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1.
Millstone Hill ionospheric storm time measurements of the electron density and temperature during the ionospheric storms (15-16 June 1965; 29–30 September 1969 and 17–18 August 1970) are compared with model results. The model of the Earth’s ionosphere and plasmasphere includes interhemispheric coupling, the H+, O+(4S), O+(2D), O+(2P), NO+, O+2 and N+2 ions, electrons, photoelectrons, the electron and ion temperature, vibrationally excited N2 and the components of thermospheric wind.In order to model the electron temperature at the time of the 16 June 1965 negative storm, the heating rate of the electron gas by photoelectrons in the energy balance equation was multiplied by the factors 5–30 at he altitude above 700 km for the period 4.50-12.00 LT, 16 June 1965. The [O]/[N2] MSIS-86 decrease and vibrationally excited N2 effects are enough to account for the electron density depressions at Millstone Hill during the three storms. The factor of 2 (for 27–30 September 1969 magnetic storm) and the & actor 2.7 (for 16–18 August 1970 magnetic storm) reduction in the daytime peak density due to enhanced vibrationally excited N2 is brought about by the increase in the O++N2 rate factor.  相似文献   

2.
Ion composition measurements on board the ACTIVE satellite during the recovery phase of a strong geomagnetic storm of 10–12 April 1990 revealed extremely high concentrations (up to 103 cm−3) of the NO+, O+2, N+2 molecular ions in the topside F2-region of the European high-latitude zone. Concentrations of O+, N+, He+, H+ light ions were slightly decreased relative to prestorm quite conditions. Theoretical calculations were used to analyze the observed variations in ion concentration. Increased neutral temperature and [O2], [N2] are shown to be the main reasons for the observed ion concentration variations.  相似文献   

3.
It has been clearly established that there is a substantial outflow of ionospheric plasma from the Earth's ionosphere in both the northern and southern polar regions. The outflow consists of both light thermal ions (H+ and He+) and an array of energized ions (NO+, O2+, N2+, O+, N+, He+, and H+). If the outflow is driven by thermal pressure gradients in the ionosphere, the outflow is called the “classical” polar wind. On the other hand, if the outflow is driven by energization processes either in the auroral oval or at high altitudes in the polar cap, the outflow is called the “generalized” polar wind. In both cases, the field-aligned outflow occurs in conjunction with magnetospheric convection, which causes the plasma to drift into and out of the sunlit hemisphere, cusp, polar cap, nocturnal auroral oval, and main trough. Because the field-aligned and horizontal motion are both important, three-dimensional (3-D) time-dependent models of the ionosphere–polar wind system are needed to properly describe the flow. Also, as the plasma executes field-aligned and horizontal motion, charge exchange reactions of H+ and O+ with the background neutrals (H and O) act to produce low-energy neutrals that flow in all directions (the neutral polar wind). This review presents recent simulations of the “global” ionosphere–polar wind system, including the classical, generalized, and neutral polar winds. The emphasis is on displaying the 3-D and dynamical character of the polar wind.  相似文献   

4.
We present a comparison of the observed behavior of the F-region ionosphere over Millstone Hill during the geomagnetically quiet and storm periods of 6–12 April 1990 with numerical model calculations from the IZMIRAN time-dependent mathematical model of the Earths ionosphere and plasmasphere. The major enhancement to the IZMIRAN model developed in this study is the use of a new loss rate of O+(4S) ions as a result of new high-temperature flowing afterglow measurements of the rate coefficients K1 and K2 for the reactions of O+(4S) with N2 and O2. The deviations from the Boltzmann distribution for the first five vibrational levels of O2(v) were calculated, and the present study suggests that these deviations are not significant. It was found that the difference between the non-Boltzmann and Boltzmann distribution assumptions of O2(v) and the difference between ion and neutral temperature can lead to an increase of up to about 3% or a decrease of up to about 4% of the calculated NmF2 as a result of a respective increase or a decrease in K2. The IZMIRAN model reproduces major features of the data. We found that the inclusion of vibrationally excited N2(v > 0) and O2(v > 0) in the calculations improves the agreement between the calculated NmF2 and the data on 6, 9, and 10 April. However, both the daytime and nighttime densities are reproduced by the IZMIRAN model without the vibrationally excited nitrogen and oxygen on 8 and 11 April better than the IZMIRAN model with N2(v > 0) and O2(v > 0). This could be due to possible uncertainties in model neutral temperature and densities, EUV fluxes, rate coefficients, and the flow of ionization between the ionosphere and plasmasphere, and possible horizontal divergence of the flux of ionization above the station. Our calculations show that the increase in the O+ + N2 rate factor due to N2(v > 0) produces a 5–36% decrease in the calculated daytime peak density. The increase in the O+ + O2 loss rate due to vibrationally excited O2 produces 8–46% reductions in NmF2. The effects of vibrationally excited O2 and N2 on Ne and Te are most pronounced during the daytime.  相似文献   

