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1.
The in situ pedogenic enhancement of ferrimagnetic content provides the well-established patterns of magnetic susceptibility variation within mid- to low-latitude loess deposits such as those of China and Central Europe. However, this pattern of high magnetic susceptibility in palaeosols, and lower values in unweathered loess, is not replicated in the higher-latitude loess deposits of Alaska and Siberia. In these localities the relationship is inverted, with high values in loess, and low values in palaeosols. This inverse relationship has been explained by the idea that magnetic susceptibility is reflecting the magnitude of an aeolian ferrimagnetic component of consistent mineralogy, the grain size of which is related to average wind velocity. However, the results of the magnetic study presented in this paper suggest that there are differences in magnetic properties between Alaskan loess and palaeosols, not only in magnetic grain size and concentration but also in magnetic mineralogy. This complicates the simple hypothesis of a `wind velocity’ signal by introducing an additional factor into the climatic signal. In contrast to the enhancement of susceptibility observed in palaeosols of the Loess Plateau, China, we suggest that the low magnetic susceptibility values in the Alaskan palaeosol units are a reflection, at least in part, of the alteration of the ferrimagnetic content by post-depositional processes associated with waterlogging (i.e. gleying) of the soils.  相似文献   

2.
Rock magnetic properties have been measured in a loess–paleosol sequence in the Gorina Quarry, which previously have been suggested to contain records of the Brunhes and part of the Matuyama polarity chrons. Lowest susceptibility values (below 50 × 10−8 m3/kg) are generally related to intensive weathered horizons, whereas highest values are obtained in loess layers (250 × 10−8 m3/kg) as a result of the greater ferromagnetic content in the parent material. The frequency-dependent part of susceptibility ranges between 0.5% and 6.8%; the higher value was obtained in B horizons of paleosols, which can be attributed to superparamagnetic contributions. Hysteresis loops indicate that the differences in ferrimagnetic and paramagnetic content in the sequence reflect the degree of pedogenesis. The same conclusion can be drawn with isothermal remanent magnetization. This point is relevant for determining past climatic changes because the wind-blown titanomagnetites from Cordillera de Los Andes during glacial periods were altered during interglacial periods. The mode of pedogenesis appears not only to control such alterations but also to produce other magnetic minerals.  相似文献   

3.
In Argentina, loess/palaeosol sequences were studied from the two sections at Monte Ralo and Corralito, located near to the city of Córdoba in the east of the Pampean ranges. Infrared optically stimulated luminescence (IRSL) and thermoluminescence (TL) dating techniques were applied to set up a more reliable chronological framework for the Upper Pleistocene loess record. IRSL ages increase with depth and are stratigraphically consistent. The oldest loess exposed correlates at least to the penultimate glaciation. The luminescence dating study gives evidence for humid climate conditions with soil formation during the last interglacial period and the middle pleniglacial correlating to Marine Isotope Stage (MIS) 5 and 3, respectively. Three extended periods of soil formation are recorded in the loess/palaeosol sequences at the Corralito section. These buried soils most likely correlate with the last interglacial and early last glacial period. During the Middle Pleniglacial, two palaeosols are intercalated in the loess successions. In the Córdoba area, the periods of increased loess accumulation and deposition of loessic sediments correlate with more arid and glacial periods during the Early Pleniglacial, the Middle Pleniglacial and the Late Glacial. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

4.
中国黄土和阿拉斯加黄土磁化率气候记录的两种模式探讨   总被引：29，自引：16，他引：29  
在中国和中欧黄土-古土壤研究中发现的磁化率与成壤作用(或古气候温湿程度)的正相关性已被第四纪科学家广泛认识,并应用于古气候研究中.成壤过程形成的亚铁磁性矿物被认为是古土壤磁化率增加的主要原因;然而,这一模式并不一定适用于其他黄土沉积地区,如阿拉斯加和西伯利亚黄土沉积显示了一个完全相反的磁化率行为,即在黄土层获高磁化率值而在古土壤层获低磁化率.这种相反的关系过去被解释为磁化率反映的是与风动力吹来的亚铁磁性矿物的含量,即与风速或风力大小有关.本研究发现阿拉斯加黄土与古土壤的磁性矿物性质有明显差异,不仅仅是粒径的大小,还有磁性矿物的种类即矿物相的差别.这一证据很难单纯以风力强度的大小来解释,意味着阿拉斯加古土壤的低磁化率至少部分是在成壤过程中亚铁磁性矿物发生改变(如溶解)而造成,表明阿拉斯加黄土和中国黄土的磁化率与古气候记录可能存在两种模式,即氧化和还原条件下的成土模式.黄土磁化率在不同的气候(温度湿度)条件下有着不同的对应关系:在低降水量、高蒸发量的干旱氧化成壤条件下,利于亚铁磁性矿物的生成,其磁化率与古气候的关系呈正相关,如中国和中亚黄土;在高纬高湿的还原成壤条件下,亚铁磁性矿物会被破坏被分解,其磁化率与古气候呈负相关关系,如阿拉斯加黄土.如果成壤条件在氧化和还原之间来回变换,那么就很难找到两者之间的联系.因此,将磁化率应用于古气候的重建时要加倍的小心.  相似文献   

