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1.
Si, Ti, Al, Fe, Mn, Ca, Mg, K, Na, P and Sr, Ba, Rb, Ga, V, Zr, Cr, Ni, Co, Cu, Zn, Pb,Nb, Y, Th, La in the core S01 were analyzed and the pattems of their enrichment are discussed.Enrichment of Na, Fe, Mn, Ba, Cu elements in the core indicates volcanic material are an importantsoarce of the sediments in the area. The enrichment frequently varying with the deposition processshows bottom volcanism is frequent in the area and that the studied area is a margin basin with distinctoceanic characteristics. The abnormal enrichment of Mn at the layers(0-15 cm and 665-670 cm) of the core could beclosely related to and so, indicate, the wide deposition hiatus that have occurred in the West PacificOcean and adjacent margin seas since Late Pleistocene.  相似文献   

2.
A total of 21 elements, Si, Al, K, Na, Ca, Mg, Fe, Mn, Ti, P, Cu, Co, Ni, Zn, Pb, Cr, Rb, Sr Ba, Cd and Corg(organic carbon), was determined in the trough. Average contents of most elements were found to be higher in the trough bottom than in the western and eastern slopes. We call these elements the indicator elements because of their “transition” property. This is in keeping with the “intermediate” geographical position of the trough where the continental crust turns to oceanic crust. Though the authigenic fraction of some elements here increases, the detrital fraction of most elements is still dominant, indicating that the influences of terrigenous and volcanic detrital materials on the trough sediments are still dominant. The abundant biogenous component in the trough is characterized by the increase of Ca, Sr, and Corg contents. Ca existes mainly in the form of CaCo3 that is mostly found in various shells. Sr often easily replaces Ca within the shells. A belt-shaped distribution pattern of elements was found in the south and a “block” pattern in the north trough. Such distribution patterns are directly controlled by water depth, topography, current sediment type, and mineral, biological, and volcanic processes. This paper was published in Chinese in Oceanologia et Limnologia Sinica15(4): 371–379, 1984.  相似文献   

3.
In the current study, we determined concentrations and transfer rates of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, Pb, P, Rb, Sr and Zn to Brown Birch Scaber Stalks (Leccinum scabrum) mushrooms emerged in the area of Sudety Mountains (Sudetes) in Poland. Fruiting bodies and topsoil samples beneath L. scabrum were collected form the K odzka Dale. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES) for final measurement. Mushrooms contained Ag, Cr, Hg, Co, Ni and Sr at < 1.0 μg/g dry weight; Ba and Pb at ~1.0 μg/g dw; Cd at < 5 μg/g dw; Cu and Mn at > 10 μg/g dw; Al and Ca at ~100 μg/g dw; Fe, Na, Rb and Zn at 100 to 500 μg/g dw, Mg at ~1,000 μg/g dw; P at ~5,000 μg/g dw and K at ~30,000 μg/g dw. Ca, Mn and Ni were nearly equally distributed between stipes and caps; stipes compared to caps were enriched in Ba, Na and Sr, while caps were enriched in Ag, Al, Cd, Co, Cr, Cu, Fe, K, P, Pb, Rb and Zn. The values of bioconcentration factor (BCF) varied highly depending on chemical element and were >1 for Ag, Cd, Cu, K, Mg, Na, P, Rb and Zn, while <1 for Al, Ba, Ca, Co, Cr, Fe, Mn, Ni, Pb and Sr. Topsoil showed elevated content of lead and mean concentration was 99 ± 32 μg/g dw, while cadmium was at 0.41 ± 0.15 and those two highly toxic to human elements occurred in edible caps of L. scabrum at 4.5 ± 2.2 and 2.9 ± 2.0 μg/g dw, respectively.  相似文献   

