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1.
New low-temperature methane absorption coefficients pertinent to the Titan environment are presented as derived from the Huygens DISR spectral measurements combined with the in-situ measurements of the methane gas abundance profile measured by the Huygens Gas Chromatograph/Mass Spectrometer (GCMS). The visible and near-infrared spectrometers of the descent imager/spectral radiometer (DISR) instrument on the Huygens probe looked upward and downward covering wavelengths from 480 to 1620 nm at altitudes from 150 km to the surface during the descent to Titan's surface. The measurements at continuum wavelengths were used to determine the vertical distribution, single-scattering albedos, and phase functions of the aerosols. The gas chromatograph/mass spectrometer (GCMS) instrument on the probe measured the methane mixing ratio throughout the descent. The DISR measurements are the first direct measurements of the absorbing properties of methane gas made in the atmosphere of Titan at the pathlengths, pressures, and temperatures that occur there. Here we use the DISR spectral measurements to determine the relative methane absorptions at different wavelengths along the path from the probe to the sun throughout the descent. These transmissions as functions of methane path length are fit by exponential sums and used in a haze radiative transfer model to compare the results to the spectra measured by DISR. We also compare the recent laboratory measurements of methane absorption at low temperatures [Irwin et al., 2006. Improved near-infrared methane band models and k-distribution parameters from 2000 to 9500 cm−1 and implications for interpretation of outer planet spectra. Icarus 181, 309-319] with the DISR measurements. We find that the strong bands formed at low pressures on Titan act as if they have roughly half the absorption predicted by the laboratory measurements, while the weak absorption regions absorb considerably more than suggested by some extrapolations of warm measurements to the cold Titan temperatures. We give factors as a function of wavelength that can be used with the published methane coefficients between 830 and 1620 nm to give agreement with the DISR measurements. We also give exponential sum coefficients for methane absorptions that fit the DISR observations. We find the DISR observations of the weaker methane bands shortward of 830 nm agree with the methane coefficients given by Karkoschka [1994. Spectrophotometry of the jovian planets and Titan at 300- to 1000-nm wavelength: the methane spectrum. Icarus 111, 174-192]. Finally, we discuss the implications of our results for computations of methane absorption in the atmospheres of the outer planets. 相似文献
2.
Paulo F. Penteado Caitlin A. Griffith Steffi Engel Lyn Doose Robert H. Brown Roger Clark Christophe Sotin 《Icarus》2010,206(1):352-365
We analyze observations taken with Cassini’s Visual and Infrared Mapping Spectrometer (VIMS), to determine the current methane and haze latitudinal distribution between 60°S and 40°N. The methane variation was measured primarily from its absorption band at 0.61 μm, which is optically thin enough to be sensitive to the methane abundance at 20-50 km altitude. Haze characteristics were determined from Titan’s 0.4-1.6 μm spectra, which sample Titan’s atmosphere from the surface to 200 km altitude. Radiative transfer models based on the haze properties and methane absorption profiles at the Huygens site reproduced the observed VIMS spectra and allowed us to retrieve latitude variations in the methane abundance and haze. We find the haze variations can be reproduced by varying only the density and single scattering albedo above 80 km altitude. There is an ambiguity between methane abundance and haze optical depth, because higher haze optical depth causes shallower methane bands; thus a family of solutions is allowed by the data. We find that haze variations alone, with a constant methane abundance, can reproduce the spatial variation in the methane bands if the haze density increases by 60% between 20°S and 10°S (roughly the sub-solar latitude) and single scattering absorption increases by 20% between 60°S and 40°N. On the other hand, a higher abundance of methane between 20 and 50 km in the summer hemisphere, as much as two times that of the winter hemisphere, is also possible, if the haze variations are minimized. The range of possible methane variations between 27°S and 19°N is consistent with condensation as a result of temperature variations of 0-1.5 K at 20-30 km. Our analysis indicates that the latitudinal variations in Titan’s visible to near-IR albedo, the north/south asymmetry (NSA), result primarily from variations in the thickness of the darker haze layer, detected by Huygens DISR, above 80 km altitude. If we assume little to no latitudinal methane variations we can reproduce the NSA wavelength signatures with the derived haze characteristics. We calculate the solar heating rate as a function of latitude and derive variations of ∼10-15% near the sub-solar latitude resulting from the NSA. Most of the latitudinal variations in the heating rate stem from changes in solar zenith angle rather than compositional variations. 相似文献
3.
