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1.
Pre-eruptive conditions and degassing processes of the AD 79 plinian eruption of Mt. Vesuvius are constrained by systematic F and Cl measurements in melt inclusions and matrix glass of pumice clasts from a complete sequence of the pumice-fallout deposits. The entire ‘white pumice’ (WP) magma and the upper part of the ‘grey pumice’ (GP) magma were saturated relative to sub-critical fluids (a Cl-rich H2O vapour phase and a brine), with a Cl melt content buffered at ~ 5300 ppm, and a mean H2O content of ~ 5%. The majority of the GP magma was not fluid-saturated. From these results it can be estimated that the WP magma chamber had a low vertical extent (< 500 m) and was located at a depth of ~ 7.5 km while the GP magma reservoir was located just beneath the WP one, but its vertical extent cannot be constrained. This is approximately two times deeper than previous estimates. H2O degassing during the WP eruption followed a typical closed-system evolution, whereas GP clasts followed a more complex degassing path. Contrary to H2O, Cl was not efficiently degassed during the plinian phase of the eruption.

This study shows that F and Cl behave as incompatible elements in fluid-undersaturated phonolitic melts. H2O saturation is necessary for a significant partitioning of Cl into the fluid phase. However, Cl cannot be extracted in significant quantity from phonolitic melts during rapid H2O degassing, e.g. during plinian eruptions, due to kinetics effects. Halogen contents are better preserved in volcanic glass (melt inclusions or matrix glass) than H2O, therefore the combined analysis of both volatile species is required for reliable determination of pre-eruptive conditions and syn-eruptive degassing processes in magmas stored at shallow depths.  相似文献   


2.
This study assesses the effect of decompression rate on two processes that directly influence the behavior of volcanic eruptions: degassing and permeability in magmas. We studied the degassing of magma with experiments on hydrated natural rhyolitic glass at high pressure and temperature. From the data collected, we defined and characterized one degassing regime in equilibrium and two regimes in disequilibrium. Equilibrium bubble growth occurs when the decompression rate is slower than 0.1 MPa s–1, while higher rates cause porosity to deviate rapidly from equilibrium, defining the first disequilibrium regime of degassing. If the deviation is large enough, a critical threshold of super-saturation is reached and bubble growth accelerates, defining the second disequilibrium regime. We studied permeability and bubble coalescence in magma with experiments using the same rhyolitic melt in open degassing conditions. Under these open conditions, we observed that bubbles start to coalesce at ~43 vol% porosity, regardless of decompression rate. Coalescence profoundly affects bubble texture and size distributions, and induces the melt to become permeable. We determined coalescence to occur on a time scale (~180 s) independent of decompression rate. We parameterized and incorporated our experimental results into a 1D conduit flow model to explore the implications of our findings on eruptive behavior of rhyolitic melts with low crystal contents stored in the upper crust. Compared to previous models that assume equilibrium degassing of the melt during ascent, the introduction of disequilibrium degassing reduces the deviation from lithostatic pressure by ~25%, the acceleration at high porosities (>50 vol%) by a factor 5, and the associated decompression rate by an order of magnitude. The integration of the time scale of coalescence to the model shows that the transition between explosive and effusive eruptive regimes is sensitive to small variations of the initial magma ascent speed, and that flow conditions near fragmentation may significantly be affected by bubble coalescence and gas escape.Editorial responsibility: D. Dingwell  相似文献   

3.
Gas emissions from Erebus volcano, Antarctica, were measured by open-path Fourier transform infrared spectroscopy to understand degassing of its magmatic system. Two degassing phonolite lava lakes were present in the summit crater during observation in December 2004. We report analyses of H2O, CO2, CO, SO2, HF, HCl and OCS, (in order of molar abundance) in the plumes. Variations in the proportions of these species strongly reflect the dynamics of degassing, and sourcing of gas from different depths in the magmatic network. The highest observed ratios of CO2 and H2O are consistent with gas extracted from the melt at a depth of up to ∼ 2 km below the lava lakes. Magma degassing above this depth contributes to a higher H2O/CO2 proportion in the airborne plume. The ratio therefore reflects the balance of deeper vs. shallower contributions of volatiles and, possibly, a combination of closed- and open-system degassing. We observe a strong contrast in HF content in emissions from the two lava lakes, which we attribute to differing levels of magma ascent and/or cooling and crystallization of the magma supply. Fluxes of all gas species were determined using independent SO2 flux determinations and measured gas ratios. In the case of CO2 and water, ∼ 1 and ∼ 0.4 m3 s− 1, respectively, of parental basanite magma are required to sustain the calculated output. The discrepancy between the two figures is readily explained by sequestration of part of the magma supply at depth such that it only partially degasses its complement of water.  相似文献   

