也控制着海水补给矿坑的方式; 而新立矿仅在采动裂隙的影响下与海水、咸水和淡水存在较弱的连通性。  相似文献   

4.
Hand-pump wells in the Tarkwa gold mining district and the geologically similar Bui area were chemically analysed and compared in an effort to determine whether groundwaters in the Tarkwa area have been affected by mining. Significant chemical differences attributed to mine water discharges have been observed in streams in the Tarkwa area. Groundwater chemistry from hand-pump wells in Tarkwa and Bui areas reveal similar hydrochemical facies, predominantly Ca–Na–Mg–HCO3–Cl. However, except for SO42–, ionic concentrations of groundwaters from Bui are greater than those from Tarkwa probably due to differences in (1) water availability during sedimentation (2) water-rock interactions and/or residence times for water. No demonstrable impact of mining on groundwaters from hand-pumped wells in the Tarkwa area has been noted. Hydrogeological inference suggests that the main streams which receive mine water discharges are both gaining and are groundwater divides. The overwhelming majority of population centres and mining operations are located on opposite sides of these groundwater divides, therefore, it is unlikely aquifers tapped for drinking by these communities would be affected by mining.  相似文献   

5.
 Several mines in the Witbank coalfield in South Africa are affected by acid mine drainage. This has led to a deterioration in the water quality in many surface streams. The Loubert Mine is one such mine. Hence, an initial investigation was carried out to determine the source of acid mine drainage pollution and the associated hydrogeological conditions. The investigation showed that most of the acid mine drainage is emanating from old opencast workings which have been backfilled. Most of the water from the backfilled area drains into control reservoirs. Unfortunately their capacity is limited, which means that water overspills and seeps from them. This water finds its way into a nearby stream, the water of which accordingly has an unacceptably low pH value and high sulphate content. The proposals advanced to control the problem basically involve inhibiting the amount of water infiltrating the backfilled opencast area on the one hand and reducing the amount of water entering the control reservoirs on the other. Received: 5 March 1997 · Accepted: 17 June 1997  相似文献   

6.
With depleted coal resources or deteriorating mining geological conditions, some coal mines have been abandoned in the Fengfeng mining district, China. Water that accumulates in an abandoned underground mine (goaf water) may be a hazard to neighboring mines and impact the groundwater environment. Groundwater samples at three abandoned mines (Yi, Er and Quantou mines) in the Fengfeng mining district and the underlying Ordovician limestone aquifer were collected to characterize their chemical and isotopic compositions and identify the sources of the mine water. The water was HCO3·SO4-Ca·Mg type in Er mine and the auxiliary shaft of Yi mine, and HCO3·SO4-Na type in the main shaft of Quantou mine. The isotopic compositions (δD and δ18O) of water in the three abandoned mines were close to that of Ordovician limestone groundwater. Faults in the abandoned mines were developmental, possibly facilitating inflows of groundwater from the underlying Ordovician limestone aquifers into the coal mines. Although the Sr2+ concentrations differed considerably, the ratios of Sr2+/Ca2+ and 87Sr/86Sr and the 34S content of SO42? were similar for all three mine waters and Ordovician limestone groundwater, indicating that a close hydraulic connection may exist. Geochemical and isotopic indicators suggest that (1) the mine waters may originate mainly from the Ordovician limestone groundwater inflows, and (2) the upward hydraulic gradient in the limestone aquifer may prevent its contamination by the overlying abandoned mine water. The results of this study could be useful for water resources management in this area and other similar mining areas.  相似文献   