4.
作者利用全省不同地质时代和不同地质构造单元内的页岩41种元素的分析数据,计算出辽宁省全域内的页岩元素丰度休系。同时探讨了元素从中、晚元古代至中生代的演化规律,指出Ca、Cd、Sb、As、Na、Mn、P、Sr的元素丰度随时间序列的演化不断增长,B、F、K、Rb、W、Mg则显示出降低的趋势。某些元素比值从老至新表现出明显的规律性变化,如Sr/Ba、Ca/Mg值的演化具有阶段性,K/Na、Th/U值的演化具有方向性,Al/Ti值的演化则具有周期性。  相似文献   

5.
This study explores the potential existence of local stocks of Synechogobius ommaturus using otolith chemical signatures. The concentrations of 10 elements (K, Ca, Na, Mg, Sr, Pb, Ba, Mn, Co, Zn) in the otoliths from eight stocks (Dandong, Dalian, Tianjin, Dongying, Weihai, Qingdao, Ganyu and Xiamen) of S. ommaturus were measured by Inductively Coupled Plasma Mass Spectrometry and regressed against otolith weight. No significant correlation between otolith weight and concentrations of Na, Mg, Ca, Sr, Co, Ba, Zn and Pb were observed. Concentrations of K and Mn were correlated with otolith weight. Consequently, the residuals of the regressions were used instead of the original concentrations in subsequent analyses. Analysis of variance (ANOVA) showed no significant difference between males and females in otolith chemical signatures. Differences were found among the locations for K, Sr, Mn, Co, Ba, Pb, but not for Ca, Na, Mg and Zn. Residuals of the regressions of elemental concentrations against otolith weight that fitted the normal distribution and homogeneity were studied by discriminant analysis. The success of the discriminant function to predict the location of S. ommaturus capture ranged from 100% for Weihai and Xiamen stocks, to only 44.4% and 62.5% for Qingdao and Dandong stocks, respectively. The average prediction success was 80.3%.  相似文献   

6.
This paper reported the results of the determination of Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sr and Zn in Common Chanterelles (Cantharellus cibarius) Fr. and surface soil layer (0-10 cm) underneath the fruiting bodies. Mushrooms and soils were collected from a lowland site in the Hel Peninsula (Baltic Sea coast) and a high mountain site in the Tatra Mountains. The trace elements were determined using validated method and inductively coupled plasma - atomic emission spectroscopy (ICP-AES). Common Chanterelles that emerged at sites poor in mineral nutrients podzols of the Hel Peninsula forests efficiently bioconcentrated several essential trace elements (K, P, Co, Cu, Mn, Na, Zn), while the abundance of those elements in carpophores was around half less compared to specimens from Zakopane region and which emerged in soils much richer in minerals. Common Chanterelles collected at two spatially distant background areas in Poland were only weakly contaminated with metals such as Ag, Cd, Hg and Pb. The maximum tolerable Cd and Pb contents of certain cultivated mushrooms are regulated in the European Union by law and these hazardous metals in C. cibarius were far below tolerance limits set.  相似文献   

7.
Using neutron activation analysis method we determined contents of rare-earth and radioactive elements (La, Ce, Nd, Sm, Eu, Tb, Yb, Lu, Cs, Rb, Sb, Sc, Sr, Ba, U, Th) in source water system of the Changjiang (Yangtze) River, which is mainly composed of the Tuotuo River, the Chumaer River, and the Buqu River. The contents of these elements in the unflltered water have a great variation and a close correlation with the water turbidity. The contents of these elements in filtered water only have a little variation and are lower than those in the unflltered water. The variations in contents of these elements in sediments are also very little. These elements in the unifiltered water are in geometric distribution, except Sc. Most of the elements in sediments are in arithmetic distribution, but Cs, Sb, Th, are in deviation distribution. The contents of most of these elements in the river source area correspond to the contents of fresh water of the earth. Most of these elements have a little variation in their c  相似文献   