4.
The style of magma eruption depends strongly on the character of melt degassing and foaming. Depending on the kinetics of these processes the result can be either explosive or effusive volcanism. In this study the kinetics of foaming due to the internal stresses of gas expansion of two types of obsidian have been investigated in time series experiments (2 min-24 h) followed by quenching the samples. The volumetric gas-melt ratio has been estimated through the density measurements of foamed samples.The variation of gas volume (per unit or rhyolite melt volume) with time may be described by superposition of two exponentials responsible for gas generation and gas release processes respectively. An observed difference in foaming style in this study is interpreted as the result of variations in initial contents of microlites that serve as bubble nucleation centers during devolatilization of the melts. Quantitatively the values of the gas generation rate constants (k g) are more than an order of magnitude higher in microlite-rich obsidian than in microlite-free obsidian. Possible origins of differences in the degassing style of natural magmas are discussed in the light of bubble nucleation kinetics in melts during foaming. In a complementary set of experiments the mechanical response of vesicular melt to external shear stress has been determined in a concentric cylinder viscometer. The response of vesicular melt to the pulse of shear deformation depends on the volume fraction of bubbles. The obtained response function can be qualitatively described by a Burgers body model. The experimental shear stress response function for bubble-bearing melt has an overshoot due to the strain-dependent rheology of a twophase liquid with viscously deformable inclusions.  相似文献   

5.
During June 1999, we measured the amplitude and rate (number of events per second) at which gas exited the vent at Stromboli volcano as discrete gas bursts or puffs. This allowed us to identify two styles of gas burst (puffing) activity. The first is characterized by frequent, rapidly rising puffs, the second by less frequent, slowly rising puffs. Each style persisted over 5–40-min-long durations and was associated with a high and low number of strombolian explosions per hour, respectively. Each period was also associated with characteristic delay times between the arrival of the infrasonic and thermal signals during strombolian explosions; the delays were longer during vigorous puffing periods. To explain our observations, we propose a model in which the degassing process cycles between vigorous and weak degassing phases. During vigorous degassing phases, bubble layers ascend the conduit at a frequency of 0.5–1.0 s−1. This high degassing level reflects a gas-rich magma column and leads to an increased rate in the formation of shallow foams and, hence, an increase in puffing and explosive activity, as well as a higher free surface level and/or gas jet velocity. During weak phases, bubble layers ascend the conduit at a reduced frequency of 0.2–0.3 s−1. During such times the magma column is poor in gas. This leads to a decreased rate of foam layer formation and hence a reduction in puffing and explosive activity, as well as a lower free surface level and/or gas jet velocity. Variations in puffing activity can thus be used to track changes in the rate at which the shallow system is supplied by fresh, gas-rich magma. Our observations indicate that the two degassing styles last from 5 to 40 min and that the switch from one to the other occurs over a matter of minutes.  相似文献   

