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1.
Summary Abundant upper mantle and rare lower crustal xenoliths have been found in the Plio-Pleistocene alkali basalts of the Nógrád-G?m?r Volcanic Field, situated in the northern Pannonian Basin, on the border between northern Hungary and southern Slovakia. A few lower crustal granulite xenoliths have been found in a small basaltic pyroclastic cone at Baglyaskő. The mafic granulite xenoliths are plagioclase-bearing hornblende clinopyroxenites, plagioclase-bearing clinopyroxene hornblendites and plagioclase-bearing clinopyroxenites. They contain unusual symplectites, composed of spinel feldspar and clinopyroxene. These symplectites are interpreted as the product of garnet breakdown. Following the breakdown reaction, the symplectite underwent in situ partial melting. Mineral constituents of these granulite xenoliths have chemical compositions similar to those of other granulite xenoliths worldwide. However, a distinctive positive Pb and Ce anomaly in mineral constituents of these granulites is characteristic. Granulite xenoliths from the Nógrád-G?m?r Volcanic Field must have experienced granulite facies metamorphism at pressures that correspond to the ‘original’ thickness of the crust (>1.1 GPa; >∼30 km), whereas the breakdown reaction of garnet and subsequent melting and recrystallization of clinopyroxenes in the symplectites happened at shallower depths close to the present-day MOHO (0.6–0.7 GPa; ∼16–19 km). Present address: Research School of Earth Sciences, Australian National University, Australia  相似文献   

2.
Corona and inclusion textures of a metatroctolite at the contact between felsic granulite and migmatites of the Gföhl Unit from the Moldanubian Zone provide evidence of the magmatic and metamorphic evolution of the rocks. Numerous diopside inclusions (1–10 μm, maximum 20 μm in size) in plagioclase of anorthite composition represent primary magmatic textures. Triple junctions between the plagioclase grains in the matrix are occupied by amphibole, probably pseudomorphs after clinopyroxene. The coronae consist of a core of orthopyroxene, with two or three zones (layers); the innermost is characterized by calcic amphibole with minor spinel and relicts of clinopyroxene, the next zone consists of symplectite of amphibole with spinel, sapphirine and accessory corundum, and the outermost is formed by garnet and amphibole with relicts of spinel. The orthopyroxene forms a monomineralic aggregate that may contain a cluster of serpentine in the core, suggesting its formation after olivine. Based on mineral textures and thermobarometric calculations, the troctolite crystallized in the middle to lower crust and the coronae were formed during three different metamorphic stages. The first stage relates to a subsolidus reaction between olivine and anorthite to form orthopyroxene. The second stage involving amphibole formation suggests the presence of a fluid that resulted in the replacement of igneous orthopyroxene and governed the reaction orthopyroxene + anorthite = amphibole + spinel. The last stage of corona formation with amphibole + spinel + sapphirine indicates granulite facies conditions. Garnet enclosing spinel, and its occurrence along the rim of the coronae in contact with anorthite, suggests that its formation occurred either during cooling or both cooling and compression but still at granulite facies conditions. The zircon U–Pb data indicate Variscan ages for both the troctolite crystallization (c. 360 Ma) and corona formation during granulite facies metamorphism (c. 340 Ma) in the Gföhl Unit. The intrusion of troctolite and other Variscan mafic and ultramafic rocks is interpreted as a potential heat source for amphibolite–granulite facies metamorphism that led to partial re‐equilibration of earlier high‐ to ultrahigh‐P metamorphic rocks in the Moldanubian Zone. These petrological and geochronological data constrain the formation of HP–UHP rocks and arc‐related plutonic complex to westward subduction of the Moldanubian plate during the Variscan orogeny. After exhumation to lower and/or middle crust, the HP–UHP rocks underwent heating due to intrusion of mafic and ultramafic magma that was generated by slab breakoff and mantle upwelling.  相似文献   

