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1.
Major and trace element and modal analyses are presented for unaltered, epidotized, and carbonated tholeiite flows from the Barberton greenstone belt. Au, As, Sb, Sr, Fe+3, Ca, Br, Ga, and U are enriched and H2O, Na, Mg, Fe+2, K, Rb, Ba, Si, Ti, P, Ni, Cs, Zn, Nb, Cu, Zr, and Co are depleted during epidotization. CO2, H2O, Fe+2, Ti, Zn, Y, Nb, Ga, Ta, and light REE are enriched and Na, Sr, Cr, Ba, Fe+3, Ca, Cs, Sb, Au, Mn, and U are depleted during carbonization-chloritization. The elements least affected by epidotization are Hf, Ta, Sc, Cr, Th, and REE; those least affected by carbonization-chloritization are Hf, Ni, Co, Zr, Th, and heavy REE. Both alteration processes can significantly change major element concentrations (and ratios) and hence caution should be used in distinguishing tholeiites from komatiites based on major elements alone. The amount of variation of many of the least mobile trace elements in the altered flows is approximately the same as allowed by magma model calculations. Hence, up to about 10% carbonization and 60% epidotization of tholeiite do not appreciably affect the interpretation of trace-element models for magma generation.  相似文献   

2.
盘石山幔源透辉石微量元素地球化学   总被引：4，自引：0，他引：4       下载免费PDF全文
支霞臣  李彬贤 《地质科学》1995,30(4):384-392
用质子探针和电子探针分别测定盘石山幔源橄揽岩包体中透辉石、橄榄石的微量元素和主量元素丰度;用X-射线荧光光谱法测定包体全岩的主量和微量元素丰度。定量讨论微量元素的分布和分配。其中绝大部分Sr、Zr、Ti、Na赋存在透辉石中,绝大部分Mn、Zn、Ni赋存在橄揽石中,在T=1194-1435K范围,分配系数变化如下:InDOl/CpxZn=1.44-2.19;InDOl/CpxMn=0.21-0.40,InDOl/CpxTi=4.76-5.61,InDOl/CpxNi(平均值)=2.20.透辉石中Ti/Zr=42-103,低于原始地幔值,由地幔隐性交代作用造成。  相似文献   

3.
This study characterizes the nature of fluid interaction andmelting processes in the lithospheric mantle beneath the Yingfenglingand Tianyang volcanoes, Leizhou Peninsula, South China, usingin situ trace-element analyses of clinopyroxene, amphibole andgarnet from a suite of mantle-derived xenoliths. Clinopyroxenesfrom discrete spinel lherzolites exhibit large compositionalvariations ranging from extremely light rare earth element (LREE)-depletedto LREE-enriched. Trace-element modelling for depleted samplesindicates that the Leizhou lherzolites are the residues of amantle peridotite source after extraction of 1–11% meltgenerated by incremental melting in the spinel lherzolite fieldwith the degree of melting increasing upwards from about 60km to 30 km. This process is consistent with gradational meltingat different depths in an upwelling asthenospheric column thatsubsequently cooled to form the current lithospheric mantlein this region. The calculated melt production rate of thiscolumn could generate mafic crust 5–6 km thick, whichwould account for most of the present-day lower crust. The formationof the lithospheric column is inferred to be related to Mesozoiclithosphere thinning. Al-augite pyroxenites occur in compositexenoliths; these are geochemically similar to HIMU-type oceanisland basalt. These pyroxenites postdate the lithospheric columnformation and belong to two episodes of magmatism. Early magmatism(forming metapyroxenites) is inferred to have occurred duringthe opening of the South China Sea Basin (32–15 Ma), whereasthe most recent magmatic episode (producing pyroxenites withigneous microstructures) occurred shortly before the eruptionof the host magmas (6–0·3 Ma). Trace-element traversesfrom the contacts of the Al-augite pyroxenite with the spinelperidotite wall-rock in composite xenoliths record gradientsin the strength and nature of metasomatic effects away fromthe contact, showing that equilibrium was not attained. Significantenrichment in highly incompatible elements close to the contacts,with only slight enrichment in Sr, LREE and Nb away from thecontact, is inferred to reflect the different diffusion ratesof specific trace elements. The observed geochemical gradientsin metasomatic zones show that Sr, La, Ce and Nb have the highestdiffusion rates, other REE are intermediate, and Zr, Hf andTi have the lowest diffusion rates. Lower diffusion rates observedfor Nb, Zr, Hf and Ti compared with REE may cause high fieldstrength element (HFSE) negative anomalies in metasomatizedperidotites. Therefore, metasomatized lherzolites with HFSEnegative anomalies do not necessarily require a carbonatiticmetasomatizing agent. KEY WORDS: China; lithosphere; mantle xenoliths; clinopyroxene trace elements; mantle partial melting; mantle metasomatism; trace-element diffusion rates  相似文献   

