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1.
石灰处理土的物理力学性质及其微观机理的研究 总被引：12，自引：0，他引：12
本文在回顾前人研究石灰与土相互作用的基础上,对石灰加固土的物理力学性质作了广泛的讨论,并结合宏观性质对加固的微观机理作了比较深入的研究。粉末 x 射线衍射法试验证实了在长期养护或高温养护下,石灰与土反应生成具有凝胶性质的产物--水化硅(铝)酸钙(CSH)微晶体。孔容试验表明,随着时间的增长,石灰与土的生成物在数量上不断增加,其孔径减小。扫描电镜的微观结构研究发现了生成物的强度随时间增长的原因--CSH 的产生和结晶使得土的微结构更加牢固。最后讨论了添加剂在提高强度方面的作用,并结合实际工程应用,讨论了影响石灰加固效果的因素。 相似文献
2.
花岗岩残积土的进失水能力与其软化崩解的特殊力学特性息息相关,现有的改良土研究都着重于土体宏观力学与微观结构的变化,忽视了固化剂对土颗粒表面性质的影响。为了探索固化剂改良后的花岗岩残积土进失水能力及三相接触角的变化规律,开展了水滴入渗试验、接触角测量试验、进水试验和失水试验,并结合扫描电镜和红外光谱方法,定性及定量分析了花岗岩残积土在不同固化剂作用下微观结构和化学成分的变化规律对花岗岩残积土进失水能力的影响机制。结果表明:（1）不同含量的改良剂能不同程度地影响花岗岩残积土表层斥水性能;随着固化剂掺量的提高,土体的表面斥水性增强,三相接触角变大,进失水能力减弱;固化剂改良土体的效果依次为石灰、水泥、高岭土,且改良土体的进失水能力变化与土体表面斥水性和三相接触角的变化有明显的相关性。（2）改良花岗岩残积土进失水能力的变化由土体内部结构的改变以及表面性质的改变共同导致。（3）水泥和石灰主要依靠离子的交换团聚作用、土壤固化剂对土颗粒的包裹作用、硬凝反应以及碳酸化作用减弱土颗粒外部的双电层及其表面自由能,使土体斥水性和初始接触角变大;而高岭土主要依靠自身对水分子的吸附作用,对土体的斥水性和接触角影响不大。结果可为固化剂改变土体表面性质导致的接触角变化规律提供一定科学依据,也为不同渗透需求的实际工程选取改良剂提供一定参考。 相似文献
3.
Ahmad Safuan A. Rashid Nima Latifi Christopher L. Meehan Kalehiwot N. Manahiloh 《Geotechnical and Geological Engineering》2017,35(6):2613-2623
Many tropical residual laterites have relatively poor engineering properties due to the significant percentage of fine-grained soil particles that they contain, which are formed by the soil weathering process. The widespread presence of laterite soils in tropical regions often requires that some form of soil improvement be performed to allow for their use in various civil engineering applications, such as for road base or subbase construction. One of the most commonly utilized stabilization techniques for laterite soils is the application of additives that chemically react with the minerals that are present in soil to enhance its overall strength; effective soil stabilization can allow for the use of site-specific soils, and can consequently result in significant cost savings for a given project. With an increasing focus on the use of more environmentally friendly and sustainable materials in the built and natural environments, there is an emerging interest in eco-friendly additives that are an alternative to traditional chemical stabilizers. The current study examines the viability of xanthan gum as an environmentally friendly stabilizer that can improve the engineering properties of tropical residual laterite soil. Unconfined compressive strength (UCS) tests, standard direct shear tests, Brunauer, Emmett, and Teller (N2-BET) surface area analysis tests and field emission scanning electron microscopy (FESEM) tests were used to investigate the effectiveness of xanthan gum for stabilization of a tropical laterite soil. The UCS test results showed that addition of 1.5% xanthan gum by weight yielded optimum stabilization, increasing the unconfined compressive strength of the laterite soil noticeably. Similarly, direct shear testing of 1.5% xanthan gum stabilized laterite specimens showed increasing Mohr–Coulomb shear strength parameters with increases in curing time. From the FESEM results, it was observed that the stabilization process modified the pore-network morphology of the laterite soil, while also forming new white layers on the surface of the clay particles. Analysis of the test results indicated that xanthan gum stabilization was effective for use on a tropical residual laterite soil, providing an eco-friendly and sustainable alternative to traditional soil stabilization additives such as cement or lime. 相似文献
4.
