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1.
Abstract— Ar‐rich noble gases, the so‐called “subsolar” noble gases, are a major component of heavy primordial noble gases in unequilibrated ordinary chondrites and some classes of anhydrous carbonaceous chondrites, whereas they are almost absent in hydrous carbonaceous chondrites that suffered extensive aqueous alteration. To understand the effects of aqueous alteration on the abundance of Ar‐rich noble gases, we performed an aqueous alteration experiments on the Ningqiang type 3 carbonaceous chondrite that consists entirely of anhydrous minerals and contains Ar‐rich noble gases. Powdered samples and deionized neutral water were kept at 200 °C for 10 and 20 days, respectively. Mineralogical analyses show that, during the 10‐day alteration, serpentine and hematite formed at the expense of olivine, low‐Ca pyroxene, and sulfide. Noble gas analyses show that the 10‐day alteration of natural Ningqiang removed 79% of the primordial 36Ar, 68% of the 84Kr, and 60% of the 132Xe, but only 45% of the 4He and 53% of the primordial 20Ne. Calculated elemental ratios of the noble gases removed during the 10‐day alteration are in the range of those of Ar‐rich noble gases. These results indicate that Ar‐rich noble gases are located in materials that are very susceptible to aqueous alteration. In contrast, heavy primordial noble gases remaining in the altered samples are close to Q gas in elemental and isotope compositions. This indicates that phase Q is much more resistant to aqueous alteration than the host phases of Ar‐rich noble gases. In the 20‐day sample, the mineralogical and noble gas signatures are basically similar to those of the 10‐day sample, indicating that the loss of Ar‐rich noble gases was completed within the 10‐day alteration. Our results suggest that almost all of the Ar‐rich noble gases were lost from primitive asteroids during early, low‐temperature aqueous alteration.  相似文献   

2.
Abstract– We have determined the elemental abundances and the isotopic compositions of noble gases in a bulk sample and an HF/HCl residue of the Saratov (L4) chondrite using stepwise heating. The Ar, Kr, and Xe concentrations in the HF/HCl residue are two orders of magnitude higher than those in the bulk sample, while He and Ne concentrations from both are comparable. The residue contains only a portion of the trapped heavy noble gases in Saratov; 40 ± 9% for 36Ar, 58 ± 12% for 84Kr, and 48 ± 10% for 132Xe, respectively. The heavy noble gas elemental pattern in the dissolved fraction is similar to that in the residue but has high release temperatures. Xenon isotopic ratios of the HF/HCl residue indicate that there is no Xe‐HL in Saratov, but Ne isotopic ratios in the HF/HCl residue lie on a straight line connecting the cosmogenic component and a composition between Ne‐Q and Ne‐HL. This implies that the Ne isotopic composition of Q has been changed by incorporating Ne‐HL (Huss et al. 1996) or by being mass fractionated during the thermal metamorphism. However, it is most likely that the Ne‐Q in Saratov is intrinsically different from this component in other meteorites. The evidence of this is a lack of correlation between the isotopic ratio of Ne‐Q and petrologic types of meteorites (Busemann et al. 2000). A neutron capture effect was observed in the Kr isotopes, and this process also affected the 128Xe/132Xe ratio. The 3He and 21Ne exposure ages for the bulk sample are 33 and 35 Ma, respectively.  相似文献   

3.
Abstract— We have measured Ne, Ar, Kr and Xe in Si2O3 “smokes” that were condensed on Al substrates, vapor-deposited with various mixtures of CH4, NH3, H2O and noble gases at 10 K and subsequently irradiated with 1 MeV protons to simulate conditions during grain mantle formation in interstellar clouds. The noble gases were analyzed using conventional stepwise heating and static noble gas mass spectrometry. Neither Ne nor Ar is retained by the samples upon warming to room temperature, but Xe is very efficiently trapped and retained. Kr is somewhat less effectively retained, typically depleted by factors of about 10–20 relative to Xe. Isotopic fractionation favoring the heavy isotopes of Xe and Kr of about 5–10‰/amu is observed. Correlations between the specific chemistry of the vapor deposition and heavy noble gas retention are most likely the result of competition by the various species for irradiation-produced trapping sites. The concentration of Xe retained by some of these smokes exceeds that observed in phase Q of meteorites and, like phase Q, they do not seem to be carriers of the light noble gases. Such artificially prepared material may, therefore, offer clues concerning the incorporation of the heavy planetary noble gases in meteoritic material and the nature of phase Q.  相似文献   

