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1.
Xiamen Western Bay‘s water and sedimem quality were studied by detemaining thelevels of sixteen polycyclic amrrmtic hydrocarbons PAHs in water, porewater and sediment samples from nine locations in the bay. Total PAH concentrations varied from 106 to 945 ng/1 in water, below detectionto 3548 ng/1 in porewater, and 247 to 480 ng/g dry weight in surface sediments. PAHs levels in porewaterwere higher than those in surface water, due to the preference of these hydrophobic compounds for sedimentary phase instead of water. Such a concentration gradient implies a potential flux of pollutants fromsediments to overlying water. The PAils levels in sediments were one to several orders of magnitude lowerthan those in 1993, suggesting their decreased input in recent years and possible degradation with time.  相似文献   

2.
ＩＮＴＲＯＤＵＣＴＩＯＮＰｏｌｙｃｙｃｌｉｃＡｒｏｍａｔｉｃＨｙｄｒｏｃａｒｂｏｎｓ(ＰＡＨｓ)ｗｉｄｅｌｙｅｘｉｓｔｉｎｔｈｅｅｎｖｉｒｏｎｍｅｎｔ(ａｔｍｏｓｐｈｅｒｅ,ｗａｔｅｒｃｏｌｕｍｎ,ｓｏｉｌ,ｒｉｖｅｒ,ｌａｃｕｓｔｒｉｎｅａｎｄｍａｒｉｎｅｓｅｄｉｍｅｎｔｓ)ａｎｄａｒｅｐｒｅｓｅｎｔａｔｔｒａｃｅｍｉｘｔｕｒｅｓａｎｄｗｉｄｅｌｙｓｐｒｅａｄｆｒｏｍｓｅｖｅｒａｌ×10-9ｇｒａｄｅｓｉｎｒｅｍｏｔｅａｒｅａｓｔｏｓｅｖｅｒａｌ×10-6ｌｅｖｅｌｓｉｎｕｒｂａｎａｎｄｉｎｄｕｓｔｒｉａｌａ…  相似文献   

3.
The aquatic ecosystem maybe significantly affected by polycyclic aromatic hydrocarbons(PAHs) released from fresh water sediments. In order to protect biodiversity, the spatial distribution and sources of PAHs in the sediment of Wolong Lake in Northeast China were studied. A total of 17 surface sediment samples were collected and 12 PAHs were analyzed. The results were as follows. The concentration of total PAHs(TPAHs) ranged between 1412.9 μg/kg and 3948.3 μg/kg(dry weight). Indeno [1, 2, 3-c, d] pyrene was the dominant contaminant which accounted for 87%–98% of TPAHs. Diagnostic ratios of PAHs and principal component analysis showed that biomass combustion and vehicle emissions were likely to be the dominant sources of PAHs in the sediment. PAHs can be considered safe in the context of environmental and human health protection, based on the overall toxicity. Individual PAHs were positively correlated with total organic carbons. These results will be helpful to control PAHs and protect the aquatic ecosystem in the lake.  相似文献   

4.
1INTRODUCTIONPolycyclicaromatichydrocarbons (PAHs)depo sit edinmarineenvironmentsfromavarietyofsourcessuchaswastewater,industrialanddomesticdischarges,andoilspills.Themajorityofthesesourcesfrompetrogenicoriginischaracterizedbyadominanceoflowmolecularweightaromaticcompounds,especiallynaphthaleneandalkylatedPAHs(Sportoletal.,1 983 ) .Crudeoilanditsrefinedproductssuchasgasoline,keroseneandotherfu eloilshaveahighcontentofalkylatedPAHsduetotheirslowformationattemperatureslowerthanthatofcomb…  相似文献   

