共查询到20条相似文献，搜索用时 15 毫秒
1.
Evaluation of ground water quality using multiple linear regression and structural equation modeling 总被引：7，自引：4，他引：3
I. Chenini S. Khemiri 《International Journal of Environmental Science and Technology》2009,6(3):509-519
A methodology for characterizing ground water quality of watersheds using hydrochemical data that mingle multiple linear regression and structural equation modeling is presented. The aim of this work is to analyze hydrochemical data in order to explore the compositional of phreatic aquifer groundwater samples and the origin of water mineralization, using mathematical method and modeling, in Maknassy Basin, central Tunisia). Principal component analysis is used to determine the sources of variation between parameters. These components show that the variations within the dataset are related to variation in sulfuric acid and bicarbonate, sodium and cloride, calcium and magnesium which are derived from water-rock interaction. Thus, an equation is explored for the sampled ground water. Using Amos software, the structural equation modeling allows, to test in simultaneous analysis the entire system of variables (sodium, magnesium, sulfat, bicarbonate, cloride, calcium), in order to determine the extent to which it is consistent with the data. For this purpose, it should investigate simultaneously the interactions between the different components of ground water and their relationship with total dissolved solids. The integrated result provides a method to characterize ground water quality using statistical analyses and modeling of hydrochemical data in Maknassy basin to explain the ground water chemistry origin. 相似文献
2.
多矩形图解法及其在塔里木盆地中的应用 总被引：1，自引：0，他引：1
周金龙 《水文地质工程地质》2006,33(2):4-6
多矩形图解法（MRD）采用9个相邻的多矩形坐标系，分别代表9种地下水类型，它具有容纳大量地下水化学分析数据的功能。图解结果不但可以清楚地显示地下水中阴、阳离子含量的信息，而且也提供了更明晰、易懂的水化学类型的信息。本文简要地叙述了MRD法的原理，并应用该方法分析了塔里木盆地各流域地下水的水化学类型，结果表明：MRD法可以清晰地表征塔里木盆地地下水水化学类型的空间变化特征。 相似文献
3.
Tolga Yalcin 《Aquatic Geochemistry》2007,13(1):75-93
Thermal water chemistry from the Biga Peninsula (NW Turkey) was investigated in order to discriminate among hydrochemical
facies, and isotopic groups and identify the major geochemical processes. A systematic hydrogeochemical survey was carried
out, incorporating new data as well as results from the previous studies. Results were used to further develop hydrogeological
and geochemical models. Thermal water compositions were classified into four groups and the processes affecting evolution
of water compositions were interpreted. Types 1, 2 and 3 are representatives of water corresponding to sulfate dominant fluids
(mainly NaSO4-type), chloride dominant fluids (mainly NaCl-type), and bicarbonate dominant fluids (Na- or CaHCO3-type), respectively. Group 4 comprises the fluids with compositions that are not dominated by any distinctive anion. Groundwater
infiltrates and circulates through the marbles of the Paleozoic basement. The isotopic composition of thermal waters revealed
that deep infiltration of meteoric water took place in periods of changed climatic conditions. 相似文献
4.
Zuhair B. Hafi 《Journal of African Earth Sciences》1998,26(4):643-648
Chemical analyses of more than 80 water wells penetrating the first aquifer in the coastal areas east of Tripoli indicate three different hydrochemical facies. Sodium chloride type water is mainly related to the encroachment of sea water as a result of excessive abstraction. The chemical interaction between groundwater and the aquifer materials led to the formation of calcium bicarbonate type water. Calcium chloride type is developed when the intruded sea water, very rich in Na ions, forced through the aquifer materials, and part of these cations replaced the Ca at the exchange sites of the clay minerals.Plotted against chloride, the concentrations of the Na, K, Ca, Mg, sulphate and bicarbonate species deviate considerably from the ideal mixing curves of fresh groundwater and sea water. Sulphate and bicarbonate enrichments are strongly related to the oxidation of sulphides and dissolution of calcite minerals present in the aquifer materials. Sea water intrusion and reverse cation exchanges reactions are the most important phenomena in the chemical evolution of the salinised groundwater. 相似文献
5.
6.
