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1.
南极中山站区电气石及其与变质作用的关系 总被引：1，自引：0，他引：1
南极中山站区的巨晶“电气石”实际上是柱晶石。电气石的确存在,但颗粒细小,含量较低。根据其颜色、成分和产出特征,至少可分为三种类型,不同的电气石与变质作用发展的不同阶段有关。电气石在麻粒岩相变质作用条件下能够稳定存在,与其它硼硅酸盐矿物（即硅硼镁铝矿和柱晶石）的缓冲作用有关。 相似文献
2.
The composition of minerals of the titanite-malayaite series and their mineral assemblages and genesis were examined at the Bol’shoi Kan’on deposit in Magadan oblast and at other deposits. These minerals were demonstrated to be typomorphic Sn-bearing silicates in postmagmatic bimetasomatic hypabyssal calc skarns and skarnoids in tin-bearing provinces. The series of these minerals with similar crystal structures has a miscibility gap, and the minerals are characterized by notably different Sn concentrations. Moreover, titanite may contain Al, Fe, F, and OH, whose concentrations decrease in the Sn-bearing members of the series (malayaite). These silicates were formed at many deposits after the successive transforms of skarn mineral assemblages. The early assemblages include wollastonite in calcic carbonate rocks and diopside and salite in skarnoids. The latter minerals are replaced first by hedenbergite with subordinate amounts of vesuvianite and garnet first of grossular and then andradite composition. This process was syngenetic with the formation of borosilicates (danburite, axinite, and tourmaline). Ti thereby may be accommodated in grossular and Sn in Fe-bearing silicates, mostly, in andradite. Skarns often contain both titanite and malayaite, which were produced in these rocks earlier than cassiterite. The isomorphic series of these minerals has a miscibility gap. The oreforming processes ended with the crystallization of quartz, fluorite, and rare sulfides, including stannite. The late Sn-bearing minerals at some deposits are stokesite and Mg, Fe, and Ca stannates, which crystallized during malayaite replacement by newly formed calcite-quartz aggregates. The Sn-bearing sulfides are replaced by varlamoffite during supergene processes. 相似文献
3.
The genesis and composition of lazurite was considered in the metasomatic rocks and deposits of the Baikal area, Pamirs, Hindu
Kush, and other regions. It was shown that formation of lazurite is related to the prograde bimetasomatic or contact-metasomatic
magnesian skarn processes developing in dolomites. The skarnized sedimentary or metamorphic rocks should be salt-bearing,
contain sulfur-bearing minerals, and be affected by Cl-bearing hydrothermal solutions. Both abyssal and hypabyssal skarn bodies
show distinct zoning. Depending on the PT parameters, their metasomatic columns can vary, with the preservation of the Mg/Ca ratio from the carbonate precursor. The
formation of contact-metasomatic lazurite mineralization is promoted by high-alkali magmatic solutions, which cause the replacement
of dolomites by skarn. Lazurite can also be formed during the postmagmatic stage, owing to a change in the mineral composition
of the adjacent aluminosilicate and magnesian-skarn rocks at abyssal and hypabyssal deposits around the world. The occurrence
of authigenic lazurite emphasizes its polygenetic formation.
Original Russian Text ? S.M. Aleksandrov, V.G. Senin, 2006, published in Geokhimiya, 2006, No. 10, pp. 1053–1067. 相似文献
4.
Granite- and gabbrodiorite-associated skarn deposits of NW Iran 总被引：1，自引：0，他引：1
Field and laboratory studies show that there are two types of skarn deposits in NW Iran: granite-associated (type I) and gabbrodiorite-associated (type II). Granite-associated deposits are accompanied by Cu and Fe mineralisation, whereas Mn and Fe are the main ore metals in gabbrodiorite-associated skarn deposits. There are some differences in the mineralogy of these skarn deposits. Bixbyite, piemontite and Cr-bearing garnet are found only in gabbrodiorite-associated skarns, whereas idocrase occurs only in granite-associated deposits. Type II skarns show exoskarn features, whereas some type I skarns have developed endoskarn as well. Evidence of boiling of hydrothermal fluid can be seen in both types and seems to be a common mechanism of mineral deposition. Gabbrodiorite-associated skarns show higher fO2 than granite-associated deposits. Based on mineralogical and textural evidence, mineralisation in both groups has started from about 550 °C. Early formed anhydrous minerals have begun to be replaced by hydrous minerals from about 400 °C.It seems that due to low fluid content in the gabbrodioritic magma, heated meteoritic water in the surrounding volcanoclastic and tuffaceous rocks was the main source of hydrothermal solution in the gabbrodiorite-associated skarn system. 相似文献
5.