5.
中国黄土磁性矿物特征及其古气候意义   总被引：71，自引：11，他引：71       下载免费PDF全文
最直观、最直接的古气候记录莫过于陆相黄土地层,它由许多黄土和古土壤层叠覆而成,详细地记录了第四纪以来的古气候变化。黄土高原中部黄土和古土壤的风化和发育程度可以用磁学参数,如磁化率等来描述。本文作者对甘肃西峰剖面约13万年以来的黄土地层做了详细采样,测量其磁滞回线各参数,频率磁化率、低场和高场磁化率、温度磁化率、磁组构等参数。研究表明,黄土与古土壤中的磁性矿物组分相似而且稳定。磁铁矿、赤铁矿和磁赤铁矿(主要是磁铁矿)的含量及其颗粒大小决定了它们的磁学特征。黄土和古土壤的磁学性质差别主要受成土过程中形成细小磁铁矿的影响。  相似文献   

6.
Magnetic susceptibility (MS) of surface sediment varies systematically across the Loess Plateau in central China, decreasing exponentially from >200×10−8 m3/kg at the northern margin of the Qinling Shan to ≤30×10−8 m3/kg near the southern margin of the Mu Us Desert. MS correlates highly with loess median grain size (r2=0.79), which decreases south-southeastward across the plateau. It also correlates with mean annual temperature (MAT) and mean annual precipitation (MAP) (r2=0.58 and 0.60, respectively), and with their product MAT×MAP (r2=0.83), which is considered a measure of potential pedogenic activity. Because regional isopleths depicting grain size and the primary meteorological parameters are nearly parallel, it is difficult to determine their relative influence on MS. A simple MS model, based on the observed spatial variation in loess thickness, permits quantitative assessment of the effect of the dust accumulation rate on the MS signal of surface sediment and isolates the likely role of climate in the production of magnetic minerals. The model suggests that 84% of the loess MS variance is dictated by the diluting effect of dust and 10–11% is associated with meteorological factors, primarily precipitation. The observed and modeled relationships support hypotheses that attribute variations in MS in the loess-paleosol succession to varying rates of dust deposition and in situ production of magnetic minerals in the accretionary soils, both of which are controlled by monsoon climate.  相似文献   

7.
《Quaternary Science Reviews》2005,24(1-2):195-210
Low-field magnetic susceptibility has been widely used to determine the pedostratigraphy of the Chinese loess/paleosol sequences. However, uncertainties remain in correlating between the loess magnetic susceptibility and the marine oxygen isotope records because susceptibility variations are affected by both global and local paleoclimatic changes. To provide a more sound paleoclimatic interpretation of magnetic susceptibility variations, age models across Marine Oxygen Isotope Stage (MIS) 5 for the Jiuzhoutai (JZT) and Yuanbao (YB) sections, western Chinese Loess Plateau, were constructed through an integrated approach by linking the major pedostratigraphic boundaries of the loess profiles to the SPECMAP oxygen isotope curve, and by correlating relative magnetic paleointensity records with both the SINT800 global paleointensity stack from marine sediments and 36Cl records from the GRIP ice core. Results indicate good correlation of SIRM60 mT (a residual remanence of saturation isothermal remanent magnetization after a 60 mT alternating field demagnetization) variations between these two sites, which agree well with fluctuations in subtropical Atlantic sea surface temperatures. All cooling events recorded by ice-core and Atlantic marine sediments within MIS5 have counterparts in SIRM60 mT. SIRM60 mT is partially controlled by the degree of low-temperature oxidation, which is strongly temperature dependent. However, strong pedogenesis can decrease SIRM60 mT due to further oxidation of partially oxidized magnetites above some critical points. Therefore, we propose that SIRM60 mT is best suited to record paleotemperature changes in loess profiles from the western Chinese Loess Plateau, where pedogenesis is the weakest. Furthermore, by inter-profile correlation between the YB and JZT sections, we note that the seemingly uniform sub-paleosol unit with a broad susceptibility peak (previously assigned to MIS5c) between ∼34.4 and ∼37.4 m in the YB profile actually consists of two independent units (lower part of S1L1/MIS5b and S1S2/MIS5c). This indicates that susceptibility values can be strongly affected by local factors (e.g., mainly precipitation). Therefore, beside the simplistic traditional paleoclimatic interpretation of variations in loess susceptibility involving only cold/dry and warm/humid scenarios, cold/humid and warm/dry scenarios should also be considered.  相似文献   