3.
Five spinel lherzolite xenoliths hosted in Neogene alkali basalts from the marginal parts of the Pannonian Basin (Styrian Basin in Austria and Persani Mts. in the Eastern Transylvanian Basin, Romania) contain orthopyroxene–clinopyroxene–spinel clusters, which are believed to represent former garnet in lherzolitic mantle material. 'Palaeo' equilibrium pressure of this former garnet lherzolite was estimated to be equivalent to depths of 90–120 km using calculated garnet compositions and measured orthopyroxene compositions from the clusters. 'Neo' equilibrium pressures of the xenoliths indicate depths of 55–65 km, suggesting c.  50–60 km uprise of the mantle section represented by these xenoliths. This petrological result confirms the observations from previous geophysical studies that significant mantle uplift has occurred beneath the Pannonian Basin.  相似文献   

4.
An isochemical kelyphite (orthopyroxene+spinel+plagioclase) that has nearly the same bulk chemical composition as the precursor garnet was found within a matrix of ordinary kelyphites (orthopyroxene+clinopyroxene+spinel±amphibole) in garnet peridotites from the Czech part of the Moldanubian Zone. It was shown that the kelyphitization of garnet took place in three stages: (1) the garnet-olivine reaction, accompanied by a long-range material transfer across the reaction zone, and (2) the isochemical breakdown of garnet, essentially in a chemically-closed system, and finally, (3) an open-system hydration reaction producing a thin hydrous zone (amphibole+spinel+plagioclase), which is located between the isochemical kelyphite and relict garnet. The presence of relict garnet suggests that this breakdown reaction of the second stage did not proceed to a completion probably being hindered by the formation of the hydrous zone at the reaction front. It was found by electron back-scattered diffraction method that orthopyroxene and spinel do not show any topotaxic relationship in the first type of kelyphite; whereas they show locally topotaxic relationship in the isochemical kelyphite. The transition from the first type to the second type of kelyphite is discussed on the basis of the detailed observations in the transition zone between the two kelyphites. More widespread occurrence of isochemical kelyphite is expected to occur in orogenic peridotites as well as from xenoliths brought by volcanics.  相似文献   

5.
We examined the textural and geochemical characteristics of spinel-pyroxene symplectites in spinel-lherzolites collected from the lowest, middle, and upper parts (LZ1, MZ, and UZ1, respectively) of the Horoman Peridotite Complex, Japan. The modal proportion of the minerals within symplectite is almost the same, i.e., orthopyroxene:clinopyroxene:spinel = 2:1:1. The size of the symplectite minerals increases from the lowest through to the middle to the upper parts in the complex. The reconstructed major element composition of the bulk symplectites is intermediate between pyrope-rich garnet and olivine. The model garnet compositions of the LZ1satisfies garnet stoichiometry and those of the MZ and UZ1 are not consistent with garnet stoichiometry. The primitive mantle-normalized pattern in trace elements for the LZ1 symplectite is similar to that of pyrope-rich garnet from fertile peridotites, particularly in its enrichment of HREE and a positive Zr anomaly. Thus, the LZ1 symplectite has inherited both major and trace element signatures from pre-existing garnet whereas the compositions of the MZ and UZ1 symplectites were modified during and/or after breakdown of pre-existing garnet. Geochemical and textural variations of symplectites might basically correspond to temperature differences within the complex during upwelling of the Horoman Complex. The basal part of the complex (LZ1) experienced the lowest temperature decompression path in the complex, which resulted in less textural and chemical modification. On the other hand, the higher part of the complex (UZ1) experienced a relatively higher temperature decompression path than other parts of the complex, resulting in chemical equilibration among the constituent minerals and coarsening of the symplectite minerals. Selective enrichment of Sr and LREE in the symplectite may indicate that the metasomatism by a Sr- and LREE-rich melt/fluid occurred during and/or after the formation of symplectite.  相似文献   

