共查询到20条相似文献，搜索用时 31 毫秒
1.
Bonang B.M. Nkoane Gerald M. Sawula Grethe Wibetoe Walter Lund 《Journal of Geochemical Exploration》2005,86(3):130-142
Plant species that accumulate high levels of metals in proportion to the metal content in the soil are of considerable interest in biogeochemical and biogeobotanical prospecting. This study was aimed at investigating copper and nickel accumulation in the plants Helichrysum candolleanum and Blepharis diversispina, to assess their potential use as mineral indicators in biogeochemical prospecting. Soils and plants were collected from copper–nickel mineralised areas in Botswana. Analyses of the soils and the respective plant parts (roots, stem, leaves and flowers) were carried out using ultrasonic slurry sampling electrothermal atomic absorption spectrometry (ETAAS), which allowed rapid determination of copper and nickel in small amounts of the samples.The metal concentration in the soil was in the range ≈ 40 μg/g–4% (w/w) for Cu and ≈ 60 μg/g–0.3% (w/w) for Ni. The concentration ranges of the elements in the plant parts were ≈ 6 μg/g–0.2% Cu and ≈ 3–210 μg/g Ni. At high soil metal content (greater than 2.5% (w/w) Cu and 0.1% (w/w) Ni), high levels of both nickel and copper were found in the shoots (leaves and flowers) of H. candolleanum. Concentrations as high as 0.2% (w/w) Cu were found in the leaves and flowers of H. candolleanum, indicating hyperaccumulation for this plant. For B. diversispina, the metal concentrations did not exceed 100 μg/g for any plant part, for both metals. Both plant species tolerate high concentrations of metals and should therefore be categorized as metallophytes. In order to evaluate metal translocation from the soil to the shoots, metal leaf transfer coefficients (ratio of metal concentration in the leaf to metal concentration in the soil) were calculated. Our data suggest that the two plant species have different metal uptake and transport mechanisms, which needs to be investigated further. The present work also suggests that H. candolleanum may be used as a copper/nickel indicator plant in biogeochemical or biogeobotanical prospecting. 相似文献
2.
H.V. Warren S.J. Horsky A. Kruckeberg G.H.N. Towers J.E. Armstrong 《Journal of Geochemical Exploration》1983,18(3):169-173
Summary of biogeochemical prospecting for mercury mineralization in the Pinchi Fault is given. One thousand two hundred and eight plant samples were collected and analyzed for mercury. In mineralized areas the typical mercury content of dried plants was not less than 0.2 and 0.4 μg/g and even concentrations between 0.6 and 1.6 μg/g were observed. In nonmineralized zones at least 90% of the plants contained no more than 0.15 μg/g of mercury. Analytical and sampling procedures are described. 相似文献
3.
A biogeochemical orientation survey was carried out in the vicinity of an epithermal Au deposit in the Moisan Au–Ag mineralized area, Haenam district in Korea. The Au–Ag bearing quartz veins of the mine occur as narrow open-space fillings within Cretaceous silicic pyroclastics. The vein minerals consist mainly of quartz, sericite, pyrite, chalcopyrite, and galena, with some electrum and argentite. The main objectives of this study were to study the geochemical characteristics of rocks, soils and plants in this area, to investigate the spatial relationship between Au and associated elements in rock–soil–plant system, and to evaluate the applicability of biogeochemical prospecting for Au vein occurrences in Korea. Samples of rocks and soils, and leaves of three plant species (Japanese red pine — P. densiflora, oriental white oak — Q. aliena, Japanese mallotus — M. japonicus) were collected from the target mineralized area and control barren locations, and analyzed for trace elements by instrumental neutron activation analysis. Sampling lines were composed of one slope line which is almost parallel to the mineralized quartz-veins, and four transect lines spaced 100 m apart across the veins at 20 m sampling intervals. From the multi-element data of rock samples (n = 9), high values of Au (maximum 2030 ppb) are spatially related to Au–quartz veins. Soil samples (n = 61) collected from five sampling lines show higher values of Au (24–825 ppb) whereas soil samples from the control locations have lower values of Au (below 25 ppb). Many plant species collected from the vicinity of the veins have high Au contents compared with those at the control locations, but the ranges of Au values are variable among plant species. In a total of 128 samples of plant leaves, Q. aliena yielded Au values of 0.4 to 6.9 ppb, and M. japonicus 0.9 to 4.1 ppb. Gold contents in P. densiflora ranged from 0.1 to 5.6 ppb. Plant leaves from control areas show less than 1.6 ppb Au. The biological absorption coefficient (BAC) of Au in plants decreases in the order of Q. aliena > M. japonicus > P. densiflora. Based on the results of the study, Q. aliena appeared to be the best sampling media for biogeochemical prospecting of Au in the study area. 相似文献
4.
