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1.
Septarian concretions in the Staffin Shales Formation (Kimmeridgian, Isle of Skye) allow controls on concretion rheology and septarian cracking to be investigated. Stratabound concretions consist of anhedral ferroan calcite microspar enclosing clay and minor pyrite. Intergranular volumes range from 77% to 88%, and calcite δ13C and δ18O values in most concretion bodies range from ?10·0‰ to ?17·3‰ and +0·3‰ to ?0·6‰ respectively, consistent with rapid and pervasive cementation in marine pore fluids. Septarian rupture occurred during incipient cementation, with a sediment volume reduction of up to 43%. Crack‐lining brown fibrous calcite records pore fluid re‐oxygenation during a depositional hiatus, followed by increasing Fe content and δ13C related to bacterial methanogenesis. Brown colouration results from an included gel‐like polar organic fraction that probably represents bacterially degraded biomass. A new hypothesis for concretion growth and septarian cracking argues that quasi‐rigid ‘proto‐concretions’ formed via binding of flocculated clays by bacterial extracellular polysaccharide substances (EPS). This provided rheological and chemical conditions for tensional failure, subcritical crack growth, volume contraction, calcite nucleation, and incorporation of degraded products into crack‐lining cements. Bacterial decay of EPS and syneresis of host muds provided internal stresses to initiate rupture at shallow burial. Development of septarian (shrinkage) cracks in muds is envisaged to require pervasive in situ bacterial colonization, and to depend on rates of carbonate precipitation versus EPS degradation and syneresis. Subsequent modification of septarian concretions included envelopment by siderite and calcite microspar, hydraulic fracturing associated with Cretaceous shallow burial or Palaeogene uplift; and cementation by strongly ferroan, yellow sparry calcite that records meteoric water invasion of the host mudrocks. An abundance of fatty acids in these spars indicates aqueous transport of organic breakdown products, and δ13C data suggest a predominantly methanogenic bicarbonate source. However, the wide δ18O range for petrographically identical cement (?1·3‰ to ?15·6‰) is difficult to explain.  相似文献   

2.
Septarian concretions are abundant in many Phanerozoic marine and marginal‐marine shales and mudstones. They range from a few centimetres to several metres in size and are spherical or ellipsoidal in morphology. In general, formation by localized calcite or siderite cementation in argillaceous sediments began under less than a few metres of burial. Septarian cracks vary widely in shape and configuration: included are networks of wide, vertically, radially and sometimes concentrically oriented, lenticular shrinkage cracks; and narrower, parallel‐sided, straight to irregular tension cracks locally accompanied by brecciation, and plumose and en échelon sigmoidal cracks indicative of shear stresses. Crack types are intergradational; many concretions exhibit multiple cracking events. Enclosed macrofossils and isopachous fibrous calcite cement that lines earlier formed cracks are commonly broken and displaced. In some cases, cracks contain injected lime mud and silt. These features, taken together, testify that cracking involved a spectrum of responses in concretion interiors, from loss of shear strength, dewatering and shrinkage to brittle failure, demonstrating variations in, and contrasts between, the rheological properties of the matrix and enclosed objects. Localization to interiors and outward tapering of lenticular cracks make a case for fracture partitioning and indicate that interiors were softer than exteriors at the time of shrinkage. Parallel‐sided cracks point to greater stiffness, and evolving crack shape in multiply cracked concretions shows that rigidity increased with time. Crack orientations indicate highly variable tensile and shear stress directions within individual concretions. Rupture, brecciation, displacement of fragments, loss of shear strength, liquefaction and injection of unconsolidated granular sediment suggest that deformation events were rapid, if not virtually instantaneous. Previous explanations for the internal cracking, such as gas generation, spontaneous chemical dehydration or localized overpressuring due to compaction, seem either untenable or fail to account for the spectrum of observed features. However, syndepositional earthquake‐induced shaking of cementing bodies of varying rigidity at shallow burial depths seems to be a plausible source for the requisite short‐lived, variable to anisotropic, high‐stress regime inside the concretions. Septarian concretions may thus preserve a signature of basin seismicity as it relates to their cementation history.  相似文献   