6.
This paper deals with sulfur, chlorine and fluorine abundances in the eruptive volcanic plume of the huge October 2002-January 2003 eruption of Mount Etna, aiming at relating the relevant compositional variations observed throughout with changes in eruption dynamics and degassing mechanisms. The recurrent sampling of plume acidic volatiles by filter-pack methodology revealed that, during the study period, S/Cl and Cl/F ratios ranged from 0.1-6.8 and 0.9-5.6, respectively. Plume S/Cl ratios increased by a factor of ∼10 as volcanic activity drifted from paroxysmal lava fountaining (mid- and late November) to passive degassing and minor effusion (early January), and then decreased to the low values (S/Cl=0.1) typical of the final stages of the eruption. Parallel variations in chlorine to fluorine ratios were also observed. A theoretical model is proposed for quantitative interpretation of these changes in plume composition. The model calculates the composition of a volatile phase exsolving from an ascending Etna magma, based on knowledge of solubilities and abundances in the undegassed melt of sulfur and halogens [T.M. Gerlach, EOS 72 (1991), 249, 254-255]. According to this model, degassing of Etnean basaltic melt at high pressures and depths (>100 MPa, 3 km) is likely to release a CO2+H2O-rich vapor phase with S/Cl molar ratios ∼1. Extensive sulfur and chlorine degassing from the melt would take place at shallower depth (P<20 MPa, 0.6 km), with S/Cl ratios in the vapor phase increasing as pressure drops to 0.1 MPa. Comparisons between model compositions and volcanic plume data demonstrate that the chemical trends observed during the eruption may be explained by increased degassing due to depressurization of a basaltic magma batch ascending toward the surface.  相似文献   

7.
Among the series of eruptions at Miyakejima volcano in 2000, the largest summit explosion occurred on 18 August 2000. During this explosion, vesiculated bombs and lapilli having cauliflower-like shapes were ejected as essential products. Petrological observation and chemical analyses of the essential ejecta and melt inclusions were carried out in order to investigate magma ascent and eruption processes. SEM images indicate that the essential bombs and lapilli have similar textures, which have many tiny bubbles, crystal-rich and glass-poor groundmass and microphenocrysts of plagioclase, augite and olivine. Black ash particles, which compose 40% of the air-fall ash from the explosion, also have similar textures to the essential bombs. Whole-rock analyses show that the chemical composition of all essential ejecta is basaltic (SiO2=51–52 wt%). Chemical analyses of melt inclusions in plagioclase and olivine phenocrysts indicate that melt in the magma had 0.9–1.9 wt% H2O, <0.011 wt% CO2, 0.04–0.17 wt% S and 0.06–0.1 wt% Cl. The variation in volatile content suggests degassing of the magma during ascent up to a depth of about 1 km. The ratio of H2O and S content of melt inclusions is similar to that of volcanic gas, which has been intensely and continuously emitted from the summit since the end of August 2000, indicating that the 18 August magma is the source of the gas emission. Based on the volatile content of the melt inclusions and the volcanic gas composition, the initial bulk volatile content of the magma was estimated to be 1.6–1.9 wt% H2O, 0.08–0.1 wt% CO2, 0.11–0.17 wt% S and 0.06–0.07 wt% Cl. The basaltic magma ascended from a deeper chamber (10 km) due to decrease in magma density caused by volatile exsolution with pressure decrease. The highly vesiculated magma, which had at least 30 vol% bubbles, may have come into contact with ground water at sea level causing the large explosion of 18 August 2000.Editorial responsibility: S. Nakada, T. DuittAn erratum to this article can be found at  相似文献   

8.
Volcanic gas samples were collected from July to November 1985 from a lava pond in the main eruptive conduit of Pu'u O'o from a 2-week-long fissure eruption and from a minor flank eruption of Pu'u O'o. The molecular composition of these gases is consistent with thermodynamic equilibrium at a temperature slightly less than measured lava temperatures. Comparison of these samples with previous gas samples shows that the composition of volatiles in the magma has remained constant over the 3-year course of this episodic east rift eruption of Kilauea volcano. The uniformly carbon depleted nature of these gases is consistent with previous suggestions that all east rift eruptive magmas degas during prior storage in the shallow summit reservoir of Kilauea. Minor compositional variations within these gas collections are attributed to the kinetics of the magma degassing process.  相似文献   