Concentrations of Au, Ag, As, Cd and Sb in aquatic bryophytes collected from the Dolgellau Mineral Belt, North Wales, U.K. are reported. One aquatic liverwort, Scapania undulata (L) Dum. and two mosses, Fontinalis squamosa Hedw. and Racomitrium aciculare (Hedw.) Brid. were collected from sites upstream and downstream of the recently reopened Gwynfyndd Au mine. There was little inter-species variation in metal contents for these three bryophytes, but Scapania undulata appeared the most sensitive to changes in water concentrations of Ag, As and Sb. Gold concentrations varied little between the contaminated and control sites. Concentrations in the range < 4–18 ng Aug g−1 D.W. were typical background levels, while bryophytes collected immediately below the mine contained 6–45 ng Au g−1. Silver and Sb both showed more pronounced ( 5–10 fold) elevations above control concentrations in samples collected downstream of the mine. Background concentrations for these elements were 5–85 ng Ag g−1 and 0.15–1.3 μg Sb g−1.Arsenic concentrations downstream of the mine (160–1080 μg g−1) greatly exceeded the background range of 9–32 μg g−1. It is suggested, therefore, that As may be an ideal ‘pathfinder’ element when prospecting for auriferous deposits using aquatic bryophytes. 相似文献
5.
The analysis of herbarium specimens has shown that unusual metal uptake by European species of Thlaspi (Cruciferae, mustard family) is not confined to the well-known accumulation of zinc from calaminiferous soils. At least twelve species show unusual accumulation of nickel, to levels of 1000–30,000 μg/g (dry-mass basis), from serpentine or other nickel-rich substrates. In addition, accumulation of zinc to levels above 1000 μg/g in the dry mass of the plant is widespread; about three-quarters of the European species, from a wide variety of soil types, have been found to exhibit this behaviour in the natural state. These observations are significant in many fields, including taxonomy, plant physiology and phytochemistry, but are particularly important in extending the potential of biogeochemical methods of mineral exploration. 相似文献
6.
An orientation survey was conducted over the Quartz Mountain, Oregon, hot-spring type disseminated gold deposit to address three questions critical to successful exploration of the area: What is the relationship between bedrock geology and the trace-element content of trees and soils; do these relationships change seasonally; are these relationships similar in the two tree species which discontinuously blanket the area?Twig, needle and wood samples were collected four times during the year from both ponderosa pine (Pinus ponderosa) and white fir (Abies concolor). Soils were collected once. All samples were analyzed for Au and As and the wood samples were analyzed also for Sb.Arsenic was the best pathfinder element, having little analytical, spatial, or seasonal variation in the twig and needle samples. Anomalous levels were 150 μg/g (ppm) As in pine and 30 μg/g in fir. Gold showed analytical variation of 20–30%, sample duplicate variation up to 90%, spatial changes, and seasonal variation ranging from winter-summer background [10–20 ng/g (ppb) Au] to anomalies of 300–400 ng/g (ppb) Au in pine and 100 μg/g (ppb) Au in fir in the spring and fall. Antimony could not be completely evaluated as a pathfinder element because it was only determined in wood samples.Needles and twigs from both species proved to be viable sample media for exploration of the area. Wood was not a suitable medium because of low, erratic values, perhaps due in part to analytical technique. Needles had 2 to 20 times higher As concentrations than did twigs. Twigs had a slightly higher Au content [25 ng/g (ppb)] than did needles. The pine samples were higher in both elements than were the fir samples. The data, normalized by species, could be treated as one homogeneous data base.The soil Au and As data outlined the mineralization clearly with a central Au anomaly [100 ng/g (ppb) and greater] surrounded by As anomalies [100 μg/g (ppm) and greater] over a distance of 594 m. Neither spring nor fall tree Au anomalies were coincident with the soil Au anomaly. Consistent throughout the year, tree As anomalies coincided with the soil As anomalies, but covered a smaller area. Both the Au and As anomalies in trees appeared to be related to bedrock contact zones rather than to the soil the trees were growing in. 相似文献
7.