4.
Over 700 apatite grains from a range of rock types have been analysed by laser-ablation microprobe ICPMS for 28 trace elements, to investigate the potential usefulness of apatite as an indicator mineral in mineral exploration. Apatites derived from different rock types have distinctive absolute and relative abundances of many trace elements (including rare-earth elements (REE), Sr, Y, Mn, Th), and chondrite-normalised trace-element patterns. The slope of chondrite-normalised REE patterns varies systematically from ultramafic through mafic/intermediate to highly fractionated granitoid rock types. (Ce/Yb)cn is very high in apatites from carbonatites and mantle-derived lherzolites (over 100 and over 200, respectively), while (Ce/Yb)cn values in apatites from granitic pegmatites are generally less than 1, reflecting both HREE enrichment and LREE depletion. Within a large suite of apatites from granitoid rocks, chemical composition is closely related to both the degree of fractionation and the oxidation state of the magma, two important parameters in determining the mineral potential of the magmatic system. Apatite can accept high levels of transition and chalcophile elements and As, making it feasible to recognise apatite associated with specific types of mineralisation. Multivariate statistical analysis has provided a user-friendly scheme to distinguish apatites from different rock types, based on contents of Sr, Y, Mn and total REE, the degree of LREE enrichment and the size of the Eu anomaly. The scheme can be used for the recognition of apatites from specific rock types or styles of mineralisation, so that the provenance of apatite grains in heavy mineral concentrates can be determined and used in geochemical exploration.  相似文献   

5.
Partial fusion hypotheses have been proposed for the origin of lherzolite-harzburgite alpine peridotite associations. Analyzed lherzolites from Othris, Ronda, Lanzo and Beni Bouchera, have light REE depleted to chondritic REE abundances, and clinopyroxenes contain most of the REE relative to depleted olivine and orthopyroxene. Variation in the level of REE enrichment within these lherzolites indicates mantle heterogeneity probably caused by partial melting processes. The Beni Bouchera spinel lherzolite and the Othris plagioclase lherzolite are the best candidates for relatively undepleted mantle based on REE studies. Fractional fusion calculations (15–25%) reveal that partial melts have REE characteristics somewhat similar to oceanic tholeiites. Conversely, computed source peridotites from oceanic tholeiites (Schilling, 1975) are similar to the alpine lherzolites reported here. Alpine lherzolites are, however, depleted in trace elements (K, Rb, Sr and Ba, Menzies and Murthy 1976). Since the lherzolites have an undepleted major, minor and REE chemistry close to that of pyrolite, the lost trace element-rich fraction must represent a small degree of melting. It is proposed that alpine lherzolites are residue left after the loss of a nephelinitic/alkalic fraction, ([Ce/Yb]N=2.0–4.01) representing a small degree of partial fusion. This labile fraction may have existed as an intergranular phase or hydrous mineral prior to melting.  相似文献   