9.
Causes and consequences of pressurisation in lava dome eruptions   总被引：3，自引：0，他引：3  
High total and fluid pressures develop in the interior of high-viscosity lava domes and in the uppermost parts of the feeding conduit system as a consequence of degassing. Two effects are recognised and are modelled quantitatively. First, large increases in magma viscosity result from degassing during magma ascent. Strong vertical gradients in viscosity result and large excess pressures and pressure gradients develop at the top of the conduit and in the dome. Calculations of conduit flow show that almost all the excess pressure drop from the chamber in an andesitic dome eruption occurs during the last several hundred metres of ascent. Second, microlites grow in the melt phase as a consequence of undercooling caused by gas loss. Rapid microlite growth can cause large excess fluid pressures to develop at shallow levels. Theoretically closed-system microlite crystallization can increase local pressure by a few tens of MPa, although build up of pressure will be countered by gas loss through permeable flow and expansion by viscous flow. Microlite crystallization is most effective in causing excess gas pressures at depths of a few hundred metres in the uppermost parts of the conduit and dome interior. Some of the major phenomena of lava dome eruptions can be attributed to these pressurisation effects, including spurts of growth, cycles of dome growth and subsidence, sudden onset of violent explosive activity and disintegration of lava during formation of pyroclastic flows. The characteristic shallow-level, long-period and hybrid seismicity, characteristic of dome eruptions, is attributed to the excess fluid pressures, which are maintained close to the fracture strength of the dome and wallrock, resulting in fluid movement during formation of tensile and shear fractures within the dome and upper conduit.  相似文献   

10.
Vulcanian eruptions are common at many volcanoes around the world. Vulcanian activity occurs as either isolated sequences of eruptions or as precursors to sustained explosive events and is interpreted as clearing of shallow plugs from volcanic conduits. Breadcrust bombs characteristic of Vulcanian eruptions represent samples of different parts of these plugs and preserve information that can be used to infer parameters of pre-eruption magma ascent. The morphology and preserved volatile contents of breadcrust bombs erupted in 1999 from Guagua Pichincha volcano, Ecuador, thus allow us to constrain the physical processes responsible for Vulcanian eruption sequences of this volcano. Morphologically, breadcrust bombs differ in the thickness of glassy surface rinds and in the orientation and density of crack networks. Thick rinds fracture to create deep, widely spaced cracks that form large rectangular domains of surface crust. In contrast, thin rinds form polygonal networks of closely spaced shallow cracks. Rind thickness, in turn, is inversely correlated with matrix glass water content in the rind. Assuming that all rinds cooled at the same rate, this correlation suggests increasing bubble nucleation delay times with decreasing pre-fragmentation water content of the melt. A critical bubble nucleation threshold of 0.4–0.9 wt% water exists, below which bubble nucleation does not occur and resultant bombs are dense. At pre-fragmentation melt H2O contents of >∼0.9 wt%, only glassy rinds are dense and bomb interiors vesiculate after fragmentation. For matrix glass H2O contents of ≥1.4 wt%, rinds are thin and vesicular instead of thick and non-vesicular. A maximum measured H2O content of 3.1 wt% establishes the maximum pressure (63 MPa) and depth (2.5 km) of magma that may have been tapped during a single eruptive event. More common H2O contents of ≤1.5 wt% suggest that most eruptions involved evacuation of ≤1.5 km of the conduit. As we expect that substantial overpressures existed in the conduit prior to eruption, these depth estimates based on magmastatic pressure are maxima. Moreover, the presence of measurable CO2 (≤17 ppm) in quenched glass of highly degassed magma is inconsistent with simple models of either open- or closed-system degassing, and leads us instead to suggest re-equilibration of the melt with gas derived from a deeper magmatic source. Together, these observations suggest a model for the repeated Vulcanian eruptions that includes (1) evacuation of the shallow conduit during an individual eruption, (2) depressurization of magma remaining in the conduit accompanied by open-system degassing through permeable bubble networks, (3) rapid conduit re-filling, and (4) dome formation prior to the subsequent explosion. An important part of this process is densification of upper conduit magma to allow repressurization between explosions. At a critical overpressure, trapped pressurized gas fragments the nascent impermeable cap to repeat the process.  相似文献   