3.
The Coinstone is a well known hiatus-concretion level in the Lower Lias (Lower Jurassic, Upper Sinemurian) of Dorset, southern England. It has long been recognized as a layer of bored and encrusted, early diagenetic, clay-hosted septarian concretions coincident with a biostratigraphic gap of three ammonite subzones. Several different types of concretion of variable complexity can be distinguished, of which two, probably derived from slightly different stratigraphic levels, have been juxtaposed by condensation at the erosion surface. Diagenetic and biological processes occurring before, during and after exhumation on the Jurassic sea-floor can be recognized. The relative timing of these events can be distinguished, suggesting that initial concretion consolidation, the first generation of septarian cracking, and the precipitation of the first generation of crack-lining calcite preceded exhumation. These, therefore, probably took place at an early stage, at shallow burial depths within the accumulating sediment pile. The early calcite is brown, UV-fluorescent and inclusion-rich, and is similar to the first calcite generations seen in many other clay-hosted septarian concretions. A generally early diagnetic origin of this material is thus inferred. Observations on crack textures and geometries and the interactions of the post-exhumation fauna of encrusters, borers and burrowers lend support to previous suggestions that initial cracking in some septarian concretions took place in a stiff rather than a fully rigid concretion body, possibly given coherence by initial growth of some organic substance that was only later replaced by the calcite cements seen in most such concretions today. The burrowing activities of a benthic fauna in muds cause resuspension of sediment and facilitate erosion, even in the absence of high energy physical processes. Regional stratigraphic gaps may be formed as a consequence of sea level rises or falls, or as a response to sediment supply reduction independent of sea level change. Such major episodes of biologically mediated erosion in mudstone sequences may be of more general importance than has hitherto been recognized.  相似文献   

4.
ABSTRACT
Large septarian concretions from the Kimmeridge Clay, up to 1.2 m in diameter, have centres comprising anhedral calcite microspar passing into margins of radiating fibrous calcite microspar, with a pyrite-rich zone at the transition. Septarian veins formed and were lined with brown calcite synchronously with fibrous matrix growth, with white calcite precipitated in septarian cavities after concretion growth ceased. Septarian veins, filled only with white calcite, formed later, at the same time as the outermost calcite microspar crystals were enlarged.
The concretions were buried in the Late Jurassic to about 130 m, and in the Late Cretaceous to about 550 m, with uplift between. Oxygen isotopes show that the concretion grew throughout the first burial, with septarian veins forming from about 30 m depth onwards. Later septarian veins formed between about 200 and 500 m during the second burial.
Carbon isotopes show that the compact inner matrix grew in the sulphate reduction zone, the end of which is marked by the pyrite-enriched zone. Dissolving shells, and possibly minor methanogenic carbonate, slowly diluted sulphate reduction-zone carbonate during deeper burial. During early concretion growth, Mg and Sr were depleted in the pore water. During later stages of the first burial, Mg, Sr, Mn and Fe all increased, especially after concretion growth ceased. During the second burial, Fe, Mn and Mg decreased as calcite precipitated, implying relatively closed systems for these elements.
Synchronous formation of septarian fractures and fibrous calcite matrix shows that the Kimmeridge Clay became overpressured during the later stages of both burials.  相似文献   