本文开展了一系列不同液限高分子吸水树脂固化工程泥浆无侧限抗压强度试验, 探讨了泥浆土液限对固化效率的影响规律, 对比研究了掺入高岭土对泥浆固化强度的改进程度, 最后基于XRD和SEM试验揭示了液限和高岭土对固化泥浆强度影响的微观机理。结果表明: 随着泥浆土液限的增大, 固化泥浆土强度逐渐降低, 固化效率随着泥浆土液限增大显著衰减, 当液限增加10%, 固化泥浆土强度qu平均减少48.2%。然而高岭土的掺入则显著提升了固化泥浆土的强度, 并且强度增长率随着龄期逐渐增大, 对于龄期为90天时, 增加40%高岭土能够提升固化泥浆土强度qu 1.17倍。微观结构试验表明泥浆土液限变化对水化产物产量的影响较小, 固化泥浆土强度随泥浆土液限减小主要是由于固化泥浆土孔隙随着泥浆土液限增大而增多, 使得微观结构松散从而导致强度降低。高岭土的掺入则显著提升了固化泥浆土的水化产物产量, 增强了固化泥浆土胶结强度, 从而提升了固化泥浆土强度。因此, 在实际工程中, 一方面可以通过调配泥浆土液限来提高固化效率; 另一方面可以通过掺入高岭土或者一些高岭土基废弃物(如高岭土尾矿)来提高固化强度, 实现“以废制废”绿色环保的理念。 相似文献
5.
石灰稳定红黏土强度的长期碳化效应 总被引：1，自引：0，他引：1
碳化效应是石灰稳定土强度增长机理之一,但长期的碳化作用是否对其强度一直起促进作用？如果没有压实作用,碳化效果到底如何？这些关键问题还没有得到充分的论证。采用灰土拌和后击实养护和养护后再击实的不同制样方法,通过承载比CBR试验,探讨压实作用对碳化效应的影响。制备4种初始含水率的击实试样,开展碳酸溶液和纯水浸泡下的CBR试验,论证长期碳化对石灰稳定土强度的作用效果。结果表明,自然养护90 d后再击实试样的CBR值明显低于击实后养护的试样;初始含水率为34%时前者约为后者的12倍。另外,碳酸溶液浸泡15 d后的试样CBR值均小于纯水浸泡的试样CBR值,但初始含水率越大其影响程度越小,当初始含水率大于34%后两者之间的强度基本没有差别。为进一步佐证长期碳化作用能弱化石灰稳定土的强度,开展不同浸泡时间的无侧限抗压强度试验,发现石灰土的强度呈现先增大后减少的变化趋势,再次证实长期的碳化作用弱化石灰稳定土的强度。最后,利用热重分析法测试经过碳酸溶液浸泡前后的石灰稳定土,发现长期碳化溶解了部分石灰土中的碳酸钙和硅酸盐类胶结物。借助扫描电镜图片和孔隙尺寸分布曲线,从微观角度揭示不同击实和养护方式对石灰稳定土强度的影响机制。 相似文献
6.