11.
Stromboli volcano has been in continuous eruption for several thousand years without major changes in the geometry and feeding system. The thermal structure of its upper part is therefore expected to be close to steady state. In order to mantaim explosive activity, magma must release both gas and heat. It is shown that the thermal and gas budgets of the volcano lead to consistent conclusions. The thermal budget of the volcano is studied by means of a finite-element numerical model under the assumption of conduction heat transfer. It is found that the heat loss through the walls of an eruption conduit is weakly sensitive to the dimensions of underlying magma reservoirs and depends mostly on the radius and length of the conduit. In steady state, this heat loss must be balanced by the cooling of magma which flows through the system. For the magma flux of about 1 kg s-1 corresponding to normal Strombolian activity, this requires that the conduits are a few meters wide and not deeper than a few hundred meters. This implies the existence of a magma chamber at shallow depth within the volcanic edifice. This conclusion is shown to be consistent with considerations on the thermal effects of degassing. In a Strombolian explosion, the mass ratio of gas to lava is very large, commonly exceeding two, which implies that the thermal evolution of the erupting mixture is dominated by that of the gas phase. The large energy loss due to decompression of the gas phase leads to decreased eruption temperatures. The fact that lava is molten upon eruption implies that the mixture does not rise from more than about 200 m depth. To sustain the magmatic and volcanic activity of Stromboli, a mass flux of magma of a few hundred kilograms per second must be supplied to the upper parts of the edifice. This represents either the rate of magma production from the mantle source feeding the volcano or the rate of magma overturn in the interior of a large chamber.  相似文献   

12.
Dacitic magma, a mixture of high-temperature (T) aphyric magma and low-T crystal-rich magma, was erupted during the 1991–1995 Mount Unzen eruptive cycle. Here, the crystallization processes of the low-T magma were examined on the basis of melt inclusion analysis and phase relationships. Variation in water content of the melt inclusions (5.1–7.2 wt% H2O) reflected the degassing history of the low-T magma ascending from deeper levels (250 MPa) to a shallow magma chamber (140 MPa). The ascent rate of the low-T magma decreased markedly towards the emplacement level as crystal content increased. Cooling of magma as well as degassing-induced undercooling drove crystallization. With the decreasing ascent rate, degassing-induced undercooling decreased in importance, and cooling became more instrumental in crystallization, causing local and rapid crystallization along the margin of the magma body. Some crystals contain scores of melt inclusions, whereas there are some crystals without any inclusions. This heterogeneous distribution suggests the variation in the crystallization rate within the magma body; it also suggests that cooling was dominant cause for melt entrapment. Numerical calculations of the cooling magma body suggest that cooling caused rapid crystal growth and enhanced melt entrapment once the magma became a crystal-rich mush with evolved interstitial melt. The rhyolitic composition of melt inclusions is consistent with this model.Editorial responsibility: H Shinohara  相似文献   

13.
 Lascar Volcano (5592 m; 23°22'S, 67°44'W) entered a new period of vigorous activity in 1984, culminating in a major explosive eruption in April 1993. Activity since 1984 has been characterised by cyclic behaviour with recognition of four cycles up to the end of 1993. In each cycle a lava dome is extruded in the active crater, accompanied by vigorous degassing through high-temperature, high-velocity fumaroles distributed on and around the dome. The fumaroles are the source of a sustained steam plume above the volcano. The dome then subsides back into the conduit. During the subsidence phase the velocity and gas output of the fumaroles decrease, and the cycle is completed by violent explosive activity. Subsidence of both the dome and the crater floor is accommodated by movement on concentric, cylindrical or inward-dipping conical fractures. The observations are consistent with a model in which gas loss from the dome is progressively inhibited during a cycle and gas pressure increases within and below the lava dome, triggering a large explosive eruption. Factors that can lead to a decrease in gas loss include a decrease in magma permeability by foam collapse, reduction in permeability due to precipitation of hydrothermal minerals in the pores and fractures within the dome and in country rock surrounding the conduit, and closure of open fractures during subsidence of the dome and crater floor. Dome subsidence may be a consequence of reduction in magma porosity (foam collapse) as degassing occurs and pressurisation develops as the permeability of the dome and conduit system decreases. Superimposed upon this activity are small explosive events of shallow origin. These we interpret as subsidence events on the concentric fractures leading to short-term pressure increases just below the crater floor. Received: 12 December 1996 / Accepted: 6 May 1997  相似文献   