5.
Plasma patches are regions of enhanced ionization that are created in the dayside cusp or equatorward of the cusp in the sunlit hemisphere during northward interplanetary magnetic field. After formation, and a change to a southward interplanetary magnetic field, they drift across the polar cap with the prevailing convection speed. As a plasma patch propagates, charge exchange reactions occur, which lead to the production of both ion and neutral particles throughout the patch. In the region directly above the patch, an upward jet of H+ and O+ forms. This ion jet, in turn, acts to produce an upward flux of neutral H and O stream particles because of charge exchange reactions between the ion jet and the background neutral atmosphere. A three-dimensional, time-dependent model of the ion and neutral polar winds was used in order to study the evolution of the neutral stream particles that are produced in a ‘representative’ propagating plasma patch, with the anticipation that the neutral stream particles produced by the ion jet would display a distinct signature. However, the outflow of neutral H atoms above a patch is only slightly visible in the simulation due to a continuous outflow flux of H (∼109 cm−2 s−1) across the entire polar cap. On the other hand, the upward flux of neutral O from the patch is more dependent on both the state of the ionosphere and the amount of heating, with increased upward fluxes over areas where the heating is high. Typically, the upward neutral O streams are predominantly located in the pre-midnight auroral oval.  相似文献   

6.
Measurements of F-region electron density and temperature at Millstone Hill are compared with results from the IZMIRAN time-dependent mathematical model of the Earths ionosphere and plasmasphere during the periods 16–23 March and 6–12 April 1990. Each of these two periods included geomagnetically quiet intervals followed by major storms. Satisfactory agreement between the model and the data is obtained during the quiet intervals, provided that the recombination rate of O+(4S) ions was decreased by a factor of 1.5 at all altitudes during the nighttime periods 17–18 March, 19–20 March, 6–8 April and 8–9 April in order to increase the NmF2 at night better to match observations. Good model/data agreement is also obtained during the storm periods when vibrationally excited N2 brings about factor-of-2-4 reductions in daytime NmF2. Model calculations are carried out using different expressions for the O+ – O collision frequency for momentum transfer, and the best agreement between the electron-density measurements and the model results is obtained when the CEDAR interim standard formula for the O+ – O collision frequency is used. Deviations from the Boltzmann distribution for the first five vibrational levels of NI were calculated. The calculated distribution is highly non-Boltzmann at vibrational levels j > 2, and the Boltzmann distribution assumption results in the increase of 10–30% in calculated NmF2 during the storm-time periods. During the March storm at solar maximum the model results obtained using the EUVAC solar flux model agree a little better with the observations in comparison with the EUV94 solar flux model. For the April storm period of moderate solar activity the EUV94X model results agree better with the observations in comparison to the EUVAC model.  相似文献   