8.
A 28-m-long section situated on the coast of the Arctic Ocean, Russia (74°N, 113°E) was extensively sampled primarily for the purpose of magnetostratigraphic investigations across the Jurassic/Cretaceous boundary. The section consists predominantly of marine black shales with abundant siderite concretions and several distinct siderite cemented layers. Low-field magnetic susceptibility (k) ranges from 8 × 10− 5 to 2 × 10− 3 SI and is predominantly controlled by the paramagnetic minerals, i.e. iron-bearing chlorites, micas, and siderite. The siderite-bearing samples possess the highest magnetic susceptibility, usually one order of magnitude higher than the neighboring rock. The intensity of the natural remanent magnetization (M0) varies between 1 × 10− 5 and 6 × 10− 3 A/m. Several samples possessing extremely high values of M0 were found. There is no apparent correlation between the high k and high M0 values; on the contrary, the samples with relatively high M0 values possess average magnetic susceptibility and vice versa. According to the low-field anisotropy of magnetic susceptibility (AMS), three different groups of samples can be distinguished. In the siderite-bearing samples (i), an inverse magnetic fabric is observed, i.e., the maximum and minimum principal susceptibility directions are interchanged and the magnetic fabric has a distinctly prolate shape. Triaxial-fabric samples (ii), showing an intermediate magnetic fabric, are always characterized by high M0 values. It seems probable that the magnetic fabric is controlled by the preferred orientation of paramagnetic phyllosilicates, e.g., chlorite and mica, and by some ferromagnetic mineral with anomalous orientation in relation to the bedding plane. Oblate-fabric samples (iii) are characterized by a bedding-controlled magnetic fabric, and by moderate magnetic susceptibility and M0 values. The magnetic fabric is controlled by the preferred orientation of phyllosilicate minerals and, to a minor extent, by a ferrimagnetic fraction, most probably detrital magnetite. Considering the magnetic fabric together with paleomagnetic component analyses, the siderite-bearing, and the high-NRM samples (about 15% of samples) were excluded from further magnetostratigraphic research.  相似文献   

9.
Typical loess-palaeosol formations in the southern part of the Russian plain (Novaya Etuliya type section), in China and in Central Asia show the same pattern of magnetic susceptibility (MS) variations with enhanced signatures in soils compared to loesses. This behavior is well known to be caused by in situ forming fine grained magnetite (maghemite) of pedogenic origin. A different pattern of MS changes has been reported for Western Siberia and Alaska: high magnetic signatures in loesses and low ones in palaeosols. The highest MS values in the Belovo type section (Ob River) are connected with the sand and silt fractions and hence are due to sedimentary processes and terrigenous magnetic minerals. Low MS in palaeosols is related to gleisation. A more complex behaviour of ms changes is observed in the Precaucasus loess section at Otkaznoe. The palaeosols here show enhanced magnetic signatures whereas the loess horizons display largely variable magnetic signals due to changing detrital material influx.  相似文献   

10.
The intrinsic room temperature magnetic properties of pure calcite were determined from a series of natural crystals, and they were found to be highly dependent on the chemical composition. In general, dia-, para-, and ferromagnetic components contribute to the magnetic susceptibility and the anisotropy of magnetic susceptibility (AMS). With a combination of magnetic measurements and chemical analysis these three contributions were determined and related to their mineralogical sources. The intrinsic diamagnetic susceptibility of pure calcite is − 4.46 ± 0.16 × 10− 9 m3/kg (− 12.09 ± 0.5 × 10− 6 SI) and the susceptibility difference is 4.06 ± 0.03 × 10− 10 m3/kg (1.10 ± 0.01 × 10− 6 SI). These diamagnetic properties are easily dominated by other components. The paramagnetic contribution is due to paramagnetic ions in the crystal lattice that substitute for calcium; these are mainly iron and manganese. The measured paramagnetic susceptibility agrees with the values calculated from the known concentration of paramagnetic ions in the crystals according to the Curie law of paramagnetic susceptibility. Substituted iron leads to an increase in the AMS. The paramagnetic susceptibility difference was found to correlate linearly with the iron content for concentrations between 500 and 10,000 ppm. An empirical relation was determined: (k1 − k3)para (kg/m3) = Fe-content (ppm) × (1 ± 0.1) × 10− 12 (kg/m3/ppm). The maximum susceptibility difference (Δk = k1 − k3) was found to be unaffected by iron contents below 100 ppm. Ferromagnetic contributions due to inclusions of ferromagnetic minerals can dominate the susceptibility. They were detected by acquisition of isothermal remanent magnetization (IRM) and their contribution to the AMS was separated by high-field measurements.  相似文献   