14.
To investigate the relationship between volatile abundances and eruption style, we have analyzed major element and volatile (H2O, CO2, S) concentrations in olivine-hosted melt inclusions in tephra from the 2000 yr BP eruption of Xitle volcano in the central Trans-Mexican Volcanic Belt. The Xitle eruption was dominantly effusive, with fluid lava flows accounting for 95% of the total dense rock erupted material (1.1 km3). However, in addition to the initial, Strombolian, cinder cone-building phase, there was a later explosive phase that interrupted effusive activity and deposited three widespread ash fall layers. Major element compositions of olivine-hosted melt inclusions from these ash layers range from 52 to 58 wt.% SiO2, and olivine host compositions are Fo84–86. Water concentrations in the melt inclusions are variable (0.2–1.3 wt.% H2O), with an average of 0.45±0.3 (1σ) wt.% H2O. Sulfur concentrations vary from below detection (50 ppm) to 1000 ppm but are mostly ≤200 ppm and show little correlation with H2O. Only the two inclusions with the highest H2O have detectable CO2 (310–340 ppm), indicating inclusion entrapment at higher pressures (700–900 bars) than for the other inclusions (≤80 bars). The low and variable H2O and S contents of melt inclusions combined with the absence of less soluble CO2 indicates shallow-level degassing before olivine crystallization and melt inclusion formation. Olivine morphologies are consistent with the interpretation that most crystallization occurred rapidly during near-surface H2O loss. During cinder cone eruptions, the switch from initial explosive activity to effusive eruption probably occurs when the ascent velocity of magma becomes slow enough to allow near-complete degassing of magma at shallow depths within the cone as a result of buoyantly rising gas bubbles. This allows degassed lavas to flow laterally and exit near the base of the cone while gas escapes through bubbly magma in the uppermost part of the conduit just below the crater. The major element compositions of melt inclusions at Xitle show that the short-lived phase of renewed explosive activity was triggered by a magma recharge event, which could have increased overpressure in the storage reservoir beneath Xitle, leading to increased ascent velocities and decreased time available for degassing during ascent.  相似文献   

15.
In addition to traditional degassing of the melt in the subsurface magma chambers of the “dormant” El’brus volcano, alsodegassing through pores and microcracks that occur in the top of magma chambers has also been detected. It is proven by studies of compactness, porosity, and permeability of the rocks. The speeds at which gases (H, He, H2S, CO2, F, and Cl) pass through gneiss and volcanic rocks were estimated. Magma chambers on the ground surface are expressed in stable thermal anomalies revealed by night-time thermal sounding from an NOAA satellite. The presence of magma chambers at depths of 2–12 km was proven by magnetotelluric sounding [Sobisevich et al., 2003] and gravity studies. In addition to occasional “columns” of bright-white fluorescence above the thermal anomalies, aerosol “clouds” and hydrogen flows were detected by lidar and hydrogen surveying [Alekseev et al., 2007, 2009]. Observation at the same sites detected steam outbursts occurring periodically, the snow-ice cover thaws and the smell of hydrogen sulfide is felt. Geochemical characteristics of degassing were studied by snow sampling from up to 1 m deep pits. They were taken within contours of the thermal anomalies, above active fault zones, in the sites of bright-white fluorescence “columns,” and on a new fumarole locality. It is shown that the degassing of melt was accompanied by the gas transporting many elements (Li, B, Si, P, S, Ca, Zn, Pb, Mo, Ba, W, Hg, Ag, U, Th, I, Au, and Pt) in a fine-grained state (a few microns or possibly nanometers) with an active participation of F and Cl. Native platinum, chalcopyrite, halite, sylvite, barite, gypsum, zircon, opal, chlorinated organics, etc. were for the first time discovered in the Mt. El’brus area using electron microscope studies of solid residue from dehydrated snow samples. “Hidden” ore mineralization genetically related to degassing of melts enriched in ore elements may be supposedly found in paleo- and present-day areas of volcanic activity.  相似文献   