6.
In mafic granulites, garnet can form by reactions such as Opx + Pl = Cpx + Grt + Qtz; Opx + Pl = Grt + Qtz. As a result of isothermal decompression (ITD), garnet can then break down to a characteristic orthopyroxene-plagioclase symplectite. Mafic, iron-rich garnet-pyroxene granulite from the Guaxupé Massif has symplectite that formed by near-isothermal decompression, as a consequence of uplift of the granulite facies terrane. This symplectite was found to consist of vermicular clinopyroxene-orthopyroxene-plagioclase, with clinopyroxene clearly growing from the garnet that is breaking down, modal amounts of clinopyroxene being less than orthopyroxene. Electron probe analyses show clear differences between core (Cpx1), rim, and symplectite clinopyroxene (Cpx2). Considering also the presence of magnetite in the symplectite texture, garnet breakdown is thought to be better represented by a reaction such as Cpx1 + Grt + O2 = Cpx2 + Opx + Pl +Mt + Qtz.  相似文献   

7.
Garnet-bearing mantle xenoliths have been recovered from Quaternary alkali basalts, both within and peripheral to the Hangay dome of central Mongolia. Microfabric analysis and thermobaromery, combining empirical thermobarometers and the self-consistent dataset of THERMOCALC, indicate that garnet websterites from the Shavaryn-Tsaram volcanic centre at the dome core were formed in the spinel-lherzolite upper mantle at pressures of 17–18 kbars and temperatures of 1,070–1,090°C, whereas garnet lherzolites were derived from greater depths (18–20 kbars). Garnet lherzolites from the Baga Togo Uul vents near the dome edge were formed at 18–22 kbars under significantly cooler conditions (960–1,000°C). These xenoliths reveal reaction coronas of (1) orthopyroxene, clinopyroxene, plagioclase and spinel mantling garnets; (2) spongy rims of olivine replacing orthopyroxene and (3) low-Na, low-Al clinopyroxene replacing primary clinopyroxene. Trace-element abundances indicate that clinopyroxene from these coronas is in chemical equilibrium with the host magma. The thermobarometric and textural data suggest that lherzolite xenoliths from both sites were derived from depths of 60–70 km and entrained in magma at 1,200–1,300°C. The average rate of ascent, as determined by olivine zoning, lies in the range 0.2–0.3 m s−1. The contrast in thermal profiles of the upper mantle between the two sites is consistent with a mantle plume beneath the Hangay dome with elevated thermal conditions beneath the core of the dome being comparable to estimates of the Pleistocene geotherm beneath the Baikal rift.  相似文献   

8.
Numerous lenticular bodies of ultramafic rocks occur withinthe upper amphibolite- to granulitefacies metamorphic terraneof the Austrides between the Non and Ultimo valleys (Nonsbergregion), northern Italy. The ultramafic rocks are divided intotwo textural types: (a) coarse-type; and (b) finetype. The coarse-typerocks have the protogranular texture and are predominantly spinellherzolite. Some coarse-type spinel lherzolites have partlytransformed to garnet lherzolite. The fine-types are consideredto be metamorphic derivatives of the former, and the observedmineral assemblages are: (1) olivine + orthopyroxene + clinopyroxene+ garnet + amphibole ? spinel, (2) olivine + orthopyroxene +garnet + amphibole + spinel; (3) olivine + orthopyroxene + amphibole+ spinel; and (4) olivine+ orthopyroxene + amphibole + chlorite.Based on the microprobe analyses of constituent minerals fromten representative peridotite samples, physical conditions ofthe metamorphism, particularly that of the spinel to garnetlherzolite transformation, are estimated. Applications of pyroxenegeothermometry yield temperature estimates of 1100–1300?Cfor the formation of the primary spinel lherzolite, and 700–800?Cfor that of the fine-type peridotites. A pressure range of 16–28kb is obtained for the garnet lherzolite crystallization dependingon the choice of geobarometers. Two alternative P-T paths, i.e.(1) isobaric cooling or (2) pressure-increase and temperaturedecrease are considered and their geodynamic implications discussed.  相似文献   