含金夕卡岩矿床产出构造环境和地质地球化学评价标志 总被引：10，自引：0，他引：10
近十几年来,含金夕卡岩矿床的勘查与研究在国内外取得了很大的进展,发现了一批大型矿床,从而引人注目。含金夕卡岩矿床主要集中分布于环太平洋成矿带,按其产出构造环境可分为三类,即中（新）生代褶皱带、古生代褶皱带和地盾（台）区。控矿地层主要为石炭—二叠系和三叠系碳酸盐岩,次为第三系和寒武系等。有关岩浆岩大多为浅成钙碱性中酸性侵入岩,属Ⅰ型;时代以燕山期和喜山期为主,少数为华力西期、加里东期和印支期。含金夕卡岩绝大多数为钙夕卡岩,只有少数属镁夕卡岩,又可进一步划分为还原型和氧化型。金属矿物组合的特征是常有砷化物、铋化物和碲化物存在,Ｃｕ,Ａｕ,Ａｇ,Ａｓ,Ｂｉ,Ｔｅ,Ｃｏ和Ｓｅ等元素组合是含金夕卡岩特征性的地球化学标志。矿床（田）常具明显的交代矿化分带,并可构成一定成矿系列,其综合交代矿化分带模式,自岩体向碳酸盐围岩方向依次为：Ｃｕ（Ｍｏ）→Ｃｕ（Ｆｅ）→Ｃｕ（Ａｕ）→Ａｕ→Ａｕ（Ｐｂ,Ｚｎ,Ａｇ）。矿物共生组合和流体包裹体研究表明,夕卡岩矿物形成于６８０～３２０℃,盐度为ｗ（ＮａＣｌ）＝５９５％～１８６％,金的沉淀发生在夕卡岩期后的退化热液交代阶段,大致相当于温度为３５０～１５３℃,盐度ｗ（ＮａＣｌ）＝２４％～? 相似文献
6.
福建马坑铁（钼）矿床矽卡岩矿物学特征及分带研究 总被引：3，自引：0，他引：3
马坑大型铁(钼)矿赋存于莒舟-大洋花岗岩体外接触带黄龙组(C2h)灰岩和林地组(C1l)碎屑岩层间构造破碎带中,铁矿与矽卡岩密切共生,但矿床成因尚存在争议。本文就马坑铁矿矽卡岩进行了矿物学特征研究。电子探针分析结果表明:该矿矽卡岩矿物组合主要为辉石、石榴子石和钙蔷薇辉石,退化蚀变岩矿物组合为角闪石、绿帘石、绿泥石、石英等。单斜辉石以透辉石和钙铁辉石为主,仅存在少量锰钙辉石;似辉石为钙蔷薇辉石和蔷薇辉石;石榴子石端元成分以钙铁榴石为主,钙铝榴石少量;角闪石属于钙角闪石,矿物学特征表明它们形成于相对较氧化的条件下。马坑铁矿的矽卡岩是由热流体沿灰岩与碎屑岩之间层间构造破碎带交代形成的,铁矿石大部分产于矽卡岩内,磁铁矿多稍晚于矽卡岩,不仅广泛交代矽卡岩,而且还直接交代灰岩、砂岩等围岩,呈交代结构;主矿体下盘常出现厚层石英岩,碎屑岩也出现了明显的交代,矽卡岩分带现象普遍,与典型矽卡岩矿床特征一致。结合矿床地质特征,马坑铁矿矿床类型应为层控矽卡岩型矿床。 相似文献
7.
The borate mineralization of the Pitkáranta skarn field of Karelia is localized in metasomatically altered Proterozoic dolomites.
