首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 156 毫秒
1.
The three isomers of C_2H_4O_2, viz., glycolaldehyde(HCOCH_2 OH), acetic acid(CH_3 COOH) and methyl formate(HCOOCH3), have been detected in copious amounts in the interstellar medium(ISM). The possibility for formation of these molecules through interstellar formaldehyde(HCHO) has been explored by using the quantum chemical approach described by density functional theory(DFT) and second order Moller-Plesset perturbation(MP2) theory with a 6–311 G(d,p) basis set in the gas phase as well as in icy grains. The associated molecule-molecule interactions have been discussed to study the formation of isomers of C_2H_4O_2 in ISM. The reactions of two formaldehyde molecules exhibit a considerable potential barrier but due to quantum tunneling, these reactions could be possible in ISM. The chemical pathway is exothermic, which gives rise to a high probability for the formation of all three isomers, viz. glycolaldehyde,methyl formate and acetic acid, in interstellar space. Anharmonic rotational vibration, centrifugal distortion constants and coupling constants are also calculated and results suggest that the vibrations are harmonic in nature.  相似文献   

2.
Astrochemical modeling is needed for understanding the formation and evolution of interstellar molecules,and for extracting physical information from spectroscopic observations of interstellar clouds.The modeling usually involves the handling of a chemical reaction network and solution of a set of coupled nonlinear ordinary differential equations,which is traditionally done using code written in compiled languages such as Fortran or C/C++.While being computationally efficient,there is room for improvement in the ease of use and interactivity for such an approach.In this work we present a new public code named CHEMPL,which emphasizes interactivity in a modern Python environment,while remaining computationally efficient.Common reaction mechanisms and a three-phase formulation of gasgrain chemistry are implemented by default.It is straightforward to run 0 D models with CHEMPL,and only a small amount of additional code is needed to construct 1 D or higher-dimensional chemical models.We demonstrate its usage with a few astrochemically relevant examples.  相似文献   

3.
Galactic winds and mass outflows are observed both in nearby starburst galaxies and in high-redshift star-forming galaxies. We develop a simple analytic model to understand the observed superwind phenomenon with a discussion of the model uncertainties. Our model is built upon the model of McKee & Ostriker for the interstellar medium. It allows one to predict how properties of a superwind, such as wind velocity and mass outflow rate, are related to properties of its starforming host galaxy, such as size, gas density and star formation rate. The model predicts a threshold of star formation rate density for the generation of observable galactic winds. Galaxies with more concentrated star formation activities produce superwinds with higher velocities. The predicted mass outflow rates are comparable to (or slightly larger than) the corresponding star formation rates. We apply our model to both local starburst galaxies and high-redshift Lyman break galaxies, and find its predictions to be in good agreement with current observations. Our model is simple and so can be easily incorporated into numerical simulations and semi-analytical models of galaxy formation.  相似文献   

4.
Interstellar graphene could be present in the interstellar medium(ISM), resulting from the photochemical processing of polycyclic aromatic hydrocarbon(PAH) molecules and/or collisional fragmentation of graphitic particles. Indeed, by comparing the observed ultraviolet(UV) extinction and infrared(IR) emission of the diffuse ISM with that predicted for graphene, as much as ～ 2% of total interstellar carbon could be locked up in graphene without violating the observational constraints. While the possible detection of planar C24, a small piece of a graphene sheet, has been reported towards several Galactic and extragalactic planetary nebulae, graphene has not yet been detected in interstellar environments. In this work, we search for the characteristic IR features of C24 at ～ 6.6, 9.8 and 20 μm toward Sgr B2, a high-mass star formation region, and find a candidate target toward R.A.(J2000) = 267.05855?and Decl.(J2000) =-28.01479?in Sgr B2 whose Spitzer/IRS spectra exhibit three bands peaking at ～ 6.637, 9.853 and 20.050 μm which appear to be coincident with those of C24. Possible features of C60 are also seen in this region. The candidate region is a warm dust environment heated by massive stars or star clusters, associated with a WISE spot(a tracer of star formation activity), close to the HII region candidate IRAS 17450–2759, and is surrounded by seven young stellar object candidates within ～ 5′, suggesting that the creation and/or excitation of C24 could be related to star formation activities.  相似文献   

5.
Injecting phase calibration (PCAL) signals to the feed horn of the observation sys- tem and analyzing the output response signals of the spectrometer, we measured the working performance of a 4096-channel digital autocalibration spectrometer. The results demonstrate that the spectrometer has a fine working performance: (1) the channels are distributed uni- formly in the spectrometer; (2) line drift produces little effect on the observation results; (3) spectral resolution shows little changes with observation time. The distribution of the fre- quency resolution in an 80 MHz bandwidth was measured. A trial observation on the two molecular spectral lines of H2CO and H110α taken with this spectrometer is described.  相似文献   