5.
选择美国环境保护署EPA优控污染物NaP（萘）、Phe（菲）、Fla（荧蒽）、BaA（苯并蒽）、Chr（屈）、Pyr（芘）和BaP（苯并芘）7种多环芳烃（polycyclic aromatic hydrocarbons,简称PAHs）作为研究对象,采用Level Ⅲ逸度模型对神农架大九湖地区PAHs多介质归趋进行了模拟,并利用神龙架大九湖大气、土壤、水体和沉积物中PAHs的实际监测数据对模型进行了验证;同时,将气候因素（温度、降水）对环境介质中PAHs转化的影响整合进模型中,探讨了气候变化对PAHs归趋的影响。结果表明:模型计算值与研究区PAHs监测值吻合良好,说明模型参数的选取合理可靠;不同PAHs的相间迁移通量具有一定差异,2环和3环PAHs则以沉积物向水体、水体向大气迁移为主,表现出由沉积物向水体和大气释放的特点,而4环和5环PAHs以大气向土壤和水体向沉积物迁移为主,体现出由大气向土壤和沉积物沉降的特点;温度与水-气、土-气和水-沉积物界面交换净通量存在明显的正相关关系,降水量与水-气、土-气界面交换净通量呈负相关关系,但与水-沉积物界面交换净通量呈正相关关系。本研究结果表明应重视因气候变化而引起的土壤、水体、沉积物的内源释放所造成的二次污染。   相似文献   

6.
黄土作为典型的多物源沉积物，粒度分布常呈现多峰分布。端元分析可以从复杂的沉积物粒度中分离出代表不同沉积物源和沉积动力的端元组分，在黄土研究中得到了广泛应用。利用Paterson参数化端元模型对处于毛乌素沙漠东南缘的靖边三道沟剖面粒度进行端元分离与解释，并讨论其代表的环境意义。靖边三道沟黄土可分为4个端元:EM1（众数粒径8.93 μm）为背景粉尘；EM2（众数粒径25.18 μm）为与季风环流有关的组分；EM3（众数粒径39.91 μm）和EM4（众数粒径56.37 μm）都是与冬季风有关的组分，其中EM3为黄土高原黄土主要组分，EM4与现代沙尘暴的粒级大致相同。通过对各端元组分随年龄变化的曲线进行分析，得到以下结论:该剖面记录了靖边地区自MIS 3以来经历了MIS 3（32.8~29.8 ka BP）、LGM（29.8~22.8 ka BP）、冰消期（22.8~11.3 ka BP）和全新世（8.7~1.7 ka BP）共4个气候时期。端元组分还记录了冰消期H 1事件（16.2~13.8 ka BP）、B/A事件（13.8~12.8 ka BP）、YD事件（12.8~11.3 ka BP）共3次气候快速变化事件和D-O旋回。该剖面还记录了毛乌素沙漠末次冰期经历的3次主要的扩张-收缩旋回以及全新世8.7~8.2，6.0~5.0，3.5~2.5 ka共3次干旱沙进事件。   相似文献   

7.
The environmental quality status of Daya Bay (22.56–22.77°N, 114.51–114.73°E), a main aquaculture area in Guangdong of China, was investigated using 16 polycyclic aromatic hydrocarbon (PAH) sediment samples of the bay. The total concentrations of 16 PAHs varied from 115 to 1 134 ng/g dry weight. The PAH composition pattern in sediments suggest dominance of 4-ring PAHs in Sites 2 and 4, and the ratio of certain related PAHs indicated important pyrolytic and petrogenic sources. The results enhance the understanding of current contamination levels and make a better assessment of likely impacts of organic contamination on ecosystems and the sustainability of local aquaculture in the area especially after the establishment of the Nuclear Power Station by the bay.  相似文献   

8.
THE VERTICAL DISTRIBUTIONS AND SOURCES OF PAHs IN SEDIMENT OF XIAMEN BAY   总被引：2，自引：0，他引：2  
INTRODUCTIONTheindustrialdevelopmentandrisingpopulationintheXiamencoastalzonearelikelytoresultinincreasingpollutantsloadingwhichcanaffecttheoceanicecosystemsenvironmentthereandthreatenhumanhealth .PAHs ,asgoodenvironmentpollutionindicators(Aizenshat,1 973 ;Randahl,1 983 ) ,arerela tivelystableinairandwater,andarewidelydistributedintheaquaticenvironmentasaresultofhumanactivities.ProposedprimarysourcesofPAHsincludecombustionofvariousfossilfuels,nat uralfires,roadrunoff streetdustaswellas…  相似文献   