GS(Gypsum-Slag)土体硬化剂是一种由水泥、钢渣、矿渣和脱硫石膏及其他外加剂组成的新型土体固化材料。将GS土体硬化剂和水泥两种固化剂固化土作为研究对象,通过室内无侧限抗压强度试验和电镜扫描试验,研究固化土的应力-应变曲线以及土质、固化剂掺量、龄期对固化土力学性能的影响,观察其微观结构,进而对比分析GS土体硬化剂和水泥的特性,并进行现场试验加以验证。研究结果表明：相比水泥土,GS固化土应力-应变曲线存在明显峰值;GS固化土和水泥土的强度均随着掺量和龄期正增长,且GS固化土的长期强度更高;GS固化土和水泥土变形模量分别是其抗压强度的31.11～77.24倍和23.24～71.62倍;GS固化土现场成桩的完整性优于水泥土。相比水泥土,GS固化土具有强度增长快、后期强度高、经济效益好的特点,可较好满足地下工程和路基工程等土体加固应用需求。 相似文献
7.
为了验证固化剂GX08加固杭州海湖相软土的效果及考察有机质对水泥固化的不利影响,对固化土的强度特性进行了试验研究。结果表明,有机质的添加会显著阻碍固化土强度的增长,而固化剂GX08能有效增强固化土的强度;固化土强度与有机质含量存在二次函数关系,与水泥掺量呈线性关系,与固化剂GX08掺量和龄期都以对数函数的形式相关;将总灰水比C/W用于固化土强度模型的建立,通过对试验数据的分析与整理,建立了同时考虑固化土中有机质含量、水泥掺量、固化剂掺量和龄期影响的固化土综合强度预测模型。最后对模型进行了推广使用,验证了模型的适用性。 相似文献
8.
环境侵蚀下水泥土力学特性的时间效应分析 总被引：2，自引：0，他引：2
采用模拟试验的方法探讨了在各种环境因素(水、不同化学溶液、不同浓度以及不同pH值等)影响下的水泥土在各个龄期的力学特性,对其相应荷载位移曲线进行了分析和讨论。得到了水泥土在各种侵蚀环境下的力学特性与时间的关系,并对环境侵蚀条件下水泥土的强度增长规律进行了分析。结果显示各种环境因素对水泥土力学性质均有明显的影响。从时间效应看,随着水泥土中水泥的水化和水泥固化体的形成,侵蚀效应在逐渐减弱。 相似文献
9.
The effect of calcium-based stabilizers such as lime on the geotechnical properties of tropical soils has been reported by
many researchers. However, the amount of literature available on the micro-structural, molecular, and leaching characteristics
of lime and in particular phosphoric acid-stabilized lateritic clays has been limited. This research was carried out in an
attempt to identify the time-dependent soil-chemical reactions. In addition, the possible mechanisms that contributed to the
stabilization process were discussed in the light of various spectroscopic and microscopic techniques such as X-ray diffractometry
(XRD), energy-dispersive X-ray spectrometry (EDAX), field emission scanning electron microscopy (FESEM), Fourier transform
infrared spectroscopy (FTIR), and nuclear magnetic resonance spectroscopy (NMR) etc. Based on the results it was found that
in lime-treated samples, the coating action of free iron oxides on clay particles imposed inhibitive effects on the dissolution
of clay alumina. On the other hand, in phosphoric acid-stabilized soil, due to the increase in solubility of metal oxides
and also the subsequent release of clay alumina the formation of cementitious compounds were more feasible. From engineering
point of view, the phosphoric acid-stabilized lateritic soil showed the highest degree of improvement with an approximately
threefold strength increase in comparison with the natural soil over an 8-month curing period. 相似文献
10.