9.
Garnet-bearing metapelites and amphibolites are exposed in the south and middle parts of the Zanhuang complex, which is located in the central segment of the nearly NS-striking Trans-North China Orogen. These rocks preserve three metamorphic mineral assemblages forming at the prograde, peak and post-peak decompression stages. The prograde metamorphic stage (M1) is represented by mineral inclusions within garnet porphyroblasts, the peak metamorphic stage (M2) is represented by garnet rims and matrix minerals, whereas the retrograde stage (M3) is represented by amphibole + plagioclase symplectite rimming garnet porphyroblasts in the amphibolites and biotite + plagioclase symplectite rimming garnet porphyroblasts in the metapelites. All garnet porphyroblasts in the metapelites preserve prograde chemical zoning except for the ubiquitous, quite narrow zones from the underwent post-peak decompression. It has been determined through thermobarometric computation that the metamorphic conditions are 650–710°C at 8.2−9.2 kbar for the M1 (inclusion) assemblages, >810°C at >12.5 kbar for the metamorphic peak M2 (matrix) assemblages, and 660–680°C at 4.4–4.5 kbar for the retrograde M3 (symplectite) assemblages. These rocks are thus determined to have undergone metamorphism with clockwise P–T paths involving nearly isothermal decompression (ITD) segments, which is inferred to be related to the amalgamation of the Eastern and Western Blocks to form the coherent basement of the North China Craton along the Trans-North China Orogen in the late Paleoproterozoic (1.88–1.85 Ga).  相似文献   

10.
Silicate-oxide symplectites in complex mineral intergrowths are relatively common in upper mantle xenoliths and in xenoliths in the Jagersfontein Kimberlite, South Africa.Harzburgites of olivine and high-Al (1.9–3.6 wt%), Ca (0.6–0.9 wt%) and Cr (0.3–0.9 wt%) enstatite contain symplectites of spinel and diopside, or spinel, diopside and lower-Al (0.8–2.2 wt%), Ca (0.1–0.4 wt%) and Cr (0.02–0.8 wt%) enstatite. From textures and mineral chemistries these symplectites are interpreted to have formed by mineral unmixing and migration from Al–Ca–Cr discrete enstatite to adjoining mineral interfaces.Garnet harzburgites are composed of large (0.5–1 cm) olivine, equally large discrete low-Al (0.6–1.1 wt%), Ca (0.1–0.5 wt%), and Cr (0.1–0.3 wt%) enstatite and smaller interstitial garnet, diopside, and high-Cr and low-Al spinel. Symplectites are composed of either spinel+diopside+garnet, or garnet+spinel. Spinel diopside garnet symplectites have cores of spinel+diopside, resembling symplectites inharzburgites, but surrounded by rims of garnet or garnet+undigested globular spinel. From textures and chemistries we suggest that the spinel+diopside cores formed from Ca-Al-Cr-rich orthopyroxene initially as a nonstoichiometric homogeneous single phase clinopyroxene enriched in Fe, Cr and Al. This was followed by decomposition of the clinopyroxene to diopside+spinel, and subsequent garnet formation in a prograde reaction with olivine or enstatite. In bothharzburgites andgarnet harzburgites the metastable cellular structures may also have formed by the simultaneous precipitation of pyroxene and spinel. In all cases there is a strongly preferred embayment of symplectite bodies into olivine. Olivine appears to have activated adjacent  相似文献   

11.
在麻粒岩相条件下，荣成含蓝晶石榴辉岩发生退变质，其中的绿辉石退变质成透辉石＋中长石组成的后成合晶，蓝晶石大部分被冠状体取代，基于详细探针分析结果的成分迁移估算显示，冠状体的形成需要从绿辉石的分解中获取CaO,MgO,FeO，绿辉石的分解包含两个反应：一个为绿辉石中的硬玉分子与石英结合形成钠长石；另一个发生在绿辉石内部各端员组分之间，后者不但形成后成合晶，而且为蓝晶石周围冠状体的形成提供CaO,MgO,FeO，蓝晶石的分解未能给后成合晶的形成提供SiO2，绿辉石与蓝晶石在分解时并冰形成一个封闭体系，它们均从周围环境中获取SiO2。  相似文献   