5.
Calcite septarian concretions from the Permian Beaufort Group in the Maniamba Graben (NW Mozambique) allow controls on the composition and nature of diagenetic fluids to be investigated. The concretions formed in lacustrine siltstones, where they occur in spherical (1 to 70 cm in diameter) and columnar (up to 50 cm long) forms within three closely spaced, discrete beds totalling 2·5 m in thickness. Cementation began at an early stage of diagenesis and entrapped non‐compacted burrows and calcified plant roots. The cylindrical concretions overgrew calcified vertical plant roots, which experienced shrinkage cracking after entrapment. Two generations of concretionary body cement and two generations of septarian crack infill are distinguished. The early generation in both cases is a low‐Mn, Mg‐rich calcite, whereas the later generation is a low‐Mg, Mn‐rich calcite. The change in chemistry is broadly consistent with a time (burial)‐related transition from oxic to sub‐oxic/anoxic conditions close to the sediment–water interface. Geochemical features of all types of cement were controlled by the sulphate‐poor environment and by the absence of bacterial sulphate reduction. All types of cement present have δ13C ranging between 0‰ and −15‰(Vienna Peedee Belemnite, V‐PDB), and highly variable and highly depleted δ18O (down to 14‰ Vienna Standard Mean Ocean Water, V‐SMOW). The late generation of cement is most depleted in both 13C and 18O. The geochemical and isotopic patterns are best explained by interaction between surface oxic waters, pore waters and underground, 18O‐depleted, reducing, ice‐meltwaters accumulated in the underlying coal‐bearing sediments during the Permian deglaciation. The invariant δ13C distribution across core‐to‐rim transects for each individual concretion is consistent with rapid lithification and involvement of a limited range of carbon sources derived via oxidation of buried plant material and from dissolved clastic carbonates. Syneresis of the cement during an advanced stage of lithification at early diagenesis is considered to be the cause of development of the septarian cracks. After cracking, the concretions retained a small volume of porosity, allowing infiltration of anoxic, Ba‐bearing fluids, resulting in the formation of barite. The results obtained contribute to a better understanding of diagenetic processes at the shallow burial depths occurring in rift‐bound, lacustrine depositional systems.  相似文献   

6.
陈明  卢文波  严鹏  胡英国  周创兵 《岩土力学》2014,35(6):1555-1560
岩体裂纹的水力劈裂是岩体开裂渗漏甚至施工涌水的重要影响因素之一,也是岩土工程界的研究热点。从断裂力学角度分析了爆破开挖对岩体含水裂纹扩展的扰动作用,结果表明,爆破开挖扰动下,岩体含水裂纹的扩展,与爆炸应力波强度及其入射角、地应力的大小与方向、孔隙水压大小、裂纹的倾角及断裂韧度等因素相关;爆炸应力波的作用,相当于增大了岩体裂纹中的孔隙水压力,每1 cm/s的峰值振动速度相当于增大100 kPa的孔隙水压力,爆破振动速度越大,所产生的爆破扰动荷载越大;岩体开挖引起的岩体裂纹近区地应力及其孔隙水压力的变化,对裂纹的失稳与扩展具有较复杂的影响,可改变裂纹的失稳扩展模式。  相似文献   

7.
Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ13C=?28·7‰ PDB and δ18O=?1·6‰ PDB through to δ13C=?6·9‰ PDB and δ18O=?14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ13C=?12·0 to ?10·1‰ PDB and δ18O=?5·7 to ?5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ34S=+24·8‰ CDT and δ18O=+16·4‰ SMOW), indicating formation from near‐surface, sulphate‐depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ34S=+6 to +11‰ CDT and δ18O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments.  相似文献   

8.
不同成因的钙质结核在研究沉积水体、早期成岩环境及泥页岩的压实程度方面具有重要意义。通过对川北地区旺苍县下寒武统筇竹寺组钙质结核抛光,发现结核内部具有层理、暗色圈层和张裂缝构造。结核和围岩的层理关系和具有漂浮状的微观结构特征表明,该地区结核是形成于压实作用之前的成岩早期结核。对结核中Al、Ti、Ca、K、Na元素分析表明,结核的元素分布受到结核内部裂缝的影响。结核内部富含生物碎屑和其形成深度为数十米的特征,推测结核主要是在硫酸盐还原带生长。结核具有暗色圈层之间层理不弯曲和元素移动的特征,揭示了结核为透入性生长,在整个结核生长阶段就开始大量同时结晶。Mg/Ca和Sr/Ca的比值说明,结核内部钙质成分为富镁方解石-生物成因方解石。结核中富含钙质成分的原因可能是围岩中的生物成因方解石大量向结核运移所致。裂缝的形态特征表明,裂缝为张裂缝。对结核上部地层的沉积特征研究表明,张裂缝的成因很可能与筇竹寺顶部的浊积岩和沧浪铺组底部的似瘤状灰岩快速搬运沉积有关。  相似文献   