The spectrometers of the Cassini mission to the Saturn system have detected haze layers reaching up to 800 km in Titan’s atmosphere. Knowledge of the complex refractive index (k) of the haze is important for modeling the surface and atmosphere of Titan and retrieving some information about the functional groups present in the aerosols. Plasma discharges or ultraviolet radiation are commonly used to drive the formation of solid organics assumed to be good analogs of the Titan aerosols. [Tran, B.N., Ferris, J.P., Chera, J.J., 2003a. The photochemical formation of a Titan haze analog. Structural analysis by X-ray photoelectron and infrared spectroscopy. Icarus 162, 114-124; Tran, B.N., Force, M., Briggs, R., Ferris J.P., Persans, P., Chera, J.J., 2008. Photochemical processes on Titan: Irradiation of mixtures of gases that simulate Titan’s atmosphere. Icarus 177, 106-115] reported the index of refraction of analogs synthesized by far ultraviolet irradiation of various gas mixtures. k was determined in the 200-800 nm wavelength range from transmission and reflection spectroscopy. However, this technique is limited by (i) uncertainties in the absorption values because of the small amounts of organics available, (ii) light scattering by the surface roughness and particulates in the sample. These limitations prompted us to perform new measurements using photothermal deflection spectroscopy (PDS), a technique based on the conversion of absorbed light into heat in the material of interest. By combining traditional spectroscopy (λ < 500 nm) and PDS (λ > 500 nm), we determined values of k over the 375-1550 nm range. k values as low as 10−4 above 1000 nm were determined. This is one order of magnitude lower than the measurements generally used as a reference for Titan’s aerosols analogs [Khare, B.N., Sagan, C., Arakawa, E.T., Suits, F., Callicott, T.A., Williams, M.W., 1984. Optical-constants of organic Tholins produced in a simulated Titanian atmosphere—from soft-X-ray to microwave-frequencies. Icarus 60(1), 127-137]. We recommend that these results were used in models to describe the optical properties of the aerosols produced in Titan’s stratosphere. 相似文献
4.
We use Cassini far-infrared limb and nadir spectra, together with recent Huygens results, to shed new light on the controversial far-infrared opacity sources in Titan’s troposphere. Although a global cloud of large CH4 ice particles around an altitude of 30 km, together with an increase in tropospheric haze opacity with respect to the stratosphere, can fit nadir and limb spectra well, this cloud does not seem consistent with shortwave measurements of Titan. Instead, the N2-CH4 collision-induced absorption coefficients are probably underestimated by at least 50% for low temperatures. 相似文献
5.
Long-slit spectroscopy observations of Uranus by the United Kingdom InfraRed Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s Northern Spring Equinox in December 2007.These spectra were analysed and presented by Irwin et al. (Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2009]. Icarus 203, 287-302), but since publication, a new set of methane absorption data has become available (Karkoschka, E., Tomasko, M. [2010]. Methane absorption coefficients for the jovian planets from laboratory, Huygens, and HST data. Icarus 205, 674-694.), which appears to be more reliable at the cold temperatures and high pressures of Uranus’ deep atmosphere. We have fitted k-coefficients to these new methane absorption data and we find that although the latitudinal variation and inter-annual changes reported by Irwin et al. (2009) stand, the new k-data place the main cloud deck at lower pressures (2-3 bars) than derived previously in the H-band of ∼3-4 bars and ∼3 bars compared with ∼6 bars in the J-band. Indeed, we find that using the new k-data it is possible to reproduce satisfactorily the entire observed centre-of-disc Uranus spectrum from 1 to 1.75 μm with a single cloud at 2-3 bars provided that we make the particles more back-scattering at wavelengths less than 1.2 μm by, for example, increasing the assumed single-scattering albedo from 0.75 (assumed in the J and H-bands) to near 1.0. In addition, we find that using a deep methane mole fraction of 4% in combination with the associated warm ‘F’ temperature profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987-15001), the retrieved cloud deck using the new (Karkoschka and Tomasko, 2010) methane absorption data moves to between 1 and 2 bars.The same methane absorption data and retrieval algorithm were applied to observations of Neptune made during the same programme and we find that we can again fit the entire 1-1.75 μm centre-of-disc spectrum with a single cloud model, providing that we make the stratospheric haze particles (of much greater opacity than for Uranus) conservatively scattering (i.e. ω = 1) and we also make the deeper cloud particles, again at around the 2 bar level more reflective for wavelengths less than 1.2 μm. Hence, apart from the increased opacity of stratospheric hazes in Neptune’s atmosphere, the deeper cloud structure and cloud composition of Uranus and Neptune would appear to be very similar. 相似文献
6.