Strength behavior and microstructural characteristics of tropical laterite soil treated with sodium silicate-based liquid stabilizer 总被引：4，自引：1，他引：3
Although the effects of nontraditional stabilizers on the geotechnical properties of tropical soils has been the issue of investigation in recent years, the micro-structural characteristics of nontraditional soil additives and in particular selected additive (TX-85) have not been fully studied. Nontraditional soil stabilization additives are widely used for stabilizing marginal materials. These additives are low-cost alternatives to traditional construction materials and have different compositions. They also differ from one another while interacting with soil. In line with that, it was the objective of this research to investigate the strength properties and physicochemical mechanisms related to tropical laterite soil mixed with the liquid stabilizer TX-85. Macro-structure study, i.e., compaction, and unconfined compression strength test were used to assess the engineering and shear properties of the stabilized laterite soil. In addition, the possible mechanisms that contributed to the stabilization process were discussed using various spectroscopic and microscopic techniques such as X-ray diffractometry (XRD), energy-dispersive X-ray spectrometry, scanning electron microscopy, and Fourier transform infrared spectroscopy. From engineering point of view, the results indicated that the strength of TX-85 stabilized laterite soil improved significantly. The degree of improvement was approximately four times stronger than natural soil after a 7-day curing period. The XRD showed no crystalline products (gel form). Moreover, weathering effects were obvious in TX-85 treated samples in most of clay minerals’ peak intensities. These effects were reduced especially for kaolinite mineral inside the soil with curing time. 相似文献
11.
Lime stabilization of clay minerals and soils 总被引：24，自引：0，他引：24
F.G. Bell 《Engineering Geology》1996,42(4):223-237
Clay soil can be stabilized by the addition of small percentages, by weight, of lime, thereby enhancing many of the engineering properties of the soil and producing an improved construction material. In order to illustrate such improvements, three of the most frequently occurring minerals in clay deposits, namely, kaolinite, montmorillonite and quartz were subjected to a series of tests. As lime stabilization is most often used in relation to road construction, the tests were chosen with this in mind. Till and laminated clay were treated in similar fashion. With the addition of lime, the plasticity of montmorillonite was reduced whilst that of kaolinite and quartz was increased somewhat. However, the addition of lime to the till had little influence on its plasticity but a significant reduction occurred in that of the laminated clay. All materials experienced an increase in their optimum moisture content and a decrease in their maximum dry density, as well as enhanced California bearing ratio, on addition of lime. Some notable increases in strength and Young's Modulus occurred in these materials when they were treated with lime. Length of time curing and temperature at which curing took place had an important influence on the amount of strength developed. 相似文献
12.
矿渣胶凝材料固化软土的力学性状及机制 总被引：4，自引：0，他引：4
利用矿渣胶凝材料固化软土,既可利用工业废渣,又能减少水泥的用量。以矿渣胶凝材料固化黏土、砂土二种软土。发现矿渣胶凝材料加固软土的效果远好于水泥、石灰,其9 %掺量的固化土28 d的无侧限强度达到2.0 MPa以上,普遍高于15 %掺量的水泥固化土,且其28 d固化土的软化系数普遍高于90 %以上,固化黏土后CBR值远高于同掺量的石灰固化土。X衍射结构分析表明,矿渣胶凝材料水化时产生的高强难溶的矿物晶体是其固化软土效果好的主要原因。因此,矿渣胶凝材料是一种性能优异的软土加固材料。 相似文献
13.
针对有机污染场地修复施工过程中出现的冒浆现象,选取2种典型有机污染泥浆,通过多组室内试验,对比分析了4种固化剂的固化稳定效果。结果表明：4种固化剂均有较好的减水效果,典型泥浆I的含水率28 d降幅可达45%,而典型泥浆II的28 d减水效果以固化剂A（5%水泥）最优,其含水率降幅为37%;固化土样孔隙水电导率EC随龄期先升高后降低,其峰值出现在3 d或7 d;固化土样pH值总体随龄期而增大,且典型泥浆II的pH值明显高于典型泥浆I;泥浆固化后qu值随龄期发展而快速增长,且典型泥浆I强度远高于典型泥浆II,并以固化剂A、C固化增强效果最佳,28 d时固化剂C固化的典型泥浆I、II的qu值分别达到233、48 kPa;添加固化剂尤其是含凹凸棒土的固化剂B、D能有效降低有机污染物的浸出,其28 d龄期对典型泥浆I、II的稳定率超过81%。固化泥浆EC、pH值与qu值关系具有明显规律,可反映其强度生长状况。 相似文献
14.