9.
A study of septarian concretions from late Cretaceous shale sequences of Texas and northern Mexico reveals complex burial-exhumation histories. First generation concretions and pre-fossilized moulds formed in silty clays before significant compaction occurred. Syneresis cracks developed and were filled by length slow fibrous calcite with a decrease in iron content toward the centre of each vein; in some cases this was succeeded by growth of equant or bladed calcite. Subsequent erosion of enclosing sediment caused collapse and break up of concretions, leaving fragments and some unbroken concretions exposed to encrustation and boring on the sea floor. These were subsequently buried and enclosed in a second generation of concretions, which also developed syneresis cracks. The calcite that filled these latter cracks was generally bladed (sometimes followed by equant calcite) and contains more iron toward the centre of the vein. Differences between the calcite filling first and second generation septarian veins indicates changing diagenetic regimes during burial in the marine environment, without a major shift in diagenetic conditions, such as the introduction of meteoric waters. These conclusions have significant implications to cementation in ancient limestones, which show textural and chemical sequences similar to those present in the septarian concretions described.  相似文献   

10.
为研究云冈石窟砂岩孔状风化现象的形成机理,对现场选取的含结核砂岩进行冻融循环实验,利用激光共聚焦显微镜对砂岩结核、砂岩基质、以及结核与基质交界面进行观测,分析冻融条件下含结核砂岩裂隙扩展规律,建立了含结核砂岩冻融破坏力学模型。研究表明:随冻融循环周期增加,结核与基质交界面、结核中心、砂岩基质先后出现裂隙。各区域裂隙宽度随冻融循环周期增多均呈增长趋势,但3个位置裂隙发展过程存在差异,交界面的裂隙沿交界面延伸;结核中心产生新裂隙,同时早期裂隙扩展、延伸、汇交形成裂隙网络;砂岩基质裂隙发展缓慢。结核的存在改变了砂岩物理力学性质,显著增强了砂岩的非均质性,建立的含结核砂岩冻融破坏模型,揭示了裂隙一般易发育于交界面的特点。砂岩的非均质性是云冈石窟砂岩形成孔状风化的内在因素。  相似文献   

11.
Samples of San Marcos gabbro were deformed to both pre- and post-failure stages at confining pressures of 100, 250 and 350 MPa. Scanning electron microscope observations were performed on the samples after ion-milling. The unstressed gabbro has insignificant crack porosity but a high volume fraction of healed and sealed cracks. Extensive stress-induced cracking at high angles to the maximum compressive stress is observed at the two higher pressures. Such high-angle cracks are mostly associated with the pre-existing healed cracks or cleavage planes, and they control the geometry and length scale of crack networks in plagioclase. Intensive kinking in biotite is widely observed at 350 MPa pressure, which together with the crack networks control the brittle fracture process. Stress-induced cracks in samples deformed at 100 MPa pressure are predominantly subparallel to the maximum compressive stress, and their coalescence leads to shear localization.Quantitative measurements of crack density as a function of differential stress indicate that crack interaction is appreciable beyond about 90% peak stress for all three pressures. The data also show significant decreases in stress-induced anisotropy as pressure increases, suggesting that there may be a threshold pressure beyond which stress-induced anisotropy vanishes with the onset of cataclasis.  相似文献   

12.
The crystallographic fabric of siderite in siderite concretions has been determined for upper Carboniferous (Westphalian‐A) non‐marine concretions and lower Jurassic (Pliensbachian) marine concretions. Compositional zoning indicates that individual siderite crystals grew over a period of changing pore water chemistry, consistent with the concretions being initially a diffuse patch of cement, which grew progressively. The siderite crystallographic fabric was analysed using the anisotropy of magnetic susceptibility, which is carried by paramagnetic siderite. The siderite concretions from marine and non‐marine formations exhibit differences in fabric style, although both display increases in the degree of preferred siderite c‐axis orientation towards the concretion margins. The Westphalian non‐marine siderites show a preferred orientation of siderite c‐axes in the bedding plane, whereas the Pliensbachian marine siderites have a preferred orientation of c‐axes perpendicular to the bedding. In addition, a single marine concretion shows evidence of earlier formed, inclined girdle‐type fabrics, which are intergrown with later formed vertical c‐axis siderite fabrics. The marine and non‐marine fabrics are both apparently controlled by substrate processes at the site of nucleation, which was probably clay mineral surfaces. Siderite nucleation processes on the substrate were most probably controlled by the (bio?) chemistry of the pore waters, which altered the morphology and crystallographic orientation of the forming carbonate. The preferred crystallographic orientation of siderite results from the orientation of the nucleation substrate. Fabric changes across the concretions partially mimic the progressive compaction‐induced alignment of the clay substrates, while the concretion grew during burial.  相似文献   