6.
We present a pilot HI survey of 17 Planck Galactic Cold Clumps(PGCCs)with the Five-hundred-meter Aperture Spherical radio Telescope(FAST).HI Narrow Self-Absorption(HINSA)is an effective method to detect cold HI being mixed with molecular hydrogen H2 and improves our understanding of the atomic to molecular transition in the interstellar medium.HINSA was found in 58%PGCCs that we observed.The column density of HINSA was found to have an intermediate correlation with that of 13CO,following log(N(HINSA))=(0.52±0.26)log(N13CO)+(10±4.1).HI abundance relative to total hydrogen[HI]/[H]has an average value of 4.4×10-3,which is about 2.8 times of the average value of previous HINSA surveys toward molecular clouds.For clouds with total column density NH>5×1020 cm-2,an inverse correlation between HINSA abundance and total hydrogen column density is found,confirming the depletion of cold HI gas during molecular gas formation in more massive clouds.Nonthermal line width of 13CO is about 0-0.5 kms-1 larger than that of HINSA.One possible explanation of narrower non-thermal width of HINSA is that HINSA region is smaller than that of 13CO.Based on an analytic model of H2 formation and H2 dissociation by cosmic ray,we found the cloud ages to be within 106.7-107.0 yr for five sources.  相似文献   

7.
Mars is the only extraterrestrial body which could host primitive lifeforms and also has the potential to host a human base in the near future. Towards fulfilling these objectives, several remote sensing missions and rover based missions have been sent to Mars. Still, confirmation of existing or extinct life on this planet in any form has not been achieved and possibly human missions at selected sites in the future are the key to addressing this problem. Here, we have used remote sensing data from Mars Reconnaissance Orbiter(MRO; NASA), Mars Global Surveyor(MGS; NASA), Mars Odyssey(NASA) and Mars Express(MEX; ESA) to devise an exploration strategy for one such area known as Hebrus Valles, which is a potential site for human exploration of the surface of Mars. A geological context map of the Hebrus Valles and Hephaestus Fossae region has been prepared and a candidate landing site has been proposed in the Hebrus Valles region. Suitable rover paths have been worked out from the proposed landing site for harnessing the science and resource potential of the region. The proposed landing site is located in the equatorial region at(20?40′N, 126?23′E) and due to its proximity to the Potential Subsurface Access Candidates(PSACs) in the region, such as sinkholes and skylights and also other resources such as crater ejecta, silicate material and fluvial channels, the site is appropriate for exploration of the region.  相似文献   

8.
We consider the BSBM(Bekenstein, Sandvik, Barrow and Magueijo) cosmological model in the presence of tachyon potential with the aim of studying the stability of the model and test it against observations. The phase space analysis shows that from fourteen critical points that represent the state of the universe, only one is stable.With a small perturbation, the universe transits from a state of unstable deceleration to stable acceleration. The stability analysis combined with the best fitting process imposes constraints on the cosmological parameters that are in agreement with observation. In the BSBM theory, the variation of fundamental constants is driven from variation of a scalar field. The tachyonic scalar field, responsible for both variation of fundamental constants and universal acceleration, is reconstructed.  相似文献   

9.
We investigate 25 H II regions that show bubble morphology in13CO(1–0)and infrared data,to search for quantitative evidence of triggered star formation by processes described by the collect and collapse(CC)and radiatively driven implosion(RDI)models.These H II regions display the morphology of a complete or partial bubble at 8μm,and are all associated with the molecular clouds that surround them.We found that the electron temperature ranges from 5627 K to 6839 K in these H II regions,and the average electron temperature is 6083 K.The age of these H II regions is from 3.0×105yr to 1.7×106yr,and the mean age is 7.7×105yr.Based on the morphology of the associated molecular clouds,we divide these H II regions into three groups,which may support CC and RDI models.We select 23 young IRAS sources which have an infrared luminosity of103L in 19 H II regions.In addition,we identify some young stellar objects(including Class I sources),which are only concentrated in H II regions G29.007+0.076,G44.339–0.827 and G47.028+0.232.The polycyclic aromatic hydrocarbon emissions of the three H II regions all show a cometary globule.Comparing the age of each H II region with the characteristic timescales for star formation,we suggest that the three H II regions can trigger clustered star formation by an RDI process.In addition,we detect seven molecular outflows in the five H II regions for the first time.These outflow sources may be triggered by the corresponding H II regions.  相似文献   