12.
Metabasites with eclogite facies relics occur in northern Sardinia as massive to strongly foliated lenses or boudins embedded within low- to medium-grade rocks (Anglona) and migmatites (NE Sardinia). U–Pb zircon dating yielded 453 ± 14, 457 ± 2 and 460 ± 5 Ma as the protolith ages; 400 ± 10 and 403 ± 4 Ma have been interpreted as the ages of the HP event and 352 ± 3 and 327 ± 7 Ma as the ages of the main Variscan retrograde events. A pre-eclogite stage is documented by the occurrence of tschermakite, zoisite relics within garnet porphyroblasts (Punta de li Tulchi) and an edenite–andesine inclusion within a relict kyanite porphyroblast (Golfo Aranci). Four main metamorphic stages have been distinguished in the eclogite evolution: (1) eclogite stage, revealed by the occurrence of armoured omphacite relics within garnet porphyroblasts. The Golfo Aranci eclogites also include kyanite, Mg-rich garnet and pargasite; (2) granulite stage, producing orthopyroxene and clinopyroxene–plagioclase symplectites replacing omphacite. At Golfo Aranci, the symplectitic rims around relict kyanite consist of sapphirine, anorthite, corundum and spinel; (3) amphibolite stage, leading to the formation of amphibole–plagioclase kelyphites between garnet porphyroblasts and pyroxene–plagioclase symplectites and to the growth of cummingtonite on orthopyroxene. Tschermakite to Mg-hornblende, plagioclase, cummingtonite, ilmenite, titanite and biotite are coexisting phases; (4) greenschist to sub-greenschist stage, defined by the appearance of actinolite, chlorite, epidote ss, titanite, sericite and prehnite. The following P–T ranges have been estimated for the different stages. Eclogite stage 550–700°C; 1.3–1.7 GPa; granulite stage 650–900°C; 0.8–1.2 GPa, clustering in the range 1.0–1.2 GPa; amphibolite stage 550–740°C; 0.3–0.7 GPa; greenschist stage 300–400°C; 0.2–0.3 GPa. Comparable ranges characterise the other Variscan massifs in Europe; eclogite stage: T = 530–800°C; P from 0.7–1.1 to 1.7 ± 0.3 GPa; granulite stage T = 760–870°C and P from 1.1–1.4 to 7.2–9.9 GPa, clustering around 1.0–1.2 GPa. Whole-rock chemistry: Sardinian eclogites are N- to T-MORB; European ones N- to E-MORB or calc-alkaline.  相似文献   

13.
Two spinel lherzolite xenoliths from Hungary that contain pyroxene–spinel symplectites have been studied using EPMA, Laser ablation ICP-MS and universal stage. Based on their geochemical and structural characteristics, the xenoliths represent two different domains of the shallow subcontinental lithospheric mantle beneath the Pannonian Basin. The occurrence of symplectites is attributed to the former presence and subsequent breakdown of garnets due to significant pressure decrease related to lithospheric thinning. This implies that both mantle domains were once part of the garnet lherzolitic upper mantle and had a similar history during the major extension that formed the Pannonian Basin.

Garnet breakdown resulted in distinct geochemical characteristics in the adjacent clinopyroxene crystals in both xenoliths. This is manifested by enrichment in HREE, Y, Zr and Hf towards the clinopyroxene porphyroclast rims and also in the neoblasts with respect to porphyroclast core compositions. This geochemical feature, together with the development and preservation of the texturally very sensitive symplectites, enables us to determine the relative timing of mantle processes. Our results indicate that garnets had been metastable in the spinel lherzolite environment and their breakdown to pyroxene and spinel is one of the latest processes that took place within the upper mantle before the xenoliths were brought to the surface.  相似文献   