6.
The volcanic rocks of the South Atlantic Ocean islands of Fernando de Noronha and Trindade comprise a diverse magmatic series ranging from nephelinites and basanites to phonolites and, on Fernando de Noronha, trachytes. All rock types are highly silica undersaturated with the exception of Fernando de Noronha trachytes_, and have high abundances of incompatible trace elements and strongly LREE (light rare earth element)-enriched REE patterns. Crystal fractionation of parental basanitic magmas produced evolved phonolites and trachytes which display severe trace-element fractionation, even among trace elements (Nb, Ta, Zr, Hf) which normally behave highly incompatibly during crystallisation of alkaline magmas. Moderately to highly evolved compositions develop strongly MREE (middle REE)-depleted REE patterns, and become increasingly depleted in elements such as Nb and, in particular, Ta. Ratios of Nb/Ta and Zr/Hf are highly fractionated in phonolites (60–65, 64–77 respectively in Fernando de Noronha phonolites) compared to ratios in basanites (14, 45 respectively). The compatibility of Nb, Ta, and the REE, and the strong fractionation of Nb/Ta and Zr/Hf ratios and the MREE, during crystallisation from basanite to phonolite are attributable to the crystallisation of small amounts (<5%) of sphene. Trace-element behaviour is relatively insensitive to the major phenocryst phases, and is controlled by minor phases in highly undersaturated alkaline suites. Incompatible trace-element ratios (e.g. La/Nb, Th/Ta) in nephelinites and basanites from Fernando de Noronha and Trindade are generally comparable with those in basaltic and hawaiitic OIB (ocean island basalt) lavas from other South Atlantic islands, but are distinct from those of Gough and Tristan da Cunha OIB. The mantle source for the highly undersaturated volcanism on Fernando de Noronha and Trindade is similar in trace-element characteristics to the typical OIB source which produces alkaline lavas with significant relative enrichment in Nb and Ta compared to other trace elements (as expressed by low La/Nb, Ba/Nb and Th/Ta ratios). The highly undersaturated nature of the magmas and the slight fractionation of some incompatible-element ratios (elevated Ba/Nb, Ba/Rb, Ba/Th etc.) is consistent with a smaller degree of melting of a typical OIB source, but with residual phlogopite in the source to account for significant K depletion and LIL-element fractionation.  相似文献   

7.
对华北克拉通重力梯度带东西两侧的河北承德袁家庄和内蒙古四子王旗白脑包出露的晚中生代火山岩进行了地球化
学对比研究。全岩主量元素、微量元素和Sr-Nd-Hf同位素数据表明,袁家庄火山岩和白脑包火山岩具有相似的地球化学特
征。这些火山岩轻、重稀土强烈分异,富集大离子亲石元素(如Rb,Ba,Th,U,K等),亏损高场强元素(如Nb,Ta,Zr,
Hf,Ti等);其同位素具有高(87Sr/86Sr)i,低εNd(t)和低εHf(t)的特征,因此认为袁家庄和白脑包火山岩具有相似的源区,即均来
源于被交代的古老岩石圈地幔的部分熔融。结合文献资料,作者认为,这些晚中生代火山岩是华北克拉通岩石圈减薄的直
接产物,中生代时期华北克拉通岩石圈的减薄不仅仅局限于重力梯度带以东地区,以西的部分地区也有发生。 chengxu    相似文献   

8.
A wide range of trace elements have been analysed in mantle xenoliths (whole rocks, clinopyroxene and amphibole separates) from alkaline lavas in the Eastern Carpathians (Romania), in order to understand the process of metasomatism in the subcontinental mantle of the Carpatho-Pannonian region. The xenoliths include spinel lherzolites, harzburgites and websterites, clinopyroxenites, amphibole veins and amphibole clinopyroxenites. Textures vary from porphyroclastic to granoblastic, or equigranular. Grain size increases with increasing equilibrium temperature of mineralogical assemblages and results from grain boundary migration. In peridotites, interstitial clinopyroxenes (cpx) and amphiboles resulted from impregnation and metasomatism of harzburgites or cpx-poor lherzolites by small quantities of a melt I with a melilitite composition. Clinopyroxenites, amphibole veins and amphibole clinopyroxenites are also formed by metasomatism as a result of percolation through fracture systems of large quantities of a melt II with a melanephelinite composition. These metasomatic events are marked by whole-rock enrichments, relative to the primitive mantle (PM), in Rb, Th and U associated in some granoblastic lherzolites and in clinopyroxene and amphibole veins with enrichments in LREE, Ta and Nb. Correlations between major element whole-rock contents in peridotites demonstrate that the formation of interstitial amphibole and clinopyroxene induced only a slight but variable increase of the Ca/Al ratio without apparent modifications of the initial mantle composition. Metasomatism is also traced by enrichments in the most incompatible elements and the LREE. The Ta, Nb, MREE and HREE contents remained unchanged and confirm the depleted state of the initial but heterogeneous mantle. Major and trace element signature of clinopyroxene suggests that amphibole clinopyroxenites and some granoblastic lherzolites have been metasomatized successively by melts I and II. Both melts I and II were Ca-rich and Si-poor, somewhat alkaline (Na > K). Melt I differed from melt II in having higher Mg and Cr contents offset by lower Ti, Al, Fe and K contents. Both were highly enriched in all incompatible trace elements relative to primitive mantle, showing positive anomalies in Rb, Ba, Th, Sr and Zr. They contrasted by their Ta, Nb and LREE contents, lower in melt I than in melt II. Melts I and II originate during a two-stage melting event from the same source at high pressure and under increasing temperature. The source assemblage could be that of a metasomatized carbonated mantle but was more likely that of an eclogite of crustal affinity. Genetic relationships between calc-alkaline and alkaline lavas from Eastern Carpathians and these melts are thought to be only indirect, the former originating from partial melting of mantle sources respectively metasomatized by the melts I and II. Received: 17 March 1997 / Accepted: 14 July 1997  相似文献   