In the contact aureole of rapakivi granites, the zoning of magnesian skarns includes spinel-diopside or fassaite skarns with
syngenetic magnetite and spinel-forsterite calciphyres surrounded by periclase marbles, which confirms their hypabyssal genesis.
Stringer-stockwork bodies developing in the brecciation zone at the roof show a primitive zoning consisting of an inner diopside
and an outer forsterite calciphyre zone grading into a dolomitic marble. All these zones inherited the Ca/Mg ratio of the
primary carbonate rocks. Rhythmically banded textures observed in the skarns and calciphyres of the deposits studied suggest
their formation under thermodynamically disequilibrium conditions typical of hypabyssal metasomatites. Magnesium and magnesium-iron
borates in marbles and calciphyres and beryllium borates in greisens were formed during the postmagmatic stage. Data are reported
on the chemical composition and genesis of suanite, kotoite, ludwigite, hulsite, pertsevite, fluoborite, szaibelyite, and
humites from the Hopunvaara, Klara, Lupikko, and Herberz deposits. The deficit of boron in magnesian borates is related to
their endogenous hydration. Data on hambergites and berborite are given according to E.I. Nefedov. 相似文献
8.
S. M. Aleksandrov 《Geochemistry International》2011,49(7):711-725
The results of skarn-forming processes at contacts of the multiphase Southern California Batholith with carbonate rocks accessible
to study in quarries in Riverside, California, involve prograde metasomatic transformations of marmorized dolomites and calcareous
rocks in contact with granitic melts and contaminated magmas. The processes of contact assimilation are proved to have been
controlled by the emplacement of granitic melts overheated relative to subliquidus melts (with the overheated melts prone
to approach the composition of granodiorite, syenite, and gabbro) into skarnified marbles. The degree of magma overheating
was evaluated based on G.F. Smith’s data on linear melting temperature variations for anhydrous intrusive rocks with various
SiO2 concentrations (<750°C for granites and >1100°C for contaminated rocks, ΔT 350°). This corresponds to the thermal regime of the development of mineralogically contrasting hypabyssal skarn aureoles:
magnesian at contacts with granite magmas and calcic at contacts with melts of high basicity. The peripheral parts of the
aureoles ubiquitously contain preserved zones of forsterite calciphyres and periclase marbles, whereas skarns at mafic intrusions
consist of high-temperature silicates of decreasing Mg contents: monticellite, merwinite, melilite, and spurrite. Prograde
and retrograde mineralforming processes in the metasomatic rocks and their facies affiliation are analyzed, and the chemical
composition of the minerals are examined. The Riverside skarn aureoles are compared with other compositionally contrasting
skarn aureoles that developed in contacts with granite magmas and melts of increasing basisity. 相似文献
9.
R. Newberry 《Mineralium Deposita》1987,22(3):207-215
The polymetallic Pb-Zn-Ag-W-Cu-Au skarn and vein ores of the Darwin area, California, represent a metal association not common in skarn deposits. Detailed and regional geologic mapping combined with modal and chemical analyses of igneous rocks and electron microprobe and assay studies of calc-silicate rocks shows that there are three separate mineralizing systems which have been superimposed by structural and intrusive events. Scheelite-bearing skarns are associated with the alkaline Darwin stock; small Cu±Au skarns are adjacent to sheared (thrust-emplaced) granite-granodiorite masses; and Pb-Zn-Ag vein skarns are zoned around small granite porphyry dikes and plugs. Calc-silicate mineral compositions are also indicative of three different mineralization systems: W-skarns have high Fe pyroxenes and moderate Fe garnets; Cu-skarns have low Fe-pyroxenes and high Fe-garnets; and Pb-Zn skarns have high-Mn pyroxenes and garnets (patterns seen in other skarn deposits). Vein ores contain metals compatible with the subjacent skarns and apparently represent lower-temperature remobilization of skarn ores. 相似文献
10.