韩城矿区奥灰水化学特征及形成机制探讨 总被引：2，自引：0，他引：2
以岩石化学成分、水质分析、同位素组分以及水质动态长期监测等资料为基础，分析了矿区岩溶水介质的赋存与分布等水文地质背景，重点研究了水化学组分特征及其形成机制。结果表明：由矿区边部至中深部，水化学类型由重碳酸硫酸钙镁型向硫酸盐氯化钠钙型过渡，TDS随含水层埋深升高而水质变差，水化学组分主要由溶滤作用经去膏盐化和脱白云岩化过程形成，开采井群水质变劣的主因是矿区中深部高矿化水的混合作用所致。 相似文献
7.
Hydrogeological and hydrochemical characterization of two karstic discharge areas in San Luis Potosí, Mexico 总被引：1，自引：0，他引：1
Lisa Krienen Michel Heuser Nicole Höbig Manuel Ernesto Mares Ochoa Thomas R. Rüde Antonio Cardona Benavides 《Environmental Earth Sciences》2017,76(24):825
Two karstic discharge areas, Río Verde (RV) and Ciénega de Cabezas (CC), located in a distance of 80 km to each other are chosen to determine the influence of local variations in geology and climatic condition on water chemistry and to examine if the groundwater, supplying the discharge areas, undergoes the same evolution and has a common source. Both study areas are situated on the carbonate platform Valles-San Luis Potosí and comprise a similar geological setting, but despite of their spatial vicinity the climate is semiarid in RV and humid in CC presenting an important factor on the amount of discharge and the concentrations of ions in the discharge. The investigation encompasses discharge, hydrochemical and physico-chemical parameter evaluations as well as the determination of saturation indices, hydrochemical modelling and water type characterization of surface water samples to derive knowledge of the groundwater systems. Scatterplots and saturation indices were used to proof the influence of lithological variability. Both study areas represent normal alkaline water, marked by high concentrations of calcium and magnesium with varying concentrations of bicarbonate and sulphate. In RV, the water interacts with dolomite rocks and gypsum layers, whereas in CC the dolomite content is depleted and the influence of limestone rocks increases. The climatic impact on the groundwater in RV is noticeable by the increase in ionic concentrations due to higher evaporation. In CC the higher amount of precipitation dilutes the groundwater and causes decreasing ionic concentrations. 相似文献
8.
黑河流域中游盆地水文地球化学演化规律研究 总被引：1，自引：0，他引：1
黑河是我国第二大内流河,研究其水化学演化规律,对于区域水资源科学利用与管理、保障饮水安全和下游生态安全都具有重要作用。本文利用2014—2018年在黑河流域开展1∶50 000水文地质调查所获取的资料,研究了黑河干流和丰乐河两个典型剖面的水化学和同位素变化规律。结果表明,黑河中游盆地地下水主要来源于祁连山区大气降水补给,黑河干流区地下水氘氧同位素比丰乐河流域更为富集,反映了氘氧同位素的高程效应。在丰乐河流域排泄区发现了非现代气候条件下形成的古水,说明现在的盐湖盆地早期就是地下水滞留区。山前戈壁带含水层经长期淋滤作用,地下水溶解性总固体(total dissolved solids,TDS)较低,水化学类型以重碳酸型为主。溢出带以北下游地区TDS逐步增高,地下水类型以硫酸型、硫酸-氯型为主,具有两种地下水化学背景和演化模式:一种是石膏溶解-碳酸盐沉淀析出-氯化物溶解-缓慢的硅酸盐非完全溶解和阳离子交换反应模式;另一种在此基础上增加硫酸钠溶解演化模式。流域补给区和径流区地下水TDS升高的主要原因是溶滤作用。丰乐河排泄区地下水TDS升高的主要原因仍是溶滤作用,溶滤盐分的来源是表层的盐分,以石盐为主。黑河干流排泄区由于含水层较薄,水位埋深较浅,蒸发对地下水咸化的影响更大。 相似文献
9.