7.
The Jharia coalfield is the most important and active minig region; it experiences groundwater inflow and affects groundwater levels in overlying aquifers, and it provides the basis for a conceptual model of the hydrogeological impacts of coal mining. The several sandstone aquifers of the overburden are separated by aquitards that limit vertical hydraulic connection, but the inflow responds to seasonal events and seems to be linked to shallow groundwater behavior. The mine drainage behavior suggests a hydraulic connection between the mine and the shallower groundwater system. The greatest declines are directly above the panels, with an immediate response to coal mining. The inflow is localized by natural and induced fracture zones and is mostly into recent workings. The groundwater behavior is controlled by hydraulic property changes caused by mine-induced fracturing. The hydrological and chemical qualities of the shallow groundwater regime in 13 mining collieries in Mukunda Block have been investigated. Water samples collected from 30 shallow monitoring dug wells were chosen for the study. Rainfall, runoff, and infiltration rates have been calculated in the area. The water-quality plottings were used to interpret the distribution of individual chemical parameters and in predicting the water quality. The underground mine water has been classified as: (1) unconfined groundwater in the calcareous siltstone and sandstone—its composition is Na, Ca, SO4 and Na-MgHCO3 with moderate total dissolved solids (TDS) 200–1480 ppm; (2) the deep groundwater originating from the coal seams and associated sediments in the near-surface environments—this is a Na-HCO3 water with higher TDS; and (3) spoil dump waters are essentially Na-HCO3 with high TDS. This article presents some hydrologic results and conclusions relating to the hydrogeological and environmental impacts of the coal mining in the Jharia coalfield.  相似文献   

8.
Since 1995, when pumps were withdrawn from deep mines in East Fife (Scotland), mine waters have been rebounding throughout the coalfield. Recently, it has become necessary to pump and treat these waters to prevent their uncontrolled emergence at the surface. However, even relatively shallow pumping to surface treatment lagoons of the initially chemically-stratified mine water from a shaft in the coastal Frances Colliery during two dynamic step-drawdown tests to establish the hydraulic characteristics of the system resulted in rapid breakdown of the stratification within 24 h and a poor pumped water quality with high dissolved Fe loading. Further, data are presented here of hydrochemical and isotopic sampling of the extended pump testing lasting up to several weeks. The use in particular of the environmental isotopes δ18O, δ2H, δ34S, 3H, 13C and 14C alongside hydrochemical and hydraulic pump test data allowed characterisation of the Frances system dynamics, mixing patterns and water quality sources feeding into this mineshaft under continuously pumped conditions. The pumped water quality reflects three significant components of mixing: shallow freshwater, seawater, and leakage from the surface treatment lagoons. In spite of the early impact of recirculating lagoon waters on the hydrochemistries, the highest Fe loadings in the longer-term pumped waters are identified with a mixed freshwater–seawater component affected by pyrite oxidation/melanterite dissolution in the subsurface system.  相似文献   

9.
The Rozna Mine is one of the last active uranium mines in Europe. When the mine is closed and flooded, the natural groundwater flow pattern will be partly restored. Re-established groundwater flow system will be associated with an increase of groundwater discharge into draining rivers and streams. Since the groundwater inflows to streams can be contaminated by the mine water, the groundwater drainage characteristic of fractured aquifer should be carefully identified. Several methods of groundwater discharge zones identification were used including morphological analysis, thermometry, and electrical conductivity (EC) measurements. Stream temperatures and EC at more than 700 points in the area covering about 85 km2 were measured. The measurements were performed during winter period, when stream discharges were low and there was a maximum temperature contrast. There was a frequent presence of preferential discharge zones with resulting anomalous temperatures and electric conductivity values of stream water. The results show evident correlation of discharge zones with surface morphology and geological settings. Just like the aquifer discharge characteristics, the aquifer is strongly heterogeneous. The thermometry supported by measurement of EC proved to be a useful tool for large-scale investigation of groundwater flow and drainage in fractured aquifers.  相似文献   

10.
In the Baltic countries — Estonia, Latvia and Lithuania — groundwater is the principal and only source of clean drinking water. Its safe yield is rather large — 6.7 mln m3/d. At present, consumption does not reach half of this amount. Therefore, the resources available will be sufficient for a rather remote future, provided that groundwater is not polluted. Under Soviet rule, insufficient attention was paid to ecological problems in the Baltic States. As a result, due to constantly increasing surface pollution, groundwater quality is decreasing. The topmost, unconfined aquifer is unfit for use, especially in many urbanized areas. Moreover, pollutants, especially organics, are starting to enter the lower, artesian aquifers. To determine and forecast groundwater quality, a monitoring system has been worked out. However, in order to protect groundwater, besides monitoring, new laws, regulations, and guarantees for their implementation are necessary.  相似文献   