8.
南岭及邻区的第四纪沉积以冲积物、残积物和洞穴堆积物为主,长期以来缺乏统一的地层格架和时间框架。基于剖面资料和实地调查,将南岭第四纪地层划分为永州-郴州、桂林-贺州、韶关-清远、赣州、道县-阳山等5个地层小区;通过厘定每个小区的岩石地层序列、生物地层和气候地层及其测年成果,建立了综合地层的对比格架。结果表明,南岭第四系与中国更新统泥河湾阶、周口店阶、萨拉乌苏阶和尚未建阶的全新统可一一对比;其生物地层以早更新世巨猿动物群和中更新世晚期以来的马坝人、道县人和柳江人等智人演化为特点;气候地层以洞穴石笋和高山泥炭重建的古气候记录为代表,主要反映东亚季风背景下的南岭局地气候。但由于测年数据较少,冲积层和残积层的对比仍然存在困难;生物演化阶段与气候变化之间也未能详细对比。因此,今后南岭的第四纪地层研究应围绕提高测年精度与建立统一的年代标尺开展,促进综合地层对比的精细化、延伸气候地层的时间尺度并拓展与南海海相地层的对比;这一基础性工作对水文、环境、工程等实践应用亦具有重要意义。   相似文献   

9.
A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard (for the trace elements). The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% (n=12).  相似文献   

10.
We applied solution-based ICP-MS method to quantify the trace-elemental signatures in statoliths of jumbo flying squid, Dosidius gigas, which were collected from the waters off northern and central Chile during the scientific surveys carried out by Chinese squid jigging vessels in 2007 and 2008. The age and spawning date of the squid were back-calculated based on daily increments in statoliths. Eight elemental ratios(Sr/Ca, Ba/Ca, Mg/Ca, Mn/Ca, Na/Ca, Fe/Ca, Cu/Ca and Zn/Ca) were analyzed. It was found that Sr is the second most abundant element next to Ca, followed by Na, Fe, Mg, Zn, Cu, Ba and Mn. There was no significant relationship between element/Ca and sea surface temperature(SST) and sea surface salinity(SSS), although weak negative or positive tendency was found. MANOVA analysis showed that multivariate elemental signatures did not differ among the cohorts spawned in spring, autumn and winter, and no significant difference was found between the northern and central sampling locations. Classification results showed that all individuals of each spawned cohorts were correctly classified. This study demonstrates that the elemental signatures in D. gigas statoliths are potentially a useful tool to improve our understanding of its population structure and habitat environment.  相似文献   

11.
Characteristics of metals in the aerosols of Zhongshan Station, Antarctica   总被引:1,自引:0,他引:1  
Instrumental neutron activation analysis (INAA) was applied to analyze the bulk, high-volume aerosol samples, collected at Zhongshan Station in the Eastern Antarctica, during 1998-2001, to study the chemical species. .A graphical technique was applied to the INAA data. Results showed that Na, Cl, Mg, Ca, Sr, Br, I, Sr and Rb were marine elements while Al, Sc, Fe and Mn were crustal elements. Compared to marine and crustal elements, five elements (Se、Co、Sb、Zn、Cr) were highly abundant in the aerosols collected at Zhongshan station, which indicated that they might come from the petroleum burning, heating and equipment operation. The presence of pollutant elements suggested that human activities have affected the local environments in Antarctica.  相似文献   

12.
石炭系—二叠系沉积以剥蚀残余状分布在渤海湾盆地之下,在已发现油气的部位均发现浅层侵入岩。通过侵入岩产状、主量元素和微量元素组成等地质和地球化学分析,发现侵入岩主要为富二氧化硅、钠、钾和镁的闪长玢岩以及贫二氧化硅和钠、富钾和镁的煌斑岩,它们与鲁西隆起同层位侵入岩具有很多相似之处。研究认为它们是侏罗纪断陷形成初期上地幔物质上涌、沿深大断裂侵入形成的,以富钾偏碱性或偏中性两种岩浆侵入在煤系烃源岩中。研究还发现,煤系地层中的这些侵入体规模不大,对烃源岩的烘烤作用范围不超过侵入体的厚度,对整体的煤系生烃演化影响较小。  相似文献   