9.
滨海平原弱透水层广布且多赋存古咸水，其盐度分布及运移过程深刻影响着含水层地下水的演变，却得到甚少关注。采集了江苏滨海区7个浅层钻孔弱透水层原状样品，压榨法收集孔隙水。利用孔隙水天然示踪剂ρ（Cl-），ρ（Br-）剖面和数值模拟分析了弱透水层孔隙水盐度特征和运移机制。得出浅层孔隙水ρ（Cl-）垂向剖面存在2个趋势:①峰值在表层，沿深度逐渐下降；②峰值在深度25m左右，向两端浓度降低。孔隙水ρ（Cl-）为486.2~38 036.7 mg/L，Cl/Br比值为72~360（均值241）。ρ（Cl-）与Cl/Br比值关系及剖面分布说明孔隙咸水为海相成因，来自于全新世海侵时期的古海水，并受到后期淡水的稀释。弱透水层孔隙水一维垂向运移数值模型表明海侵-海退事件控制了海岸带弱透水层孔隙水的盐度演变，全新世古海水仍封存在沉积物中，更新世时期的海水已被驱替。孔隙水运移以扩散为主，垂向运移速率为0.43~15.8 mm/Ma。在相对高渗透性的粉砂地层中，可能还受到侧向对流的影响。弱透水层中古海咸水的重新分布，尤其在地下水超采条件下，可能成为地下水的重要咸化来源。   相似文献   

10.
The Holocene environmental evolution in coastal area, including deltas and estuaries, is vital to the Neolithic colonization in the eastern China. A 29-m long sediment core XL was obtained from the region between the Taihu Lake and Qiantang Estuary, and multiple analyses on the core sediments have been done to investigate the evolution history of the inner coastal zone of Hangzhou Bay during the Holocene. Six sedimentary facies are identified since the late Pleistocene, including the paleosol at the bottom, overlain by tidal-flat-channel complex(TFC), tidal-distributary-channel(TDC), inner estuarine basin(IEB), subtidal-to-intertidal-flat, and fluvial-plain facies. The TFC and TDC facies are dated to be formed before 8500 cal yr BP, featured by relatively coarse sediments, high magnetic properties and less abundant foraminifera, denoting the tide-influenced setting with large terrestrial inputs. The IEB facies characterized by the most abundant foraminifera fossils and the lowest sediment magnetic properties, is inferred to be deposited during the maximum flooding period between 8500 and 7900 cal yr BP. The branch estuary was then infilled by local sediments with a shallowing-upward subtidal-to-intertidal sequence during 7900–4300 cal yr BP. At last the fluvial plain system developed since no later than 4300 cal yr BP, favouring the rapid development of Neolithic cultures in the region.  相似文献   

11.
Accumulation and distributions of aliphatic and polyaromatic hydrocarbons (PAHs) and heavy metals were measured in tissues of the clam Ruditapes philippinarum collected from 5 sites in Jiaozhou Bay, Qingdao, China. The concentrations of total aliphatic hydrocarbon and PAHs ranged from 570 to 2 574 ng/gdw (gram dry weight) and from 276 to 939 ng/gdw, in the most and least polluted sites, respectively. The bio-accumulation of hydrocarbons and PAHs in the clams appeared to be selective. Aliphatic hydrocarbons were predominantly represented by short chain (<nC23) n-alkanes, suggesting that petroleum hydrocarbons were likely the major contamination source. The selective uptake of 3 and 4 ring PAHs, such as naphthalene, fluorene, phenanthrene, fluoranthene and pyrene, by the clams was probably related to the physiological and bio-kinetic processes that were energetically favorable for uptake of compounds with fewer rings. Accumulation of the metals Cd, Cu, Zn, Pb, Cr, Hg, and As in the clam tissues also showed high variability, ranging from 0.043 to 87 μg/gdw. Among the 7 detected metals, Zn, Cd, Cu, and As had a particularly high potential of accumulation in R. philippinarum. In general, a positive correlation was found between the tissue concentrations and sediment concentrations of hydrocarbons and of some metals. Our study suggests that moderate contamination with polyaromatic hydrocarbons, and low to moderate contamination with metals, currently exists for clam R. philippinarum in Jiaozhou Bay, in comparison with other regional studies. A long-term monitoring program is certainly needed for assessment of the potential ecological influence and toxicity of these contaminants of R. philippinarum in Jiaozhou Bay.  相似文献   