14.
Chemical variations along with changes in microstructure ofthe principal constituent minerals make it possible to identifyat least four equilibrium stages in the evolution of the Yangkougarnet peridotite in the Su-Lu ultrahigh-pressure metamorphicbelt, eastern China: Stage I—a primary garnet lherzolitestage represented by coarse-grained (a few millimeters size)porphyroclastic aluminous pyroxenes + chromian spinel ±garnet; Stage II—an ultrahigh-pressure (UHP) stage definedby fine-grained matrix phases (0·1–0·3 mmsize) of garnet + extremely low-Al orthopyroxene + high-Na clinopyroxene+ chromite; Stage III—a medium-pressure stage definedby fine-grained mineral aggregates (<0·1–0·2mm size) mainly composed of aluminous spinel + high-Al orthopyroxenein the matrix; Stage IV—an amphibolite- to greenschist-faciesstage defined by poikiloblastic amphibole. Orthopyroxene–clinopyroxenethermometry and an empirical spinel barometer give temperaturesof around 800–830°C and pressures of 1·2–2·9GPa for porphyroclasts of Stage I. Garnet–orthopyroxene,garnet–clinopyroxene and empirical spinel geothermobarometersgive relatively uniform P–T conditions for the matrixgarnet–orthopyroxene–clinopyroxene–chromiteassemblage of Stage II (  相似文献   

15.
Garnet pyroxenite from high pressure granulite facies occurs with different mineral assemblages which involve garnet, clinopyroxene, orthopyroxene, plagioclase, amphibole and quartz with spinel developing as symplectite with orthopyroxene and plagioclase in large cracks. Three successive parageneses have been identified. The primary assemblage is characterised by the presence of quartz. The second assemblage involves orthopyroxene–plagioclase–hornblende symplectite, and the third assemblage is characterised by the development of spinel in symplectites with orthopyroxene and plagioclase. Using THERMOCALC (V2.7), a quantitative pseudosection in the system CaO–FeO–MgO–Al2O3–SiO2–H2O has been calculated. The assemblage involving quartz developed at high pressure, while the assemblage involving spinel developed at lower pressure. The peak of metamorphism in Tin Begane was calculated at 860 °C and 13.5 kb with aH2O=0.2. These conditions are followed by a decrease of pressure down to 4.8 kb.  相似文献   

16.
Summary Lenses and pods of mafic rocks from the Monotonous Unit near Svetlik are characterized by eclogite facies mineral assemblages; however some inclusion patterns (oriented quartz rods in clinopyroxene and cuboids of disordered graphite in garnet) that are usually known from ultra-high pressure rocks were also observed in one sample. Conventional thermobarometry yielded maximum P–T conditions of 2.0–2.5 GPa and 750 °C. Decompression and heating at amphibolite and granulite facies conditions resulted in the formation of at least five distinct types of symplectites. These include symplectitic intergrowth of ilmenite and clinopyroxene after titanite, described here for the first time from the Moldanubian Zone. In addition, symplectites of plagioclase and biotite with accessory amounts of spinel after tabular pseudomorphs (after phengite?) are also reported here. Mass balance relations indicate that symplectites of diopside + plagioclase after omphacite and plagioclase + spinel (sapphirine) after kyanite + garnet, formed by nearly isochemical reactions. All other symplectite-forming reactions were allochemical and were accelerated by the presence of fluid in the primary phases. Preserved zoning pattern in garnet with high compositional gradient in some samples suggests that the rocks were affected briefly by granulite facies overprint.  相似文献   