4.
Abstract— We have carried out noble gas measurements on graphite from a large graphite‐metal inclusion in Canyon Diablo. The Ne data of the low‐temperature fractions lie on the mixing line between air and the spallogenic component, but those of high temperatures seem to lie on the mixing line between Ne‐HL and the spallogenic component. The Ar isotope data indicate the presence of Q in addition to air, spallogenic component and Ar‐HL. As the elemental concentration of Ne in Q is low, we could not detect the Ne‐Q from the Ne data. On the other hand, we could not observe Xe‐HL in our Xe data. As the Xe concentration and the Xe/Ne ratio in Q is much higher than that in the HL component, it is likely that only the contribution of Q is observed in the Xe data. Xenon isotopic data can be explained as a mixture of Q, air, and “El Taco Xe.” The Canyon Diablo graphite contains both HL and Q, very much like carbonaceous chondrites, retaining the signatures of various primordial noble gas components. This indicates that the graphite was formed in a primitive nebular environment and was not heated to high, igneous temperatures. Furthermore, a large excess of 129Xe was observed, which indicates that the graphite was formed at a very early stage of the solar system when 129I was still present. The HL/Q ratios in the graphite in Canyon Diablo are lower than those in carbonaceous chondrites, indicating that some thermal metamorphism occurred on the former. We estimated the temperature of the thermal metamorphism to about 500–600 °C from the difference of thermal retentivities of HL and Q. It is also noted that “El Taco Xe” is commonly observed in many IAB iron meteorites, but its presence in carbonaceous chondrites has not yet been established.  相似文献   

5.
Effects of aqueous alteration on primordial noble gas carriers were investigated by analyzing noble gases and determining presolar SiC abundances in insoluble organic matter (IOM) from four Tagish Lake meteorite (C2‐ung.) samples that experienced different degrees of aqueous alteration. The samples contained a mixture of primordial noble gases from phase Q and presolar nanodiamonds (HL, P3), SiC (Ne‐E[H]), and graphite (Ne‐E[L]). The second most altered sample (11i) had a ~2–3 times higher Ne‐E concentration than the other samples. The presolar SiC abundances in the samples were determined from NanoSIMS ion images and 11i had a SiC abundance twice that of the other samples. The heterogeneous distribution of SiC grains could be inherited from heterogeneous accretion or parent body alteration could have redistributed SiC grains. Closed system step etching (CSSE) was used to study noble gases in HNO3‐susceptible phases in the most and least altered samples. All Ne‐E carried by presolar SiC grains in the most altered sample was released during CSSE, while only a fraction of the Ne‐E was released from the least altered sample. This increased susceptibility to HNO3 likely represents a step toward degassing. Presolar graphite appears to have been partially degassed during aqueous alteration. Differences in the 4He/36Ar and 20Ne/36Ar ratios in gases released during CSSE could be due to gas release from presolar nanodiamonds, with more He and Ne being released in the more aqueously altered sample. Aqueous alteration changes the properties of presolar grains so that they react similar to phase Q in the laboratory, thereby altering the perceived composition of Q.  相似文献   

6.
Abstract— Noble gases in two ureilites, Kenna and Allan Hills (ALH) 78019, were measured with two extraction methods: mechanical crushing in a vacuum and heating. Large amounts of noble gases were released by crushing, up to 26.5% of 132Xe from ALH 78019 relative to the bulk concentration. Isotopic ratios of the crush‐released Ne of ALH 78019 resemble those of the trapped Ne components determined for some ureilites or terrestrial atmosphere, while the crush‐released He and Ne from Kenna are mostly cosmogenic. The crush‐released Xe of ALH 78019 and Kenna is similar in isotopic composition to Q gas, which indicates that the crush‐released noble gases are indigenous and not caused by contamination from terrestrial atmosphere. In contrast to the similarities in isotopic composition with the bulk samples, light elements in the crush‐released noble gases are depleted relative to Xe and distinct from those of each bulk sample. This depletion is prominent especially in the 20Ne/132Xe ratio of ALH 78019 and the 36Ar/132Xe ratio of Kenna. The values of measured 3He/21Ne for the gases released by crushing are significantly higher than those for heating‐released gases. This suggests that host phases of the crush‐released gases might be carbonaceous because cosmogenic Ne is produced mainly from elements with a mass number larger than Ne. Based on our optical microscopic observation, tabular‐foliated graphite is the major carbon mineral in ALH 78019, while Kenna contains abundant polycrystalline graphite aggregates and diamonds along with minor foliated graphite. There are many inclusions at the edge and within the interior of olivine grains that are reduced by carbonaceous material. Gaps can be seen at the boundary between carbonaceous material and silicates. Considering these petrologic and noble gas features, we infer that possible host phases of crush‐released noble gases are graphite, inclusions in reduction rims, and gaps between carbonaceous materials and silicates. The elemental ratios of noble gases released by crushing can be explained by fractionation, assuming that the starting noble gas composition is the same as that of amorphous carbon in ALH 78019. The crush‐released noble gases are the minor part of trapped noble gases in ureilites but could be an important clue to the thermal history of the ureilite parent body. Further investigation is needed to identify the host phases of the crush‐released noble gases.  相似文献   