9.
Mineral/melt trace element partition coefficients were determined for rutile (TiO2) for a large number of trace elements (Zr, Hf, Nb, Ta, V, Co, Cu, Zn, Sr, REE, Cr, Sb, W, U, Th). Whilst the high field strength elements (Zr, Hf, Nb, Ta) are compatible in rutile, other studied trace elements are incompatible (Sr, Th, REE). In all experiments we found DTa > DNb, DHf > DZr and DU > DTh. Partition coefficients for some polyvalent elements (Sb, W, and Co) were sensitive to oxygen fugacity. Melt composition exerts a strong influence on HFSE partition coefficients. With increasing polymerization of the melt, rutile/melt partition coefficients for the high field strength elements Zr, Hf, Nb and Ta increase about an order of magnitude. However, DNb/DTa and DHf/DZr are not significantly affected by melt composition. Because DU ? DTh, partial melting of rutile-bearing eclogite in subducted lithosphere may cause excesses of 230Th over 238U in some island arc lavas, whereas dehydration of subducted lithosphere may cause excesses of 238U over 230Th. From our partitioning results we infer partition coefficients for protactinium (Pa) which we predict to be much lower than previously anticipated. Contrary to previous studies, our data imply that rutile should not significantly influence observed 231Pa-235U disequilibria in certain volcanic rocks.  相似文献   

10.
Ion microprobe data for minerals from the eclogites of the Atbashi Range (South Tianshan) constrain the distribution of trace (Rb, Sr, Ba, Cr, V, Zr, Hf, Nb, Ta, U, Th, and Y) and rare-earth elements (REE) in zoned garnets and mineral inclusions in them. This study showed that garnets from the Atbashi eclogites are the main hosts for heavy REE; epidotes are important hosts for REE, Y, Sr, Th, and U; and omphacites are depleted in almost all trace elements compared with the bulk-rock compositions. Garnet, as well as epidote and omphacite inclusions exhibit systematic rimward depletion in a number of trace elements, which is related to the depletion of the rock matrix in these elements during crystallization. Deviations from this trend, including the enrichment of garnet rims in HREE and strong variations in the REE contents of garnets and mineral inclusions, can be explained by metamorphic reactions involving the destabilization of REE-bearing minerals. Our data suggest that the mobility of trace elements under eclogites-facies conditions is mainly controlled by the stability of certain minerals.  相似文献   

11.
Seventeen upper-mantle ultramafic xenoliths from the Lower Quaternary Tal Khodr Imtan cinder cone in southern Syria have revealed a dominant protogranular texture of nine spinel lherzolites, two spinel harzburgites, four spinel dunites, one spinel olivine websterite, and one spinel clinopyroxenite. The lherzolites, harzburgites, and dunites contain Cr-diopside and brown-red picotite, with a basanitic host rock; the websterite and clinopyroxenite contain Ti-Al-augite and Cr-hercynite. A lherzolite to dunite depletion trend is shown in the abundance of intermediate- and lightrare-earth elements (IREE and LREE) and from analytical data of dunitic olivine, with Ca, Al, Fe, Cr, and Si being the most depleted elements. The depletion probably resulted from successive partial melting. The scoriaceous basanite shows enrichments in REE and trace elements from a plume; the basanitic coating (around ultramafic xenoliths) increases in Mg/Mg+Fe+2 and concentrations of Al2O3, TiO2, and Na2O by contamination from peridotitic olivine, and also from eclogite-gabbro and nephelinite near the bottom of the rifted crust.

