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1.
刘玉山  张大捷  易哲  颜廷舟 《岩土力学》2006,27(Z1):615-618
固化疏浚淤泥作为堤防填筑材料,既解决淤泥的处置,又可解决堤防建设中填土的缺乏。用灰渣胶凝材料(HAS)固化淤泥并测试固化淤泥土的主要物理力学性质,发现掺6 %灰渣胶凝材料固化后的淤泥土,在自然堆积28 d后的液塑限达到60 %,有机质含量降低到2 %,淤泥由原来的有机质高液限黏土(CHO)变成高液限粉质黏土(MH),其28 d的无侧限抗压强度普遍大于1.4 MPa,凝聚力c≥100 kPa,内摩擦角?>35°,渗透系数小于10-6 cm/s,远高于提防填筑材料的标准,表明灰渣胶凝材料固化改性淤泥成为堤防填土是可行的。  相似文献   

2.
废弃黏土工程特性较差,难以作为路基材料进行资源化利用,还有工业废渣的产量日益增长,其利用率根本追不上产量,针对该问题研究了不同掺量矿渣-脱硫石膏-电石渣(GGBS-DG-CCS,GDC)固化剂对黏土力学性能和微观机理的影响。采用Design Expert中的box-behnken design(BBD)得出矿渣、脱硫石膏、电石渣的最佳配合比,通过无侧限抗压强度、劈裂抗拉强度和水稳试验评价了GDC固化土的宏观力学性能;然后采用SEM和XRD分析了GDC固化剂与黏土之间的相互作用机理,并与同掺量的传统水泥固化方案进行对比。结果表明:矿渣、脱硫石膏、电石渣的最佳配合比为11.93︰1.53︰6.01,GDC固化黏土的无侧限抗压强度均随固化剂掺量和养护龄期的增加而增大;相较于水泥固化土,GDC固化土具有更好的水稳定性,且随着养护龄期的增长,GDC固化土呈现出更高的抗压强度、抗劈裂性以及更低的脆性;SEM和XRD分析显示,GDC固化土在养护过程中会不断生成水化硅酸钙(C-S-H)、水化铝酸钙(C-A-H)等胶凝性水化物以及膨胀性水化产物钙矾石(Aft),与水泥土相比,28 d龄期的GDC固化土微...  相似文献   

3.
地聚物胶凝材料能够替代水泥基胶凝材料作为固化剂应用于狭窄肥槽回填等工程问题中,有效降低水泥生产过程中的污染及能耗,但目前对于流态地聚物固化土胶凝材料的研究较少。采用3种新型绿色胶凝材料联合碱激发剂固化工程渣土形成流态地聚物固化土,通过对比其无侧限抗压强度,探究每种胶凝材料对于固化土强度特性的影响,同时建立强度预测模型,分析不同因素对于强度的影响程度。研究结果表明:固化土的强度随着碱激发剂模数的增加先提高后降低;固化土强度随着高炉矿渣(GGBS)、粉煤灰、稻壳灰掺量的增加均呈上升趋势,随着稻壳灰粒径的增长呈下降趋势;碱激发剂模数增至1.2、GGBS掺量增至10%、粉煤灰掺量增至8%和稻壳灰掺量增至11%时,固化土强度提升最为显著;强度预测模型预测结果的平均相对误差仅为5.57%,预测结果较为精准;预测模型中各层权值的计算结果表明养护龄期对于固化土强度影响最大,稻壳灰粒径影响程度最小。研究结果可以为固化土在实际工程的应用提供理论支持。  相似文献   

4.
天津滨海软土力学性质较差,不能直接满足工程需要,在软土中加入固化剂能有效提高软土的工程力学性能,但若在固化剂中再添加适量外加剂,又能再次提高固化土的强度。本文以石灰作为主剂,水泥、石膏作为辅剂改良天津滨海软土,以无侧限抗压强度作为固化效果判断标准,同时进行相应的微观结构测试,并对破坏后的试样进行抗压试验。试验结果表明:水泥的最佳掺量仅随石灰掺量不同而变化,如12%的石灰固化土中,水泥掺量不超过3%可以最好地提高石灰固化土强度; 石膏则不能改善土体强度,并且会使土体水稳定性差,遇水开裂。纯石灰固化土及掺外加剂的石灰固化土都是低压缩性土,各种力学性质都得到明显提高,其破坏形式为脆性破坏,破坏后强度很低且不能恢复,在实践中值得重视。微观结构分析表明:固化土中有CSH网状胶凝(水化硅酸钙)、针状钙矾石、无定形文石(CaCO3)、Ca(OH)2晶体等能够填充孔隙、胶结颗粒的物质生成,有效、适量的生成物有利于固化土强度的提高。土体中总孔隙个数及总颗粒个数都随荷载的增加而增多,孔隙面积、孔隙等效直径及颗粒等效直径都随荷载的增加而减少。  相似文献   

