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1.
Summary. The 300 km ECORS - Bay of Biscay profile was carried out along the Aquitaine shelf and comprised a complete set of experiments including zero-offset and 7.5 km constant offset vertical seismic reflection and six expanding spread profiles. Large offset recordings were fundamental for the definition of the layered lower crust and the Moho, while ESPs provided decisive complementary information for the geological interpretation. These data show a strong variation in crustal thickness from about 20 km beneath the rifted Parentis basin, a failed arm of the oceanic Bay of Biscay, up to 35 km to the north below the Armorican shelf, in the Hercynian domain, and to the south below the Cantabria shelf, in the vicinity of the Pyrenean deformation front. The results have important implications for the behaviour of the crust during the formation of rifted sedimentary basins and during continental collision.  相似文献   

2.
When using hyphenated methods in analytical chemistry,the data obtained for each sample are given asa matrix.When a regression equation is set up between an unknown sample (a matrix) and a calibrationset (a stack of matrices),the residual is a matrix R.The regression equation is usually solved by minimizing the sum of squares of R.If the sample containssome constituent not calibrated for,this approach is not valid.In this paper an algorithm is presentedwhich partitions R into one matrix of low rank corresponding to the unknown constituents,and onerandom noise matrix to which the least squares restrictions are applied.Properties and possibleapplications of the algorithm are also discussed.In Part 2 of this work an example from HPLC with diode array detection is presented and the resultsare compared with generalized rank annihilation factor analysis (GRAFA).  相似文献   

3.
Traditionally,one form of preprocessing in multivariate calibration methods such as principal componentregression and partial least squares is mean centering the independent variables(responses)and thedependent variables(concentrations).However,upon examination of the statistical issue of errorpropagation in multivariate calibration,it was found that mean centering is not advised for some datastructures.In this paper it is shown that for response data which(i)vary linearly with concentration,(ii)have no baseline(when there is a component with a non-zero response that does not change inconcentration)and(iii)have no closure in the concentrations(for each sample the concentrations of allcomponents add to a constant,e.g.100%)it is better not to mean center the calibration data.That is,the prediction errors as evaluated by a root mean square error statistic will be smaller for a model madewith the raw data than a model made with mean-centered data.With simulated data relativeimprovements ranging from 1% to 13% were observed depending on the amount of error in thecalibration concentrations and responses.  相似文献   

4.
中原城市群城市规模等级的时空演变分析   总被引：1，自引：1，他引：0  
综合运用分形、马尔科夫转移矩阵、等级钟和空间自相关等方法对中原城市群城市规模等级的时空演变进行了分析,得出结论:①城市规模等级分布趋于"扁平化",首位城市郑州的垄断性较弱;城市在不同规模类型间的转移过程中,小城市向中等城市的转移概率低,中等城市向大城市的转移概率高,中等规模城市数量增长缓慢;城市个体位序的变化相对较小,城市规模发展具有较强的路径依赖和连续性;②城市规模分布依然以省辖市为基础,在省辖市与周围县市的空间互动上,开封和平顶山对周围县市有显著的极化作用,郑州和新乡对周围县市产生了极化作用但不显著,其余省辖市与周围县市未形成紧密的空间互动关系.  相似文献   

5.
The geometric properties of three common object-preprocessing transformations(constant sum,orclosure;constant length,or normalization;and maximum value,or ratioing)are investigated.Anargument is made for using absolute values in the constant sum and maximum value transformations.In general,each transformation distorts the shape and dimensionality of patterns in the data:transformed data lie on(C-l)-dimensional surfaces in the original C-dimensional space.A data set thathas been closed by one of these transformations can be reopened if a vector containing the constant sums,constant lengths or maximum values of the original objects was retained.Transformed data sets may befreely interconverted among these three transformations without the loss of information.  相似文献   