Si Jianhua Feng Qi Wen Xiaohu Su Yonghong Xi Haiyang Chang Zongqiang 《Environmental Geology》2009,57(5):1079-1087
The Ejina Basin, located in arid northwest China, is one of the most arid areas in the world. In recent years, rapid development
has created a greater demand for water which is increasingly fulfilled by groundwater abstraction. Detailed knowledge of geochemical
evolution of groundwater and water quality can improve the understanding of a hydrochemical system, and promote sustainable
development and effective management of groundwater resources. To this end, a hydrochemical survey was conducted in the Ejina
Basin in order to identify the major hydrochemical characteristics. The results of chemical analysis indicate that groundwater
in the area is brackish. The major ions, TDS, and hydrochemical types of different areas are highly variable and show an obvious
zonation from the recharge area to the discharge area. Saturation index (SI), calculated according to the ionic ration plot,
indicates that the gypsum-halite dissolution reactions take place under the condition of the rock weathering to some extent,
and evaporation is the dominant factor to determine the major ionic composition in the study area. 相似文献
10.
环境调查研究表明,大武地下水水源地上游邻近的石化厂区出现严重的地下管道石油污染物持续泄漏现象。堠皋－柳杭地段地下水环境在成为集中污染地段的同时,水文地球化学环境也发生了迥然的变化：地下水中电子接受体溶解氧,ＮＯ３＾－末检出,ＳＯ４＾２－呈低值分布。这与地下水中存在微生物降解烃污染物的作用有关。其作用类型包括需氧降解,脱硝降解,脱硫降解以及有Ｆｅ＾３＋参与的降解作用。然而由于该地段需氧降解、脱硝降解、脱硫降懈以及有F3+参与的降解作用。然而由于废地段需氧降解、脱硝降懈难以进行,导致了生物降解污染物的速度降低 其研究意义是提高地下水中电子接受体的浓度．增强微生物的活性,以促进生物降解速度,将有利于含水层中这类污染物的清除。 相似文献
11.
The sea level rise has its own-bearing on the coastal recession and hydro-environmental degradation of the River Nile Delta.
Attempts are made here to use remote sensing to detect the coastal recession in some selected parts and delineating the chemistry
of groundwater aquifers and surface water, which lie along south-mid-northern and coastal zone of the Nile Delta. Eight water
samples from groundwater monitoring wells and 13 water samples from surface water were collected and analyzed for various
hydrochemical parameters. The groundwater samples are classified into five hydrochemical facies on Hill-Piper trilinear diagram
based on the dominance of different cations and anions: facies 1: Ca–Mg–Na–HCO3–Cl–SO4 type I; facies 2: Na–Cl–HCO3 type II; facies 3: Na–Ca–Mg–Cl type III, facies 4: Ca–Na–Mg–Cl–HCO3 type IV and facies 5: Na–Mg–Cl type V. The hydrochemical facies showed that the majority of samples were enriched in sodium,
bicarbonate and chloride types and, which reflected that the sea water and tidal channel play a major role in controlling
the groundwater chemical composition in the Quaternary shallow aquifers, with a severe degradation going north of Nile Delta.
Also, the relationship between the dissolved chloride (Cl, mmol/l), as a variable, and other major ion combinations (in mmol/l)
were considered as another criterion for chemical classification system. The low and medium chloride groundwater occurs in
southern and mid Nile Delta (Classes A and B), whereas the high and very high chloride (classes D and C) almost covers the
northern parts of the Nile Delta indicating the severe effect of sea water intrusion. Other facets of hydro-environmental
degradation are reflected through monitoring the soil degradation process within the last two decades in the northern part
of Nile Delta. Land degradation was assessed by adopting new approach through the integration of GLASOD/FAO approach and Remote
Sensing/GIS techniques. The main types of human induced soil degradation observed in the studied area are salinity, alkalinity
(sodicity), compaction and water logging. On the other hand, water erosion because of sea rise is assessed. Multi-dates satellite
data from Landsat TM and ETM+ images dated 1983 and 2003 were used to detect the changes of shoreline during the last two
decades. The obtained results showed that, the eroded areas were determined as 568.20 acre; meanwhile the accreted areas were
detected as 494.61 acre during the 20-year period. 相似文献
12.