12.
To reconstruct the productivity changes for the last 10 500 a in the northeastern East China Sea (ECS), biogenic compounds (such as carbonate, organic carbon and opal), marine micropaleontological fossils (planktonic foraminifera, benthic foraminifera, radiolarian and silicoflagellate) and the compositional characters of benthic foraminifera fauna analyses were carried out on a sediment core DOC082 obtained from the western slope of Okinawa Trough (29°13.93′N, 128°08.53′E; 1 128 m water depth). The long-term changes of biogenic and micropaleontological proxies display some similarities through the last 10 500 a, which show three different phases: lower values are recorded during the early and middle Holocene (before about 4 000 a BP), followed by an abrupt and remarkable increase at about 4 000 a BP, the late Holocene (after about 3 000 a BP) is characterized by continuously high values. The multi-proxy data of paleoproductivity and percents of benthic foraminifera genera (Uvigerina and Bulimina) show that during the early and middle Holocene (10 500–4 000 a BP) productivity was relatively low with a sudden and distinct increase at about 4 000 a BP, and the late Holocene (3 400–0 a BP) is marked by significantly higher productivity. Also, the radiolarian-based sea surface temperature (SST) records reveal a distinct decline in SST in the late Holocene after 3 200 a BP, very different from the early and middle Holocene. For the last 3 000 a, the enhanced biological productivity and distinctly lower SST indicate a major change of oceanographic conditions in the northeastern ECS. These marine environmental anomalies are consistent with other paleoclimatic records for the late Holocene in the Chinese continent and its surrounding regions. After analyzing the mechanisms of modern productivity and SST changes in the northeastern ECS, and based on the climatic anomalies in the Chinese continent and variations in the Kuroshio Current during modern El Niño periods, we suggest that the anomalous environmental conditions in the northeastern ECS may imply intensified El Niño activity during the late Holocene.  相似文献   

13.
Assemblages of benthic foraminifera in a sediment core (C02) near the western margin of the southern Yellow Sea Mud were studied to decipher the phase evolution of Holocene paleoenvironmental changes associated with the Holocene marine transgression. It appears that during the early Holocene (11.2–10.1 kyr BP), the faunal was dominated by low salinity and shallow water species Cribrononion subincertum, Buccella frigida and Ammonia beccarii, reflecting a near coast depositional environment. A rapid increase of the relative abundance of Ammonia compressiuscula between 10.1–9.3 kyr BP indicates that the sea level rose rapidly during that time period. From 9.3–7.7 kyr BP, the benthic foraminiferal assemblage was dominated by high percentage of A. compressiscula, suggesting that the sea level was relatively stable. An obvious transition of benthic foraminifera, from the A. compressiuscula-dominated assemblage to an Ammonia ketienziensis-dominated assemblage, occurred between 7.7–6.2 kyr BP, possibly corresponding to a second sea level rapid rise period in the Yellow Sea during the Holocene. This transition may correspond to the gradually strengthened Yellow Sea warm current (YSWC) and finally is established the modern-type circulation in the Yellow Sea. It may also mark the formation of the Yellow Sea cold bottom water (YSCBW) during that period. Since then, the benthic foraminiferal assemblage based on core C02 was dominated by typical YSCBW species, A. ketienziensis, Astrononion italicum and Hanzawaia nipponica, at 6.2–4 kyr BP. A non-deposition period occurred since ～4 kyr BP, which possibly related to the hydrology changes caused by the East Asia monsoon. The two obvious benthic foraminiferal transitions recorded in core C02 during the early and middle Holocene provide evidence that the Yellow Sea has undergone a two-phase rapid sea level rise during the Holocene marine transgression.  相似文献   

