共查询到20条相似文献，搜索用时 31 毫秒
1.
INTR0DUCnONAlloycoatingscandetivelyproteCtsteelagainstcormsioninseri0uscormsionenvir-orunent,suchasthedrinesplashandtidalzones-TwoInainhodiptincaldrinumalloycOaingswidelyusedcommroiallyareGalfancoaing(contalningZn-5wt%kl-us)devel-oPedbytheIntemaionaltalZincReenhheZaionandhocoating(c0n-talningZn-55Wt%Al-1.6Wt%Si)develoPedbytheBethlehemSteelCorpOration-Anewrinc-basedalloycOaingdevel0PedbyNortheaStemUniversityisdiscussedinthesPaperbyelecthehendcalmethod.FromSun(l996),welmOWthecorms… 相似文献
2.
The surface of ZrO2 nanoparticles was modified by styrene coupling grafting method to improve the dispersion and interaction of the nanoparticles with the epoxy coating in which the modified ZrO2 nanoparticles were used as an additive. The grafting performance and microstructure of the nano- ZrO2/epoxy coating were analyzed by Fourier transformation infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. The corrosion behavior of the nano-ZrO2/epoxy coating on mild steel was evaluated in neutral 3.5 wt% NaC1 solution using electrochemical impedance spectroscopy （EIS）. Both the coating capacitance and coating resistance fitted by the equivalent circuit from EIS were used to evaluate the protective performance of the coating towards the mild steel. The results show a superior stability and efficient corrosion protection by the modified ZrO2 nanoparticles. The epoxy coating containing 2 wt% modified ZrO2 nanoparticles exhibited the best corrosion performance among all the coating specimens. This research may provide an insight into the protection of mild steel using modified epoxy coatings. 相似文献
3.
《中国海洋湖沼学报》2017,(5)
Defects in protective-coating systems on steel surfaces are inevitable in practical engineering applications.A composite coating system,including a primer,middle coat and topcoat,were used to protect carbon steel from corrosion in a marine environment.Two environmental additives,glass fi bers and thiourea,were applied in the middle coat to modify the coating system.The long-term corrosion durability and self-healing ability of the scratched coating system were evaluated by multiple methods.Results of the electrochemical technologies indicated that the coating system that contained 0.5 wt.%fi bers and 0.5 wt.%thiourea presented good corrosion protection and self-healing for carbon steel when immersed in 3.5%Na Cl for 120 d.Evolution of localized corrosion factors with time,as obtained from the current distribution showed that fi bers combined with thiourea could inhibit the occurrence of local corrosion in scratched coating systems and retarded the corrosion development signifi cantly.Surface characterization suggested that adequate thiourea could be absorbed uniformly on fi bers for a long time to play an important role in protecting the carbon steel.Finally,schematic models were established to demonstrate the action of fi bers and thiourea on the exposed surface of the carbon steel and the scratched coating system in the entire deterioration process. 相似文献
4.
魏续占 《地球科学与环境学报》1996,(2)
用多种分析手段分析了Ｓｏｌ－ｇｅｌ法制取的Ａｌ２Ｏ３系陶瓷涂层在烧结过程中的组织变化以及烧结后涂层的成分和组织结构；对涂层的高温抗氧化性、耐蚀性、耐磨性以及涂层与金属基体的结合力进行了测试，结果表明，Ｓｏｌ－ｇｅｌ法制取的Ａｌ２Ｏ３系陶瓷涂层由氧化物晶体、过渡相和玻璃体混合而成，涂层与基体之间有很好的结合力，金属基体的抗氧性、耐蚀性、耐磨性能有明显提高． 相似文献
5.