11.
This study documents the environmental impacts of borate mines in Bigadiç district, which are the largest colemanite and ulexite deposits in the world. Borate-bearing formations have affected the concentrations of some contaminants in groundwater. Groundwater quality is directly related to the borate zones in the mines as a result of water–rock interaction processes. Calcium is the dominant cation and waters are Ca–SO4 and HCO3 type in the mine (Tülü borate mine) from which colemanite is produced. However in the Simav and Acep Borate Mines, ulexite and colemanite minerals are produced and waters from these open pit mines are Na–HCO3–SO4 types. High SO4 concentrations (reaching 519 mg/L) might be explained by the existence of anhydrite, gypsum and celestite minerals in the borate zone. Groundwater from tuff and borate strata showed relatively low pH values (7–8) compared to surface and mine waters (>8). EC values ranged from 270 to 2850 μS/cm. Boron and As were the two important contaminants determined in the groundwaters around the Bigadiç borate mines. Arsenic is the major pollutant and it ranged from 33 to 911 μg/L in the groundwater samples. The concentrations of B in the study area ranged from 0.05 to 391 mg/L. The highest B concentrations were detected at the mine areas. The extension of the borate zones in the aquifer systems is the essential factor in the enrichment of B and As, and some major and trace elements in groundwaters are directly related to the leaching of the host rock which are mainly composed of tuffs and limestones. According to drinking water standards, all of the samples exceed the tolerance limit for As. Copper, Mn, Zn and Li values are enriched but do not exceed the drinking water standards. Sulfate, Al and Fe concentrations are above the drinking water standard for the groundwater samples.  相似文献   

12.
We have studied sediments of the Piscinas beach (SW Sardinia, Italy), which is supplied by two streams that wash mine dumps of abandoned lead and zinc mines at Montevecchio and Ingurtosu, situated inland from the supply basin of the beach itself. A study of the texture, mineralogy and geochemistry of the sediments was conducted for the purpose of assessing the possible influence of the mine waste on the composition of the sediments, looking for any anomalous enrichments in heavy metals. Furthermore, to evaluate and quantify metal release into the sea, samples of Posidonia oceanica, a bioaccumulator marine plant, were also examined. The results indicate that the distribution of heavy metals in the foreshore sediments is particularly affected by the contribution of the streams, while in the shoreface the distribution is affected by the currents that disperse the sediments both out to sea and southwards. The metal contents of the Posidonia oceanica are correlated with the different stages of activity of the mines. Received: 28 January 1998 · Accepted: 22 April 1998  相似文献   

13.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements.  相似文献   

14.
露天开采是我国煤矿开采的两大方式之一。与地下开采煤矿类似，露天煤矿在开采过程中同样面临防治水问题，由于我国露天煤矿水害类型相对单一，国内学者鲜有对露天煤矿的水害特征和防治水技术进行深入研究。以我国露天煤矿分布范围为出发点，从充水水源、充水通道、充水强度3方面分析露天煤矿水害特征，得出大气降水、地表水和浅层地下水是主要充水水源；人为开挖形成的直通式通道、强渗透含水层或透水层、垂向导水钻孔、滑坡形成的地表裂缝等是主要充水通道；季节性变化明显、疏排水周期长、排水量大是露天煤矿疏排水主要水害特征的结论。归纳目前我国露天煤矿常用的7种防治水技术，提出露天煤矿由远及近、由上而下、由面至点的立体防治水技术体系。从地下水资源保护和生态环保角度出发，为实现露天煤矿绿色开采和可持续发展，提出以切断补给通道、减小矿坑疏排水量为目的的帷幕截流技术是今后露天煤矿防治水的主要技术方法。   相似文献   