7.
Abstract— The trapped noble gas record of 57 enstatite chondrites (E chondrites) has been investigated. Basically, two different gas patterns have been identified dependent on the petrologic type. All E chondrites of type 4 to 6 show a mixture of trapped common chondritic rare gases (Q) and a subsolar component (range of elemental ratios for E4–6 chondrites: 36Ar/132Xe = 582 ± 270 and 36Ar/84Kr = 242 ± 88). E3 chondrites usually contain Q gases, but also a composition with lower 36Ar/132Xe and 36Ar/84Kr ratios, which we call sub‐Q (36Ar/132Xe = 37.0 ± 18.0 and 36Ar/84Kr = 41.7 ± 18.1). The presence of either the subsolar or the sub‐Q signature in particular petrologic types cannot be readily explained by parent body metamorphism as postulated for ordinary chondrites. We therefore present a different model that can explain the bimodal distribution and composition of trapped heavy noble gases in E chondrites. Trapped solar noble gases have been observed only in some E3 chondrites. About 30% of each group, EH3 and EL3 chondrites, amounting to 9% of all analyzed E chondrites show the solar signature. Notably, only one of those meteorites has been explicitly described as a regolith breccia.  相似文献   

8.
The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of 40Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of 40Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H2 resulting from efficient H2O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in 20Ne and 36Ar from Venus to Earth to Mars; (2) a nearly constant 20Ne/36Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for 36Ar/132Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO2 and N2.  相似文献   

9.
Abstract— We present an isotope study of noble gases in Divnoe, an anomalous meteorite, and also Rb-Sr and K-Ar dating of this meteorite. The relatively young Rb-Sr age obtained (3.39 Ga) seems doubtful and, most probably, results from weathering or contamination. The ancient K-Ar age (4.67+0.20–0.40), together with clear excess of 129Xe, allows the suggestion of very early formation of the Divnoe meteorite. Concentrations and isotope ratios of noble gases in Divnoe are: 17.9 ≤ 3He ≤ 29.0 × 10?8; 20Ne = 6.22 × 10?8; 2.44 ≤ 36Ar ≤ 5.10 × 10?8; 130Xe = 41.3 × 10?12 cm3/g; 0.079 ≤ 3He/4He ≤ 0.193; 20Ne/22Ne = 0.860; 21Ne/22Ne = 0.927; 3.47 ≤ 40Ar/36Ar ≤ 9.47; 2.22 ≤ 36Ar/38Ar ≤ 3.27; 129Xe/132Xe = 1.09. The exposure age calculated from cosmogenic 3He, 21Ne, and 38Ar is 17.9 ± 0.9 Ma. On the basis of the isotope data for the noble gases and O, and abundances of K, Rb, and Sr, an attempt was made to estimate the relationship of Divnoe to other meteorite types. The O-isotope characteristics of Divnoe are clearly distinct from those of ordinary chondrites, acapulcoites/lodranites, and SNC meteorites (Petaev et al., 1994, Clayton, 1993). In plots of 136Xe vs. 129Xe/130Xe, the Divnoe data fall outside of the data fields for carbonaceous and enstatite chondrites. The light noble gas data, especially the 40Ar/38Ar ratio, and the 40Ar, 38Ar, 3He, and 4He contents of Divnoe differ significantly from those of all meteorite types except diogenites. The K, Rb, and Sr abundances in Divnoe are substantially lower than in most other meteorites. In the concentrations of these elements, as well as in the REE pattern, the Divnoe meteorite is similar only to diogenites. Divnoe probably should be treated as a restite remaining after partial melting of the chondritic mantle of a parent asteroid body.  相似文献   