5.
城市河道淤泥特性及改良试验初探   总被引:4,自引:1,他引:3       下载免费PDF全文
以南京内秦淮河疏浚淤泥为例,通过土工试验、XRD和X射线荧光光谱试验等方法,研究了城市河道淤泥的物理性质、矿物成分、化学成分等特性。试验结果显示:秦淮河淤泥粘粒含量低、有机质含量极高,矿物成分主要有石英和少量粘土矿物等。为了实现淤泥的资源化处理,运用水泥、石灰无机固化材料对淤泥进行固化改良试验及改性土无侧限抗压强度试验,结果表明随着水泥掺量增加,水泥固化土由塑性破坏向脆性破坏过渡,破坏应变在1.8%~2.2%,而石灰固化土均表现为脆性破坏,且破坏应变小于水泥土,为1%左右。水泥固化土28d强度为670kPa,固化效果优于石灰,但略低于处理一般软土的固化土强度。研究结果对处置城市河道淤泥有一定参考价值。  相似文献   

6.
超微粒子水泥加固软土试验研究   总被引:1,自引:0,他引:1  
应用和研发各种固化材料,对软土进行固化和改性,以改善其工程特性是当今国际上研究的热点课题。通过室内试验,研究了一种新型超微粒子水泥材料(ALOFIX-MC,简称MC)加固软土的效果,分析了其加固和改性机制。试验中,MC以0 %、1 %、2 %、3 %、4 %和5 %的掺量分别掺入到水泥掺量15 %和石膏掺量2 %的软土试样中,配制了6组试样。室内无侧限抗压强度试验结果表明,在15 %掺量的普通水泥土中掺入少量MC就可以显著提高软土的强度和稳定性。扫描电镜(SEM)分析表明,MC的胶结填充作用和MC对水泥水化的促进、孔隙的填充以及其本身的表面吸水作用对加固效果有重要影响。研究成果为进一步提高水泥土的工程性质和减少常规水泥土中水泥掺量提供了一条新的途径。  相似文献   

7.
为研究超细水泥含量对水泥固化软土的早期力学性能的影响,本文通过在普通水泥中加入不同掺量的超细水泥组成复合水泥固化剂用以固化软土。具体研究不同超细水泥掺量、不同初始含水率、及不同养护围压条件下,复合水泥固化剂对固化软土早期抗压强度及刚度的影响。采用自制K0围压养护装置(施加不同轴向压力的方式)、无侧限抗压强度仪(UCS)、X射线衍射仪(XRD)、电镜扫描仪(SEM)和低场核磁共振孔隙测试仪(NMR)等试验手段获取复合水泥固化软土不同龄期的抗压强度、刚度及微观结构的变化规律,并揭示其固化机理。研究结果表明:(1)相同轴向压力作用下,随着超细水泥掺量的增加,固化软土的抗压强度和弹性模量均有提高,其中复合固化剂中的活性颗粒发生水化反应生成大量胶凝产物用以黏聚土颗粒和填充孔隙,惰性颗粒用于填充土颗粒间的孔隙;(2)随着含水率的提高,固化软土中孔相对发育,从而使固化软土结构致密性减弱,抗压强度降低;(3)在K0围压养护7d时,固化软土的抗压强度和弹性模量随着轴向压力的提高而增加,表明养护围压对软土颗粒的压缩作用能提高固化软土的密实性,同时围压对固化软土产生有效应力,与水化产物共同促进固化软土形成密实的土骨架,进而使其在7d内具有较高的抗压强度。基于试验结果,建立轴向压力、含水率和超细水泥掺量等多因素的固化软土强度预测公式,并提出复合水泥固化软土结构模型,为工程实践提供理论基础。  相似文献   