Fluid metasomatic genesis of stratiform skarn in the Suoerkuduke Cu-Mo deposit,East Junggar,NW China
Stratiform skarns associated with ore deposits are widespread in the north of East Junggar, particularly in the Suoerkuduke Cu-Mo deposit. The Suoerkuduke stratiform and stratoid skarns are hosted by Devonian intermediate-mafic volcanic and pyroclastic rocks, mainly andesite, andesitic porphyry and tuffaceous sandstone, without carbonate or calcareous rocks. The skarns consist of dominant andradite-grossular, epidote, diopside-hedenbergite and minor actinolite, quartz, magnetite and metallic sulfides. The garnet and epidote composition, especially Fe3 + and Al contents, is largely a function of the bulk composition and physicochemical environment (particularly fO2) during crystallization. Such mineralogy indicates a relatively oxidizing environment and medium acidity of solution during skarnization.The Suoerkuduke skarns are distinct from typical contact metasomatic skarn in wall rock, as no carbonate or calcareous rocks were found, and differ in the distribution patterns of skarn zonation in that gradually weakened skarn zones are not quite symmetrically distributed on both sides of the alteration center (a garnet skarn). Abundant remnants of andesite, andesitic porphyry and tuffaceous sandstone in the weakened skarn zone indicate that the protolith of the skarn is andesite, andesitic porphyry and tuffaceous sandstone. Magmatic water, meteoric and seawater are involved in skarn alteration. Moyite and granitic porphyry are not coeval with skarn, and their emplacement resulted in the hornfelization of wall rock instead of skarnization, and themselves keep away from skarn alteration. Therefore, there was probably a huge batholith supplying magmatic fluid for skarn formation. Mass balance estimates suggest that hydrothermal fluid must contribute a portion of Ca and Fe to ensure sufficient supply for skarn formation in the absence of local carbonate and calcareous rocks. In conclusion, the stratiform skarns in the Suoerkuduke are products of intermediate-mafic volcanic and pyroclastic rocks metasomatised by hydrothermal fluid that probably leached calcareous wall rock during ascent. 相似文献
11.
Dušan Němec 《Mineralogy and Petrology》1968,12(4):321-349
Summary The iron-ore skarns of the core of the Bohemian Massif is an old petrographic unit which is already doeply metamorphosed under conditions of an abyssal metamorphism. The paragenetical analysis as well as the chemical study of their mineral assemblages makes it clear that the amphibole occuring in subordinate quantities in these skarns is not a relic mineral (having not originated during the premetamorphic skarnization period). It appeared only in the course of the regional metamorphism in connection with the migmatization processes which took place in the rocks adjoining the skarn bodies and in connection with the injections of pegmatites traversing the skarn rocks.
Mit 11 Textabbildungen 相似文献
Mit 11 Textabbildungen 相似文献
12.
《International Geology Review》2012,54(11):1020-1039
The Shizhuyuan deposit is the largest among the economically important polymetallic tungsten deposits in China. The deposit occurs within the thermal aureole of Yanshanian felsic intrusions that were emplaced into Devonian carbonates and marls. The mineralization can be divided into three phases that are genetically associated with three episodes of granitic emplacement-pseudoporphyritic biotite granite, equigranular biotite granite, and granite porphyry. During the emplacement of pseudoporphyritic biotite granite, thermal metamorphism and subsequent skarnization developed around the stock. The pure limestone was transformed to marble, whereas marls and argillite interlayers were changed to a series of metamorphic rocks such as grossular-diopside hornfels, wollastonite hornfels, diopside hornfels, wollastonite-vesuvianite hornfels, muscovite-K-feldspar-anorthite hornfels, and prehnitevermiculite hornfels. Because of the subsequent strong skarn development, most