Layered methane clouds in Titan’s troposphere with an upper methane ice cloud, a lower liquid methane-nitrogen cloud, and a gap in between were suggested from in situ measurements and ground-based observations. Here we report laboratory investigations under conditions that mimic Titan’s troposphere providing a detailed picture of the cloud layers. A solid methane cloud with a nitrogen content of less than 14% and a liquid methane-nitrogen cloud with a nitrogen content of ∼30% form above ∼19 km and below ∼16 km altitude, respectively. Contrary to previous assertions, long-lived supercooled liquid methane-nitrogen droplets can be sustained in the region in between. The results demonstrate that a cloud gap could only form in the presence of high amounts of other traces species (ethane nuclei, tholin particles, etc.). 相似文献
7.
Analysis of Titan’s hemispheric brightness asymmetry from mapped Cassini images reveals an axis of symmetry that is tilted with respect to the rotational axis of the solid body. Twenty images taken from 2004 through 2007 show a mean axial offset of 3.8 ± 0.9° relative to the solid body’s pole, directed 79 ± 24° to the west of the sub-solar longitude. These values are consistent with recent measurements of an implied atmospheric spin axis determined from isothermal mapping by [Achterberg, R.K., Conrath, B.J., Gierasch, P.J., Flasar, F.M., Nixon, C.A., 2008. Icarus 197, 549-555]. 相似文献
8.
Methane is, together with N2, the main precursor of Titan’s atmospheric chemistry. In our laboratory, we are currently developing a program of laboratory simulations of Titan’s atmosphere, where methane is intended to be dissociated by multiphotonic photolysis at 248 nm. A preliminary study has shown that multiphotonic absorption of methane at 248 nm is efficient and leads to the production of hydrocarbons such as C2H2 (Romanzin et al., 2008). Yet, at this wavelength, little is known about the branching ratios of the hydrocarbon radicals (CH3, CH2 and CH) and their following photochemistry. This paper thus aims at investigating methane photochemistry at 248 nm by comparing the chemical evolution observed after irradiation of CH4 at 248 and at 121.6 nm (Ly-α). It is indeed important to see if the chemistry is driven the same way at both wavelengths in particular because, on Titan, methane photolysis mainly involves Ly-α photons. An approach combining experiments and theoretical analysis by means of a specifically adapted 0-D model has thus been developed and is presented in this paper. The results obtained clearly indicate that the chemistry is different depending on the wavelength. They also suggest that at 248 nm, methane dissociation is in competition with ionisation, which could occur through a three-photon absorption process. As a consequence, 248 nm photolysis appears to be unsuitable to study methane neutral photochemistry alone. The implications of this result on our laboratory simulation program and new experimental developments are discussed. Additional information on methane photochemistry at 121.6 nm are also obtained. 相似文献
9.