16.
The onset of double diffusion convection (DDC) is modeled in a two-dimensional case in respect to magma chambers. The viscosity model for the melt takes into account the effects of temperature and concentration of the dissolved component (H2O). The upper boundary of the convecting magma chamber is assumed to be anhydrous and at constant temperature, whereas the lower boundary is treated as being hydrous permeable with a temperature greater than that within the upper boundary. The case of positive compositional and thermal buoyancy of melt is studied assuming a H2O diffusion coefficient small in comparison with thermal diffusivity. The DDC has been modeled using a system of equations solved by the finite difference method on a square grid. The convective pattern evolution has been studied for fixed boundary conditions as well as for cooling and degassing. Due to the higher viscosity in the upper zone, the upper boundary layer is thicker than the lower one. The variation of water concentration in this zone of the convective cell can be significant. In nature, the high gradient of water concentration can be responsible for the observed variations of water content in minerals crystallized from a granite melt (e.g., biotite). Because of a high Lewis number (= 100), temperature variations in the magma chamber decay much faster than the water concentration. In this case the intensive convection can continue at a constant temperature due to the non-zero water content in the chamber. In principle, the effect can be applied to the formation of magmatic bodies. If the cooling and degassing system reaches a uniform temperature distribution prior to the crystallization temperature, water content throughout the body may still remain variable.  相似文献   

17.
Magma degassing at Soufrière Hills Volcano (SHV) is characterised by an almost permanent SO2 flux and a HCl production rate which mainly depends on dome growth rate. Degassing processes have been studied through textural, H2O and halogen analyses of clasts collected between 1995 and 2006 on the dome and in pyroclastic flows and vulcanian eruption deposits. Cl, Br and I are strongly depleted in melts during H2O degassing with no significant Cl–Br–I fractionation, whereas F is almost unaffected. All magmas erupted at SHV have followed a multi-step degassing path from the magma chamber up to a shallow depth ( 1 km, P  20 MPa). From that depth, however, effusive and explosive paths are distinct; vulcanian eruptions are the result of closed system degassing (CSD), while effusive dome growth is the result of CSD up to a very shallow depth (≤ 200 m, P  5–2 MPa) followed by open system degassing (OSD). CSD is modelled using the H2O solubility law, the perfect gas law and partition coefficients of halogens between a rhyolitic melt and H2O vapour (dv − li). Gas loss characteristic of OSD is modelled using a Rayleigh law. Degassing induced crystallisation is introduced through the ratio of crystallisation and degassing rates, which ranges from 150–500. dv − lCl for OSD ranges between 50–300, increasing with melt Cl content. For CSD, the lower effective dv − lCl ( 20) is attributed to kinetic effects.

Dome forming activity has a greater impact on atmospheric chemistry than vulcanian eruptions because OSD is much more efficient at extracting halogens. The model shows that HCl flux is a good proxy for the dome forming eruption rate. Comparison between model and measured gas compositions suggests a high HBr–BrO conversion rate (BrO/Total Br  1/3) in the SHV gas plume.

The degassing behaviour of Cl, Br and I implies similar Cl/Br ( 160) and Br/I ( 90) in initial melts, volcanic clasts and high temperature gases. The low Cl/Br at SHV compared to other island arcs ( 250–300) is attributed to a shallow, pre-eruptive Br enrichment. The almost permanent dome extrusion at SHV since 1995 has likely had a significant regional atmospheric impact because of the very efficient effusive degassing and the high conversion rate of halogens into reactive species within the gas plume.  相似文献   