13.
利用空气—乙炔火焰原子吸收光谱法对马氏珍珠进行了13个元素的测定,结果表明优质珍珠与劣质珍珠主要在Zn、Mg、Cu、Mn、Ph、K、Cr、Sr等元素含量方面有差异。珍珠在加工前后变化很大的元素是Zn、Mg、Cu、Na、Mn、Cr、Sr等。根据一些元素对珍珠质量的显著影响,提出在加工过程应注意对珍珠质量有利元素的加入和有损珍珠质量的元素的去除。  相似文献   

14.
利用元素分析仪和原子吸收光谱仪分析了褶纹冠蚌(Cristaria plicata Leach)的四个不同培育阶段的珍珠的十三种元素的含量,以期从连续动态的角度探讨珍珠的形成机制。结果表明,随着育珠时间的延长,珍珠中Ca元素的含量是逐渐增加的,C和H元素的含量则是逐渐下降的。在微量元素中,Na、Cu、Zn、Mg和Sr的含量比较高,其中Na在晚期的珍珠中的含量显著高于早期的珍珠,而CuZn、Mg等其它微量元素则是在早期珍珠中的含量明显高于晚期珍珠,它们随着育珠时间的延长呈指数下降。  相似文献   

15.
Surface sediments were collected from Lake Manzala, the Mediterranean coastal wetland located to the east of the Nile Delta, Egypt, to assess the effect of drain effluent on the spatial variations of sedimentary characteristics and heavy metal pollution. Grain-size compositions, textures, and heavy metal distribution patterns in sediments are presented using GIS technique. Results of the analysis of the sediment showed a clear effect of drain effluent, with an increase in fine fractions and homogeneous suspensions in transportation mode. Lake sediments were dominated by sandy mud textures, and mode of transportation was homogeneous suspension and rolling. Spatial distribution of heavy metals(Fe, Mn, Zn, Cu, Ni, Cr, and Pb) was studied in the lake's surficial sediments, along with their relationship to drain effluent and their contamination status in the ecological system. Heavy metal pollution status was assessed by means of accepted sediment quality guidelines and contamination assessment methods(contamination factor, contamination degree, modified contamination degree, geo-accumulation, and enrichment factor). Among the determined heavy metals, Pb had the most ecological risk. Generally, the heavy metals in the surface sediments indicated pollution risk ranging from moderate to considerable, particularly, in those sites facing drains and inlets that had the highest toxic effluent. The results were interpreted by statistical means. A cluster analysis defined areas facing drain discharge and inlets as separated groups. ANOVA indicated that most of the sedimentation and studied metals directed this clustering.  相似文献   

16.
The concentrations of major elements and some trace elements were determined at 8 core locations in Taihu Lake. The chemical composition of the cores was related to the sediment particle size-chronology and location of sampling site.Concentrations of Al, Mg, K, Ca and Na, the major mineral species in the sediments, were generally uniform, with only slight fluctuation influenced by water waves and current. Surface enrichment of Cu, Zn, and Ni at some locations was observed to be greater than that of the sediments accumulated 100 years ago. The enrichment of these elements is attributed to anthropogenic input in recent years. Concentration profiles for Mn and Fe are related to the migration of these elements in the pore water.  相似文献   