10.
Stars form through the gravitational collapse of molecular cloud cores.Before collapsing,the cores are supported by thermal pressure and turbulent motions.A question of critical importance for the understanding of star formation is how to observationally discern whether a core has already initiated gravitational collapse or is still in hydrostatic balance.The canonical method to identify gravitational collapse is based on the observed radial density profile,which would change from Bonnor-Ebert type toward power laws as the core collapses.In practice,due to the projection effect,the resolution limit and other caveats,it has been difficult to directly reveal the dynamical status of cores,particularly in massive star forming regions.We here propose a novel,straightforward diagnostic,namely,the collapsing index(CI),which can be modeled and calculated based on the radial profile of the line width of dense gas.A meaningful measurement of CI requires spatially and spectrally resolved images of optically thin and chemically stable dense gas tracers.ALMA observations are making such data sets increasingly available for massive star forming regions.Applying our method to one of the deepest dense-gas spectral images ever taken toward such a region,namely,the Orion molecular cloud,we detect the dynamical status of selected cores.We observationally distinguished a collapsing core in a massive star forming region from a hydrostatical one.Our approach would help significantly improve our understanding of the interaction between gravity and turbulence within molecular cloud cores in the process of star formation.  相似文献   

11.
Recently a new molecule, cyanomethamine, has been detected towards Sagittarius B2(N)(Sgr B2(N)). Studying the formation mechanisms of complex interstellar molecules is difficult. Hence,a theoretical quantum chemical approach for analyzing the reaction mechanism describing the formation of interstellar cyanomethamine through detected interstellar molecules and radicals(NCCN+H) is discussed in the present work. Calculations are performed by using quantum chemical techniques, such as Density Functional Theory(DFT) and M?ller-Plesset perturbation(MP2) theory with a 6-311G(d,p)basis set, both in the gas phase and in icy grains. The proposed reaction path(NCCN+H+H) has exothermicity with no barrier which indicates the possibility of cyanomethamine formation in the interstellar medium.  相似文献   

12.
This paper has been devoted to a basic molecular studies of polyatomics. A critical analysis of the 70 available references in literature has been made to select 37 polyatomic molecules, molecular ions, and radicals containing six, seven, eight, nine, ten, eleven, twelve, and thirteen atoms of astrophysical significance. The results have been arranged in a text-cum-tabular form. The compilation contains various information for each molecule, such as the spectral region, transition levels, astrophysical objects where the respective molecules have been detected (say, comet, meteorite, Sun, planet, star, interstellar matter, interstellar cloud, molecular cloud, interstellar space, Galaxy, etc.). Two-hundred fourteen new polyatomic molecules (containing 6, 7, 8, 9, and 10 atoms) of astrophysical significance have also been listed.Astrophysics and Space Science Review Paper II.  相似文献   

13.
This paper has been devoted to basic molecular studies of polyatomics. A critical analysis of the 356 available references in literature has been made to select 98 polyatomic molecules, molecular ions, and radicals containing three, four, and five atoms of astrophysical significance. The results have been arranged in a text-cum-tabular form. The compilation contains various information for each molecule, such as the spectral region, transition levels, astrophysical objects, where the respective molecules have been detected (say, comet, meteorite, Sun, planet, star, interstellar matter, interstellar cloud, molecular cloud, interstellar space, Galaxy, etc.).A few important areas of active research in laboratory astrophysics have also been identified in this article: laboratory astrophysics, molecular cloud chemistry, isotopic abundance, planetary and cometary atmospheres through satellites. Seventy-five new polyatomic molecules (containing three, four, and five atoms) of astrophysical significance have also been listed.Astrophysics and Space Science Review Paper I  相似文献   

14.
Increase in the statistical average molecular weight up to 1200–1300 in different fractions of glycerides from 250–300 starting value was determined by gel permeation chromatography for fractions kept in thin layer contact with lunar grains for two years at 25 °C. An additional shoulder maximum was present atM = 2000. This highest distribution fraction mean value indicates degrees of polymerization of 8, if the 250–300 non-aggregated fraction is a monoglyceride and the 800–810 fraction its trimer. Assuming that the 800–810 refers to a triglyceride, only aDP = 3 is characteristic of theM = 2000. Spectrographic analysis was used for further elucidation of the distribution data; and reaction mechanisms are discussed. The main conclusion is that the lunar grain surfaces have exerted a catalytic action for production of the high molecular weight species. Information of this kind is of profound importance in evaluations of formation i.e. synthesis of more complicated and especially CH-radicals containing molecules that have been spectroscopically identified in interplanetary and interstellar space and extensively discussed in recent literature. If heterogeneous nucleation and growth on catalytically active solid surfaces is found to be one feasible reaction mechanism for syntheses in space, the reaction yields will not necessarily depend on collision encounter reactions exclusively. Since the latter have low reaction cross sections even in resonating filaments of space molecular and ionic aggregates, the solid substrate anchored reactions might make an essential contribution to the final yield. This mechanism will undoubtedly act also as a selector system so far that it via lattice isomorfism, epitaxy, and via a set of discrete surface energies will favor synthesis of preferred molecular bonds and aggregates and by this way guide the molecular ‘evolution’ along selected paths only.  相似文献   