6.
Each eigenvector of the dispersion matrix[X]~T[X]was shown to be a partial predictor of the originaldata matrix [X],the sum of the predictions from the individual principal components being equal to theexpectance of [X].By comparing the distributions of the members of two neighbouring predictedmatrices,[X]_(1...i)and [X](1...i+1)(i.e.the sums of the first i and i+1 individual predictions respectively),it was shown that they should be indistinguishable provided that i is equal to or greater than the effectiverank of [X],and significantly different otherwise.This was confirmed by analysing the visible absorptionspectra of methyl orange and methyl red solutions as well as the Raman spectra of Na_2SO_4 and MgSO_4solutions.On the grounds of these findings,a non-parametric goodness-of-fit test for assessing theeffective rank of[X]was proposed which proved to be comparatively conservative and more robust thanmost currently used tests.  相似文献   

7.
Application of principal component analysis to Cu(II)-ethanolamine complex formation data is shown.Determination of the number of complex species is obtained from the rank of the matrix of spectral datausing either Gauss elimination or factorial analysis.Relevant information concerning species distributionversus pH is obtained from the plot of the signficant factors upsurging from the evolution of spectraltitration data.  相似文献   

8.
Owing to difficulties in interpretation, the application of higher-order factor analysis has been limited in geographical research, yet it is particularly appropriate to regionalization problems using transport-network data. A 162-node shortest-path matrix of the Australian internal air network is resolved into a two-higher-order factor system.  相似文献   

9.
Summary. Independent sets of LISPB data are presented, having as a common feature a local lateral variation in the Moho beneath northern Britain.
The evidence for this step-like feature on the Moho is taken from P and S travel times and from PS reflection times and phase velocities.
Another important observation is that a high-frequency Moho refraction is generated north of the step, whilst the refraction from the step region and south of it contains only low frequencies. This leads to the assumption that a change in the Moho structure exists in the same region as where the step has been deduced from travel-time interpretation. A numerical model is presented which generates a high-frequency refracted wave from an input signal which contains low- and high-frequency spectral energy.
The significance of this offset on the Moho, in particular its relationship to surface tectonics, is critically discussed.  相似文献   

10.
国内外环境解说研究综述   总被引：47，自引：1，他引：46  
环境解说最早出现在美国国家公园的服务体系中,伴随着新兴的旅游方式、目的地竞争日益激烈和居民游憩需求的增加,其概念内涵与功能不断发展,并且解说的研究也得到不断完善。本文分别从国外环境解说研究的时代发展和内容上进行划分,而由于国内的研究很少,只作为综述的补充。从20世纪60年代至今环境解说分别经历了"形成期"、"媒介期"、"名正期"以及"初熟期"。在研究内容上,国外的相关研究主要有对解说特征与功能的研究,包括其概念性框架与目标、手段选择、管理功能与经济功能的研究;对解说受众的研究,主要包括对游客的分类研究及解说方式的研究,以及对解说员与游客之间沟通过程的研究等。在西方,环境解说研究通过借助其他各学科的理论而逐渐成熟,笔者建议引入国外成熟理论以建设并完善环境解说学科体系来填补我国在这一研究领域的空白。  相似文献   

11.
Abstract

Raster land cover data has been used to construct adjacency matrices by scanning the pixel edges and calculating proportions according to the land cover types joined. Like joins (e.g., forest to forest) are most common because pixel size is typically much smaller than the average patch size. The dominance of like joins (the matrix diagonal) of the adjacency matrix has led to one interpretation of the matrix as landscape contagion (the tendency of land cover to cluster into a few, large patches). Construction of the adjacency matrix in a vector environment results in a different measurement. In a vector environment, land cover patches are not sub–divided into pixels. Therefore, the main diagonal of the adjacency matrix is zero. Construction of an adjacency matrix in a vector environment estimates the evenness of distribution of edge types, not contagion. The same edge type evenness metric is estimated in a raster environment by ignoring the matrix diagonal and re-scaling the off-diagonal elements so that they sum to one (1).  相似文献   