17.
在山东省北部(鲁北)地区,当地群众由于长期饮用高氟深层地下水,极易导致地氟病,严重影响当地群众的身体健康。根据取样分析,研究区深层地下水氟离子含量大致呈现由南向北、由东向西依次增大的趋势,并且同一地段不同深度、不同岩性的氟离子含量也不尽相同,粘土中氟离子含量普遍大于粉砂层中的含量,高氟地下水多为弱碱性水,高氟地下水Na/Ca比高,高氟水与Na/Ca呈对数相关,相关性较好;高氟水水化学类型一般为HCO_3·Cl-Na型。从地质环境、水文地质环境、水文地球化学角度初探了鲁北平原深层高氟地下水的水文地球化学成因,认为鲁北深层高氟水的形成及分布规律主要受沉积环境、径流条件以及开采量的影响。由于沉积物来源的不同、水化学特征的迥异以及深层地下水的大量开采,粘土层压密释水过多补给,同时由于粘土层由南向北厚度逐渐增大,地下水径流进一步变缓,造成氟离子含量逐步增高,形成了南北部相差较大的氟离子分布特征。  相似文献   

18.
Since Late Proterozoic era, the Korean Peninsula has been evolved into a state with relatively stable regions and orogenic beltswhich were developed differently each other. The Late Paleozoic (Late Carboniferous-Early Triassic) sediments are well developed in the Korean Peninsula, and called the Pyongan System. The Pyongan System from Late Carboniferous to Lower Triassic is distributed in the Pyongnan and Hyesan-Riwon Basins, and Rangrim Massif, and divided into Hongjom (C2 ) , Ripsok (C2 ) , Sadong (C2-P1 ) , Kobangsan and Rokam ( Taezhawon) ( P2-T1 ) sequences. The sediments of the Tumangang Orogenic Belt are called Tuman System which is composed of the Amgi Series, consisting of clastic formation with mafic effusive material, overlaid by the Kyeryongsan Series, consisting mainly of mafic volcano sediments. The Songsang Series which rests on the Kyeryongsan Series mainly consists of clastic formation with minor felsic effusive material. In the Tuman- gang Orogenic Belt the tectonic movement, called Tumangang Tectonic Movement, occurred in the Lower Permian-Lower Triassic.  相似文献   

19.
辽宁金伯利岩地质—地球化学研究结果表明,辽宁金伯利岩主元素丰度较世界金伯利岩的平均成分,显示富Ca、Al和贫K、Na、Mg、Si,碱度偏低;与南非、苏联和我国山东含金刚石金伯利岩相比,Fe 质偏高。辽宁金伯利岩含矿程度由富到贫,有 Fe、Mg 组分增高,Ca 质降低,微量元素多趋富集的总体变化趋势。辽南金伯利岩较辽北金伯利岩具有碱性程度相对偏高,V、Li、Rb、Nb、La、Sn、Mo、Cu、Pb、Zn、Ag、Ba、Cd、B、S、F 等元素相对富集,Co、Ni、Cr、Th、Bi、Au、As、Sb、Hg、Sr 等元素相对贫化的特点。二者的元素组合和相关特征有明显差别。辽南金伯利岩 Na、Ca、Mn 3元素的相关组合特征是富、贫(中)金刚石金伯利岩的一个地球化学标志。  相似文献   

20.
In order to study the element contents and distribution of various mosses collected in the Antarctica, we analyzed the heavy elements of 3 species of Polytri-chum in the Fildes Peninsula, P. alpinum, P. juniperinum and P. alpestre, by synchrotron radiation X-ray fluorescence ( SR-XRF). The result shows that the elements, such as K, Ca, Mn, Fe, Cu, Zn and Sr, are nearly the same in Potytrichum. The peak intensity of K is higher than that of Ca, and the peak intensity of Ca is higher than that of Fe in P. alpinum. In P. juniperinum, the peak intensity of K is higher than that of Ca, and the peak intensity of Ca is close to that of Fe. The peak intensity of K is nearly equal to those of Ca and Fe in P. alpestre. Therefore, the habitats of 3 species of Polytrichum are similar in the Fildes Peninsula. By XRF analyzing of different parts of P. alpestre, we found that the peak intensities of relative concentration of elements are obviously different. The peak intensity of K in apical-bud is the highest in orga  相似文献   

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