13.
Sparry calcite fracture fills and concretion body cements in concretions from the Flodigarry Shale Member of the Staffin Shale Formation, Isle of Skye, Scotland, entrap and preserve mineral and organic materials of sedimentary and diagenetic origin. Fatty acids are a major component of the lipids recovered by decarbonation and comprise mainly n-alkanoic and α-ω dicarboxylic acids. Two generations of fracture-fill calcite (early brown and later yellow) and the concretion body microspar yield significantly different fatty acid profiles. Early brown calcites yield mainly medium-chain n-alkanoic acids with strong even predominance; later yellow calcites are dominated by α-ω dicarboxylic acids with no even predominance. Both fracture fills lack the long-chain n-alkanoic and α-ω dicarboxylic acids additionally recovered from the concretion bodies. The absence of longer chain acids in the calcite spar fracture fills is inferred to result from the transport of fatty acids by septarian mineralising fluids whereby low-aqueous solubility of longer chain acids or their salts accounts for their relative immobility.Comparative experiments have been carried out using conventional solvent extraction on the concretion body and associated shales, both decarbonated and untreated. Extracted lipid yields are higher, but the fatty acids probably derive from mixed locations in the rock including both kerogen- and carbonate-associated lipid pools. Only experiments involving decarbonation yielded α-ω dicarboxylic acids in molecular distributions probably controlled mainly by fluid transport. Alkane biomarker ratios indicate very low thermal maturity has been experienced by the concretions and their host sediments. Septarian cracks lined by brown calcite formed during early burial. Microbial CO2 from sulphate-reducing bacteria was probably the main source of mineralising carbonate. Emplacement of the later septarian fills probably involved at least one episode of fluid invasion.  相似文献   

14.
Concretions from the Kimmeridge Clay Formation are of three types: calcareous concretions, septarian calcareous concretions and pyrite/calcite concretions and nodules, which occur within different mudstone facies. Isotopic and chemical analysis of the concretionary carbonates indicate growth in the Fe-reduction, sulphate-reduction and decarboxylation zones. The septarian concretions show a long and complex history, with early initiation of growth and development spanning several phases of burial, each often resulting in the formation of septaria. Growth apparently ceased in the transitional zone between the sulphate-reduction and the methanogenesis zones. Very early growth in the Fe-reduction zones is also seen in one sample. The non-septarian concretions began growth later within the sulphate-reduction zone and have had a simpler burial history while the pyrite/calcite concretions show carbonate cementation in the sulphate-reduction-methanogenesis transition zone. A ferroan dolomite/calcite septarian nodule with decarboxylation zone characteristics also occurs. Development of concretions appears to be indirectly controlled by the sedimentation rate and depositional environment, the latter determining the organic matter input to the sediments. Calcareous concretions predominate in swell areas and during periods of low sedimentation rate in the basins with poor organic matter preservation and deposition of calcareous mudstones. Pyrite/calcite concretions occur in organic-rich mudstones deposited under higher sedimentation rates in the basins, while the ferroan dolomite nodule grew under very high sedimentation rates.  相似文献   