This contribution is a short history of the Zambian copper flower, Becium homblei (recently renamed B. centraliafricanum that has attracted attention as a plant associated with Cu-rich soils. It has a peculiar discontinuous distribution in Central Africa which has been explained in terms of biotype depletion. A field investigation into the ecology of the species shows that it is able to tolerate soil Cu concentrations of up to 15,000 μg/g (ppm), and soil nickel concentrations of nearly 5000 μg/g. B. homblei is also found on areas where soil metals are in trace quantities, and where soil bases, particularly Ca, are low. In spite of its tolerance to a wide range of edaphic conditions, the distribution of the species is very restricted in Zimbabwe, and this is almost certainly due to severe interspecific competition with a closely related species, B. obovatum, which is common on soils not unusually enriched in heavy metals. Pioneering work on geobotanical prospecting by use of Becium homblei was carried out by the late G. Woodward and others in the 1950s and 1960s. This species was used successfully for geobotanical prospecting for Cu. This present report is a brief history of these pioneering studies 相似文献
8.
遥感生物地球化学找金矿方法研究进展 总被引：7，自引：0，他引：7
总结了金矿的生物地球化学性质、植物的生物地球化学效应特征以及其波谱和遥感影像特征，以及利用遥感图像处理提取生物地球化学效应引起的植被光谱异常信息的专题信息提取方法。研究表明，在金矿区上生长的植物对金及伴生元素有较强的吸收和聚积作用，植物明显受到生物地球化学效应的毒化作用；金及伴生元素的过量吸收，使植物叶片中的叶绿素、类胡萝卜素含量、水含量和叶面温度相应降低；植物叶片细胞结构发生变异，叶冠波谱反射率和波形等光谱特征明显变化；在遥感图像上，金矿区的植被表现出异常特征信息。这些信息可以作为在植被区寻找隐伏矿床的遥感生物地球化学找矿的标志。利用遥感生物地球化学的理论和技术方法，从遥感数据中分析金矿的植被图像特征，提取与金矿化有关的植被异常特征信息，可以优先出金矿化遥感异常区，并列举了几个应用实例。同时，指出了需加强该领域的理论和应用研究，为广大植被覆盖地区寻求一种快速有效的探矿方法。 相似文献
9.
The Okchon black shale in Korea provides a typical example of natural geological materials enriched with potentially toxic elements. The Chung-Joo, Duk-Pyung, Geum-Kwan, I-Won, Bo-Eun and Chu-Bu areas are underlain by these black shales and slates of the Guryongsan Formation or the Changri Formation, which are parts of the Okchon Group in the central part of the southern Korean Peninsula. In order to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock–soil–plant system, environmental geochemical surveys were undertaken in the above six study areas in the Okchon Zone. After appropriate preparation, rock and soil samples were analyzed for potentially toxic elements by instrumental neutron activation analysis (INAA) and inductively coupled plasma atomic emission spectrometry (ICP-AES), and plant samples by atomic absorption spectrometry (AAS). In particular, Ba, Cd, Mo, V and U in Okchon black shales are highly enriched, and their mean concentrations are significantly higher than those in black slates. These elements are geochemically associated, and might be enriched simultaneously. The highest mean concentrations of 42.0 μg g−1 As, 2100 μg g−1 Ba, 10.9 μg g−1 Cd, 213 μg g−1 Mo, 83 μg g−1 U, 938 μg g−1 V and 394 μg g−1 Zn are found in black shales from the Duk-Pyung area. Mean concentrations of As, Mo and U in soils overlying black shales occurring in the Duk-Pyung area (30 μg g−1 As, 24 μg g−1 Mo and 50 μg g−1 U) and Chu-Bu area (39 μg g−1 As, 15 μg g−1 Mo and 27 μg g−1 U) are higher than the permissible level. Enrichment index values of the six study areas decrease in the order of Duk-Pyung > Chu-Bu > Bo-Eun > Chung-Joo > Geum-Kwan = I-Won areas. Relationships between trace element concentrations in soils and plants are significantly correlated, and the biological absorption coefficients (BAC) in plants are in the order of Cd > Zn = Cu > Pb, which suggests that Cd is more bioavailable to plants than the other elements. Cadmium concentrations in plant species decrease in the order of chinese cabbage > red pepper > soybean = sesame > rice stalk > corn > rice grain. From the result of sequential extraction analysis of soils, relatively high proportions of Cu, Pb and Zn are present as residual fractions, and that of Cd as non-residual fractions. Cadmium occurs predominantly as exchangeable/water-acid soluble phase in soils, and this is in agreement with the findings of high Cd concentrations in plants. 相似文献
10.