7.
This study compares the Isis II satellite measurements of the electron density and temperature, the integral airglow intensity and volume emission rate at 630 nm in the SAR arc region, observed at dusk on 4 August, 1972, in the Southern Hemisphere, during the main phase of the geomagnetic storm. The model results were obtained using the time dependent one-dimensional mathematical model of the Earth’s ionosphere and plasmasphere (the IZMIRAN model). The major enhancement to the IZMIRAN model developed in this study to explain the two component 630 nm emission observed is the analytical yield spectrum approach to calculate the fluxes of precipitating electrons and the additional production rates of N+2, O+2, O+(4S), O+(2D), O−(2P), and O+(2P) ions, and O(1D) in the SAR arc regions in the Northern and Southern Hemispheres. In order to bring the measured and modelled electron temperatures into agreement, the additional heating electron rate of 1.05 eV cm−3 s−1 was added in the energy balance equation of electrons at altitudes above 5000 km during the main phase of the geomagnetic storm. This additional heating electron rate determines the thermally excited 630 nm emission observed. The IZMIRAN model calculates a 630 nm integral intensity above 350 km of 4.1 kR and a total 630 nm integral intensity of 8.1 kR, values which are slightly lower compared to the observed 4.7 kR and 10.6 kR. We conclude that the 630 nm emission observed can be explained considering both the soft energy electron excited component and the thermally excited component. It is found that the inclusion of N2(v > 0) and O2(v > 0) in the calculations of the O+(4S) loss rate improves the agreement between the calculated Ne and the data on 4 August, 1972. The N2(v > 0) and O2(v > 0) effects are enough to explain the electron density depression in the SAR arc F-region and above F2 peak altitude. Our calculations show that the increase in the O+ + N2 rate factor due to the vibrationally excited nitrogen produces the 5–19% reductions in the calculated quiet daytime peak density and the 16–24% decrease in NmF2 in the SAR arc region. The increase in the O+ + N2 loss rate due to vibrationally excited O2 produces the 7–26% decrease in the calculated quiet daytime peak density and the 12–26% decrease in NmF2 in the SAR arc region. We evaluated the role of the electron cooling rates by low-lying electronic excitation of O2(a1δg) and O2(b1σg+), and rotational excitation of O2, and found that the effect of these cooling rates on Te can be considered negligible during the quiet and geomagnetic storm period 3–4 August, 1972. The energy exchange between electron and ion gases, the cooling rate in collisions of O(3P) with thermal electrons with excitation of O(1D), and the electron cooling rates by vibrational excitation of O2 and N2 are the largest cooling rates above 200 km in the SAR arc region on 4 August, 1972. The enhanced IZMIRAN model calculates also number densities of N2(B3πg+), N2(C3πu), and N2(A3σu+) at several vibrational levels, O(1S), and the volume emission rate and integral intensity at 557.7 nm in the region between 120 and 1000 km. We found from the model that the integral integral intensity at 557.7 nm is much less than the integral intensity at 630 nm.  相似文献   

8.
The purpose of this research was to study the complexity of the energization of the ring current during a geomagnetic storm, produced during southern Bz(IMF) by the injection of plasma sheet ions, accelerated by enhanced convective electric fields. This model assumes that the plasma sheet is continuously populated by H+ from the sun and the ionosphere, and sporadically by ionospheric O+, making the ring current a coupled system whose energy can hardly be expressed analytically. When Bz(IMF) turns north, the ring current becomes uncoupled, and the energy decays exponentially if the storm is weak, or can be expressed as a combination of exponentials during strong storms representing the quick decay of O+ and the slower decay of H+, as has been shown.  相似文献   

9.
The Global Coupled Ionosphere–Thermosphere-Electrodynamics Model developed at Institute of Geology and Geophysics, Chinese Academy of Sciences (GCITEM-IGGCAS), is introduced in this paper. This new model self-consistently calculates the time-dependent three-dimensional (3-D) structures of the main thermospheric and ionospheric parameters in the height range from 90 to 600 km, including neutral number density of major species O2, N2, and O and minor species N(2D), N(4S), NO, He and Ar; ion number densities of O+ ,O2+, N2+, NO+, N+ and electron; neutral, electron and ion temperature; and neutral wind vectors. The mid- and low-latitude electric fields can also be self-consistently calculated. GCITEM-IGGCAS is a full 3-D code with 5° latitude by 7.5° longitude cells in a spherical geographical coordinate system, which bases on an altitude grid. We show two simulations in this paper: a March Equinox one and a June Solstice one, and compare their simulation results to MSIS00 and IRI2000 empirical model. GCITEM-IGGCAS can reproduce the main features of the thermosphere and ionosphere in both cases.  相似文献   

10.
We analyze the data obtained using the Arecibo incoherent scatter radar to examine the response of the topside ionosphere to a moderate geomagnetic storm that occurred during the period March 7–11, 2008. During this time period a magnetic storm with a non-monotonic main phase decrease in the Dst index occurred. The recovery phase also exhibited a secondary Dst decrease. During the initial phase of the storm, Te and Ti increased coincident with the arrival of the solar wind. The main phase registered an increase in proton concentration proportional to Ne while temperatures reached the lowest values. Variations in O+ concentration were not significant but a reduction in helium fraction was observed. Soon after the peak of the storm, the transition height between the topside ionosphere and the protonosphere, where H+ ions dominate composition, was lower than would be expected during quiet conditions and this behavior lasted for approximately 12 h.  相似文献   