17.
Troctolitic gabbros from Valle Fértil and La Huerta Ranges, San Juan Province, NW‐Argentina exhibit multi‐layer corona textures between cumulus olivine and plagioclase. The corona mineral sequence, which varies in the total thickness from 0.5 to 1 mm, comprises either an anhydrous corona type I with olivine|orthopyroxene|clinopyroxene+spinel symplectite|plagioclase or a hydrous corona type II with olivine|orthopyroxene|amphibole|amphibole+spinel symplectite|plagioclase. The anhydrous corona type I formed by metamorphic replacement of primary olivine and plagioclase, in the absence of any fluid/melt phase at <840 °C. Diffusion controlled metamorphic solid‐state replacement is mainly governed by the chemical potential gradients at the interface of reactant olivine and plagioclase and orthopyroxene and plagioclase. Thus, the thermodynamic incompatibility of the reactant minerals at the gabbro–granulite transition and the phase equilibria of the coronitic assemblage during subsequent cooling were modelled using quantitative μMgO–μCaO phase diagrams. Mineral reaction textures of the anhydrous corona type I indicate an inward migration of orthopyroxene on the expense of olivine, while clinopyroxene+spinel symplectite grows outward to replace plagioclase. Mineral textures of the hydrous corona type II indicate the presence of an interstitial liquid trapped between cumulus olivine and plagioclase that reacts with olivine to produce a rim of peritectic orthopyroxene around olivine. Two amphibole types are distinguished: an inclusion free, brownish amphibole I is enriched in trace elements and REEs relative to green amphibole II. Amphibole I evolves from an intercumulus liquid between peritectic orthopyroxene and plagioclase. Discrete layers of green amphibole II occur as inclusion‐free rims and amphibole II+spinel symplectites. Mineral textures and geochemical patterns indicate a metamorphic origin for amphibole II, where orthopyroxene was replaced to form an inner inclusion‐free amphibole II layer, while clinopyroxene and plagioclase were replaced to form an outer amphibole+spinel symplectite layer, at <770 °C. Calculation of the possible net reactions by considering NCKFMASH components indicates that the layer bulk composition cannot be modelled as a ‘closed’ system although in all cases the gain and loss of elements within the multi‐layer coronas (except H2O, Na2O) is very small and the main uncertainties may arise from slight chemical zoning of the respective minerals. Local oxidizing conditions led to the formation of orthopyroxene+magnetite symplectite enveloping and/or replacing olivine. The sequence of corona reaction textures indicates a counter clockwise P–T path at the gabbro–granulite transition at 5–6.5 kbar and temperatures below 900 °C.  相似文献   

18.
The granulite complex at Anakapalle, which was metamorphosedat 1000 Ma, comprises orthopyroxene granulites, leptynite, khondalite,mafic granulites, calc-silicate rock, spinel granulites, andtwo types of sapphirine granulites—one quartz-bearingand migmatitic and the other devoid of quartz and massive. Reactiontextures in conjunction with mineral-chemical data suggest severalcontinuous and discontinuous equilibria in these rocks. In orthopyroxenegranulites, dehydration-melting of biotite in the presence ofquartz occurred according to the reaction biotite+quartz= garnet (Py37)+K-feldspar+orthopyroxene + liquid. Later, this garnet broke down by the reaction garnet (Py37)+quartz= orthopyroxene + plagioclase. Subsequently, coronal garnet (Py30) and quartz were producedby the same reaction but proceeding in the opposite direction.In spinel granulites, garnet (Py42) and sillimanite were producedby the breakdown of spinel in the presence of quartz. In thetwo types of sapphirine granulites, garnet with variable pyropecontent broke down according to the reaction garnet = sapphirine + sillimanite + orthopyroxene. The highest pyrope content (59 mol %) was noted in garnets fromquartz-free sapphirine granulites compared with the quartz-bearingone (53 mol % pyrope). The calculated positions of the mineralreactions and diserete P-T points obtained by thermobarometrydefine a retrograde P-T trajectory during which a steep decompressionof 1.5 kbar from P-Tmax of 8 kbar and 900C was followed bynear-isobaric cooling of 300C. During this decompression, garnetwith variable pyrope contents in different rocks broke downon intersection with various divariant equilibria. Near-isobariccooling resulted in the formation of coronal garnet around second-generationorthopyroxene and plagioclase replacing earlier porphyroblasticgarnet in orthopyroxene granulites. It has been argued thatthe deduced P-T trajectory originated in an extensional regimeinvolving either a crust of near-normal thickness of a slightlyoverthickened crust owing to magmatic underaccretion.  相似文献   