Over 1000 laboratory measurements of the 2-4 mm-wavelength opacity of ammonia have been made under simulated jovian atmospheric conditions using a high-precision laboratory system developed at Georgia Tech. These laboratory measurements of the opacity of ammonia were made of various gas mixtures of hydrogen (∼77.5-85.5%), helium (∼12.5-13.5%), and ammonia (1-10%) at pressures between 1 and 3 bars and temperatures between 200 and 300 K. Laboratory measurements were also made of the opacity of pure ammonia at pressures between 0.05 and 1 bar and temperatures between 200 and 300 K. Using these millimeter-wavelength measurements and close to 2000 cm-wavelength measurements made by Hanley et al. (2009), a new consistent model has been developed to accurately characterize the absorption spectra of ammonia in a hydrogen/helium atmosphere in the 1 mm to 30 cm wavelength range. This model can be used in the 1-30 cm wavelength range at pressures up to 20 bars and temperatures from 200 to 500 K and in the 1 mm to 1 cm wavelength range at pressures up to 3 bars and temperatures from 200 to 300 K. These measurements and the accompanying model will enable better interpretation of the centimeter- and millimeter-wavelength emission spectra of the jovian planets. 相似文献
10.
This work presents the first study of the gaseous products resulting from the partial dissociation of methane and nitrogen in the PAMPRE experimental setup simulating Titan’s atmospheric chemistry.Using cryogenic trapping, the gaseous products generated from the chemical reactions occurring in the reactor have been trapped. Analyses of these products by gas chromatography coupled to mass spectrometry have allowed the detection and identification of more than 30 reaction products. Most of them are identified as nitrile species, accompanied by aliphatic hydrocarbons and a few aromatics compounds. The observed species are in agreement with the data from the recent Cassini-Huygens mission as well as from other laboratory setups capable of dissociating nitrogen and methane. This work emphasizes the probable importance of nitrogen-bearing compounds in the chemistry taking place in Titan’s atmosphere.Furthermore, a quantification of mono-nitriles with saturated alkyl chains has been performed relatively to hydrogen cyanide and shows a power law dependence in their concentration. This dependence is consistent with the Cassini-INMS data and Titan’s photochemical models.An empirical relationship has been extracted from our experimental data: [CxH2x−1N] = 100x−5, where x is the number of carbon atoms in the nitrile molecule. This relationship can be directly used in order to foretell the concentration of heavier nitriles induced by chemistry in Titan’s atmosphere. 相似文献
11.
Detection and measurement of atmospheric water vapor in the deep jovian atmosphere using microwave radiometry has been discussed extensively by Janssen et al. (Janssen, M.A., Hofstadter, M.D., Gulkis, S., Ingersoll, A.P., Allison, M., Bolton, S.J., Levin, S.M., Kamp, L.W. [2005]. Icarus 173 (2), 447-453.) and de Pater et al. (de Pater, I., Deboer, D., Marley, M., Freedman, R., Young, R. [2005]. Icarus 173 (2), 425-447). The NASA Juno mission will include a six-channel microwave radiometer system (MWR) operating in the 1.3-50 cm wavelength range in order to retrieve water vapor abundances from the microwave signature of Jupiter (see, e.g., Matousek, S. [2005]. The Juno new frontiers mission. Tech. Rep. IAC-05-A3.2.A.04, California Institute of Technology). In order to accurately interpret data from such observations, nearly 2000 laboratory measurements of the microwave opacity of H2O vapor in a H2/He atmosphere have been conducted in the 5-21 cm wavelength range (1.4-6 GHz) at pressures from 30 mbars to 101 bars and at temperatures from 330 to 525 K. The mole fraction of H2O (at maximum pressure) ranged from 0.19% to 3.6% with some additional measurements of pure H2O. These results have enabled development of the first model for the opacity of gaseous H2O in a H2/He atmosphere under jovian conditions developed from actual laboratory data. The new model is based on a terrestrial model of Rosenkranz et al. (Rosenkranz, P.W. [1998]. Radio Science 33, 919-928), with substantial modifications to reflect the effects of jovian conditions. The new model for water vapor opacity dramatically outperforms previous models and will provide reliable results for temperatures from 300 to 525 K, at pressures up to 100 bars and at frequencies up to 6 GHz. These results will significantly reduce the uncertainties in the retrieval of jovian atmospheric water vapor abundances from the microwave radiometric measurements from the upcoming NASA Juno mission, as well as provide a clearer understanding of the role deep atmospheric water vapor may play in the decimeter-wavelength spectrum of Saturn. 相似文献
12.