11.
Li Miao Ruisong Xu Yueliang Ma Jinhong Xu Jie Wang Rui Cai Yu Chen 《Journal of Geochemical Exploration》2008,96(1):43-52
In the Hetai goldfield, Guangdong Province, China, samples including rocks, soils and leaves of four plants (Pinus massoniana, Rhodomyrms tomenlosa, D. linearis var. dichotoma and Embelia laeta) collected from the gold mineralization zone and the background area were analyzed for Au, Ag, Cu, Pb, Zn, Hg, As and physiological parameters. The objective of this investigation is to study the geochemical and biogeochemical characteristics of studied plants, aiming at biogeochemical methods in Au exploration. The goldfield region shows geochemical and biogeochemical anomalies. Abundances of Au in rocks, soils, plants and the leaf pigments in the mineralized area are much higher than those in the surrounding region. The plants display unhealthy physiological and ecological characteristics in the Hetai goldfield area. The cell structures of the goldfield plants were anomalous and aberrant, and there were many nano-metal particles diffused in mitochondria and chloroplasts. Macro- and microscopic evidences of the vegetation in the goldfield areas are distinctly different from the background regions. The strongly anomalies in responses to Au are profound in further geochemical and botanic exploration studies. 相似文献
12.
The Nickel Plate deposit, in which gold occurs as <25 μm blebs associated with arsenopyrite in garnet-pyroxene skarns, is in the subalpine zone near the southern limit of the Thompson Plateau. During the last glaciation the Cordilleran ice sheet moved south-southwest across the deposit and deposited a stony basal till. A dispersion train with anomalous concentrations of gold in tills and soils now extends 2 km down ice from the deposit.Gold contents of samples of humus (LFH horizon) and the −212 μm fraction of mineral soils (A, B and C horizons) was determined by instrumental neutron activation and fire assay-atomic absorption, respectively. Selected samples were examined in detail to determine distribution of gold between different size and density fractions.Despite erratic variability, Au contents of the −212 μm fraction generally decrease from 200–400 ppb close to the mine site to <50 ppb at distal sites. At most sites there is also a twofold increase of gold values down the soil profile. Within samples concentrations of Au in the −420 + 212 μm, −212 + 106 μm, −106 + 53 μm and −53 μm fractions are usually roughly constant. However, because of its abundance, the −53 μm fraction contains more than 70% of the gold. Amenability of gold in this fraction to cyanidation suggests that it is largely free gold. For size fractions > 53 μm the contribution of the heavy mineral (SG > 3.3) fraction to total gold content increases with decreasing grain size.Distribution of gold between size and density fractions is consistent with its release from the bedrock or pre-glacial regolith by glacial abrasion. The bulk of the gold was incorporated into the fine fractions of the till at or close to the source. However, differences between down ice dilution ratios for gold in different heavy mineral size fractions suggest that comminution of host minerals continued to transfer gold to the finer size fractions during glacial transport.For exploration purposes, B and C horizon samples provide the best anomaly contrast. Estimates of the abundance of gold particles in different size fractions indicate that the nugget effect, which causes erratic gold values in the −212 μm fraction, can be avoided by analysis of 30 g of −53 μm material. 相似文献
13.