hornfelses later were transformed into skarns. The skarns distributed around the granite stock are mainly calcic. They are massive in structure, and are composed mainly of garnet, pyroxene, vesuvianite, and wollastonite, with interstitial fluorite, scheelite, and bismuthinite. Although there is no cassiterite in the early skarns, their tin contents average 0.1%. The distribution and compositional and mineralogical relationships of skarn minerals suggest that they formed as a result of progressive reactions of a hydrothermal solution with a limestone of generally constant composition, and that the dominant process was progressive removal of Ca and addition of other constituents to the rocks. Following the primary skarn formation, some of the assemblages were retrograded to new assemblages such as fluorite-magnetite-salite rock, magnetite-fluorite-amphibole rock, and magnetite-fluorite-chlorite rock. The retrograde alteration of the skarns is characterized by a progressive addition of fluorine, alkali components, silica, tin, tungsten, and bismuth. A zonation from garnet-pyroxene skarn or garnet skarn, through fluorite-magnetite-salite rock, to magnetite-fluorite-chlorite rock frequently can be recognized in the deposit. All retrograde-altered rocks contain scheelite, cassiterite, molybdenite, and bismuthinite. During the emplacement of equigranular biotite granite, skarn veins several tens of centimeters wide were developed; they contain large crystals of garnet and vesuvianite, and interstitial scheelite, wolframite, cassiterite, and molybdenite. This second stage of mineralization occurs predominantly as coarse and fine stockwork greisens, which were superimposed on the massive skarns and surrounding marble. Such W-Sn-Mo-Bi-bearing greisens can be divided into topaz greisen, protolithionite greisen, muscovite greisen, and margarite greisen. Besides calcic skarn veins and greisens, manganese skarn veinlets also were developed; they consist of rhodonite, spessartine-almandine solid solution, spessartine, and helvite. The distribution of greisens is responsible for a metal zonation—i.e., W-Sn-Mo-Bi and Sn-Be-Cu-F zones from the contact boundary between the granite stock and skarns outward in the deposit. A third stage of mineralization is represented by lead-zinc veins, which also are accompanied by manganese skarns consisting of spessartine, rhodonite, manganese-rich pyroxene, helvite, tephroite, fluorite, tourmaline, and manganese-rich phlogopite. 相似文献
13.
滇东南老君山锡-钨-锌-铟多金属矿集区含矿矽卡岩成因研究 总被引：2，自引：2，他引：0
滇东南老君山矿集区广泛分布的矽卡岩是本区锡-钨-锌-铟多金属矿床的主要赋存围岩。长期以来,该区含矿矽卡岩的成因争议较大,由此也制约了对该区锡钨多金属成矿规律的认识。本文以区内代表性的都龙和南秧田矿区含矿矽卡岩为研究对象,在对其地质特征详细研究的基础上,运用电子探针和ICP-MS分别测定了上述两个矿区含矿矽卡岩的矿物成分、微量和稀土元素组成,探讨了它们和多金属矿床的成岩成矿机制的关系。结果表明,区内同时存在与地层产状一致的"层状"含矿矽卡岩和明显切割层理的穿层含矿矽卡岩。都龙矿区含矿矽卡岩富Fe、贫Al,主要矿物端元成分为钙铁榴石(And_(52-69)Gro_(28-45)Spe_(1-4))、钙铁辉石(Di_(11-41)Hd_(51-73)Jo_(0-28))和铁阳起石等,从干矽卡岩到退化蚀变阶段,形成环境由酸性的弱还原环境向偏碱性的相对氧化环境变化。南秧田矿区含矿矽卡岩富Mg、Al,贫Fe,主要矿物端元成分为钙铝榴石(Gro_(82-89)Alm_(7-13)And_(2-5))、透辉石(Di_(55-81)Hd_(18-42)Jo_(0-5))和透闪石(阳起石)等,形成于相对还原的环境。都龙和南秧田矿区含矿矽卡岩与花岗岩都显示出相似的、LREE相对富集的右倾型稀土配分模式,多具有中等-弱Eu负异常,与典型的热液交代成因矽卡岩特征相似。综合分析认为,该区含矿矽卡岩主要形成于燕山晚期花岗岩浆热液与围岩的交代作用,"层状"矽卡岩可能是热液沿层间构造、岩相突变带等有利位置进行交代的结果。 相似文献
14.
S. M. Aleksandrov 《Geochemistry International》2010,48(12):1220-1236
The boron, tin, tungsten, beryllium, and fluorite deposits of the York Range, Seward Peninsula, represent the continuation
of the Asian segment of the Pacific ore belt and are globally conjugate with the Verkhoyan-Chukotka ore province of Northeastern
Russia. They are localized in the alteration aureoles of dolomites and limestones of the Paleozoic Port Clarence Formation
at the contact with the Mesozoic leucocratic granites and genetically belong to the magnesian-skan ore formation. Ore-generating
process developed in marbles, skarns, and greisens under hypabyssal conditions in several stages and was accompanied by sequential
formation of polymineral assemblages. Early mineralization is represented by magnetite in prograde pyroxene skarns after dolomites.