14.
Ten stenols and stanols were identified by TLC , GC and GC-MS-DS in a marine sediment core from Beibu Bay , the South China Sea .C27, C28 and C29 A5 stenols and 5a- stanols mainly come from zoopiankton, algae and phytoplankton in marine environment. C29 24-ethylcholest- 5 - en- 3B- ol is thought to indicate input of terrigenous organic matter . The increase of C27 . C28 and C29 5a-stanol /5 stenol ratios with sediment depth shows the evolution of stenols and stanols in the marine sediment core .  相似文献   

15.
Peat in boreholes is the most important ~(14)C dating material used for constructing age framework. 20 bulk peat samples were collected from five boreholes, the ~(14)C ages of two fractions(organic sediment fraction and peat fraction) of the bulk peat samples were investigated by AMS-dating and which fraction is better to help construct an age framework for the boreholes were compared and discussed. The results indicated that the peat fraction give a good dating results sequence in the boreholes, compared with the corresponding organic sediment fraction. And the dating results of organic sediment fraction show 161-6 702 years older than corresponding peat fraction, which was caused by marine influence. Then, we suggest an experience formula as y =0.99 x-466.5 by the correlation analysis for correcting the marine influenced organic sediment ages within the conventional ages between 4 000 to 9 000 yrs BP, and more study should be carried out for the AMS ~(14)C dating of the bulk organic sediments.  相似文献   

16.
The wet canopy evaporation rate (Er) was calculated by Penman-Monteith combination model based on three assumptions and with meteorological variables 2 m above the canopy in three stands, dominated by spruce (SF), fir (FF) and birch (BF) trees, respectively, in the subalpine forests in western Sichuan, China over a growing season. The total amount of the E was 44.5 mm for SF, 88.5 mm for FF and 57.8 mm for BF, accounting for 9.2%, 16.6% and 10.2% of the gross rainfall, respectively, in the measuring period. There was the highest average monthly Er and percentage of E to gross rainfall for FF compared with SF and BF.Mean Er was 0.097 mm h^-1 (ranging from 0.028 to0.487 mm h^-1), 0.242 mm h^-1 (from 0.068 to 0.711 mm h^-1) and 0.149 mm h^-1 (from 0.060 to 0.576 mm h^-1) for SF, FF and BF, respectively. The highest average monthly Er occurred in June was 0.120 mm h^-1 for SF, 0.317 mm h^-1for FF and 0.169 mm h^-1 for BF, and the lowest value in October was 0.083 mm h^-1 for SF, 0.187 mm h^-1 for FF and 0.101 mm h^-1 for BF, respectively. The averages of Er from 8:00 to16:00 were significantly higher than those from 0:00 to 8:00 and from 16:00 to 0:00 for the three stands. The marked daily and monthly differences of Er were contributable to the variations of solar radiation, air temperature and relative humidity above the canopy.  相似文献   

17.
The relationship between the East Asian winter monsoon (EAWM) and East Asian summer monsoon (EASM) during the Holocene is complicated and remains controversial. In this study, analysis of grain size and benthic foraminiferal oxygen isotope, as well as accelerator mass spectrometry 14C dating was performed on a sediment core retrieved from the newly revealed muddy deposit on the northern South China Sea continental shelf. The history of the EAWM and EASM were reconstructed for the last 8200 a BP. Further analysis in conjunction with previously published paleo-climate proxies revealed that the relationship between the EAWM and EASM during the Holocene is more complex than a simple and strict anti-phase one-both negative and positive correlations were identified. The EAWM and EASM are negatively correlated around 7500, 4800, 4200, 3200, and 300 a BP (cooling periods), while positively correlated around 7100, 3700, and 2100 a BP (warm periods). In particular, both the EAWM and EASM intensified during the three positive correlation periods. However, we also found that the relationship between these two sub-monsoons is anti-phase during the final phase of particularly hot periods like Holocene Optimum and Medieval warm period. The possible impact from variations of solar irradiance on the relationship between the EAWM and EASM was also discussed.  相似文献   