《中国海洋大学学报(英文版)》2015,(2)
The current distributions over carbon steel under iron red alkyd primer exposed to 3.5% sodium chloride solution were mapped using the wire beam electrode(WBE). The electrochemical impedance spectroscopy(EIS) of the WBE was carried out to analyze the performance of coating delamination and corrosion behavior of carbon steel beneath defective coating. The EIS data revealed that protective capability of coating decreased with immersion time and the degree of cathodic delamination showed a rapid rise. The current density distribution of WBE indicated that cathodic sites was located at the defect at the beginning of immersion and gradually spread into the intact coating. The cathodic regions were distinguished from the anodic area and distributed over the WBE. The changes of cathodic sites could reflect the deterioration process of defective coating. The cathodic area ratio was a more useful parameter than the cathodic delamination degree to evaluate the coating cathodic delamination. The polarity reversals of electrodes at the defect and beneath coating were observed. A simple discussion of relationship between the blister and the polarity reversal was made from a standpoint of electrochemical distribution. WBE method was able to map and record the changes of local cathodic sites beneath defective coating in real time, which could provide more detailed information about the local degradation of coating. 相似文献
6.
Heavy paint coating loss and localized corrosion of the Al alloy hull occur red after less than a year's service of a ship
at sea. Examination and analysis showed that the Mg-basic sacrificial anodes originally used for cathodic protection were
not suitable as the resulting −1.3V-plus (vs Ag/AgCl) protection potential for the hull was too negative for the purpose.
A new protection system was designed in which the protection current densities were 15mA/m2 for the hull and 350mA/m2 for the propeller. The hull protection potential under actual condition at sea was between −920mV and −1100mV (Ag/AgCl) and
the protection efficiency was over 90%. The protection areas were calculated by using the formulas A=1.8×LBP×D+BC×LB×B for
the hull and As=2Aas for the propeller.
Contribution No. 1640 from the Institute of Oceanology, Academia Sinica. 相似文献
7.
《中国海洋湖沼学报》2020,(2)
Copper has long been utilized as a disinfectant for bacteria,but its impact on microbial communities attached to the steel surface in seawater remains unknown.In the present study,3 mooring chain steels of different copper contents are subjected to a 3-month marine field exposure,and the corrosion rate increases in the order of BR5 steel(without copper) BR5 CuH steel(0.8% copper) BR5 CuL steel(0.4% copper).The microbial community results show that copper introduction does not result in an obvious change in microbial quantity,but it alters the diversity,richness,and structure of microbial communities due to the variation in copper-resistance of different species.BR5 CuH steel holds microbial communities with the highest percentage of some well-known corrosive microbes including sulfate-reducing bacteria,sulfuroxidizing bacteria,and iron-oxidizing bacteria,but possesses the lowest community diversity/richness owing to the toxicity of copper.The microbial community diversity/richness is stimulated by the low-copper content of BR5 CuL steel,and this steel also carries an intermediate proportion of such corrosive bacteria.Both well-known corrosive bacteria and microbial community diversity/richness seem to be involved in the corrosion acceleration of copper-bearing mooring chain steels. 相似文献
8.
Watershed prioritization of Palar sub-watershed based on the morphometric and land use analysis 总被引：2，自引：1，他引：1
Evangelin Ramani Sujatha Radhakrishnan Selvakumar Balasubramaniam Rajasimman 《山地科学学报》2014,11(4):906-916
Morphometric analysis is an indispensable tool for hydrological investigation that involves the development and management of drainage basin. This study characterizes the micro watersheds in the Palar sub-watershed using morphometric analysis and assesses its risk by land use and land cover features in a particular micro watershed. Palar sub-watershed is divided into 6 micro watersheds for prioritization based on morphometric and land use analysis. Several morphometric parameters （linear, shape and relief） are determined from the drainage map; ranks are assigned based on their capacity to induce erodability and degradation. Final ranking is based on the composite index calculated from the sum of the ranks of each morphometric parameter. Morphometric analysis reveals micro watersheds 5 and 6 as most susceptible and 2 and 3 as low susceptible. Land use is mapped using IRS ID LISS III satellite data. The risk in terms of watershed degradation involved to each micro watershed is based on the ranks of each land use feature, obtained from a similar composite index as that of morphometric analysis. Land use analysis shows that micro watersheds 2 and 4 fall under high priority category while 5 and 6 under low priority category. Integration of the morphometric and land use analysis shows that only microwatershed 1 falls under the same category in both analyses. Control measures are suggested to contain degradation depending on its specific land use pattern and morphometric features. This study ean be used to prepare a comprehensive watershed plan for the development or for planning resource conservation strategies, by integrating land use features with the drainage characteristics of the region, in particular for a hill ecosystem as the prioritization is at micro level. 相似文献
9.