The genesis of the Houzhai karstic water system of the Guanling Formation, southwestern China, dates back to the Middle Triassic. Due to differences in the geomorphology and the extent of the underground river system with highly developed conduits, the hydrologic function appears to be complex. The hydrologic function and behavior of the karst system were analyzed by spring hydrograph (Mangin 1975) and by groundwater hydrochemical methods. The result obtained from the former shows that the Houzhai karstic water system behaves in a non-karstic way, with slow infiltration and a large regulation power. This study shows that Mangin’s karst classification is not applicable in the karstic water systems of southwest China. The hydrodynamic parameters obtained from Mangin’s spring hydrograph and the hydrochemical parameters obtained from the analysis of the bicarbonate relative frequency were combined to characterize the hydrologic function and behavior of the Houzhai karstic water system. The synthesized result shows that the distortion degree of the precipitation input is lower upstream, due to the different surface landform and the degree of karst heterogeneity. Mangin A (1975) Contribution à l’étude hydrodynamique des aquifères karstiqus (Contribution to the hydrodynamic study of karst aquifers). Thèse, Université of Dijon, France (Annales de Spéléologie 29(3), 283–332; 29(4), 495–601; 30(1), 21–124). 相似文献
13.
开展河流和地下水转换关系研究对于区域水资源合理开发利用具有重要意义。文章以大西沟河水与地下水转换关系为目标,在分析地下水动力场的基础上,通过水化学类型、溶解性总固体(TDS)、氯离子（Cl-）等水化学以及环境同位素18O、D、T等指标作为示踪剂,分析大西沟河和地下水的转换关系和转化强度。结果表明:研究区河流和地下水化学类型主要为HCO3—Ca,水化学类型空间分布特征相似;TDS和Cl-浓度表现为先增加后下降,但地下水的变化幅度大于河水。通过对大西沟河水和地下水中的水化学和环境同位素指标对比分析,发现研究区河流与地下水之间补给排泄关系具有明显的分段性;从河流出山口到下游地区,河水和地下水之间发生了三次转化关系:在山前倾斜砾质平原区以河水入渗补给地下水为主,补给量占该段潜水径流量的56%;到了细土平原区出现地下水补给河水地段,补给源为承压水越流补给潜水后的混合水体,潜水和承压水补给比例占该段河水径流量的20.4%与58.4%;风成沙漠区河水沿途渗漏补给地下水直至河流断流。本次研究结果为建立研究区水循环演化模式和水资源合理开发利用提供了理论和技术支持。 相似文献
14.
宁夏银川平原是继河套平原之后,在黄河流域发现的又一个高砷地下水分布区.为了总结其高砷地下水的水化学特征,并探索水化学因素对地下水砷释放和富集的影响机制,本文以银川平原北部（银北平原）作为典型研究区,采取野外水文地质调查、水样采集与测试、砷与水化学组分散点图相关分析及水文地球化学方法进行了综合研究.结果表明,银北平原地下水砷含量在0.2~177 μg/L之间;高砷地下水（大于50 μg/L） pH值多在7.5~8.5,水化学类型主要为HCO3-Na·Ca、Cl·HCO3-Na及Cl·HCO3-Na·Ca型,Eh多在-200~-100 mV.银北平原砷含量较高的地下水中COD、NH4+、HCO3-含量相应也较高,而NO3-和SO42-含量较低.高砷富有机质的冲-湖积含水层经过长期演化,形成偏碱性的中强还原性地下水环境和特殊的水化学特征,也具备极大的砷释放能力.较高的pH导致砷从铁锰氧化物或氢氧化物等水合物或黏土矿物表面解吸.其次部分铁锰氧化物在高pH、低Eh条件下可被还原为低价态可溶性铁锰,从而使与其结合的砷也得以释放进入地下水中.此外重碳酸根与砷酸根、亚砷酸根的竞争吸附行为促使含水层砷的解吸. 相似文献
15.