Jin Liu Bin Shi Hongtao Jiang He Huang Gonghui Wang Toshitaka Kamai 《Engineering Geology》2011,117(1-2):114-120
The topsoil of clayey slope is easy to erosion because it is weak in its strength, water stability and erosion resistance. A new organic polymer soil stabilizer, which was developed for the stabilization treatment of clay slope topsoil and was named as STW, was introduced in this study. In order to understand the effect of STW on the stabilization of clayey soil, laboratory tests on the unconfined compressive strength, shear strength, water stability and erosion resistance of untreated and treated soil specimens are performed, The results indicated that STW soil stabilizer can significantly increased the unconfined compression strength, shear strength, water stability and erosion resistance of clayey soil. The unconfined compression strength increased with the increasing of curing time and the variation mainly occurs in the first 24-hour. With the addition amounts of STW increasing, the strength, water stability and erosion resistance increased at the curing time being 48 h, but in the case of friction angle, no major change was observed. Based on the scanning electron microscopy (SEM) analysis of the stabilized soil, the stabilization mechanisms of STW soil stabilizer in the clayey soil were discussed. Finally, a field test of the stabilization treatment of clay slope topsoil with STW was carried out, and the results indicated that the STW soil stabilizer on the stabilization treatment of clay slope topsoil is effective for improving the erosion resistance of slope topsoil, reducing the soil loss and protecting the vegetation growth. Therefore, this technique is worth popularizing for the topsoil protection of clay slope. 相似文献
15.
Amin Eisazadeh Khairul Anuar Kassim Hadi Nur 《Geotechnical and Geological Engineering》2012,30(6):1435-1440
Studies on the chemically stabilized soils have shown that the effectiveness of treatment is largely dependent on soil??s natural environment. In this research, the time-dependent changes induced in permanent cation exchange capacity of lime and phosphoric acid treated soils, comprised mainly of montmorillonite and kaolinite minerals, were investigated. Also, in order to study the relationship between the exchange capacity and acidity/alkalinity of pore water, pH measurements were performed on cured samples. Based on the collected data, it was found that the pH of stabilized soils showed a tendency for reaching soil??s natural pH with increasing curing time. In addition, the increase in number of broken bonds around the edges of soil particles and also the formation of cementitious compounds that acquired negative charges contributed to achieving higher CECp values at longer curing periods. Nevertheless, the kaolinite mineral with pH-dependent structural properties, showed a rather limited behavior in the acidic medium. From engineering point of view, the lime treated samples revealed the highest degree of improvement with an approximately ten-fold strength increase in comparison to the natural soil over an 8?months curing period. 相似文献
16.
硅酸盐水泥作为常规的土壤固化剂存在高能耗、高排放等问题,研究人员一直在寻求一种更加经济环保的水泥代替品。使用基于高炉矿渣（ground granulated
blast-furnace slag,简称 GGBS）、粉煤灰（ fly ash,简称 FA）的地聚合物对砂土进行加固,通过调整激发剂的种类和配比、矿渣与粉煤灰比例、水灰比和养护条件等,研究不同因素对地聚合物固化砂土力学性能的影响。通过无侧限抗压强度（unconfined compressive
strength,简称 UCS）测试、电子计算机断层扫描（ computed tomography,简称 CT ）分析、扫描电子显微镜（scanning electron
microscope,简称 SEM）对试样进行了深入研究。结果表明：基于 GGBS-FA 的地聚合物可有效地提高砂土的力学性能;复合激发剂的加固效果优于单组分激发剂;低温不会明显降低地聚合物固化砂土的最终力学性能,仅延缓了地质聚合反应和结构的形成;碱性环境对地聚合物固化砂土的强度有促进作用;酸性环境及长时间暴露在空气中,会降低地聚合物固化砂土的强度。 相似文献
17.