Postmagmatic ore stage is represented by formation of endogenous borates, including their tin-bearing Mg-Fe species, in the
magnesian skarns, superposition of calcareousskarn assemblages containing calcium borates, borosilicates, and scheelite, formation
of cassiterite and wolrframite in the greisenized granites, and precipitation of sulfides, chrysoberyl, and fluorite. The
mineral composition of the rocks and ores was formed under the influence of F-bearing hydrothermal solutions, which caused
the presence of fluorine in borates, rock-forming silicates, and the replacement of calcite by fluorite. Boron, tin, beryllium,
and fluorine participate at all the stages of endogenous process, but the mineral modes of their occurrence are varied, which
is confirmed by data on their chemical composition. The results of studying the skarns and ores of the Alaska deposits are
of great applied and scientific significance, and can be used for study of skarn-greisen deposits localized at the contacts
of carbonate rocks with granite intrusions of the Pacific ore belt and other world’s regions. 相似文献
15.
从地质产状、矿物组合和岩石化学成分等方面探讨了个旧塘子凹接触带不同类型夕卡岩的特征。该夕卡岩带从内侧到外侧常具有辉石夕卡岩带和石榴子石夕卡岩带交替出现的现象，其岩石化学成分也相应地发生韵律变化，表现为在辉石夕卡岩带中SiO2和MgO含量较高，而在石榴子石夕卡岩带中CaO、TFe和Al2O3含量较高。认为夕卡岩带中的韵律变化一方面与被交代围岩中存在灰质白云岩和大理岩的互层带有关，另一方面与岩浆期后热液的渗滤交代作用有关。围岩中的灰质白云岩层被交代后形成辉石带，大理岩层被交代后形成石榴子石带。 相似文献
16.
繁昌桃冲铁矿成因探讨 总被引：1，自引：0，他引：1
The problems of the formation conditions for stratiform skarns and the genesis of the Taochong iron deposits are dealt with in this paper. Following is a summary of this discussion: 1. Stratiform skarns in this area occur in carbonate rocks of the Upper and Middle Carboniferous Period and the lower part of the Permian Qixia Group. No outcropping or concealed igneous bodies have ever been found, let alone any indications of an igneous contact zone or a corresponding zonality from "dry" skarn to "wet" skarn. The mineral facies and zonation of the skarns depend predominantly on the properties of the initial host rocks, and the development of skarns seems to have had much to do with chemical potential of silicon in these host rocks. As a result of the reaction of iron-bearing carbonates with siliceous materials in the rocks, iron-bearing silicates were formed, which in turn were transformed by pneumato-hydrothermal processes of the later stage. The stratiform skarns of this area, therefore, probably fall into the category of stratabound skarns subjected to transformation of thermometamorphism. 2. The iron deposits bear undisputable stratabound characteristics. The positions of ore-bearing beds and the petrological features as well as the mineral associations all point to a sedimentary ore-forming process of iron-carbonate (siderite). The presumption of siderite ore source is supported by the following facts: (l) Remnants of sedimentary siderite which survived the metamorphism have recently been observed in magnetite ore from neighbouring Xinqiao mining area. Siderite can have as many as 12.07% Fe++ and, after corrosion, shows oolitic texture. (2) The ore is mainly of calcite/ dolomite- magnetite type. Mineral associations are quite simple and sulfides are rarely seen. (3) A comparison of the analytical data suggests that the content of organic carbon in iron ore decreases due to oxidation caused by metamorphism but is still higher than that in magnetite of contact- metasomatic skarn. (4) The paleogeographic reconstruction shows that this area was once an ancient underwater uplift favorable for the precipitation of iron carbonates. After its formation, the siderate bed underwent thermodynamic metamorphism and was hence decomposed into magnetite, which was then subjected to the superimposed transformation by subsequent hydrothermal fluids, leading to the partial activation and migration of iron matter and thus the formation of such ore as hematite (specularite) at shallow depth of the Changlongshan mining area. In brief, this deposit has a complex genesis: it experienced sedimentation, thermal metamorphism and transformation by hydrothermal fluids. 相似文献
17.