Rognvald Boyd Heikki Niskavaara Esko Kontas Victor Chekushin Vladimir Pavlov Morten Often Clemens Reimann 《Journal of Geochemical Exploration》1997,58(2-3)
Eight catchments, an area of 15 to 35 km2, have been studied within an ecogeochemical mapping programme in the western Kola Peninsula and contiguous parts of Finland and Norway. Three catchments, one northeast of Zapolyarniy (1) and two, 5 and 25 km south of Monchegorsk (2 and 4) show high levels of deposition of heavy metals, especially nickel (Ni) and copper (Cu), related to the metallurgical industry in these cities. Twenty-five topsoil samples, from sites evenly distributed over catchment 2, have mean contents of Ni and Cu 1 to 2 orders of magnitude higher than both C-horizon samples from the same sites and topsoil samples from catchment 4, providing strong evidence for the anthropogenic origin of the heavy metals. The same samples show geometric mean total contents for the noble metals analysed of: 1.4 μg/kg rhodium (Rh), 49.6 μg/kg platinum (Pt), 187.6 μg/kg palladium (Pd) and 9.5 μg/kg gold (Au). The pattern of concentration of the noble metals mirrors that found in published averages for ore from the Talnakh mineralizations in the Noril'sk province, though 1–2 orders of magnitude lower. This also clearly shows that the noble-metal contents of the topsoil are anthropogenic, and suggests that they emanate from the plants in Monchegorsk at an early stage in treatment of the ore, probably as a minor component of Ni-Cu rich particles. The noble-metal geochemistry of the topsoil in the other catchments also reflects the nature of the ore being processed at the plants nearby. 相似文献
14.
Douglas fir trees and associated soils were sampled from the slopes of a small ( 4 km2) drainage basin in northeastern Washington to investigate the biogeochemical response to locally uraniferous groundwater. Uranium is preferentially incorporated in needles and twigs compared to larger branches or the trunk. The U concentration in needle ash ranges from 0.2 to 5.8 μg g−1 (ppm) and shows no correlation with the U concentration in associated soils. Rather, the distribution of anomalously uraniferous douglas fir (>1.0μg g−1 U in needle ash) appears to be controlled by observed or readily inferred pathways of near-surface groundwater movement in the drainage. These pathways include: (1) general downslope movement of subsurface runoff; (2) increased flux of near-surface groundwater near the toe of an alluvial fan; and (3) emergence of uraniferous (100–150 ng ml−1 [ppb] groundwater in the vicinity of a slope spring. The data also indicate the presence of near-surface uraniferous groundwater along a structurally controlled zone that parallels the north-south strike of the valley, and that includes the slope spring. The results suggest that biogeochemical sampling may be used to supplement more direct, but more limited, measurements of groundwater quality and flow regime in areas of near-surface contaminated groundwater. 相似文献
15.
The results described relate to an investigation into the nature of Au dispersion in glacial till, undertaken to identify optimum search techniques for use in exploration for Au mineralization.The diversity of Au mineralization, in terms of the host rock lithologies, mineralogy and grain size of the Au, would be expected to give rise to differences in the secondary response in the associated overburden. Common exploration procedures involve the analyses of the heavy-mineral fraction or a particular size fraction of the tills. However, having regard to the expected variable response of Au in associated glacial till, attributed to variations in primary mineralization, effective exploration requires that the methodology employed is capable of locating all types of Au mineralization.Bulk till samples were collected from various sites associated with the Owl Creek deposit near Timmins and the Hemlo deposits. Grain size analyses were carried out on the till samples and on the heavy-mineral concentrates. The concentration of the Au in the various fractions was determined by Instrumental Neutron Activation Analysis.Preliminary results allow a number of provisional conclusions to be drawn:
- 1. (1) Grain size analysis of the −2 mm fraction of tills indicates that the silt and clay fraction constitutes 20–50%, whereas, in contrast, the equivalent heavy-mineral concentrates are dominantly composed of the coarser −500 + 63 μm material.