设计一种新型光纤光栅锈蚀传感器,主要由锈蚀体、不锈钢体和2段串联的光纤布拉格光栅（FBG）组成。缠绕于锈蚀体表面的FBG监测钢筋的锈胀应变,缠绕于不锈钢体表面的FBG用作温度补偿器,消除温度变化对锈胀应变监测的影响。此外,设计电化学加速腐蚀实验,探究该传感器在不同强度等级混凝土中的工作性能。结果表明,该传感器监测质量腐蚀率的灵敏度为0.02%,监测范围大于1%,可实时监测混凝土中钢筋的锈蚀过程及特征,为预警钢筋锈蚀引起的钢筋混凝土结构耐久性损失提供阈值,在结构健康监测领域具有较大的应用价值。 相似文献
10.
Steel piles at the tidal zone can be seriously corroded. Common protective methods such as painting or coating with rubber
or other protective materials, etc. cannot provide full protection when used as supplementary protection because these traditional
methods require strict pretreatment and sealing of the metallic surface from the corrosive mediums, and time for the protective
coatings to solidify. This is very difficult under the severe action of waves and surges on the sea.
With our oil-soluble DZ-2 tape, protection efficiency for hanging steel plates at the tidal and splash zones reaches to 82–99%.
The protection efficiency of water soluble DZ tape at the tidal zone reaches to 92.9%. The DZ and DZ-2 tapes can rapidly reduce
the original corrosion velocity to ten percent and one percent respectively as fully proved by the 500 hour rapid corrosion
testing with indoor salt fog and by the relevant electrochemical parameters of instantaneous corrosion velocity, etc.
DZ tape absorbs much OH− to cause a pH rise. A synergistic protective effect is gained when DZ tape is used together with cathodic protection of steel
piles at the tidal zone. The working principle of DZ tape is different from that of DZ-2 tape even though they are composed
of the same chemical materials. The latter provides protection because of the close affinity between metal and its carboxyl
group shields the active centre at the metal surface to reduce the activation energy of metal. The carbon chain forms a covering
oil film of netted structure.
Dai Tao, Dai Wei and Xia Caiyuan et al. participated in the research and made useful contribution. Contribution No. 1656 from
the Institute of Oceanology, Academia Sinica. 相似文献
11.
GAO Rongjie DU Min SUN Xiaoxia PU Yanli 《中国海洋大学学报(英文版)》2007,6(4):349-354
The corrosion resistance of electroless Ni-P deposits with phosphorous contents from 12% to 14% in sodium chloride solutions was studied. The deposits were immersed in 3.5% NaCl solutions for 29 d to obtain the electrochemical parameters and were examined in a standard salt spray test for 15 d respectively. The corrosion resistance of the deposits was studied by poten- tio-dynamic scan, electrochemical impedance spectroscopy (EIS), X-ray diffraction (XRD) and cold-field emission scanning electron microscopy (FE-SEM) equipped with an energy dispersive X-ray detector (EDX). The patterns of XRD and the results of FE-SEM showed that the prepared deposits were amorphous. But after a 15 d standard salt spray test, a few pinholes appeared on the surface of the deposit and the weight content of phosphorus on the surface of the deposit was higher (which was beneficial to the formation of the passivation films) than that before the standard salt spray test when the nickel content was lower because the dissolved weight of nickel was greater than that of phosphorus. The results from potentio-dynamic scan and EIS showed that passivation films formed on the Ni-P deposit after immersion in the NaCl solutions, which decreased the corrosion rate of Ni-P samples. The results of this work show their potential applications in marine corrosion. 相似文献
12.