8.
海底淤泥具有特殊的土性特点,其固化研究尚处于起步阶段。GS固化剂是一种以工业固废为主要原料的适用于软土加固的绿色固化材料。本文开展了GS固化剂加固海底淤泥的应用研究。以香港某工程海底淤泥为加固对象,对比分析了GS固化剂和水泥的掺量、龄期对固化土无侧限抗压强度的影响。研究结果表明,相比于普通水泥,GS固化土的早期强度更高...  相似文献   

9.
利用工业固体废弃物碱渣和矿渣作为固化剂,水玻璃作为激发剂,对高含水率疏浚淤泥的强度性质进行试验研究,并通过X射线衍射测试探讨固化机理。研究表明,在对含水率为110%疏浚淤泥固化的正交试验中,碱渣、矿渣和水玻璃掺量越多固化土的无侧限抗压强度越大,影响3 d强度的因素主次关系为碱渣>水玻璃>矿渣,而7 d和28 d时变为水玻璃>碱渣>矿渣,水玻璃对28 d强度的影响显著。当水玻璃掺量一定而碱渣与矿渣总掺量相同时,碱渣对固化淤泥的作用强于矿渣。固化土中的水化产物包括钙矾石、水化氯铝酸钙、水钙沸石和水化硅酸钙等,其填充和胶结作用使淤泥强度得到提高。研究确定了满足一般填土工程要求的固化方案,为碱渣和矿渣作为高含水率淤泥固化剂的资源化利用提供理论依据和参数支持。  相似文献   

10.
为了验证固化剂GX08加固杭州海湖相软土的效果及考察有机质对水泥固化的不利影响,对固化土的强度特性进行了试验研究。结果表明,有机质的添加会显著阻碍固化土强度的增长,而固化剂GX08能有效增强固化土的强度;固化土强度与有机质含量存在二次函数关系,与水泥掺量呈线性关系,与固化剂GX08掺量和龄期都以对数函数的形式相关;将总灰水比C/W用于固化土强度模型的建立,通过对试验数据的分析与整理,建立了同时考虑固化土中有机质含量、水泥掺量、固化剂掺量和龄期影响的固化土综合强度预测模型。最后对模型进行了推广使用,验证了模型的适用性。  相似文献   

11.
谈云志  柯睿  陈君廉  吴军  邓永锋 《岩土力学》2020,41(4):1146-1152
淤泥富含有机质,分解后产生腐殖酸,进而影响淤泥固化效果。仅掺入12%水泥固化淤泥,当标准养护期超过60 d,其强度不增反减。联合掺入3%石灰和12%水泥,固化淤泥的pH值持续180 d处于10.5以上;无侧限抗压强度由750 kPa(养护期28 d)提升到1 500 kPa(120 d),说明借助石灰营造强碱性环境,可以提高水泥固化淤泥的强度;但养护到180 d后,其强度又降到1 250 kPa;钙离子浓度变化规律表明,这是由于腐殖酸溶蚀水泥和石灰的水化胶结物所致。借助偏高岭土卓越的火山灰反应能力,掺入3.0%偏高岭土,提升石灰(3%)?水泥(12%)固化淤泥的耐久性,发现180 d养护期内,其强度始终处于增长趋势,究其原因是偏高岭土富含无定形硅、铝氧化物,具有快速捕获氢氧化钙溶液中钙离子的能力,形成稳定的胶结物,而且不易受腐殖酸的侵蚀作用,证明偏高岭土能够有效提升石灰?水泥固化淤泥长期强度。  相似文献   

12.
GS(Gypsum-Slag)土体硬化剂是一种由水泥、钢渣、矿渣和脱硫石膏及其他外加剂组成的新型土体固化材料。将GS土体硬化剂和水泥两种固化剂固化土作为研究对象,通过室内无侧限抗压强度试验和电镜扫描试验,研究固化土的应力-应变曲线以及土质、固化剂掺量、龄期对固化土力学性能的影响,观察其微观结构,进而对比分析GS土体硬化剂和水泥的特性,并进行现场试验加以验证。研究结果表明:相比水泥土,GS固化土应力-应变曲线存在明显峰值;GS固化土和水泥土的强度均随着掺量和龄期正增长,且GS固化土的长期强度更高;GS固化土和水泥土变形模量分别是其抗压强度的31.11~77.24倍和23.24~71.62倍;GS固化土现场成桩的完整性优于水泥土。相比水泥土,GS固化土具有强度增长快、后期强度高、经济效益好的特点,可较好满足地下工程和路基工程等土体加固应用需求。  相似文献   