- 2. (2) The amount of Au present in the heavy-mineral concentrates of tills represents only a minor proportion of the total Au in the original till samples. In addition, the proportion of the total Au recovered in the heavy-mineral concentrate varies from 4 to 15%. Both factors indicate that caution is necessary in interpreting the significance of heavy-mineral Au data.
- 3. (3) Examination of the size distribution of Au within the heavy-mineral concentrate indicates that the majority of the Au is contained in the −125 μm fraction.
- 4. (4) The concentration factor (the original sample weight divided by the heavy-mineral concentrate weight) varies up to 7-fold between samples due presumably to the differing proportions of heavy minerals. Hence, in Au deposits of equivalent economic significance this gives rise to varying Au concentrations in heavy-mineral concentrates according to the quantity of heavy minerals present. Significant interpretation can only be achieved by re-expressing the Au contents of heavy-mineral concentrates in terms of the absolute amount of Au in heavy-mineral concentrates.
- 5. (5) A comparison of the heavy-mineral concentrates produced by different laboratories indicates marked differences in the weight of the heavy-mineral concentrate, the Au concentration of the heavy-mineral concentrate, the total weight of Au in the heavy-mineral concentrate and the size distribution of the Au in the heavy-mineral concentrate.
- 6. (6) Analysis of the −63 μm silt and clay size fraction indicates anomalous Au contents within this fraction of the tills collected from Owl Creek and Hemlo, extending over 500 m down-ice from mineralization at Hemlo.
- 7. (7) Analysis of the −63 μm silt and clay size fraction is suitable for the detection of fine-grained Au deposits that are not amenable to detection on the basis of heavy-mineral concentrate analyses.
- 8. (8) The analysis of the silt and clay fraction reduces the sample representativity problems associated with analyzing coarser fractions.
- 9. (9) A comparison of the Au distribution in heavy-mineral concentrates and the −63 μm fraction of till down-ice from the Owl Creek deposit indicates broadly similar dispersion patterns.
16.
W.B. Coker C.E. Dunn G.E.M. Hall A.N. Rencz R.N.W. DiLabio W.A. Spirito J.E. Campbell 《Journal of Geochemical Exploration》1991,40(1-3)
A multidisciplinary geochemical study of the distribution, dispersion, and glacial dispersal, of the pge and associated elements has been undertaken within soil, till, humus, vegetation and water at Ferguson Lake, Northwest Territories, Rottenstone Lake, Saskatchewan and Sudbury, Ontario.As the pge generally are present at low levels in surficial materials, development work on analytical techniques was an essential part of this study.At Ferguson Lake, the spatial distribution patterns of Au, Pt and Pd in till clearly indicate the exposed gossan zones, as expected, but also indicate a possible extension of the zone beneath a peat bog- and till-covered area. Down-ice dispersal of Au, Pt and Pd is limited to one to two hundred metres, in the <63 μm component of the till samples collected from frost boils. In vegetation the pge enrichment extends for several hundred metres down-ice and is best defined by Pd in birch twigs. Detectable, although extremely low, levels of Pt (2.8 ppt) and Pd (2.0 ppt) are present in waters in the vicinity of the gossanous zones at Ferguson Lake.At Rottenstone Lake, moderate to high concentrations of pge, Au, and base metals were found in ashed twigs of black spruce and the hmc of the tills for a distance of less than two hundred metres down-ice of the mineralization. Low Pd and Au concentrations were present in ashed spruce twigs about one kilometre down-ice of the mineralization, where only the hmc of the tills yielded anomalous concentrations of Pt and Au. There appears to be only limited dispersal of the pge and Au. These data indicate that only the hmc and the spruce twigs are of value in detecting Pt and Au in this area. Palladium presents a different picture, being detectable in only some of the soils, absent in the tills and hmc, yet appreciably enriched in the twig ash. The inference is that Pd is moving in solution and is being somewhat adsorbed in the soil but is much more significantly being taken up by the plant roots.At the Sudbury areas the pge, hosted in the Ni-Cu mineralization, are best reflected by elevated levels in the ashed humus of almost all elements examined. There is only minimal response in pge and Au to the mineralization from any of the fractions of the soil; whereas the <2 μm fraction of the B-horizon soil reflects the mineralization by elevated levels of As, Sb, Se, Cr, Co, Ni, Cu, Pb and Zn. Only hmc from the tills show elevated pge, Au and variable enhancement in As, Sb, Se and the base metals. The < 2 μm portion of the tills tends to be highest in As, Se, Cr and the base metals.This ongoing study shows that surficial materials and vegetation are effective in identifying areas of concealed pge mineralization. Various pathfinder elements, primarily Cu and Ni, but perhaps also As, Se, Sb and the other base metals, in the < 2 μm B-horizon soils and tills, may be informative in a preliminary evaluation of the pge potential of an area, prior to undertaking the more expensive precious-metal analyses. Humus and vegetation both appear extremely effective, and most cost efficient, and heavy-mineral concentrates (hmc) appear effective, for identifying areas with pge potential, whereas hmc from tills appear most effective for zeroing in on the site of the pge mineralization. 相似文献
17.