11.
Geomagnetic activity dependence of O in transit from the ionosphere   总被引：1，自引：0，他引：1  
Energetic O+ ions have important dynamic effects on the ring current. Insights into the effects of O+ on ring current dynamics have come primarily from models, not observations. Here, we discuss observations of O+ populations escaping from the ionosphere and their access to the plasma sheet and ring current. We review data establishing that a significant flux of O+ escapes the ionosphere during geomagnetically quiet intervals. We then estimate the relative magnitude of the O+ population in transit between the ionosphere and ring current during quiet intervals before geomagnetic storms. Our analysis suggests that dynamic reconfigurations of the magnetosphere during geomagnetic storms significantly alter the O+ transport paths from the ionosphere to the ring current. During these reconfigurations some of the pre-existing, quiet time, in-transit O+ populations are captured on magnetic field lines leading to the ring current. The prompt appearance of this O+ population in the ring current could modify the evolution of the ring current in the storm growth phase. Our analysis suggests that the consequences of an activity-dependent O+ transport path to the ring current should be systematically investigated.  相似文献   

12.
This study compares the OV1-10 satellite measurements of the integral airglow intensities at 630 nm in the SAR arc regions observed in the northern and southern hemisphere as a conjugate phenomenon, with the model results obtained using the time-dependent one-dimensional mathematical model of the Earth ionosphere and plasmasphere (the IZMIRAN model) during the geomagnetic storm of the period 15–17 February 1967. The major enhancements to the IZMIRAN model developed in this study are the inclusion of He+ ions (three major ions: O+ H+ and He+ and three ion temperatures), the updated photochemistry and energy balance equations for ions and electrons, the diffusion of NO+ and O+2 ions and O(1D) and the revised electron cooling rates arising from their collisions with unexcited N2, O2 molecules and N2 molecules at the first vibrational level. The updated model includes the option to use the models of the Boltzmann or non-Boltzmann distributions of vibrationally excited molecular nitrogen. Deviations from the Boltzmann distribution for the first five vibrational levels of N2 were calculated. The calculated distribution is highly non-Boltzmann at vibrational levels v > 2 and leads to a decrease in the calculated electron density and integral intensity at 630 nm in the northern and southern hemispheres in comparison with the electron density and integral intensity calculated using the Boltzmann vibrational distribution of N2. It is found that the intensity at 630 nm is very sensitive to the oxygen number densities. Good agreement between the modeled and measured intensities is obtained provided that at all altitudes of the southern hemisphere a reduction of about factor 1.35 in MSIS-86 atomic oxygen densities is included in the IZMIRAN model with the non-Boltzm-ann vibrational distribution of N2. The effect of using of the O(1D) diffusion results in the decrease of 4–6% in the calculated integral intensity of the northern hemisphere and 7–13% in the calculated integral intensity of the southern hemisphere. It is found that the modeled intensities of the southern hemisphere are more sensitive to the assumed values of the rate coefficients of O+(4S) ions with vibrationally excited nitrogen molecules and quenching of O+(2D) by atomic oxygen than the modeled intensities of the northern hemisphere.  相似文献   

13.
A mathematical model of the middle and high latitude ionosphere   总被引：5，自引：0，他引：5  
  相似文献   

14.
The influence of atmospheric solar radiation absorption on the photodetachment, dissociative photodetachment, and photodissociation rate coefficients (photodestruction rate coefficients) of O?, Cl?, O2 ?, O3 ?, OH?, NO2 ?, NO3 ?, O4 ?, OH?(H2O), CO3 ?, CO4 ?, ONOO?, HCO3 ?, CO3 ?(H2O), NO3 ?(H2O), O2 +(H2O), O4 +, N4 +, NO+(H2O), NO+(H2O)2, H+(H2O) n for n = 2–4, NO+(N2), and NO+(CO2) at D-region altitudes of the ionosphere is studied. A numerical one-dimensional time-dependent neutral atmospheric composition model has been developed to estimate this influence. The model simulations are carried out for the geomagnetically quiet time period of 15 October 1998 at moderate solar activity over the Boulder ozonesonde. If the solar zenith angle is not more than 90° then the strongest influence of atmospheric solar radiation absorption on photodestruction of ions is found for photodissociation of CO4 ? ions when CO3 ? ions are formed. It follows from the calculations that decreases in the photodestruction rate coefficients of ions under consideration caused by this influence are less than 2 % at 70 km altitude and above this altitude if the solar zenith angle does not exceed 90°.  相似文献   