10.
Abstract— We studied the elemental and isotopic abundances of noble gases (He, Ne, Ar in most cases, and Kr, Xe also in some cases) in individual chondrules separated from six ordinary, two enstatite, and two carbonaceous chondrites. Most chondrules show detectable amounts of trapped 20Ne and 36Ar, and the ratio (36Ar/20Ne)t (from ordinary and carbonaceous chondrites) suggests that HL and Q are the two major trapped components. A different trend between (36Ar/20Ne)t and trapped 36Ar is observed for chondrules in enstatite chondrites indicating a different environment and/or mechanism for their formation compared to chondrules in ordinary and carbonaceous chondrites. We found that a chondrule from Dhajala chondrite (DH‐11) shows the presence of solar‐type noble gases, as suggested by the (36Ar/20Ne)t ratio, Ne‐isotopic composition, and excess of 4He. Cosmic‐ray exposure (CRE) ages of most chondrules are similar to their host chondrites. A few chondrules show higher CRE age compared to their host, suggesting that some chondrules and/or precursors of chondrules have received cosmic ray irradiation before accreting to their parent body. Among these chondrules, DH‐11 (with solar trapped gases) and a chondrule from Murray chondrite (MRY‐1) also have lower values of (21Ne/22Ne)c, indicative of SCR contribution. However, such evidences are sporadic and indicate that chondrule formation event may have erased such excess irradiation records by solar wind and SCR in most chondrules. These results support the nebular environment for chondrule formation.  相似文献   

11.
Abstract— We analyzed the noble gas isotopes in the Fe‐Ni metal and inclusions of the Saint‐Aubin iron meteorite, utilizing the stepwise heating technique to separate the various components of noble gases. The light noble gases in all samples are mostly cosmogenic, with some admixture from the terrestrial atmosphere. Total abundances of noble gases in metal are one of the lowest found so far in iron meteorites and the 4He/21Ne ratio is as high as 503, suggesting that the Saint‐Aubin iron meteorite was derived from a very large meteoroid in space. The exposure ages obtained from cosmogenic 3He were 9–16 Ma. Saint‐Aubin is very peculiar because it contains very large chromite crystals, which—like the metal—contain only cosmogenic and atmospheric noble gases. The noble gases in all the samples do not reveal any primordial components. The only exception is the 1000 °C fraction of schreibersite which contained about 5% of the Xe‐HL component. The Xe‐Q and the El Taco Xe components were not found and only the Xe‐HL is present in this fraction. Some presolar diamond, the only carrier for the HL component known today, must have been available during growth of the schreibersite. However, it is also possible that this excess is due to the addition of cosmogenic and fission components. In this case, all the primordial components are masked (or lost) by the later events such as cosmic‐ray irradiation, heating, and radioactive decay.  相似文献   

12.
Abstract— Calcium‐aluminum‐rich inclusions (CAIs) were among the first solids in the solar system and were, similar to chondrules, created at very high temperatures. While in chondrules, trapped noble gases have recently been detected, the presence of trapped gases in CAIs is unclear but could have important implications for CAI formation and for early solar system evolution in general. To reassess this question, He, Ne, and Ar isotopes were measured in small, carefully separated and, thus, uncontaminated samples of CAIs from the CV3 chondrites Allende, Axtell, and Efremovka. The 20Ne/22Ne ratios of all CAIs studied here are <0.9, indicating the absence of trapped Ne as, e.g., Ne‐HL, Ne‐Q, or solar wind Ne. The 21Ne/22Ne ratios range from 0.86 to 0.72, with fine‐grained, more altered CAIs usually showing lower values than coarse‐grained, less altered CAIs. This is attributed to variable amounts of cosmogenic Ne produced from Na‐rich alteration phases rather than to the presence of Ne‐G or Ne‐R (essentially pure 22Ne) in the samples. Our interpretation is supported by model calculations of the isotopic composition of cosmogenic Ne in minerals common in CAIs. The 36Ar/38Ar ratios are between 0.7 and 4.8, with fine‐grained CAIs within one meteorite showing higher ratios than the coarse‐grained ones. This agrees with higher concentrations of cosmogenic 36Ar produced by neutron capture on 35Cl with subsequent β?‐decay in finer‐grained, more altered, and thus, more Cl‐rich CAIs than in coarser‐grained, less altered ones. Although our data do not strictly contradict the presence of small amounts of Ne‐G, Ne‐R, or trapped Ar in the CAIs, our noble gas signatures are most simply explained by cosmogenic production, mainly from Na‐, Ca‐, and Cl‐rich minerals.  相似文献   