Differences in the REE and trace-element concentrations among the peridotite xenoliths, the basanite host rock, and websterite indicate at least three different depths for their parent sources. The ultramafic inclusions in the basanitic host rock, as well as xenoliths in a carbonatite dike, suggest a deeper source for the carbonatite magma. At least part of the enrichment of the plume probably was accomplished by the subducted Tethys oceanic crust, suboceanic litho-sphere, and eclogite-gabbro. The thick plateau basalt in southern Syria indicates heavy and deep fracturing, and the extrusions of successive magmas from the upper mantle created a stretching and thinning in the continental crust. The proximity of this plateau basalt area to the Dead Sea-Jordan River Valley Rift, together with the source of the ultramafic xenoliths, points to a possible close relationship between the Red Sea Rift and the fracturing (offshoot rifting) in southern Syria.  相似文献   

12.
This paper reports new petrological, geochemical and isotopic data for Carlsberg Ridge Basalts (CRB) of northwest Indian Ocean and evaluates their petrogenetic aspects in the context of the geochemical and tectonic evolution of the Indian Ocean mantle. The CRB samples exhibit tholeiitic to transitional composition of precursor melts derived by high degree, shallow level partial melting of a spinel peridotite mantle source. CRB reflects distinct E-MORB affinity with selective enrichment in incompatible trace elements. Higher values of Zr/Hf (33.8–47.3) and Zr/Sm (24.9–36.4) in conjunction with lower Nb/Ta (1.7–7.3) ratio corroborate their origin from an enriched mantle source. Negative Nb anomalies with lower Nb/Y (0.04–0.11) and Zr/Y (2.5–3.5) conform to a non-plume origin of these basalts. Higher Zr/Nb (25.5–71.5) and Th/Nb (0.6–0.42) compared to OIB substantiate contributions from recycled subduction-processed components in the source mantle. Lower Nb/U (6.2–37.9) values with higher Ba/Nb (6.1–21.9), Ba/Th (27.7–147.5), Zr/Nb (25.5–71.5) and Th/Nb (0.6–0.42) compared to OIB and N-MORB attest to role of a metasomatized oceanic lithosphere that recycled into the depleted upper mantle attributing to the source heterogeneity. Sr-Nd isotopic signatures (87Sr/86Sr: 0.702668 to 0.702841 and 143Nd/144Nd: 0.512972 to 0.513068) of CRB suggest a HIMU source component preserved in the northwest Indian Ocean Ridge mantle. The compositional diversity of the Indian Ocean mantle can be translated in terms of periodic refertilization of depleted N-MORB type mantle through delamination and recycling of oceanic (HIMU component) and continental lithosphere (EM I component) concurrent with Neoproterozoic-Palaeozoic amalgamation and Jurassic dispersal of Gondwana Supercontinent respectively. This study complies with the derivation of CRB from a geochemically heterogeneous Indian Ocean mantle that experienced a protracted residence beneath the Gondwana Supercontinent prior to the opening of Indian Ocean and trapped recycled metasomatized oceanic lithosphere genetically linked with multiple stages of paleo-ocean closure and continental convergence during Gondwana assembly.  相似文献   