A newly identified skarn occurrence is described from the Neoproterozoic rocks of the SW Arabian shield. It is exposed to the SE, E and NE of the Al-Madhiq town. The skarn attributes correspond to those typical of the calcic skarns that host W-deposits. It is characterized as an exoskarn of the proximal type, related to a granitoid contact close to an impure quartzite bed within the regional metamorphic rocks of mixed sedimentary and volcanic derivation. The skarn is localized along a shear zone parallel to the regional faults and other major shear zones. Samples from the studied area contain characteristic skarn minerals that include both the prograde (brownish red grossular, ferrosalite, aluminian titanite-grothite, albite-oligoclase, scapolite), and retrograde (epidote, quartz, hornblende, calcite) assemblages. The pyroxenes are ferrosalites, Mn-bearing, and more like those from “oxidized” skarns; although garnets indicate it to be a “reduced” type skarn. Epidote mimicks that from typical skarns, as it bears a pistacite content of 15.9–20.7%. Grossular composition reflects a largely reduced genetic environment; as it is in solid solution with 6.5–21.6% andradite, 0–0.15% uvarovite, 0–0.47% pyrope, 4.33–18.75% almandine, and 0.4–8.58% spessartine molecules. Titanite composition varies from aluminian titanite to grothite, that may be analogous to the newly described Al-rich titanite from the low-pressure calc-silicate rocks. 相似文献
18.
繁昌桃冲铁矿成因探讨 总被引：3，自引：0，他引：3
桃冲铁矿,开采历史悠久,由于其品位富,以平炉富矿为主要矿石类型,受到了重视。有关矿床的成因也一直被人们所注意。自三十年代提出火成接触变质——热液成因的观点以来(谢家荣、程裕淇1935),人们习惯于将矿床划归于矽卡岩型。作者通过野外调查和初步研究之后,对本区铁矿的成因产生了疑问。本文就现有资料的分析,对层状矽卡岩的形成条件和铁矿的成因,做如下讨论。 相似文献
19.
The paper addresses the composition and genesis of endogenous borates from hypabyssal skarn deposits of Japan (Honshu Island) that were formed after dolomitic, rhodochrosite, and calcareous marbles in the contact aureoles of magmatic intrusions of diverse felsicity (from granites to diorite-monzonites). Metasomatic bodies formed at the prograde stage of the mineral formation are characterized by clearly expressed zoning of primitive type. Borates occur in the calciphyres at the Neichi, Kaso, and Rito mines, and are developed in calcitic marbles at the Fuka mine. Depending on initial composition of carbonate rocks, borates are represented by suanite, kotoite, jimboite, and takedaite in the outer zones of spinel-forsterite and galaxite-jacobsite-tephroite calciphyres or calcitic marbles, respectively. It was shown that early borates are subjected to hydration that is expressed in variable deficit of boron. At the next stages of hydrothermal mineral formation, they are replaced by pertsevite, wiserite, sibirskite, and other borates. 相似文献
20.
R. Kretz 《Geochimica et cosmochimica acta》1960,20(3-4):161-162
Skarns composed predominantly of Ca pyroxene, Ca amphibole, and biotite occur locally in the Grenville metamorphic terrain of the Canadian pre-Cambrian Shield. The enclosing rocks are Grenville gneisses and limestones, gabbroic rocks, veined gneisses, and granitic rocks. The metamorphic grade of the skarns is identical to that of the enclosing rocks, namely the upper region of the amphibolite facies.
Twelve skarn specimens were selected for chemical study. An investigation is made of the concentrations of Al, Fe, Mg, Mn, Ti, Ca, Na, K, Ba, V, Cr, Zr, Y, and Sc in eleven Ca pyroxenes, ten Ca amphiboles, and eleven biotites.
Consideration is given to the distribution of elements among coexisting minerals. Regular relationships appear when
1. (1) the concentration of an element in a mineral is related to the concentration of the element in a coexisting mineral by a linear or non-linear function
2. (2) the linear or non-linear function is itself a function of the concentration of another element in one or both of the coexisting minerals. These relationships indicate that, for the most part, minerals within each skarn specimen closely approached a state of chemical equilibrium.
A preliminary attempt is made to explain the distribution relationships in terms of crystal chemistry. 相似文献