The Natuf drainage basin in the western hills of Ramallah district is about 200 km2
. Many springs emerge in the area from perched aquifers and outcrop from limestone and dolomite limestone formations. This study
aims to add more information about hydrochemical parameters and the chemical changes in spring water between dry and wet seasons
and to locate possible sources of pollution and their effect on the water quality of water from the springs for domestic and
agricultural uses. The study involved collection and analysis by conventional and available instrumental methods for the hydrochemical
parameters from 12 springs before and after recharge. Water samples of runoff from two places in eastern and western parts
of the study area were collected and analyzed as well. Most of the springs in the study area are of good water quality for
domestic and agricultural uses. Variations in the chemical composition between dry and wet seasons, and from one spring to
another, were observed. Springs near densely populated areas and agricultural activities show higher values of EC, SSP, SAR
and TH. Also uncountable colonies of faecal- and total coliform were detected. Trace amounts, within World Health Organization
(WHO) and the Palestinian standard limits, of cadmium, chromium, cobalt and lead are found in some springs; while concentrations
of iron and zinc that were detected in springs near populated areas are higher than other springs. Water types of Ein Musbah,
Al Alaq and Ein Arik El Tehta are of earth alkaline with increased portion of alkalis with prevailing bicarbonate and chloride
in wet and dry seasons. Other springs show a variation in water type between earth alkaline with prevailing bicarbonate in
the wet seasons to earth alkaline with prevailing bicarbonate and chloride in the dry seasons.
相似文献
| Marwan Ghanem (Corresponding author)Email: |
16.
艾比湖区域地表水水化学特征干湿季变化及其控制因素 总被引：1，自引：0，他引：1
对2014年艾比湖区域的地表水进行观测和取样,综合运用多元统计、Piper阴阳离子三角图、Gibbs图等方法,对艾比湖区域干湿季地表水化学特征及控制因素进行了分析.结果表明：在湿季5月,Na+和Cl-是占绝对优势的离子,分别占阳离子和阴离子总量的70.34%和52.97%,其次是Mg2+和SO42-;在干季10月,Na+和Cl-是占绝对优势的离子,分别占阳离子和阴离子总量的70.57%和66.48%,其次是Mg2+和SO42-.进而判断出在湿季,艾比湖区域地表水水化学类型为以碳酸盐岩石和蒸发岩来源为主的HCO3--Ca2+-Na+型;而在干季,艾比湖区域地表水水化学类型为以碳酸盐岩石和蒸发岩来源为主的HCO3--Ca2+型.此外,探讨了离子控制的因素.就自然因素而言,在干湿季,艾比湖区域地表水化学离子组成受岩石风化作用和蒸发结晶作用的共同影响,大气降水的输入作用十分微弱.就人为因素而言,根据相关研究,干湿季人为活动中的主要因素是人口和地区生产总值,说明该区域受到人为活动的影响.本研究为我国干旱地区对于河水水化学变化、水质特征、水质保护都具有重要的意义. 相似文献
17.
西藏搭格架地热区天然水的水化学组成与稳定碳同位素特征 总被引：1，自引：1，他引：0
为探究青藏高原搭格架地热区地热水、湖水、河水、冰雪融水等天然水体的水化学组成及物质来源控制因子,于2014年8月对该地区进行了考察和取样。利用紫外-可见光分光光度计和ICP-OES测定了水样中各阴、阳离子含量,利用Gas Bench连接同位素质谱仪测定了水样中溶解无机碳（DIC）同位素比值。结果表明,地热水中总溶解固体（TDS）含量为977.13~1 279.50 mg/L,阳离子以K+和Na+为主,阴离子以HCO3-和Cl-为主,湖水的TDS含量为77.81~810.94 mg/L,阳离子以Na+和Ca2+为主,阴离子以HCO3-(CO32-)和SO42-为主,地热水和湖水的水化学类型为HCO3-Na型;河水和冰雪融水的各离子含量较低,水化学类型为HCO3-Ca型;地热水的DIC浓度范围为9.2~15.4 mmol/L,δ13CDIC值为-9.09‰~-0.95‰;湖水的DIC浓度为1.1~9.7 mmol/L,δ13CDIC值为-8.84‰~-0.27‰。根据水化学Gibbs分布模式图判断出区域水化学特征主要受硅酸盐岩风化控制,以钠长石和钾长石风化为主,但是地热水的水化学组分受到硅酸盐岩和蒸发盐岩共同控制。通过碳同位素比值分析对区域主要风化过程中CO2的来源示踪表明,湖区周围的硅酸盐风化其碳源主要为土壤CO2,热泉区硅酸盐水解其碳源为地球深部CO2输入。 相似文献
18.