15.
16.
为了探究有效应力对高煤级煤储层渗透率的控制作用及其应力敏感性的各向异性,对5块高煤级煤样进行了覆压孔渗实验,揭示了有效应力对煤储层渗透率的控制机理。以3.5 MPa模拟原始地层压力发现,煤岩在平行主裂隙和层理面方向具有最高的初始渗透率,垂直层理面方向初始渗透率最低;有效应力从3.5 MPa增加到15.5 MPa的过程中,渗透率呈现出良好的幂函数降低趋势;渗透率伤害/损失的各向异性表明平行主裂隙方向渗透率伤害率和损失率最大,且不同方向应力敏感性受裂隙的宽度及其展布方向的控制;裂隙压缩系数随应力的增加呈现降低趋势,但由于高煤级煤岩压缩难度大,裂隙压缩系数的各向异性不明显。有效应力对渗透率控制的实质为通过减小煤储层孔裂隙体积降低渗透率,从而对各个方向上的渗透率均造成较大的不可逆伤害。   相似文献   

17.
现场测试结果表明:深层搅拌桩施工可以在周围土体中产生很高的超静孔隙水压力,其量值可能超过土体的静水劈裂压力。搅拌桩施工时和周围土体的相互作用可以用受剪的孔穴扩张过程来模拟。针对搅拌桩施工引起的周围土体的劈裂现象,提出了一种基于拉伸破坏原理的劈裂分析方法。分析结果表明:搅拌叶片的旋转对桩周围土体的劈裂起着很重要的作用。通过室内模型桩打设试验可以观测到搅拌桩周围土体的劈裂现象。分析现场搅拌桩施工时桩周土体中的孔隙水压力测试结果,表明现场施工可以引起劈裂。劈裂裂缝对于搅拌桩的性状有如下两方面的正面作用:其一,水泥浆体可以流入劈裂裂缝;其二,超静孔隙水压可以通过劈裂裂缝快速消散。这两者的作用加快了受扰动的周围土体的强度恢复。  相似文献   

18.
金爱兵  王树亮  王本鑫  孙浩  赵怡晴 《岩土力学》2020,41(10):3214-3224
为了准确表征不同角度预制节理岩石在单轴压缩下的变形破坏模式,基于3D打印技术制作了节理模型用于模拟岩体中的结构面,通过水泥砂浆的浇筑得到含不同角度预制节理的岩石试件并进行单轴压缩试验,同时采用数字图像相关技术(DIC)观测、分析试验过程中试件裂纹产生、扩展以及贯通过程。结果表明:随着预制节理从0°增加到90°,试件强度与峰值应变均呈现先降低后升高的变化趋势,0°和45°试件弹性模量相对于完整试件有所降低。基于DIC检测结果,0°、30°、45°及60°试件裂纹皆从预制节理尖端部位起裂,各角度试件的起裂应力与试件强度变化规律一致。各角度试样起裂时在剪应力控制下以剪切翼型裂纹形式起裂,0°与45°试件裂纹在扩展过程由剪切发展为张拉型裂纹,30°和60°试件以剪切裂纹形式贯穿始终,90°试件从底部起裂并最终表现为张拉破坏。研究还发现,下翼起裂角θ2和上翼起裂角θ1之间存在明显的线性正相关关系,关系式为θ2 =0.828 6θ1 +12.185,且起裂应力大小变化与峰值应力变化一致,皆随节理角度的增加先减小后增大。  相似文献   

19.
天津滨海吹填土结构强度增长机理   总被引:1,自引:0,他引:1  
为了研究影响天津滨海吹填土结构强度增长的因素,分析了等效荷载、有效应力增量、孔隙比和含水量与结构强度之间的关系,得出随着等效荷载和有效应力增量的增大,吹填土的结构强度呈增高的趋势。含水量和孔隙比越大,吹填土的结构强度越低。研究认为,吹填土结构强度的形成与吹填土的排水固结密切相关。吹填土在真空预压条件下,排水固结过程分为早期空气排出、真空渗流场作用下的渗透固结和真空条件下的水分气化排出3个阶段。   相似文献   

20.
磷酸盐结核主要由磷质凝块、藻类碎屑和纤柱状磷灰石组成。呈特殊的栉壳状结构。结核中的凝块和藻屑与围岩中的氧化硅、粘土是同时在海底沉积的。纤状磷灰石则是在成岩期间从孔隙水中沉淀的。这些磷酸盐结核是由于纤状磷灰石在碱性微环境中不断淀积增长而成。  相似文献   

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