Study on rust layers on steel in different marine corrosion zone 总被引：1，自引：0，他引：1
IrmODUCnONTheMossbaureffect(ME)isalsoknOWnasrecoil-thenuclearresonaneabsorp-hon.MossbaursPeCboscoPy(MS)haspIDvedtobeaveryuSefultecheqUeforstudytngcormsionPimessesandcedon-cts.TheInainadvantagsofMSincormsionre-enhare:(l)thenon-deStrutivechateroftheteCboqUe;(2)possibilltyforquali-tativeandqUanitativephaanalsis;(3)uSehassinidenificationofPOOrlycrystal-lizedoramorphouscormsionpnhats.WththedeVfoPmntofInarineresomees,InansteelconstrUctionswerebulltatsea'MSwasusedforanalfongcormsion~t… 相似文献
13.
《中国海洋湖沼学报》2016,(3)
Pyropia haitanensis(T.J.Chang et B.F.Zheng) N.Kikuchi et M.Miyata( Porphyra haitanensis) is an economically important genus that is cultured widely in China.P.haitanensis is cultured on a larger scale than Pyropia yezoensis,making up an important part of the total production of cultivated Pyropia in China.However,the majority of molecular mechanisms underlying the physiological processes of P.haitanensis remain unknown.P.haitanensis could utilize inorganic carbon and the sporophytes of P.haitanensis might possess a PCK-type C 4-like carbon-fixation pathway.To identify micro RNAs and their probable roles in sporophyte and gametophyte development,we constructed and sequenced small RNA libraries from sporophytes and gametophytes of P.haitanensis.Five micro RNAs were identified that shared no sequence homology with known micro RNAs.Our results indicated that P.haitanensis might posses a complex s RNA processing system in which the novel micro RNAs act as important regulators of the development of different generations of P.haitanensis. 相似文献
14.
A review of colloid transport in fractured rocks 总被引：3，自引：0，他引：3
WEISBROD Noam 《山地科学学报》2012,9(6):770-787
Recent recognition of colloid and colloidassociated transport of strongly sorbing contaminants in fractured rocks highlights the importance of exploring the transport behavior of colloids under conditions prevailing in the field.The rapid transport of colloids through fractured rocks-as affected by the hydraulic properties of the flow system,the properties of fracture surface and the geochemical conditionshas not been sufficiently elucidated,and predictions of colloid transport through fractures have encountered difficulties,particularly at the field scale.This article reviews the current understanding of the mechanisms and modeling of colloid transport and retention in fractured rocks.Commonly used experimental techniques and approaches for conducting colloid transport experiments at different scales,ranging from the laboratory to the field scale,are summarized and commented upon.The importance of various interactions(e.g.,dissolution,colloid deposition,generation,mobilization and deposition of filling materials within fractures) between the flowing solution and the fracture walls(in many cases,with skin or coating on the host rock at the liquid-solid interface) has been stressed.Colloid transport through fractures of high heterogeneity has not yet been well understood and modeled at the field scale.Here,we summarize the current knowledge and understanding accumulated in the last two decades in regard to colloid and colloidassociated transport through fractures.Future research needs are also discussed. 相似文献
15.
【目的】研究添加芒果粉对真空油炸面包虾裹浆特性及其品质的影响。【方法】以小麦粉和大豆分离蛋白的裹浆作为对照,研究芒果粉替代部分小麦粉和大豆分离蛋白的裹浆流变学特性;以裹涂率、油脂含量、水分含量、色泽及质构特性为考察指标,研究芒果粉替代部分小麦粉和大豆分离蛋白的裹浆对真空油炸面包虾品质的影响;以最佳芒果粉添加量的真空油炸面包虾为研究对象,测定外裹层黄酮物质含量,并采用羟自由基和DPPH自由基体系对产品外裹层黄酮物质的抗氧化性进行分析。【结果】所有配方的裹浆均表现为触变性,呈现剪切稀化特性,具有假塑性流体特征,并符合幂率流体,芒果粉可显著提升裹浆的黏度;芒果粉可显著增大面包虾裹涂率,改善产品质构和色泽特性,降低产品油脂含量并提升其水分含量(P <0.05)。当芒果粉添加量从10%增加到30%时,面包虾产品油脂质量分数从24.84%降低到20.58%,产品的脆性和色泽中的亮度值(L*)、黄度值(b*)均得到了显著提升(P <0.05)。当小麦粉质量分数66%、大豆分离蛋白质量分数4%、芒果粉质量分数30%时,真空油炸面包虾产品的各项品质最佳;真空油炸面包虾产品外裹层黄酮物质质量分数为(46.75±2.87)mg/100g,其对羟自由基和DPPH自由基的清除效果方面都均强于维生素C。【结论】芒果粉可提升裹浆黏度,改善真空油炸面包虾产品品质,其外裹层较强的抗氧化性对于真空油炸裹涂制品延长货架期具有一定积极作用。 相似文献
16.