TitanWRF general circulation model simulations performed without sub-grid-scale horizontal diffusion of momentum produce roughly the observed amount of superrotation in Titan’s stratosphere. We compare these results to Cassini-Huygens measurements of Titan’s winds and temperatures, and predict temperature and winds at future seasons. We use angular momentum and transformed Eulerian mean diagnostics to show that equatorial superrotation is generated during episodic angular momentum ‘transfer events’ during model spin-up, and maintained by similar (yet shorter) events once the model has reached steady state. We then use wave and barotropic instability analysis to suggest that these transfer events are produced by barotropic waves, generated at low latitudes then propagating poleward through a critical layer, thus accelerating low latitudes while decelerating the mid-to-high latitude jet in the late fall through early spring hemisphere. Finally, we identify the dominant waves responsible for the transfers of angular momentum close to northern winter solstice during spin-up and at steady state. Problems with our simulations include peak latitudinal temperature gradients and zonal winds occurring ∼60 km lower than observed by Cassini CIRS, and no reduction in zonal wind speed around 80 km, as was observed by Huygens. While the latter may have been due to transient effects (e.g. gravity waves), the former suggests that our low (∼420 km) model top is adversely affecting the circulation near the jet peak, and/or that we require active haze transport in order to correctly model heating rates and thus the circulation. Future work will include running the model with a higher top, and including advection of a haze particle size distribution. 相似文献
13.
We analyzed a data cube of Neptune acquired with the Hubble STIS spectrograph on August 3, 2003. The data covered the full afternoon hemisphere at 0.1 arcsec spatial resolution between 300 and 1000 nm wavelength at 1 nm resolution. Navigation was accurate to 0.004 arcsec and 0.05 nm. We constrained the vertical aerosol structure with radiative transfer calculations. Ultraviolet data confirmed the presence of a stratospheric haze of optical depth 0.04 at 370 nm wavelength. Bright, discrete clouds, most abundant near latitudes −40° and 30°, had their top near the tropopause. They covered 1.7% of the observed disk if they were optically thick. The methane abundance above the cloud tops was 0.0026 and 0.0017 km-am for southern and northern clouds, respectively, identical to earlier observations by Sromovsky et al. (Sromovsky, L.A., Fry, P.M., Dowling, T.E., Baines, K.H., Limaye, S.S., [2001b]. Icarus 149, 459-488). Aside from these clouds, the upper troposphere was essentially clear. Below the 1.4-bar layer, a vertically uniform haze extended at least down to 10 bars with optical depth of 0.10-0.16/bar, depending on the latitude. Haze particles were bright at wavelengths above 600 nm, but darkened toward the ultraviolet, at the equator more so than at mid and high latitudes. A dark band near −60° latitude was caused by a 0.01 decrease of the single scattering albedo in the visible, which was close to unity. A comparison of methane and hydrogen absorptions contradicted the current view that methane is uniformly mixed in latitude and altitude below the ∼1.5-bar layer. The 0.04 ± 0.01 methane mixing ratio is only uniform at low latitudes. At high southern latitudes, it is depressed roughly between the 1.2 and 3.3-bar layers compared to low-latitude values. The maximum depression factor is ∼2.7 at 1.8 bars. We present models with 2° latitude sampling across the full sunlit globe that fit the observed reflectivities to 2.8% rms. 相似文献
14.
Darrell F. Strobel 《Icarus》2010,208(2):878-886
The third most abundant species in Titan’s atmosphere is molecular hydrogen with a tropospheric/lower stratospheric mole fraction of 0.001 derived from Voyager and Cassini infrared measurements. The globally averaged thermospheric H2 mole fraction profile from the Cassini Ion Neutral Mass Spectrometer (INMS) measurements implies a small positive gradient in the H2 mixing ratio from the tropopause region to the lower thermosphere (∼950-1000 km), which drives a downward H2 flux into Titan’s surface comparable to the H2 escape flux out of the atmosphere (∼2 × 1010 cm−2 s−1 referenced to the surface) and requires larger photochemical production rates of H2 than obtained by previous photochemical models. From detailed model calculations based on known photochemistry with eddy, molecular, and thermal diffusion, the tropospheric and thermospheric H2 mole fractions are incompatible by a factor of ∼2. The measurements imply that the downward H2 surface flux is in substantial excess of the speculative threshold value for methanogenic life consumption of H2 (McKay, C.P., Smith, H.D. [2005], Icarus 178, 274-276. doi:10.1016/j.icarus.2005.05.018), but without the extreme reduction in the surface H2 mixing ratio. 相似文献
15.