13.
Abstract— The noble gases He, Ne, Ar, Kr, and Xe were measured in 27 individual Antarctic micrometeorites (AMMs) in the size range 60 to 250 μm that were collected at the Dome Fuji Station. Eleven of the AMMs were collected in 1996 (F96 series) and 16 were collected in 1997 (F97 series). One of the F97 AMMs is a totally melted spherule, whereas all other particles are irregular in shape. Noble gases were extracted using a Nd‐YAG continuous wave laser with an output power of 2.5‐3.5 W for ?5 min. Most particles released measurable amounts of noble gases. 3He/4He ratios are determined for 26 AMMs ((0.85‐9.65) × 10?4). Solar energetic particles (SEP) are the dominant source of helium in most AMMs rather than solar wind (SW) and cosmogenic He. Three samples had higher 3He/4He ratios compared to that of SW, showing the presence of spallogenic 3He. The Ne isotopic composition of most AMMs resembled that of SEP as in the case of helium. Spallogenic 21Ne was detected in three samples, two of which had extremely long cosmic‐ray exposure ages (> 100 Ma), calculated by assuming solar cosmic‐ray (SCR) + galactic cosmic‐ray (GCR) production. These two particles may have come to Earth directly from the Kuiper Belt. Most AMMs had negligible amounts of cosmogenic 21 Ne and exposure ages of <1 Ma. 40Ar/36Ar ratios for all particles (3.9–289) were lower than that of the terrestrial atmosphere (296), indicating an extraterrestrial origin of part of the Ar with a very low 40Ar/36Ar ratio plus some atmospheric contamination. Indeed, 40Ar/36Ar ratios for the AMMs are higher than SW, SEP, and Q‐Ar values, which is explained by the presence of atmospheric 40Ar. The average 38Ar/36Ar ratio of 24 AMMs (0.194) is slightly higher than the value of atmospheric or Q‐Ar, suggesting the presence of SEP‐Ar which has a relatively high 38Ar/36Ar ratio. According to the elemental compositions of the heavy noble gases, Dome Fuji AMMs can be classified into three groups: chondritic (eight particles), air‐affected (nine particles), and solar‐affected (eight particles). The eight AMMs classified as chondritic preserve the heavy noble gas composition of primordial trapped component due to lack of atmospheric adsorption and solar implantation. The average of 129Xe/132Xe ratio for the 16 AMMs not affected by atmospheric contamination (1.05) corresponds to the values in matrices of carbonaceous chondrites (?1.04). One AMM, F96DK038, has high 129Xe/132Xe in excess of this ratio. Our results imply that most Dome Fuji AMMs originally had chondritic heavy noble gas compositions, and carbonaceous chondrite‐like objects are appropriate candidate sources for most AMMs.  相似文献   

14.
Abstract— Chondrules are generally believed to have lost most or all of their trapped noble gases during their formation. We tested this assumption by measuring He, Ne, and Ar in chondrules of the carbonaceous chondrites Allende (CV3), Leoville (CV3), Renazzo (CR2), and the ordinary chondrites Semarkona (LL3.0), Bishunpur (LL3.1), and Krymka (LL3.1). Additionally, metalsulfide‐rich chondrule coatings were measured that probably formed from chondrule metal. Low primordial 20Ne concentrations are present in some chondrules, while even most of them contain small amounts of primordial 36Ar. Our preferred interpretation is that‐in contrast to CAIs‐the heating of the chondrule precursor during chondrule formation was not intense enough to expel primordial noble gases quantitatively. Those chondrules containing both primordial 20Ne and 36Ar show low presolar‐diamond‐like 36Ar/20Ne ratios. In contrast, the metal‐sulfide‐rich coatings generally show higher gas concentrations and Q‐like 36Ar/20Ne ratios. We propose that during metalsilicate fractionation in the course of chondrule formation, the Ar‐carrying phase Q became enriched in the metal‐sulfide‐rich chondrule coatings. In the silicate chondrule interior, only the most stable Ne‐carrying presolar diamonds survived the melting event leading to the low observed 36Ar/20Ne ratios. The chondrules studied here do not show evidence for substantial amounts of fractionated solar‐type noble gases from a strong solar wind irradiation of the chondrule precursor material as postulated by others for the chondrules of an enstatite chondrite.  相似文献   