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????3?????1996??2006?????????????????????о????????????????????????????????? ?о??????????????仯?????????????????????????й????仯?????????????????????й???????????????????仯??????????????????????????仯??????????????????????仯?? 相似文献
17.
The ratio of nitrogen/phosphorus (N/P) is known to affect cell proliferation of some marine micro algae. We evaluated the effect of N/P ratios on the proliferation and succession of phytoplankton using five marine micro algae species. We used two sources of nitrogen, NH4Cl (N1) and urea (N2), and a single source of phosphorous, NaH2PO4(P). The optimal N/P ratio that differed among the five species was affected by the source of nitrogen, being as follows (N1/P, N2/P in order): Thalassiosira sp. (30/1, 20/1),... 相似文献
18.
Laboratory and field tests on our newly developed embeddable reference electrode for reinforced concrete show it can be embedded
into reinforced concrete structures and be used for measuring the potentials of the rebar or other metal elements in the outer
structural part exposed to seawater. Its potential varies little with the change of Cl− concentration of the electrolyte and is stable over a time range of 260 days. The electrode can be used for monitoring corrosion
and cathodic protection of reinforced concrete structures in seawater.
Contribution No. 1605 from the Institute of Oceanology, Academia Sinica. 相似文献
19.
Cao Pan Liu De Liu Yuhan Wang Huming Zhang Chao Yuan Chengqing Liu Xiaodan 《中国海洋湖沼学报》2023,41(1):174-188
Marine biofouling causes serious harms to surfaces of marine devices in transportation, aquaculture, and offshore construction. Traditional antifouling methods pollute the environment. A novel and green antifouling strategy was developed to prevent effectively the adhesion of bacteria and microalgae. An antifouling surface was fabricated via coating Turgencin BMox2 (TB) onto dopamine-modified 304 stainless steel (304 SS). The surface physical and chemical properties before and after modification were characterized by Fourier transform infrared spectrometer (FTIR), X-ray photoelectron spectrometer (XPS), contact angle measurement (CA), 3D optical profilometer, ellipsometer, and atomic force microscope (AFM). Antimicrobial peptide was coated onto the surface of 304 SS successfully, and the surface morphology and wettability of the modified sample were modified. Moreover, cytocompatibility of the peptide was evaluated by co-culture of peptide and cells, indicating promising cell biocompatibility at the modified sample surface. At last, antifouling performance and electrochemical corrosion were tested. Results show that the adhesion rates of Vibrio natriegens and Phaeodactylum tricornutum on the antifouling surface were reduced by 99.85% and 67.93%, respectively from those of untreated samples. Therefore, the modified samples retained superior corrosion resistance. The study provide a simply and green way against biofouling on ship hulls and marine equipment.
相似文献20.
The high strength low-alloy steels are welded by underwater wet welding with stainless steel electrodes. The micro-structural and electrochemical corrosion study of base metal (BM), weld zone (WZ) and heat affected zone (HAZ) are carried out to understand the influence of the corrosion product layer generated on the high strength low-alloy steels welded by underwater wet welding with stainless steel electrodes, methods used including, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and scanning electron microscope (SEM). The results indicate that the WZ acts as a cathode and there is no corrosion product on it throughout the immersion period in seawater. The HAZ and BM acts as anodes. The corrosion rates of the HAZ and BM change with the immersion time increasing. In the initial immersion period, the HAZ has the highest corrosion rate because it has a coarse tempered martensite structure and the BM exhibites a microstructure with very fine grains of ferrite and pearlite. After a period of immersion, the BM has the highest corrosion rate. The reason is that the corrosion product layer on the HAZ is dense and has a better protective property while that on the BM is loose and can not inhibit the diffusion of oxygen. 相似文献