15.
This study compares the measurements of electron density and temperature and the integral airglow intensity at 630 nm in the SAR arc region and slightly south of this (obtained by the Isis 2 spacecraft during the 18 December 1971 magnetic storm), with the model results obtained using the time dependent one-dimensional mathematical model of the Earth’s ionosphere and plasmasphere. The explicit expression in the third Enskog approximation for the electron thermal conductivity coefficient in the multicomponent mixture of ionized gases and a simplified calculation method for this coefficient presents an opportunity to calculate more exactly the electron temperature and density and 630 nm emission within SAR arc region are used in the model. Collisions between N2 and hot thermal electrons in the SAR arc region produce vibrationally excited nitrogen molecules. It appears that the loss rate of O+(4S) due to reactions with the vibrationally excited nitrogen is enough to explain electron density depression by a factor of two at F-region heights and the topside ionosphere density variations within the SAR arc if the erosion of plasma within geomagnetic field tubes, during the main phase of the geomagnetic storm and subsequent filling of geomagnetic tubes during the recovery phase, are considered. To explain the disagreement by a factor 1.5 between the observed and modeled SAR arc electron densities an additional plasma drift velocity \sim-30 m s−1 in the ion continuity equations is needed during the recovery phase. This additional plasma drift velocity is likely caused by the transition from convecting to corotating flux tubes on the equatorward wall of the trough. The electron densities and temperatures and 630 nm integral intensity at the SAR arc and slightly south of this region as measured for the 18 December 1971 magnetic storm were correctly described by the model without perpendicular electric fields. Within this model framework the effect of the perpendicular electric field \sim100 mv m−1 with a duration \sim1 h on the SAR arc electron density profiles was found to be large. However, this effect is small if \sim1-2 h have passed after the electric field was set equal to zero.  相似文献   

16.
The polar wind is an ambipolar outflow of thermal plasma from the high-latitude ionosphere to the magnetosphere, and it primarily consists of H+, He+ and O+ ions and electrons. Statistical and episodic studies based primarily on ion composition observations on the ISIS-2, DE-1, Akebono and Polar satellites over the past four decades have confirmed the existence of the polar wind. These observations spanned the altitude range from 1000 to ∼50,500 km, and revealed several important features in the polar wind that are unexpected from “classical” polar wind theories. These include the day–night asymmetry in polar wind velocity, which is 1.5–2.0 times larger on the dayside; appreciable O+ flow at high altitudes, where the velocity at 5000–10,000 km is of 1–4 km/s; and significant electron temperature anisotropy in the sunlit polar wind, in which the upward-to-downward electron temperature ratio is 1.5–2. These features are attributable to a number of “non-classical” polar wind ion acceleration mechanisms resulting from strong ionospheric convection, enhanced electron and ion temperatures, and escaping atmospheric photoelectrons. The observed polar wind has an averaged ion temperature of ∼0.2–0.3 eV, and a rate of ion velocity increase with altitude that correlates strongly with electron temperature and is greatest at low altitudes (<4000 km for H+). The rate of velocity increase below 4000 km is larger at solar minimum than at solar maximum. Above 4000 km, the reverse is the case. This suggests that the dominant polar wind ion acceleration process may be different at low and high altitudes, respectively. At a given altitude, the polar wind velocity is highly variable, and is on average largest for H+ and smallest for O+. Near solar maximum, H+, He+, and O+ ions typically reach a velocity of 1 km/s near 2000, 3000, and 6000 km, respectively, and velocities of 12, 7, and 4 km/s, respectively, at 10,000 km altitude. Near solar minimum, the velocity of all three species is smaller at high altitudes. Observationally it is not always possible to unambiguously separate an energized “non-polar-wind” ion such as a low-energy “cleft ion fountain” ion that has convected into a polar wind flux tube from an energized “polar-wind” ion that is accelerated locally by “non-classical” polar-wind ion acceleration mechanisms. Significant questions remain on the relative contribution between the cleft ion fountain, auroral bulk upflow, and the topside polar-cap ionosphere to the O+ polar wind population at high altitudes, the effect of positive spacecraft charging on the lowest-energy component of the H+ polar wind population, and the relative importance of the various classical and non-classical ion acceleration mechanisms. These questions pose several challenges in future polar wind observations: These include measurement of the lowest-energy component in the presence of positive spacecraft potential, definitive determination and if possible active control of the spacecraft potential, definitive discrimination between polar wind and other inter-mixed thermal ion populations, measurement of the three-dimensional ion drift velocity vector and the parallel and perpendicular ion temperatures or the detailed three-dimensional velocity distribution function, and resolution of He+ and other minor ion species in the polar wind population.  相似文献   