15.
Abstract— We measured abundances and isotopic compositions of noble gases in metal and schreibersite of the Acuña (IIIAB) iron meteorite. The concentrations of noble gases in Acuña metal are very low compared to those reported so far for other iron meteorites. The isotopic ratios of He, Ne and Ar indicate that they are mostly of cosmogenic origin. Cosmogenic components are even present in Kr and Xe, which could not have been produced from Fe, Ni and P and are probably due to the spallation of trace elements of higher masses. The high 4He/21Ne ratio of 420 in Acuña metal indicates that the samples were at a deep position within a very large meteoroid. The exposure ages of Acuña were estimated to be 50–200 Ma from 3He, 21Ne and 38Ar abundances and by utilizing the diagrams of production rates vs. the 4He/21Ne ratio based on the Signer-Nier model. The low exposure age of Acuña may indicate a history different from that of other IIIAB irons whose exposure ages cluster at ～670 Ma. Otherwise, Acuña may be one of the samples with the low production rate, which can not be estimated from the diagrams of the Signer-Nier model.  相似文献   

16.
Abstract— In this paper, we present concentration and isotopic composition of the light noble gases He, Ne, and Ar as well as of 84Kr, 132Xe, and 129Xe in bulk samples of 33 Rumuruti (R) chondrites. Together with previously published data of six R chondrites, exposure ages are calculated and compared with those of ordinary chondrites. A number of pairings, especially between those from Northwest Africa (NWA), are suggested, so that only 23 individual falls are represented by the 39 R chondrites discussed here. Eleven of these meteorites, or almost 50%, contain solar gases and are thus regolithic breccias. This percentage is higher than that of ordinary chondrites, howardites, or aubrites. This may imply that the parent body of R chondrites has a relatively thick regolith. Concentrations of heavy noble gases, especially of Kr, are affected by the terrestrial atmospheric component, which resides in weathering products. Compared to ordinary chondrites, 129Xe/132Xe ratios of R chondrites are high.  相似文献   

17.
Abstract— Abundances and isotopic compositions of noble gases in metal and graphite of the Bohumilitz IAB iron meteorite were measured. The abundance ratios of spallogenic components in metal reveal a 3He deficiency which is due to the diffusive loss of parent isotopes, that is, tritium (Tilles, 1963; Schultz, 1967). The diffusive loss likely has been induced by thermal heating by the Sun during cosmic‐ray exposure (～160 Ma; Lavielle et al, 1999). Thermal process such as impact‐induced partial loss may have affected the isotopic composition of spallogenic Ne. The 129Xe/131Xe ratio of cosmogenic components in the metal indicates an enhanced production of epi‐thermal neutrons. The abundance ratios of spallogenic components in the graphite reveal that it contained small amounts of metal and silicates. The isotopic composition of heavy noble gases in graphite itself was obtained from graphite treated with HF/HCl. The isotopic composition of the etched graphite shows that it contains two types of primordial Xe (i.e., Q‐Xe and El Taco Xe). The isotopic heterogeneity preserved in the Bohumilitz graphite indicates that the Bohumilitz graphite did not experience any high‐temperature event and, consequently, must have been emplaced into the metal at subsolidus temperatures. This situation is incompatible with an igneous model as well as the impact melting models for the IAB‐IIICD iron meteorites as proposed by Choi et al. (1995) and Wasson et al (1980).  相似文献   

18.
Abstract— We present concentration and isotopic composition of He, Ne, and Ar in ten chondrites from the Nullarbor region in Western Australia as well as the concentrations of 84Ke, 129Xe, and 132Xe. From the measured cosmogenic 14C concentrations (Jull et al. 1995), shielding‐corrected production rates of 14C are deduced using cosmogenic 22Ne/21Ne ratios. For shielding conditions characterized by 22Ne/21Ne >1.10, this correction becomes significant and results in shorter terrestrial ages. The exposure ages of the ten Nullarbor chondrites are in the range of values usually observed in ordinary chondrites. Some of the meteorites have lost radiogenic gases as well as cosmogenic 3He. Most of the analyzed specimens show additional trapped Ar, Kr, and Xe of terrestrial origin. The incorporation of these gases into weathering products is common in chondrites from hot deserts.  相似文献   