18.
The mechanics of explosive eruptions influence magma ascent pathways. Vulcanian explosions involve a stop–start mechanism that recurs on various timescales, evacuating the uppermost portions of the conduit. During the repose time between explosions, magma rises from depth and refills the conduit and stalls until the overpressure is sufficient to generate another explosion. We have analyzed major elements, Cl, S, H2O, and CO2 in plagioclase-hosted melt inclusions, sampled from pumice erupted during four vulcanian events at Soufrière Hills volcano, Montserrat, to determine melt compositions prior to eruption. Using Fourier transform infrared spectroscopy, we measured values up to 6.7 wt.% H2O and 80 ppm CO2. Of 42 melt inclusions, 81 % cluster between 2.8 and 5.4 wt.% H2O (57 to 173 MPa or 2–7 km), suggesting lower conduit to upper magma reservoir conditions. We propose two models to explain the magmatic conditions prior to eruption. In Model 1, melt inclusions were trapped during crystal growth in magma that was stalled in the lower conduit to upper magma reservoir, and during trapping, the magma was undergoing closed-system degassing with up to 1 wt.% free vapor. This model can explain the melt inclusions with higher H2O contents since these have sampled the upper parts of the magma reservoir. However, the model cannot explain the melt inclusions with lower H2O because the timescale for plagioclase crystallization and melt inclusion entrapment is longer than the magma residence time in the conduit. In Model 2, melt inclusions were originally trapped at deeper levels of the magma chamber, but then lost hydrogen by diffusion through the plagioclase host during periodic stalling of the magma in the lower conduit system. In this second scenario, which we favor, the melt inclusions record re-equilibration depths within the lower conduit to upper magma reservoir.  相似文献   

19.
The 79 ad Plinian eruption of Vesuvius produced first a white pumice fallout from a high steady eruptive column, and then a grey pumice fallout originating from an oscillatory eruptive column with several partial column collapse events after which there was a total column collapse. This first total collapse was followed by renewed Plinian activity and produced the last grey pumice (GP) fallout deposit of the eruption. Textural characteristics (vesicularity and microcrystallinity) of a complete sequence of the pumice fallout deposits are presented along with the major element compositions and residual volatile contents (H2O, Cl) to constrain the degassing processes and the eruptive dynamics. Large variations in residual volatile contents exist between the different eruptive units. Textural features also strongly differ between white and grey pumices, but also within the grey pumices. The degassing processes were thus highly heterogeneous. We propose a new model of the 79 ad eruption in which pre-eruptive conditions (H2O saturation, magma temperature and viscosity) are the critical controls on the diversity of the syn-eruptive degassing processes and hence the eruptive dynamics. Cl contents measured in melt inclusions show that only the white pumice and the upper part of the grey pumice magma were H2O saturated prior to eruption. The white pumice eruptive units represent a typical closed-system degassing evolution, whereas the first grey pumice one, stored under similar pre-eruptive saturation conditions, follows a particular open-system degassing evolution. We suggest that the oscillatory regime that dominated the grey pumice eruptive phase is linked to pre-eruptive water undersaturation of most of the grey magma, and the associated time delays necessary for H2O exsolution. We also suggest that the high residual H2O content of the last grey pumice, deposited after the renewal of Plinian activity following the first total column collapse event, is due to syn-eruptive saturation of GP magma and reduced H2O exsolution efficiency resulting from speciation of dissolved H2O in the melt.  相似文献   

20.
An understanding of the mechanisms responsible for persistent volcanism can be acquired through the integration of geophysical and geochemical data sets. By interpreting data on micro-gravity, ground deformation and SO2 flux collected at Masaya Volcano since 1993, it is now clear that the characteristically cyclical nature of the activity is not driven by intrusion of additional magma into the system. Rather, it may be due in large part to the blocking and accumulation of gas by restrictions in the volcano substructure. The history of crater collapse and formation of caverns beneath the crater floor would greatly facilitate the trapping and storage of gas in a zone immediately beneath San Pedro and the other craters. Another mechanism that may explain the observed gravity and gas flux variations is the convective overturn of shallow, pre-existing, degassed, cooled, dense magma that is replaced periodically by lower density, hot, gas-rich magma from depth. Buoyant gas-rich magma rises from depth and is emplaced near the surface, resulting in the formation and fluctuation of a low-density gas-rich layer centred beneath Nindirí and Santiago craters. As this magma vigorously degasses, it must cool, increase in density and eventually sink. Five stages of activity have been identified at Masaya since 1853 and the most recent data suggest that the system may have been entering another period of reduced degassing in 2000. This type of analysis has important implications for hazard mitigation because periods of intense degassing are associated with poor agricultural yields and reduced quality of life. A better understanding of persistent cyclically active volcanoes will allow for more effective planning of urban development and agricultural land use.  相似文献   

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