15.
黄河流域中上游矿区煤?水矛盾突出,煤炭开采对地下水环境造成一定的破坏。基于此,以鄂尔多斯盆地北部侏罗纪煤田榆神府矿区为研究区,在野外调查、数据分析、室内测试的基础上,分析研究区矿井水的量质特征,揭示煤炭高强度开采对地下水环境的影响,并开展矿井水生态利用研究。结果表明:研究区矿井富水系数在0.23~2.28,平均为0.91,评估2020年区内矿井排水量高达4.70亿m3,受采掘活动影响,浅埋煤层开采区地下水位下降趋势明显;区内矿井水出现不同程度的污染组分超标现象,主要超标指标为化学需氧量(COD)、Na+、SO4 2?、溶解性总固体(TDS),未处理的矿井水外排将会污染区内地下水环境;研究区浅层地下水超限的水质指标主要为NO3-N,与矿井水超限水质指标差别较大,反映出浅层地下水水质受采矿活动影响较小;提出矿井水浅层回灌和矿井水生态灌溉2种模式开展研究区矿井水的生态利用,矿井水回灌对矿井水中的溶解性有机碳、色度具有较好的去除效果,回灌后出水满足Ⅲ类地下水限值;浅埋煤矿矿井水具有作为矿区生态修复灌溉用水的较好潜力,中深埋煤矿和深埋煤矿矿井水不适宜作为灌溉用水。研究结果为我国西部煤矿区水资源保护和生态修复提供重要依据。   相似文献   

16.
As hydrogeological conditions of coal field in North China are complicated, coal mine water hazards have been occurring frequently. Nearly 80% of coal mines are affected by Ordovician and Permo-Carboniferous Karst water. According to rough statistics, 200 incidents of water inrush have occurred since 1950, 1,500 persons have died, and there is an economic loss of 3 billion Yuan (RMB). The climate of North China belongs to drought or semi-drought zone. So the recharge amount of ground water by infiltration of precipitation is limited. Stronger coal mine water drainage has brought a series of environmental problems, such as water resource and lots of famous Karst springs exhausted, surface collapse emerged, mine water contaminated. Coal mine water hazards are so serious that the economic benefit of coal mines is dropping. Sustainable development of coal mines is affected. So, preventing coal mine water hazards and protecting geological environment are essential. This thesis focuses on preventing coal mine water hazards technologies. The technologies include four aspects: exploration of hydrogeological conditions; prediction and forecast of water inrush; mining under safe water pressure; and sealing off groundwater by grouting.  相似文献   

17.
Hydrochemical studies were carried out in parts of Oban Massif and Mamfe Embayment, Southeastern Nigeria to examine the contributions of barite mining activities on water quality. Pond and stream water samples were collected from six abandoned barite mines and adjoining streams areas during dry and wet seasons. These samples were analysed for physicochemical parameters using standard techniques. The results showed that the quality of water samples in the vicinity of barite mine sites was characterized by low pH, low mineralization, high suspended solids and deep colour. Sodium (Na+) and calcium (Ca2+) are the dominant cations and bicarbonate (HCO3 ?) and sulphate (SO4 2?) the dominant anions. The low concentration of dissolved silica, relatively high concentrations of Na+, HCO3 ? and SO4 2? suggest a combined influence of silicate, carbonate and weathering of mine spoils. The total dissolved solids, total suspended solids, electrical conductivity and major ions (except Na+ and K+) are higher for water draining barite mines from Cretaceous sediments, while Na+, K+, Ba2+ are higher in basement rock areas. Correlation and factor analyses suggest that the main components of the water samples are related to anthropogenic, geogenic, mineralization and environmental controls, while Gibbs diagram plots indicate weathering as the main process controlling the chemistry of water. Computed values of hardness and some irrigational parameters showed that the pond and stream water samples are generally soft and can be used for irrigation. Generally, the water quality satisfied the WHO (2008) and NIS (2007) standards for domestic, agriculture and industrial. However, there is the need to assess the impact of the pollution on the ecosystem and human health while remediation measures are being considered.  相似文献   