Chemical reactions and volatile supply through hypervelocity impacts may have played a key role for the origin and evolution of both planetary and satellite atmospheres. In this study, we evaluate the role of impact-induced N2 production from reduced nitrogen-bearing solids proposed to be contained in Titan’s crust, ammonium sulfate ((NH4)2SO4), for the replenishment of N2 to the atmosphere in Titan’s history. To investigate the conversion of (NH4)2SO4 into N2 by hypervelocity impacts, we measured gases released from (NH4)2SO4 that was exposed to hypervelocity impacts created by a laser gun. The sensitivity and accuracy of the measurements were enhanced by using an isotope labeling technique for the target. We obtained the efficiency of N2 production from (NH4)2SO4 as a function of peak shock pressure ranging from ∼8 to ∼45 GPa. Our results indicate that the initial and complete shock pressures for N2 degassing from (NH4)2SO4 are ∼10 and ∼25 GPa, respectively. These results suggest that cometary impacts on Titan (i.e., impact velocity vi > ∼8 km/s) produce N2 efficiently; whereas satellitesimal impacts during the accretion (i.e., vi < 4 km/s) produce N2 only inefficiently. Even when using the proposed small amount of (NH4)2SO4 content in the crust (∼4 wt.%) (Fortes, A.D. et al., 2007. Icarus 188, 139-153), the total amount of N2 provided through cometary impacts over 4.5 Ga reaches ∼2-6 times the present atmospheric N2 (i.e., ∼7 × 1020-2 × 1021 [mol]) based on the measured production efficiency and results of a hydrodynamic simulation of cometary impacts onto Titan. This implies that cometary impacts onto Titan’s crust have the potential to account for a large part of the present N2 through the atmospheric replenishment after the accretion. 相似文献
16.
Fine scale layering of haze and composition in Titan’s stratosphere and mesosphere was investigated using visible/UV images from Cassini’s Imaging Science Sub-system (ISS) and IR spectra from Cassini’s Composite Infra-Red Spectrometer (CIRS). Both ISS and CIRS independently show fine layered structures in haze and composition, respectively, in the 150-450 km altitude range with a preferred vertical wavelength of around 50 km. Layers are most pronounced around the north polar winter vortex, although some weaker layers do exist at more southerly latitudes. The amplitude of composition layers in each trace gas profile is proportional to the relative enrichment of that species in the winter polar vortex compared to equatorial latitudes. As enrichment is caused by polar subsidence, this suggests a dynamical origin. We propose that the polar layers are caused by cross-latitude advection across the vortex boundary. This is analogous to processes that lead to ozone laminae formation around Earth’s polar vortices. 相似文献
17.
Molecular level Monte Carlo simulations have been performed with various model potentials for the CH4-N2 vapor-liquid equilibrium at conditions prevalent in the atmosphere of Saturn’s moon Titan. With a single potential parameter adjustment to reproduce the vapor-liquid equilibrium at a higher temperature, Monte Carlo simulations are in excellent agreement with available laboratory measurements. The results demonstrate the ability of simple pair potential models to describe phase equilibria with the requisite accuracy for atmospheric modeling, while keeping the number of adjustable parameters at a minimum. This allows for stable extrapolation beyond the range of available laboratory measurements into the supercooled region of the phase diagram, so that Monte Carlo simulations can serve as a reference to validate phenomenological models commonly used in atmospheric modeling. This is most important when the relevant region of the phase diagram lies outside the range of laboratory measurements as in the case of Titan. The present Monte Carlo simulations confirm the validity of phenomenological thermodynamic equations of state specifically designed for application to Titan. The validity extends well into the supercooled region of the phase diagram. The possible range of saturation levels of Titan’s troposphere above altitudes of 7 km is found to be completely determined by the remaining uncertainty of the most recent revision of the Cassini-Huygens data, yielding a saturation of 100 ± 6% with respect to CH4-N2 condensation up to an altitude of about 20 km. 相似文献
18.