19.
Abstract— From November 1998 to January 1999, the 39th Japanese Antarctic Research Expedition (JARE) conducted a large‐scale micrometeorite collection at 3 areas in the meteorite ice field around the Yamato Mountains, Antarctica. The Antarctic micrometeorites (AMMs) collected were ancient cosmic dust particles. This is in contrast with the Dome Fuji AMMs, which were collected previously from fresh snows in 1996 and 1997 and which represent modern micrometeorites. To determine the noble gas concentrations and isotopic compositions of individual AMMs, noble gas analyses were carried out using laser‐gas extraction for 35 unmelted Yamato Mountains AMMs and 3 cosmic spherules. X‐ray diffraction analyses were performed on 13 AMMs before the noble gas measurement and mineral compositions were determined. AMMs are classified into 4 main mineralogical groups, defined from the heating they suffered during atmospheric entry. Heating temperatures of AMMs, inferred from their mineral compositions, are correlated with 4He concentrations and reflect the effect of degassing during atmospheric entry. Jarosite, an aqueous alteration product, is detected for 4 AMMs, indicating the aqueous alteration during long‐time storage in Antarctic ice. Jarosite‐bearing AMMs have relatively low concentrations of 4He, which is suggestive of loss during the alteration. High 3He/4He ratios are detected for AMMs with high 20Ne/4He ratios, showing both cosmogenic 3He and preferential He loss. SEP (solar energetic particles)‐He and Ne, rather than the solar wind (SW), were dominant in AMMs, presumably showing a preferential removal of the more shallowly implanted SW by atmospheric entry heating. The mean 20Ne/22Ne ratio is 11.27 ± 0.35, which is close to the SEP value of 11.2. Cosmogenic 21Ne is not detected in any of the particles, which is probably due to the short cosmic ray exposure ages. Ar isotopic compositions are explained by 3‐component mixing of air, Q, and SEP‐Ar. Ar isotopic compositions can not be explained without significant contributions of Q‐Ar. SEP‐Ne contributed more than 99% of the total Ne. As for 36Ar and 38Ar, the abundance of the Q component is comparable to that of the SEP component. 84Kr and 132Xe are dominated by the primordial component, and solar‐derived Xe is almost negligible.  相似文献   

20.
Abstract— This study provides a complete data set of all five noble gases for bulk samples and mineral separates from three Martian shergottites: Shergotty (bulk, pyroxene, maskelynite), Zagami (bulk, pyroxene, maskelynite), and Elephant Moraine (EET) A79001, lithology A (bulk, pyroxene). We also give a compilation of all noble gas and nitrogen studies performed on these meteorites. Our mean values for cosmic‐ray exposure ages from 3He, 21Ne, and 38Ar are 2.48 Myr for Shergotty, 2.73 Myr for Zagami, and 0.65 Myr for EETA79001 lith. A. Serious loss of radiogenic 4He due to shock is observed. Cosmogenic neon results for bulk samples from 13 Martian meteorites (new data and literature data) are used in addition to the mineral separates of this study in a new approach to explore evidence of solar cosmic‐ray effects. While a contribution of this low‐energy irradiation is strongly indicated for all of the shergottites, spallation Ne in Chassigny, Allan Hills (ALH) 84001, and the nakhlites is fully explained by galactic cosmic‐ray spallation. Implanted Martian atmospheric gases are present in all mineral separates and the thermal release indicates a near‐surface siting. We derive an estimate for the 40Ar/36Ar ratio of the Martian interior component by subtracting from measured Ar in the (K‐poor) pyroxenes the (small) radiogenic component as well as the implanted atmospheric component as indicated from 129Xe, * excesses. Unless compromised by the presence of additional components, a high ratio of ～2000 is indicated for Martian interior argon, similar to that in the Martian atmosphere. Since much lower ratios have been inferred for Chassigny and ALH 84001, the result may indicate spatial and/or temporal variations of 40Ar/36Ar in the Martian mantle.  相似文献   

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