18.
Based on the stratigraphic sequence formed since the last glaciation and revealed by 3000 km long high-resolution shallow seismic profiles and the core QDZ03 acquired recently off the southern Shandong Peninsula, we addressed the sedimentary characteristics of a Holocene subaqueous clinoform in this paper. Integrated analyses were made on the core QDZ03, including sedimentary facies, sediment grain sizes, clay minerals, geochemistry, micro paleontology, and AMS 14 C dating. The result indicates that there exists a Holocene subaqueous clinoform, whose bottom boundary generally lies at 15–40 m below the present sea level with its depth contours roughly parallel to the coast and getting deeper seawards. The maximum thickness of the clinoform is up to 22.5 m on the coast side, and the thickness contours generally spread in a banded way along the coastline and becomes thinner towards the sea. At the mouths of some bays along the coast, the clinoform stretches in the shape of a fan and its thickness is evidently larger than that of the surrounding sediments. This clinoform came into being in the early Holocene(about 11.2 cal kyr BP) and can be divided into the lower and upper depositional units(DU 2 and DU 1, respectively). The unit DU 2, being usually less than 3 m in thickness and formed under a low sedimentation rate, is located between the bottom boundary and the Holocene maximum flooding surface(MFS), and represents the sediment of a post-glacial transgressive systems tract; whereas the unit DU 1, the main body of the clinoform, sits on the MFS, belonging to the sediment of a highstand systems tract from middle Holocene(about 7–6 cal kyr BP) to the present. The provenance of the clinoform differs from that of the typical sediments of the Yellow River and can be considered as the results of the joint contribution from both the Yellow River and the proximal coastal sediments of the Shandong Peninsula, as evidenced by the sediment geochemistry of the core. As is controlled mainly by coactions of multiple factors such as the Holocene sea-level changes, sediment supplies and coastal dynamic conditions, the development of the clinoform is genetically related with the synchronous clinoform or subaqueous deltas around the northeastern Shandong Peninsula and in the northern South Yellow Sea in the spatial distribution and sediment provenance, as previously reported, with all of them being formed from the initial stage of the Holocene up to the present.  相似文献   

19.
Study on the carbonate content and oxygen isotope of a sediment section in Dabusu Lake revealed that this region has experienced several cold-wet and warm-dry climatic cycles since 15400 a BP. It was about 6740 a BP when the climate in the region reached a relatively stable warm stage, so that the lake water was gradually condensed and finally a saline lake was formed.  相似文献   

20.
海南岛是我国主要的热带农作物种植基地,对海南岛种植园土壤污染物评估具有重要意义。对海南岛北部种植园土壤中的16种多环芳烃（PAHs）质量分数、来源及生态风险进行评估。使用气相色谱-质谱联用技术对咖啡、香蕉、山药、甘蔗、橙子、百香果和石榴种植园中100件表层土壤样品进行PAHs质量分数测定。结果表明,研究区种植园土壤平均∑16PAHs为37.6 ng/g,低于我国土壤背景值和荷兰无污染土壤限值（< 200 ng/g）。三环、四环和五环PAHs为主要组成成分,分别占据∑16PAHs质量分数的25.8%,26.8%和23.5%。源识别显示,种植园内PAHs主要来自机动车尾气排放,部分来自石油产品的泄露及煤和生物质的低温燃烧。生态风险评价结果显示,等效毒性当量∑16BaPeq低于国家标准,表明土壤中PAHs污染物水平处于可接受范围。   相似文献   

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