13.
The presence of heavy metals at high concentrations (percent levels) in soils has been a growing concern to human health and the environment, and the cement stabilization is considered to be an effective and practical approach to remediate such soils. The compressibility of such stabilized soils is an important consideration for redevelopment of the remediated sites for building and/or roadway construction. This paper investigates the effects of high levels of zinc concentration on the compressibility of natural clay stabilized by cement additive. Several series of laboratory compression (oedometer) tests were conducted on the soil specimens prepared with the zinc concentrations of 0, 0.1, 0.2, 0.5, 1, and 2 %, cement contents of 12 and 15 %, and curing time of 28 days. The results show that the yield stress and compression index at the post-yield state decrease with an increase in the zinc concentration regardless of the cement content. The observed results are attributed to the decrease in the cement hydration of the soil. Overall, this study demonstrates that the cementation structure of the soils is weakened, and the compressibility increases with the elevated zinc concentration, particularly at relatively high levels of zinc concentration.  相似文献   

14.
湖泊底泥改性固化的强度特性和微观结构   总被引:1,自引:0,他引:1  
将灰渣胶凝材料作为改性剂应用于湖泊环境疏浚底泥的固化处理,研究了改性淤泥的强度特性,探讨灰渣胶凝材料对淤泥的改性机理。改性淤泥的抗压强度试验结果表明,当灰渣胶凝材料质量掺入比为5 %时,能够显著提高改性淤泥的各个龄期强度;当掺入质量比为12.5 %时,28天强度可以达到1.55 MPa。改性淤泥的早期强度较高,后期强度能持续增长,同时具有良好的耐水浸泡性能。SEM分析表明,灰渣胶凝材料能与底泥颗粒中的活性物质发生火山灰反应,形成高强难溶的胶结物,使改性淤泥中大孔隙数量减少,改善了淤泥土颗粒之间的胶结性能。这说明灰渣胶凝材料是一种性能优异的底泥改性材料。  相似文献   

15.
通过系列室内试验,研究了硫酸盐长期浸泡环境下GGBS-MgO固化黏土的物理和力学性质及微观特征变化规律,并与水泥固化黏土进行对比,揭示了GGBS-MgO固化黏土抵抗硫酸盐侵蚀的机制。与水泥固化黏土相比,硫酸盐浸泡条件下GGBS-MgO固化黏土表面完整度较好;质量变化率在浸泡120 d时仅为水泥固化黏土的0.25倍;固化黏土体pH略小于同期水泥固化黏土;浸泡初期GGBS-MgO固化黏土强度增长达20%,同周期时无侧限抗压强度较水泥固化黏土高15%~80%。X射线衍射试验(XRD)表明,硫酸盐侵蚀下GGBS-MgO固化黏土中水化硅酸钙(C-S-H凝胶)的峰值高于水泥固化黏土,而钙矾石(AFt)的XRD图谱峰值明显低于水泥固化黏土。电镜扫描试验结果表明,两种固化黏土中钙矾石形态明显不同:钙矾石在水泥固化黏土中以团聚型晶体存在,可具较强膨胀性,而在GGBS-MgO固化黏土中则以细短形态分布于颗粒间,可有效填充试样孔隙,使其具备良好的抗硫酸盐侵蚀能力。  相似文献   

16.
王领  沈水龙  白云  彭少杰 《岩土力学》2010,31(3):743-747
对于使用水泥与上海黏性土进行混合加固的土体,其强度增长特性与水泥含量、加固土的初期pH值、养护时间有关。以上海4类黏土为研究对象,对加固土的强度增长特性进行了试验研究;探讨了加固土的养护时间、水泥含量、初期pH等与加固土强度的关系。试验结果表明,当上海黏土中水泥含量或者加固土的初期pH值大于某一临界值时,水泥加固土的强度将迅速增加,对于上海黏土,该临界pH值为11.7,对应的水泥含量为17%~20%。但当水泥含量达到一定值后,它对土体的pH值的影响开始变小,而且水泥土的强度趋于稳定的时间变长。  相似文献   