Farnoosh Farjandi Abdolghader Faiziev Mokhtar Fozilov Hassan Bastani Sara Soleimani 《Arabian Journal of Geosciences》2013,6(5):1435-1446
The aims of present study are investigation of endemic plants at Masjed–Daghi area introducing hyperaccumulator and indicator plants for Au, Ag, As, Cu, Mo, Hg, Re, Sb, and Te mineralization and also describe the biogeochemical response pattern over a known Au–Cu mineralized site. The Masjed–Daghi prospecting area is covered by Eocene flysch, andesite, trachyandesite, dacite, rhyodacite, Oligocene agglomerate, and Quaternary deposits. Previous researches reported copper porphyry mineralization and related epithermal gold veins in this area. This study presents that plants with high metal intake enabled us to obtain invaluable information about natural concentrations of chemical elements in the substrate and to recognize new potential areas for mineral prospecting. Stachys inflata has biological absorption coefficient mean exceeding or near hyperaccumulating criterion >1 for most of the elements investigated then could be as a hyperaccumulator. The indicator values belong to S. inflata, Artemisia sp., Salvia sp., Astragalus sp., Peganum harmala, Moltkia coerulea, and Cousinia sp. 相似文献
18.
Metal response in plants to sulfide mineralization in the Longobucco area (Calabria, southern Italy)
G. M. Crisci B. De Vivo R. LaFratta V. La Valva A. Lima 《Journal of Geochemical Exploration》1982,17(3):187-204
The results of a multielemental biogeochemical orientation survey carried out in Calabria, southern Italy, are reported in this paper. Five plant species: three herbaceous species, Oenanthe pimpinelloides, Anthemis triumphetti, and a stonecrop (Sedum tenuifolium), a leguminous shrub, spanish broom (Spartium junceum) and laricio pine (Pinus nigra ssp laricio) were studied to determine which species is the most responsive to sulfide mineralization and which are the best indicator elements. Si, Fe, Ti, Mn, Zn, Mo, Cu, and Pb were determined in ashed material by X-ray fluorescence analysis. All the data were treated statistically and classified into geometrically increasing intervals, in order to discriminate anomalous from background values. In addition, an R-mode factor analysis and a correlation analysis were performed to find out whether any specific metal association that could characterize both the lithology and mineralization existed for each plant species. The herbaceous plants, particularly Oenanthe, were much more effective as indicators of mineralization compared with laricio pine. The elements that gave the best indication of sulfide mineralization were Zn and Pb, confirming the usefulness of biogeochemical methods as an additional prospecting tool in Calabria, where such exploration has never been attempted before. R-mode factor analysis was found to be extremely promising as a supplemental tool in the interpretation of results from this biogeochemical survey. Each plant species is always characterized by a metal association (predominantly Pb-Zn-Mn) whose high factor loading scores constantly show a close relationship with proven sulfide mineralization. 相似文献
19.