The hydrochemical and multivariate statistical techniques such as the principal component analysis (PCA) and the cluster analysis (CA) were used to identify the hydrochemical processes and their relation with groundwater quality and also to get an insight into the hydrochemical Zana aquifer groundwater chemistry evaluation. Twenty-four samples during the wet season and even during the dry season are analyzed. The Piper diagram showed that water facies are magnesium bicarbonate on the sides of the western reliefs and magnesium chloride-sulfated at the north and the center of the plain. The PCA carried out on three factors revealed that on the factorial design F1-F3, nitrates negatively determine factor 3, indicating the presence of an agriculture pollution. On the factorial design F1-F2, HCO3? positively determine the factor 2, indicating the carbonated origin. However, the CA, based on variables, showed that the waters in the region can be classified into three groups according to flow direction while the CA, based on major ion contents, defined three groups, reflecting the same hydrochemical facies. The first group with dry residue varying between 360 and 1700 mg/l and characterized by Mg2+ and Cl?, HCO3?. Samples of this group are mostly located in the north and northeastern part of the region. The second group with highest dry residue (2080 to 3820 mg/l) characterized by Mg2+ and SO4?, Cl? is located near the Northwestern and western outcrops. The third group coincides with the central part, the lowest of the plain, with heightened dry residue (4140 to 13,950 mg/l), characterized by Mg2+ and SO4?. The hydrochemical study made it possible to allot the evaporitic origin to the elements Na+, Mg2+, K+, Cl?, and SO4?, while for element HCO3?, it results from the carbonated formations. These results showed that the presence of nitrates in the studied area is closely linked to the agricultural activity. 相似文献
19.
Deterioration of groundwater quality in the vicinity of an active open-tipping site in West Malaysia 总被引：3，自引：0，他引：3
Bahaa-eldin E. A. Rahim I. Yusoff A. R. Samsudin W. Z. W. Yaacob A. G. M. Rafek 《Hydrogeology Journal》2010,18(4):997-1006
There is an urgent need for characterization of leachate arising from waste disposal to ensure a corresponding effective leachate management policy. Field and laboratory studies have been carried out to investigate the impact of municipal landfill leachate on the underlying groundwater at a site in West Malaysia. The solid waste was disposed of directly onto an unprotected natural soil formation. This situation was made worse by the shallow water table. The hydrochemical composition of groundwater in the vicinity of the site (background) is a dilute mixed cation, bicarbonate water. The high ionic balance error of ~13.5% reveals that the groundwater body underneath the site was a highly contaminated leachate rather than contaminated groundwater. Elevated concentration of chloride (355.48 mg/L), nitrate (10.40 mg/L as NO3), nitrite (14.59 mg/L), ammoniacal-N (11.61 mg/L), sodium (227.56 mg/L), iron (0.97 mg/L), and lead (0.32 mg/L) measured downgradient indicate that the contamination plume has migrated further away from the site. In most cases, the concentration of these contamination indicators, together with the ranges of sodium percentage (66.3–89.9%) and sodium adsorption ratio (10.1–19.7%), were found to be considerably higher than the limit values of safe water for both domestic and irrigation purposes, respectively. 相似文献
20.
为了揭示黄土高原山地-沟壑区黄土地下水水化学特征及成因,对六盘山东西两侧山区及其西部典型黄土高原山地-沟壑区进行了多次实地考察,合理选择采样点,采集了浅层地下水监测水样。对采集的样品水化学数据进行了分析,结果表明:六盘山地区浅层地下水以低TDS重碳酸盐型为主,径流途径较短,循环条件较好,保持了较好的天然淡水资源状态;而在山地-沟壑区水化学类型则复杂多样,TDS平均值达1 870mg/L,淡水资源相对匮乏。结合各类水化学图可以看出,浅层地下水和地表水的离子来源优势机制以岩石风化为主,并且在山地-沟壑区受到不同程度蒸发作用控制。通过分析地下水中的离子浓度比以及锶元素,发现六盘山区主要为补给区和径流区,山地-沟壑区则是补给区、径流区和径流滞缓区,黄土地下水可能有来自六盘山岩溶水的补给。氟离子浓度和硬度超标是影响区域内水质的最主要因素,在受蒸发作用影响较大的地区尤为突出。黄土高原地下水资源的分布状况和质量参差不齐,保护好区域内较好的淡水资源并且按照地下水分布规律进行合理的开发与宏观调控,是缓解黄土高原水资源问题的关键。 相似文献