12.
A 9000-year carbonate-rich sediment sequence from a small hard-water lake in northernmost Sweden was studied by means of multi-component stable carbon isotope analysis. Radiocarbon dating of different sediment fractions provides chronologic control and reveals a rather constant hard-water effect through time, suggesting that the lake has remained hydrologically open throughout the Holocene. Successive depletion of 13C in fine-grained calcite and carbonate shells during the early Holocene correlate with a change in catchment vegetation from pioneer herb communities to boreal forest. The vegetational change and associated soil development likely gave rise to an increased supply of 13C-depleted carbon dioxide in groundwater recharging the lake. This process is therefore believed to be the main cause of decreasing values of 13C in dissolved inorganic carbon of the lake and thereby in limnic carbonates. Strongly 13C-depleted sedimentary organic matter may be related to enhanced kinetic fractionation during photosynthetic assimilation by means of proton pumping in Characean algae. This interpretation is supported by a substantial offset between 13C of DIC as recorded by mollusc shells and 13C of fine-grained calcite.  相似文献   

13.
Concentration estimates of components present in a sample mixture can be obtained using matrixmathematics. In the past, the condition number of the calibration matrix has been used to give anamplification factor by which uncertainties in data can work through to errors in the concentrationestimates. This paper explores an additional interpretation of condition numbers with regards tosignificant figures and rounding errors. A procedure is suggested which will always give the most accurateconcentration estimates provided the calibration matrix is not too ill-conditioned. Condition numbershave also been used by analytical chemists to discuss the error bounds for concentration estimates.Unfortunately, only one representative error bound can be approximated for all the components. Thispaper will show how to compute bounds for individual concentration estimates obtained as solutions to asystem of m equations and n unknowns. The procedure is appropriate when calibration data and sampleresponses are inaccurate.  相似文献   

14.
多光谱遥感数据最佳波段选择方法试验研究   总被引：15，自引：1，他引：15  
分析了多光谱遥感数据最佳波段选择的标准差、熵和联合熵、相关性系数及最佳指数等计算方法的内在联系。通过试验,说明了各种计算方法的有效性和局限性,最后得出OIF指数法为多光谱遥感数据最佳波段选择的最优方法。  相似文献   

15.
This study is devoted to the numerical simulation of the artificial ground freezing process in a fluid-saturated rock mass of the potassium salt deposit. A coupled model of nonstationary thermal conductivity, filtration and thermo-poroelasticity, which takes into account dependence of the physical properties on temperature and pressure, is proposed on the basis of the accepted hypotheses. The considered area is a cylinder with a depth of 256 meters and diameter of 26.5 meters and includes 13 layers with different thermophysical and filtration properties. Numerical simulation was carried out by the finite-element method. It has been shown that substantial ice wall formation occurs non-uniformly along the layers. This can be connected with geometry of the freezing wells and with difference in physical properties. The average width of the ice wall in each layer was calculated. It was demonstrated that two toroidal convective cells induced by thermogravitational convection were created from the very beginning of the freezing process. The effect of the constant seepage flow on the ice wall formation was investigated. It was shown that the presence of the slow flow lead to the delay in ice wall closure. In case of the flow with a velocity of more than 30 mm per day, closure of the ice wall was not observed at all in the foreseeable time.  相似文献   

16.
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17.
Rank estimation by canonical correlation analysis in multivariate statistics has been proposed as analternative approach for estimating the number of components in a multicomponent mixture.Amethodological turning point of this new approach is that it focuses on the difference in structure ratherthan in magnitude in characterizing the difference between the signal and the noise.This structuraldifference is quantified through the analysis of canonical correlation,which is a well-established datareduction technique in multivariate statistics.Unfortunately,there is a price to be paid for having thisstructural difference:at least two replicate data matrices are needed to carry out the analysis.In this paper we continue to explore the potential and to extend the scope of the canonical correlationtechnique.In particular,we propose a bootstrap resampling method which makes it possible to performthe canonical correlation analysis on a single data matrix.Since a robust estimator is introduced to makeinference about the rank,the procedure may be applied to a wide range of data without any restrictionon the noise distribution.Results from real as well as simulated mixture samples indicate that when usedin conjunction with this resampling method,canonical correlation analysis of a single data matrix isequally efficient as of replicate data matrices.  相似文献   