13.
Trace element partitioning between apatite and silicate melts   总被引：7，自引：0，他引：7  
We present new experimental apatite/melt trace element partition coefficients for a large number of trace elements (Cs, Rb, Ba, La, Ce, Pr, Sm, Gd, Lu, Y, Sr, Zr, Hf, Nb, Ta, U, Pb, and Th). The experiments were conducted at pressures of 1.0 GPa and temperatures of 1250 °C. The rare earth elements (La, Ce, Pr, Sm, Gd, and Lu), Y, and Sr are compatible in apatite, whereas the larger lithophile elements (Cs, Rb, and Ba) are strongly incompatible. Other trace elements such as U, Th, and Pb have partition coefficients close to unity. In all experiments we found DHf > DZr, DTa ≈ DNb, and DBa > DRb > DCs. The experiments reveal a strong influence of melt composition on REE partition coefficients. With increasing polymerisation of the melt, apatite/melt partition coefficients for the rare earth elements increase for about an order of magnitude. We also present some results in fluorine-rich and water-rich systems, respectively, but no significant influence of either H2O or F on the partitioning was found. Furthermore, we also present experimentally determined partition coefficients in close-to natural compositions which should be directly applicable to magmatic processes.  相似文献   

14.
Mafic dikes, which transect the Mesoarchaean Singhbhum Granitoid Complex, are the most abundant members of the Newer Dolerite dikes of the Singhbhum Orissa craton. These dikes are subalkaline and exhibit a tholeiitic differentiation trend. Studied dikes underwent fractional crystallization of clinopyroxene and plagioclase. They show enriched patterns for the light rare earth elements (LREE) and large ion lithophile elements (LILE). On primitive mantle-normalized multi-element patterns, they possess Ba, Nb, Sr, P, and Ti depletions similar to subduction-related basaltic rocks. The high (La/Yb) n and (Gd/Yb) n ratios suggest that the studied mafic dikes were derived by low degrees of partial melting of a garnet-bearing source. Judging by trace elemental ratios (e.g. Ba/Y, Nb/Y, Ba/Th and Th/Nb), the studied dikes were derived from a mantle source metasomatized by a subduction component (e.g. fluids derived by dehydration of the subducting slab). We conclude that interaction between these fluids and the overlying mantle was the main cause of (LREE and LILE) enrichment and Nb (high field strength elements) depletion in the mafic dikes.  相似文献   

15.
Trace element profiles for common divalent cations (Sr, Zn, Ba), rare-earth elements (REE), Y, U, and Th were measured in fossil bones and teeth from the c. 25 ka Merrell locality, Montana, USA, by using laser-ablation ICP-MS. Multiple traverses in teeth were transformed into 2-D trace element maps for visualizing structural influences on trace element uptake. Trace element compositions of different soils from the fossil site were also analyzed by solution ICP-MS, employing progressive leaches that included distilled H2O, 0.1 M acetic acid, and microwave digestion in concentrated HCl-HNO3. In teeth, trace element uptake in enamel is 2-4 orders of magnitude slower than in dentine, forming an effective trace element barrier. Uptake in dentine parallel to the dentine-enamel interface is enhanced by at least 2 orders of magnitude compared to transverse, causing trace element “plumes” down the tooth core. In bone, U, Ba and Sr are nearly homogeneous, implying diffusivities ∼5 orders of magnitude faster than in enamel and virtually complete equilibration with host soils. In contrast all REE show strong depletions inward, with stepwise linear segments in log-normal or inverse complementary error function plots; these data require a multi-medium diffusion model, with about 2 orders of magnitude difference in slowest vs. fastest diffusivities. Differences in REE diffusivities in bone (slow) vs. dentine (fast) reflect different partition coefficients (Kd’s). Although acid leaches and bulk digestion of soils yield comparable fossil-soil Kd’s among different elements, natural solutions are expected to be neutral to slightly basic. Distilled H2O leachates instead reveal radically different Kd’s in bone for REE than for U-Sr-Ba, suggest orders of magnitude lower effective diffusivities for REE, and readily explain steep vs. flat profiles for REE vs. U-Sr-Ba, respectively. Differences among REE Kd’s and diffusivities may explain inward changes in Ce anomalies. Acid washes and bulk soil compositions yield misleading Kd’s for many trace elements, especially the REE, and H2O-leaches are preferred. Patterns of trace element distributions indicate diagenetic alteration at all scales, including enamel, and challenge the use of trace elements in paleodietary studies.  相似文献   