17.
Gypsum Induced Strength Behaviour of Fly Ash-Lime Stabilized Expansive Soil   总被引:1,自引:1,他引:0  
Physical and engineering properties of soil are improved with various binders and binder combinations. Fly ash and lime are commonly used to improve the properties of expansive soils. An attempt has been made, in this paper, to examine the role of gypsum on the physical and strength behaviour of fly ash-lime stabilized soil. The change in strength behaviour is studied at different curing periods up to 90 days, and the mechanism is elucidated through pH, mineralogical, microstructural and chemical composition study. The strength of soil-fly ash mixture has improved marginally with the addition of lime up to 4 % lime and with curing period for 28 day. Significant increase in strength has been observed with 6 % lime and enhanced significantly after curing for 90 days. The variations in the strength of soil with curing period is due to cation exchange and flocculation initially, and binding of particles with cementitious compounds formed after curing. With addition of 1 % gypsum to soil-fly ash-lime, the strength gain is accelerated as seen at 14 day curing. The accelerated strength early is due to formation of compacted structure with growth of ettringite needles within voids. However, strength at curing for 28 day has been declined due to annoyance of clay matrix with the increase in size of ettringite needle; and again increased after curing for 90 days. The rearrangement of clay matrix and suppression of sulphate effects with formation of cementitious compounds are observed and found to be the main responsible factors for strength recovered.  相似文献   

18.
Silica fume is identified as a pozzolan and supplementary cementitious material that can utilize to improve the mechanical properties of stabilized soil with cement. Silica fume wherein mixes with cemented soil in a proper dosage, it is susceptible to induce pozzolanic effect in cemented soil due to its fineness and high content of SiO2 and Al2O3. The pozzolanic effect is vital to ensure ongoing strength of stabilized soil with cement. Up to now, stabilization of clay with cement and silica fume is not completely explored. This paper investigates: (i) the capability of utilizing the silica fume as a supplementary material for cement to maximize the filler and pozzolanic effects of compacted and stabilized soil (ii) the mechanical properties of compacted and stabilized clay with various proportions of cement and silica fume. For this purpose, a total of 120 untreated and stabilized soil admixtures were prepared by replacing ordinary Portland cement with silica fume. The influence of partial replacement of cement with silica fume on the bearing capacity, shear and compressive strength of compacted and stabilized soil was investigated. To achieve such aims, the stabilized soil specimens were examined in laboratory under direct shear, unconfined compression and California bearing ratio tests. Based on the findings of this paper the 28-day UCS of the stabilized soil with 2% partial substitution of cement with silica fume is almost 3.5-fold greater than that of the untreated. It was found that the optimum mix design for the stabilized soil is 6% cement and 2% silica fume. In conclusion, a notable discovery is that the partial substitution of cement with 2% silica fume in the optimum mix design significantly refined the pore spaces as a result of pozzolanic activity and filler effect of silica fume.  相似文献   

19.
Clay soils, especially clay soils of high or very high swelling potential often present difficulties in construction operations. However, the engineering properties of these clay soils can be enhanced by the addition of cement, thereby producing an improved construction material. Higher strength loss of cement stabilized clay soils after soaking in water is attributed to water absorbing capacity of the clay fraction (e.g. montmorillonite). Kaolinite and illitic soils are largely inert and resist to water penetration. These clays generally develop satisfactory strengths resulting to low strength reduction [Croft, 1967]. The swelling clays such as bentonite soaked in water, due to environmental conditions, result to volume increase causing macro and micro-fracturing in engineering structures. These fractures accelerate water penetration and consequently cause greater strength loss [Sällfors and Öberg-Högsta, 2002]. The water intrusion during soaking creates swelling and disrupts the cement bonds. The development of internal and external force systems in soil mass, due to soaking conditions, establish the initiation of slaking. Internal force system of a stabilized clayey soil consists of the resultant stresses established by the bonding potential of a cementing agent and the swelling potential of a clay fraction. In an effort to study this influence of soaking conditions and final absorbed water content on the stabilization parameters (cement, compaction, curing time), both unconfined compressive strength and slaking (durability) tests were carried out on two different cement stabilized clayey mixtures consisted of active bentonite, kaolin and sand.  相似文献   

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