18.
A photogrammetric and sediment analysis is presented to illustrate the relationship between beach erosion and seacliff recession on Thompson Island, Boston Harbor, Massachusetts. Aerial photographs taken in 1938, 1952, 1963, and 1977 were measured to determine rates of shoreline change around the island. The 39-year average rate of beach erosion is 0.3 m/yr ± 2% with an average rate of cliff recession at 0.2 m/yr ± 2%. Rates of beach erosion between six orientations that reflect principal wave approach to the island were not found to be significantly different (0.05) for the 39-year period. The rank order correlation between beach erosion and cliff recession for these six orientations was moderately well correlated (0.63). To determine possible controls of cliff erosion, 58 sediment samples were collected from glacial cliffs along the shoreline. The textural composition was determined, and then tested with discriminant function analysis. Partial correlation analysis between beach erosion and cliff recession holding a surrogate for sediment size constant improved the rank order from 0.63 to 0.84. The results indicate that coarser-grained cliffs recede at faster rates, but with less erosion occurring on adjacent beaches. Alternatively, finer-grained cliffs recede at slower rates, but with greater erosion occurring on adjacent beaches.  相似文献   

19.
The effects of sedimentation and compaction on oceanic heat flow   总被引：1，自引：0，他引：1  
Summary. The estimation of environmental effects forms an important part of the interpretation of oceanic heat flow measurements. In particular, the perturbations associated with sedimentation and surface temperature changes must be taken into account. Analytical solutions can be obtained only for individual, simplified versions of these problems, whereas any real example is complicated by the process of sediment compaction which changes the bulk thermal properties with depth. A physical model is developed which uses sediment porosity trends to predict the thermal parameters and material advection rates for an evolving sediment/basement system. These values are then used in a numerical solution to the heat flow equation to give estimates of the perturbed surface heat flux through time. In addition to variations in sedimentation rate, sediment type, radioactive heat production and surface temperature changes are considered. Heat flow corrections may vary by up to a factor of 2 according to sediment type while radioactive heat production can offset the effects of sedimentation by as much as 40 per cent. The results also indicate that alterations determined from simple analytical models tend to over-estimate the true perturbation to the flux.  相似文献   

20.
In order to understand the significance of detrital grain ages in sedimentary basins, a new approach is presented. Five characteristic paths, identified by the change in age of detrital grain populations combined with the change in lagtime over time, can be related to different geodynamic settings in the source regions. When lagtime and grain age increase over time, a change in source must be invoked – this is usually a direct response to a geological event. A constant cooling age, a vertical path, associated implicitly with increasing lagtime, implies erosion of materials that had passed through the closure temperature rapidly – exhuming sufficient rock to supply detritus over the time of the path. Constant lagtimes, regardless of the lagtime itself, are indicative of thermochronological stability in the source region. This can involve fast or slow cooling. Finally, decreasing lagtimes support the notion of increasing cooling rates in the source regions over time. A test study is presented from sediments of the northern Ecuadorian Sub‐Andean Zone where geological events had previously been identified using alternative methods. The addition of heavy‐mineral studies increased the precision in the interpretation. At 90 Ma, rapidly decreasing lagtimes point to a phase of tectonic activity. From about 85 Ma until about 60 Ma the lagtimes were approximately zero. This represents a phase of rapid exhumation of the source regions correlating with the previously identified Pallatanga event. An associated increase of metamorphic minerals occurs over this time span, pointing to increased erosion from deeper horizons. At about 70 Ma, the oldest source region, the shield to the east, was switched off. This timing correlates with a change from marine to continental conditions in the basin, a change in palaeocurrent directions from the east to the west, as well as an associated influx of material from the growing Cordillera Real. At about 55 Ma, a change in source is identified by a change in slope of the lagtime curve together with a change in heavy minerals. From 50 to 35 Ma a renewed period of tectonism in the source region is correlated with the docking of the Macuchi terrane which clearly had an effect of increased erosion in the Cordillera Real bringing in higher grade metamorphic minerals. From about 32 Ma onwards the lagtime has been somewhat constant at about 30 Myr. This does not imply, however, a steady‐state environment as it is well known from other geological evidence that there have been other events within this time frame. One must be cautious about over‐interpreting the lagtime as a method to determine steady state in any region. It is a matter of scale.  相似文献   

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