David J. Grimes Walter H. Ficklin Allen L. Meier John B. Mchugh 《Journal of Geochemical Exploration》1995,52(3)
Ground-water, alluvium, and bedrock samples were collected from drill holes near the Chimney Creek, Preble, Summer Camp, and Rabbit Creek disseminated gold deposits in northern Nevada to determine if Au and ore-related metals, such as As, Sb, and W, are being hydromorphically mobilized from buried mineralized rock, and, if they are, to determine whether the metal-enriched ground water is reacting with the alluvial material to produce a geochemical anomaly within the overburden.Results of chemical analyses of drill-hole water samples show the presence of hydromorphic dispersion anomalies of Au, As, Sb, and W in the local ground-water systems associated with these deposits. Background concentrations for Au in the ground water up-gradient from the buried deposits was less than 1 nanogram per liter (ng/L), near the deposits the Au values ranged from 1 to 140 ng/ L, and in drill holes penetrating mineralized rock, concentrations of Au in the ground water were as high as 4700 ng/L. Highest concentrations of Au were found in ground-water samples where the measured Eh and the distribution of arsenic species, arsenite [As(III)] and arsenate [As(V)], indicated oxidizing redox potentials. Similarly, As, Sb, and W concentrations in the ground water near the deposits were significantly enriched relative to concentrations in the ground water up-gradient from the deposits. In general, however, the highest concentrations of As, Sb, and W occurred in ground-water samples where the measured Eh and the distribution of arsenic species indicated reducing conditions. Arsenic concentrations ranged from 9 to 710 micrograms per liter (μg/L); Sb, from less than 0.1 to 250 μg/L; and W, from 1 to 260 μg/L.In addition, analysis of sequential dissolution and extraction solutions of drill cuttings of alluvium and bedrock indicate geochemical anomalies of gold and ore-related metals in the overburden at depths corresponding to the location of the present-day water table. This relationship suggests that water-rock reactions around these buried deposits are active and that this information could be very useful in exploration programs for concealed disseminated gold deposits. 相似文献
20.
H. Rolf Schmitt Eion M. Cameron Gwendy E.M. Hall Judy Vaive 《Journal of Geochemical Exploration》1993,48(3)
To be an effective indicator of mineralization in lake sediment surveys within the Canadian Shield, it is desirable that an element migrate in solution or adsorbed on suspensates. Given the low relief and disorganized drainage patterns of this region, dispersal in clastic form in drainage systems is limited and gives rise to erratic distributions. The purpose of this study was to discover whether Au shows significant hydromorphic mobility, which would justify the increasing use that is being made of this element in lake sediments as an indicator for gold mineralization.Waters and lake sediments were collected from Napier Lake, Ontario; PAP Lake, Saskatchewan; and Foster Lake, Manitoba, all of which contain Au-quartz vein mineralization and lie within the glaciated boreal forest zone of the Canadian Shield. In all three areas, profundal lake sediments down-drainage of mineralization contain Au concentrations higher than regional mean concentrations. Significant dissolution and transport of Au was found under oxidizing conditions associated with waters with pH that varied from acid to alkaline. Waters from drill holes penetrating mineralization contain up to 401 ng L−1 Au (note; 1 ng L−1 is equivalent to 1 part per trillion, 10−12). Surface waters overlying or near mineralization collected from bogs, seeps, ponds and streams contain up to 13 ng L−1. The content of Au in lake waters is lower, with a maximum of 1.1 ng L−1. There is also a detectable quantity of Au present in suspensates. Two samples of particulates (> 1 μm) filtered from lake water have Au equivalent to 0.17 ng L−1 and 0.039 ng L−1. While the contents of Au present in solution or as suspensates in lake and stream water are relatively small, they are sufficient, if precipitated, to generate anomalies in lake sediments. Thus for Reservoir Lake, in the Foster Lake area, water from the principal stream entering the lake carries 0.3 ng L−1 Au. This provides an annual flux which far exceeds that required to generate the 7.3 ppb Au contained in profundal sediments of this lake; a content that is anomalous relative to the regional median content of < 1 ppb Au for lake sediments.Hydrogeochemical prospecting involving analysis for Au is one method for tracing the source of anomalous Au in lake sediments. Collection of 1 L samples without field treatment, followed by extraction of Au into MIBK, then analysis by graphite-furnace atomic absorption spectrophotometry, permits detection levels for Au of 0.5 ng L−1. This is below the contents of Au found in some waters from mineralized areas. A detection limit of 0.3 ng L−1 was obtained using larger water samples. 相似文献