18.
Domestic water supply impacts by underground coal mining in Virginia, USA   总被引：2，自引：0，他引：2  
 Underground coal mining can affect wells and springs used as water supplies. In Virginia, concerns over such impacts are felt by both surface owners and coal-mining firms. Virginia's geologic history has caused faults and fractures to be common in its coalfield region, relative to other Appalachian coal-mining areas. The results of 73 investigations of alleged domestic water supply impacts by underground mining were analyzed; the investigations were conducted by the Virginia Division of Mined Land Reclamation (VDMLR). This analysis was conducted with reference to guidelines that define a primary zone of underground mining influence where dewatering of aquifers is to be expected. The VDMLR data set included 27 investigations of alleged water supply impacts by partial-extraction room-and-pillar mines, 41 investigations of high-extraction room-and-pillar mines, and 4 investigations of longwall mines. VDMLR investigators found that 14 of 16 water supplies within the primary zone of influence were likely to have been affected by pillar-retreat mining, but no water supplies within the primary zone of influence for longwall and room-and-pillar mines were represented in the data base. VDMLR investigators found 42 of 56 water supplies outside of the primary zones were likely to have been affected by mining; these cases represented room-and-pillar, pillar-retreat, and longwall mining. Geologic circumstances not directly related to subsidence were found to be responsible for 31 of these 42 impacts. These geologic circumstances included subsurface fractures and other geologic features acting as aquifers that were drained by underground mining operations. VDMLR investigators also found some of the investigated water losses to have been caused by factors other than mining. These results demonstrate the inherent difficulties of any attempt to rigidly define a "zone of underground mining impact" based solely on mine subsidence effects, especially in regions where geologic faults and fractures are common such as the southwest Virginia coalfield. Received: 4 August 1995 · Accepted: 23 October 1995  相似文献   

19.
In this study we investigated the sulphidic mine tailings from Frongoch and Grogwynion, two abandoned lead zinc mines in mid-Wales, UK. Despite falling within the same ore field the mine waste characterisation has identified differences in the tailings from the two sites. Bulk concentrations range from 10 to 52 g kg− 1 for Pb, 1.1 to 2.9 g kg− 1 for Zn in Grogwynion and from 1.0 to 130 g kg− 1 for Pb, 11 to 110 g kg− 1 for Zn in Frongoch. An experimental (European standard leaching tests TS 14429 and TS 14405) and geochemical modelling approach was used to study the leaching composition as a function of pH and liquid/solid ratio. There was little correlation between the tailings bulk metal concentrations and the leachate composition, but variations in Pb and Zn concentrations were found to be consistent with control of dissolved Pb and Zn by secondary minerals and the mechanisms of dissolution/precipitation/sorption involving them. Specifically, the Grogwynion mine tailings with near-neutral pH have predominantly lead and zinc carbonates controlling Pb and Zn solubility in the leachates, whereas the Pb and Zn concentrations in Frongoch leachates are best modelled with a surface complexation model for metal sorption to oxyhydroxides. The different speciation results in a greater sensitivity of Grogwynion tailings to acidification with a potential release of Pb in solution up to 10 times higher than in Frongoch, despite similar bulk Pb concentrations. At acid pH, Zn is similarly dissolved to a greater extent in Grogwynion than in Frongoch tailings. There was no evidence of sulphide oxidation during the batch and column leaching tests and the suitability of using these European leaching standards for the characterisation of sulphidic mine waste materials for waste management purposes has been considered.  相似文献   

20.
Loading trends and sources of CI– in the South Fork of the Shenandoah River, Virginia were analyzed for the period 1929–1982. CI– has increased from approximately 2 mg/L (2,776 tons/yr) to over 10 mg/L (14,256 tons/yr). Natural CI– is estimated to be 1.01 mg/L (1,388 tons/yr) with precipitation providing 0.99 mg/L and rocks 0.02 mg/L. From 1929 to 1949 CI– concentrations were relatively constant and independent of discharge, conforming to the Type II curve of Davis and Zobrist (1978), indicative of natural or relatively uncontaminated streams. Since 1952 CI– concentrations increased exponentially as river discharge decreases conforming to the Type I curve of Davis and Zobrist for polluted streams. Since 1965 anthropogenic CI– loading at 12,868 tons/yr has remained relatively constant. Four major sources contribute 92.2 percent (11,871 tons/yr) of the anthropogenic CI–: (1) deicing salts—4,149 tons/yr, (2) domestic sewage—3,015 tons/yr, (3) livestock and poultry wastes—2,458 tons/yr, and (4) commercial fertilizers—2,249 tons/yr.  相似文献   

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