16.
李双喜 《地质与勘探》2022,58(6):1196-1208
本文对苏北地区锦屏组磷矿石及地层样品进行了岩相学及地球化学分析,研究了磷矿初始沉积环境和源区特征。磷矿类微量元素富集Ba、Pb、U、Sr,贫Th、Ta、Nb、Ti;REE配分曲线为LREE富集型,Ce负异常,表明成矿环境为陆缘海,且成矿过程受深海热水沉积和生物作用影响。Sr、Nd同位素初始值判断磷灰岩物质来源为年轻的地壳物质。绿片岩类微量元素富集Rb、Th、K,贫Th、U、Ta、Nb、Sr、Ti;REE配分曲线为LREE富集型,判断其原岩为陆源碎屑岩。（混合）片麻岩类微量元素富集Pb、Th、K,亏损Ba、Ta、Nb、Sr、Ti;REE配分曲线为LREE富集型,具地幔源区特征。  相似文献   

17.
The South Platte pegmatite district is well known for its significant enrichment in the rare earth elements (REE), Y, Nb, F, and for the exceptionally well-developed internal zonation of the complex pegmatites located within a reversely zoned portion of the Pikes Peak batholith. Chemical trends both within and between pegmatites define the behavior of major and trace elements and the role of F in the fractionation of the granitic magma and pegmatitic fluids, suggesting a new model for the evolution of the granite-pegmatite system.Whole-rock XRF and INAA analyses of the host Pikes Peak granite and quartz monzonite and pegmatite wall zones provide strong evidence that all three are related by differentiation. With increasing SiO2, there is systematic enrichment in K2O, Na2O, and Rb, and depletion in CaO, MgO, FeO1, TiO2, P2O5, Ba, Sr, and Sc. REE, Y, Zr, and Th were strongly partitioned out of the wall zone into the final residual fluids where they were concentrated up to an order of magnitude over levels in the granite.Within the district, there is also chemical zonation of F, Nb, Th, U, and REE between groups of pegmatites. Polyzonal quartz-core types typically contain more fluorite, samarskite, HREE-zircon, and yttrian-fluorite than their bizonal composite-core counterparts, which contain only sparse fluorite and allanite.The sequence of magmatic evolution involved: (1) a process of diffusive differentiation and fractional crystallization which produced a chemically stratified magma chamber with a hotter more mafic quartz monzonitic base and a more felsic, granitic top enriched in H2O, F, HREE, Nb, and Y; (2) resurgence of the more mafic lower level crystal mush in to the upper more felsic part of the pluton; and (3) separation of pegmatitic fluids from the juxtaposed magmas giving rise to two compositionally distinct groups of pegmatites.  相似文献   

18.
We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation.  相似文献   

19.
INTRODUCTIONThe Keliyang potassic lamprophyre dykes are lo-catedin the Keliyang mountain range , Pishan Coun-ty ,southern Xinjiang, Northwest China . They aretectonically situated at the Tiekelike block uplift ofthe southwest margin of the Tari m platform (Fig.1a) . The regional stratigraphic sequence includes thePrecambrian Ailiankate Group of sericite-chlorite-quartz schist and metamudstone ,and the Lower Car-boniferous li mestone and basalt . The dykes are gen-erally 50 -60 mlong…  相似文献   

20.
云南龙脖河铜矿区变火山岩地球化学再研究   总被引：1，自引：1，他引：0  
龙脖河铜矿床位于滇中地区红河成矿带南段,矿区火山岩发育、与铜矿化时空密切共生。区内火山岩遭受了不同程度的蚀变或区域变质作用,根据矿物组合可分为变安山岩、变次火山岩和变基性火山岩。三类变火山岩均相对富Na,在地球化学分类图解上样品主要位于碱性玄武岩区域。除个别微量元素外,三类岩石的微量元素含量相近,与各种构造环境玄武岩相比,本区变火山岩富集HFSE(Th、Nb等)、亏损LILE(Sr、Ba等),微量元素配分模式出现明显Th、Nb正异常和Sr、Ba负异常。三类岩石的REE含量范围相互重叠,除Eu异常外,其REE配分模式均为相似的LREE富集型。各种地球化学证据表明,本区三类变火山岩为同源岩浆不同演化阶段的产物,其原始岩浆为大陆板内拉张构造环境交代富集地幔部分熔融的产物,结晶分异作用在岩浆演化过程中具有重要地位。  相似文献   

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