15.
银盘外区存在翘曲结构和近边增厚现象已是不争的观测事实.自20世纪50年代通过中性氢的射电观测发现此类结构以来,对不同示踪天体(包括各类星族1天体、分子云、星际尘埃、老年恒星等)的观测都确认了这一重要发现.关于翘曲结构已提出若干形成机制,但尚未达成共识.  相似文献   

16.
We analyze the influence of errors in the rate constants of gas-phase chemical reactions on the model abundances of molecules in the interstellar medium using the UMIST 95 chemical database. By randomly varying the rate constants within the limits of the errors given in UMIST 95, we have estimated the scatters in theoretical abundances for dark and diffuse molecular clouds. All of the species were divided into six groups by the scatter in their model equilibrium abundances when varying the rate constants of chemical reactions. The distribution of the species in groups depends on the physical conditions. The scatters in the abundances of simple species lie within 0.5–1 order of magnitude, but increase significantly as the number of atoms in the molecule increases. We suggest a simple method for identifying the reactions whose rate constants have the strongest effect on the abundance of a selected species. This method is based on an analysis of the correlations between the abundance of species and the reaction rate constants and allows the extent to which an improvement in the rate constant of a specific reaction reduces the uncertainty in the abundance of the species concerned to be directly estimated.  相似文献   

17.
Despite the low elemental abundance of atomic deuterium in the interstellar medium (ISM), observational evidence suggests that several species, both in the gas phase and in ices, could be heavily fractionated. We explore various aspects of deuterium enrichment by constructing a chemical evolution model in both gaseous and granular phases. Depending on various physical parameters, gases and grains are allowed to interact with each other through the exchange of their chemical species. It is known that HCO+ and N2H+ are two abundant gas phase ions in the ISM and, their deuterium fractionation is generally used to predict the degree of ionization in the various regions of a molecular cloud. For a more accurate estimation, we consider the density profile of a collapsing cloud. The radial distributions of important interstellar molecules, along with their deuterated isotopomers, are presented. Quantum chemical simulations are computed to study the effects of isotopic substitution on the spectral properties of these interstellar species. We calculate the vibrational (harmonic) frequencies of the most important deuterated species (neutral and ions). The rotational and distortional constants of these molecules are also computed in order to predict the rotational transitions of these species. We compare vibrational (harmonic) and rotational transitions as computed by us with existing experimental and theoretical results. It is hope that our results will assist observers in detecting several hitherto unobserved deuterated species.  相似文献   

18.
We carry out a quantum chemical calculation to obtain the infrared and electronic absorption spectra of several complex molecules of the interstellar medium (ISM). These molecules are the precursors of adenine, glycine & alanine. They could be produced in the gas phase as well as in the ice phase. We carried out a hydro-chemical simulation to predict the abundances of these species in the gas as well as in the ice phase. Gas and grains are assumed to be interacting through the accretion of various species from the gas phase onto the grain surface and desorption (thermal evaporation and photo-evaporation) from the grain surface to the gas phase. Depending on the physical properties of the cloud, the calculated abundances varies. The influence of ice on vibrational frequencies of different pre-biotic molecules was obtained using Polarizable Continuum Model (PCM) model with the integral equation formalism variant (IEFPCM) as default SCRF method with a dielectric constant of 78.5. Time dependent density functional theory (TDDFT) is used to study the electronic absorption spectrum of complex molecules which are biologically important such as, formamide and precursors of adenine, alanine and glycine. We notice a significant difference between the spectra of the gas and ice phase (water ice). The ice could be mixed instead of simple water ice. We have varied the ice composition to find out the effects of solvent on the spectrum. We expect that our study could set the guidelines for observing the precursor of some bio-molecules in the interstellar space.  相似文献   

19.
The use of interstellar molecules as probes of physical conditions in interstellar clouds is hampered by the lack of basic laboratory data. The excitation of interstellar molecules is poorly understood because the nature of the interaction of molecules with radiation and with neutral particles is largely undknown. The mechanisms of formation and destruction of interstellar molecules are presently speculative, because little data exists in such areas as gas-phase ion-molecule reactions and exchange reactions, and reactions of various types on surfaces. Specific needs with regard to laboratory data are discussed in these and other areas. Operated by Associated Universities, Inc., under contract with the National Science Foundation.  相似文献   

20.
The temperature of graphite grains in the interstellar medium has been computed with different assumptions on the extrapolation of its optical constants into infrared. It is found that values computed up to now are generally underestimated by 10–20% in normal interstellar conditions. For extreme conditions (very dark clouds) errors by a factor of two are possible and more attention has to be paid in dealing with problems related to molecule formation.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号