17.
This study compares the observed behavior of the F region ionosphere over Millstone Hill with calculations from the IZMIRAN model for solar minimum for the geomagnetically quiet period 23–25 June 1986, when anomalously low values of hmF2(<200 km) were observed. We found that these low values of hmF2 (seen as a G condition on ionograms) exist in the ionosphere due to a decrease of production rates of oxygen ions resulting from low values of atomic oxygen density. Results show that determination of a G condition using incoherent scatter radar data is sensitive both to the true concentration of O+ relative to the molecular ions, and to the ion composition model assumed in the data reduction process. The increase in the O+ + N2 loss rate due to vibrationally excited N2 produces a reduction in NmF2 of typically 5–10%, but as large as 15%, bringing the model and data into better agreement. The effect of vibrationally excited NO+ ions on electron densities is negligible.  相似文献   

18.
Ion Chemistry of the Ionosphere at E- and F-Region Altitudes: A Review   总被引：2，自引：2，他引：0  
The current state of knowledge of E- and F-region ion chemistry is reviewed. Considerable attention is given to the progress in the chemistry of unexcited N2 +, O2 +, NO+, O+(4S), N+, H+, He+, Fe+, Mg+, Na+, Ca+, and K+ ions and electronically excited O+(2D), O+(2P), O+(4P), and $ {\text{O}}^{ + } (^{2} {\text{P}}^{*} ) $ ions. Achievements in our understanding of the role of vibrationally excited N2 +, O2 +, and NO+ ions in the ionosphere are discussed.  相似文献   

19.
It is now well known that there is a substantial outflow of ionospheric plasma from the terrestrial ionosphere at high latitudes. The outflow consists of light thermal ions (H+, He+) as well as both light and heavy energized ions (H+, He+, O+, N+, NO+, O2+, N2+). The thermal ion outflows tend to be associated with the classical polar wind, while the energized ions are probably associated with either auroral energization processes or nonclassical polar wind processes. Part of the problem with identifying the exact cause of a given outflow relates to the fact that the ionosphere continuously convects into and out of the various high-latitude regions (sunlight, cusp, polar cap, nocturnal oval) and the time-constant for outflow is comparable to the convection time. Therefore, it is difficult to separate and quantify the possible outflow mechanisms. Some of these mechanisms are as follows. In sunlit regions, the photoelectrons can heat the thermal electrons and the elevated electron temperature acts to increase the polar wind outflow rate. At high altitudes, the escaping photoelectrons can also accelerate the polar wind as they drag the thermal ions with them. In the cusp and auroral oval, the precipitating magnetospheric electrons can heat the thermal electrons in a manner similar to the photoelectrons. Also, energized ions, in the form of beams and conics, can be created in association with field-aligned auroral currents and potential structures. The cusp ion beams and conics that have been convected into the polar cap can destabilize the polar wind when they pass through it at high altitudes, thereby transferring energy to the thermal ions. Additional energization mechanisms in the polar cap include Joule heating, hot magnetospheric electrons and ions, electromagnetic wave turbulence, and centrifugal acceleration.Some of these causes of ionospheric outflow will be briefly reviewed, with the emphasis on the recent simulations of polar wind dynamics in convecting flux tubes of plasma.  相似文献   

20.
Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg0.975Fe0.015Mn0.006Ca0.004CO3) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K0 = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V0 = 279.55 ± 0.02 Å3. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂KT/∂T)P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a0 + a1T with a0 = 4.03 (7) × 10−5 K−1 and a1 = 0.49 (10) × 10−8 K−2. The Anderson–Grüneisen parameter is estimated to be δT = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (KTc = 47 ± 1 GPa) than the a-axis (KTc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a0 = 6.8 (2) × 10−5 K−1 and a1 = 2.2 (4) × 10−8 K−2) is greater than that of the a-axis (a0 = 2.7 (4) × 10−5 K−1 and a1 = −0.2 (2) × 10−8 K−2). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.  相似文献   

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