Sina Kazemian Bujang B. K. Huat Hossein Moayedi 《Geotechnical and Geological Engineering》2012,30(4):753-759
Peat commonly occurs as extremely soft, wet, unconsolidated surface deposits that are integral parts of wetland systems. Cement is widely used for the stabilization of peat by deep mixing method. This paper presents the results of the shear strength parameters of study models (fibrous, hemic and sapric peats stabilized with columns formed by dry mixing method). The columns were formed of peat treated with cement in different proportions. Triaxial test was performed after curing the samples for 28?days to evaluate the shear strength parameters. The results showed that the shear strength of peats can be improved significantly by the installation of cement stabilized soil columns. The amount of cement used to form the column and its diameter were observed to influence the strain–stress graph of peat reinforced. Furthermore, the result showed that the effect of cement was the highest on sapric peat due to its physico-chemical properties. 相似文献
18.
P. K. Kolay M. R. Aminur S. N. L. Taib M. I. S. Mohd Zain 《Geotechnical and Geological Engineering》2011,29(6):1135-1141
This paper describes a study on tropical peat soil stabilization to improve its physical properties by using different stabilizing
agents. The samples were collected from six different locations of Sarawak, Malaysia, to evaluate their physical or index
properties. Out of them, sample having the highest percentage of organic content has been selected for stabilization purposes.
In this study, ordinary portland cement (OPC), quick lime (QL), and class F fly ash (FA) were used as stabilizer. The amount
of OPC, QL, and FA added to the peat soil sample, as percentage of dry soil mass, were in the range of 5–20%; 5–20% and 2–8%,
respectively for the curing periods of 7, 14, and 28 days. The Unconfined Compressive Strength (UCS) test was carried out
on treated/stabilized samples with the above mentioned percentages of the stabilizer and the result shows that the UCS value
increases significantly with the increase of all stabilizing agent used and also with curing periods. However, in case of
FA and QL, the UCS value increases up to 15 and 6%, respectively with a curing period of 28 days but decreases rather steady
beyond this percentage. Some UCS tests have been conducted with a mixture of FA and QL to study the combined effect of the
stabilizer. In addition, Scanning Electron Microscope (SEM) study was carried out on original peat soil and FA, as well as
some treated samples in order to study their microstructures. 相似文献
19.
加锚节理岩体有着复杂的细部结构和力学行为,常规的数值模型很难满足模拟这种力学行为的要求。进一步发展了笔者建立的加锚岩体的复合单元法,提出加锚节理岩体的复合单元法研究。在不考虑锚杆、节理等细部结构的情况下划分网格,分别定义了加锚岩体复合单元、不连续岩体复合单元和加锚节理岩体复合单元,并建立了其数值模型。同时,在复合单元中还定义了不同材料介质的子单元用来模拟加锚节理岩体内复杂的细部构造。对加锚节理复合单元法进行了理论推导和算例研究,通过与常规有限单元法计算结果的比较,表明了加锚节理岩体复合单元法的合理性,同时也突出体现了其前处理简便的优势。 相似文献
20.
采用磷酸镁水泥（MPC）对铅污染土进行固化/稳定化处理。基于无侧限抗压强度试验、渗透试验和浸出试验,研究了养护龄期和铅含量对污染土固稳性能的影响规律。试验结果表明：固化土的强度随养护龄期增加而增大,渗透系数和浸出浓度减小,7 d龄期的固化土强度和浸出浓度分别为0.36 MPa、1.75 mg/L,均满足环境安全标准;铅含量对固化土的强度及渗透特性的影响均存在临界值,为500 mg/kg。铅含量低于临界值时,固化土的强度随着铅含量的增加而增加,渗透系数随着铅含量的增加而减小。浸出浓度随铅含量的增加而增加,但浸出浓度均低于浸出安全标准。压汞试验结果表明,随养护龄期的增大,固化土孔隙体积减小,铅含量不超过临界值时,固化土孔隙体积随着铅含量的增大而减小。扫描电镜试验结果表明：随着养护龄期的增加,土颗粒团聚化越明显,胶结程度加强;铅含量不超过临界值时,土颗粒团聚体增多。镁钾磷酸盐晶体（MKP）主要通过减少孔径大于0.1 ?m的孔隙体积来影响固化土的渗透特性。 相似文献