Olivier Mousis Jonathan I. Lunine Daniel Cordier J. Hunter Waite Jr. William S. Lewis 《Icarus》2009,204(2):749-751
The origin of Titan’s atmospheric methane is a key issue for understanding the origin of the saturnian satellite system. It has been proposed that serpentinization reactions in Titan’s interior could lead to the formation of the observed methane. Meanwhile, alternative scenarios suggest that methane was incorporated in Titan’s planetesimals before its formation. Here, we point out that serpentinization reactions in Titan’s interior are not able to reproduce the deuterium over hydrogen (D/H) ratio observed at present in methane in its atmosphere, and would require a maximum D/H ratio in Titan’s water ice 30% lower than the value likely acquired by the satellite during its formation, based on Cassini observations at Enceladus. Alternatively, production of methane in Titan’s interior via radiolytic reactions with water can be envisaged but the associated production rates remain uncertain. On the other hand, a mechanism that easily explains the presence of large amounts of methane trapped in Titan in a way consistent with its measured atmospheric D/H ratio is its direct capture in the satellite’s planetesimals at the time of their formation in the solar nebula. In this case, the mass of methane trapped in Titan’s interior can be up to ∼1300 times the current mass of atmospheric methane. 相似文献
19.
We have developed a one-dimensional thermochemical kinetics and diffusion model for Jupiter’s atmosphere that accurately describes the transition from the thermochemical regime in the deep troposphere (where chemical equilibrium is established) to the quenched regime in the upper troposphere (where chemical equilibrium is disrupted). The model is used to calculate chemical abundances of tropospheric constituents and to identify important chemical pathways for CO-CH4 interconversion in hydrogen-dominated atmospheres. In particular, the observed mole fraction and chemical behavior of CO is used to indirectly constrain the jovian water inventory. Our model can reproduce the observed tropospheric CO abundance provided that the water mole fraction lies in the range (0.25-6.0) × 10−3 in Jupiter’s deep troposphere, corresponding to an enrichment of 0.3-7.3 times the protosolar abundance (assumed to be H2O/H2 = 9.61 × 10−4). Our results suggest that Jupiter’s oxygen enrichment is roughly similar to that for carbon, nitrogen, and other heavy elements, and we conclude that formation scenarios that require very large (>8× solar) enrichments in water can be ruled out. We also evaluate and refine the simple time-constant arguments currently used to predict the quenched CO abundance on Jupiter, other giant planets, and brown dwarfs. 相似文献
20.
We have obtained spatially resolved spectra of Titan in the near-infrared J, H and K bands at a resolving power of ∼5000 using the near-infrared integral field spectrometer (NIFS) on the Gemini North 8 m telescope. Using recent data from the Cassini/Huygens mission on the atmospheric composition and surface and aerosol properties, we develop a multiple-scattering radiative transfer model for the Titan atmosphere. The Titan spectrum at these wavelengths is dominated by absorption due to methane with a series of strong absorption band systems separated by window regions where the surface of Titan can be seen. We use a line-by-line approach to derive the methane absorption coefficients. The methane spectrum is only accurately represented in standard line lists down to ∼2.1 μm. However, by making use of recent laboratory data and modeling of the methane spectrum we are able to construct a new line list that can be used down to 1.3 μm. The new line list allows us to generate spectra that are a good match to the observations at all wavelengths longer than 1.3 μm and allow us to model regions, such as the 1.55 μm window that could not be studied usefully with previous line lists such as HITRAN 2008. We point out the importance of the far-wing line shape of strong methane lines in determining the shape of the methane windows. Line shapes with Lorentzian, and sub-Lorentzian regions are needed to match the shape of the windows, but different shape parameters are needed for the 1.55 μm and 2 μm windows. After the methane lines are modeled our observations are sensitive to additional absorptions, and we use the data in the 1.55 μm region to determine a D/H ratio of 1.77 ± 0.20 × 10−4, and a CO mixing ratio of 50 ± 11 ppmv. In the 2 μm window we detect absorption features that can be identified with the ν5 + 3ν6 and 2ν3 + 2ν6 bands of CH3D. 相似文献