19.
A zoned kelyphite after garnet, from a garnet pyroxenite layer,the Ronda peridotite. Spain, has been studied and the mechanismof kelyphite formation is discussed. The kelyphite is an extremelyfinegrained symplectitic mixture of orthopyroxene, spinel, olivine,plagioclase, and ilmenite. It is concentrically zoned, formingthree mineralogical subzones. They are, from adjacent to a garnetgrain toward a clinopyroxene side, zone I (orthopyroxene+spinel+ plagioclase), zone II (olivine+spinel+plagioclase), and zoneIII (olivine+plagioclase). The analysis of phase equilibriashows that this mineralogical zonation can develop stably asa result of the presence of chemical potential gradients. Onthe basis of microprobe chemical analyses for each zone, materialtransfer across the zone that took place during the kelyphitizationwas quantitatively evaluated, and by locating the initial grainboundary between garnet and clinopyroxene grains and by writingmetasomatic reactions for each zone boundary, a simple dynamicmodel for the kelyphite formation is proposed. The kelyphiteformation probably took place when the host Ronda peridotiteascended from the upper mantle to the crust. It involved a co-operativebreakdown of the garnet and aluminous clinopyroxene, being accompaniedby a material transfer across the zone boundaries. By examiningthe Fe-Mg partitioning between olivine, spinel, and orthopyroxenein the kelyphite and by examining the Al content of the orthopyroxene,an attainment of local equilibrium has been confirmed, and thephysical conditions of the kelyphite formation have been estimatedto be 620–700C and 4–8 kbar.  相似文献   

20.
T. Ikeda  T. Nishiyama  S. Yamada  T. Yanagi 《Lithos》2007,97(3-4):289-306
Two types of reaction rims occur between olivine and plagioclase in ultramafic rocks from the Sefuri Mountains, NW Kyushu, Japan, which were metamorphosed under granulite-facies conditions. One occurs as a thin film of orthopyroxene along the boundary between olivine and plagioclase (orthopyroxene zone). The other is composed of two zones: symplectite of calcic amphibole and spinel on the plagioclase-side (symplectite zone) and calcic amphibole with sporadic orthopyroxene on the olivine-side (tremolite zone). In the tremolite zone, calcic amphibole shows a systematic decrease in Al content and increase in Mg/(Fe +Mg) with decreasing distance from olivine. Local equilibria maintained during the diffusion-controlled corona-forming reaction enable us to apply equilibrium thermodynamics to calcic amphibole and adjacent orthopyroxene. An integrated formulation of the Gibbs method for an Fe–Mg exchange reaction constrains the equilibrium temperature recorded in the tremolite zone to be 600–710 °C. It is significantly lower than the temperature of the granulite-facies metamorphism (800–900 °C) estimated using conventional geothermobarometry. Except for H2O, the association of calcic amphibole and spinel in the symplectite zone is chemically equivalent to the association of olivine, plagioclase and orthopyroxene that was stable before the corona formation. This suggests that the following orthopyroxene-consuming reaction describes the paragenetic change taking place between 800–900 °C and 600–710 °C, olivine + plagioclase + orthopyroxene + aqueous fluid = calcic amphibole + spinel. In contrast, the overall reaction inferred from microstructures produces orthopyroxene as well as calcic amphibole and spinel at the expense of olivine and plagioclase. This reaction requires removal mainly of MgO that is also responsible for destabilizing the local association of olivine and plagioclase. These features suggest that the presence of orthopyroxene as a product in the corona is not always indicative of an orthopyroxene-producing reaction being responsible for the change of paragenetic relation. Microstructural features should be carefully applied to infer the reaction describing paragenetic change by which we argue the P–T path of the rocks.  相似文献   

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