11.
The Sierra Norte-Ambargasta batholith is one of the largest plutonic expressions of the Pampean orogeny in western Argentina. A thorough petrographic, geochemical, isotopic (Sr and Nd) and geochronological (U–Pb SHRIMP) study is reported. The batholith comprises granitoid rocks that may be subdivided into those affected by Pampean D2 dextral shearing and mylonization and those emplaced after deformation had ceased; representative samples gave U–Pb zircon ages of 537 ± 4 Ma and 530 ± 4 Ma respectively. The earlier, dominant, group were derived largely from metaluminous calc-alkaline subduction-related magmas, whereas the late granites are peraluminous. However, all have relatively high initial 87Sr/86Sr ratios (0.706 to at least 0.710, strongly negative εNdt values (−1.7 to −5.9) and, in some cases inherited 600 Ma and 970 Ma zircon, similar to the isotopic and zircon provenance seen in the metamorphic host rocks. A high degree of contamination of the magmas, possibly anatexis in the case of the post-mylonite granite, is related to emplacement during the latestage transpressional docking of the Pampean terrane against the Rio de la Plata craton. The absence of detrital zircon derived from the craton in either the Pampean metasedimentary host rocks or the batholith supports this collisional model for the Pampean orogen.  相似文献   

12.
This paper reports the results of an investigation of the Weichselian Upper Pleniglacial loess sequences of Nussloch (Rhine Valley, Germany) based on stratigraphy, palaeopedology, sedimentology, palynology, malacology and geochemistry (δ13C), supported by radiocarbon, TL and OSL dating. Grain-size and magnetic susceptibility records are taken at 5 cm intervals from the Upper Pleniglacial (UPG) loess. The data indicate cyclic variations in loess deposition between ca 34 and 17 ka, when the sedimentation rate is especially high (1.0–1.2 m per ka for more than 10 m). The grain-size index (GSI: ratio of coarse silt versus fine silt and clay) shows variations, which are assumed to be an indirect measurement of wind intensity. The sedimentation rate, interpreted from the profiles, indicates high values in loess (Loess events LE-1 to LE-7) and low or negligible values in tundra gley horizons G1 to G8. OSL ages from the loess and 14C dates from organic matter in the loess show that loess deposition was rapid but was interrupted by shorter periods of reduced aeolian sedimentation. Comparison between the data from Nussloch and other European sequences demonstrates a progressive coarsening of the loess deposits between ca 30 and 22 ka. This coarsening trend ends with a short but major grain-size decrease and is followed by an increase to a new maximum at 20 ± 2 ka (“W” shape). Correlation between the loess GSI and the Greenland ice-core dust records, suggests a global connection between North Atlantic and Western European global atmospheric circulation and wind regimes. In addition, the typical Upper Pleniglacial loess deposition begins at ca 30–31 ka, close to Heinrich event (HE) 3, and the main period of loess sedimentation at about 25 ± 2 ka is coeval to HE 2. Correlation of magnetic susceptibility and grain-size records shows that the periods, characterised by high GSI, coincide with an increase in the amount of ferromagnetic minerals reworked from the Rhine alluvial plain. They suggest enhancement in the frequency of the storms from N–NW. These results are integrated within a palaeogeographical model of dust transport and deposition in Western Europe for the Weichselian Upper Pleniglacial (or Late Pleniglacial).  相似文献   

13.
Excessive arsenic concentrations above the Argentinean and WHO guidelines for drinking water (10 μg L−1) affects shallow aquifers of the southern Pampean Plain (Argentina) hosted in the Pampean and the Post Pampean formations (loess and reworked loess; Plio-Pleistocene–Holocene). Health problems related to high As concentrations in drinking waters are known as Endemic Regional Chronic Hydroarsenicism. Hydrochemistry of shallow groundwaters and soil geochemistry were investigated aiming to (1) understand the partition of As in the solid phase and its relationship with unacceptable As concentrations in waters, (2) identify the provision source of As to groundwaters. Only 5% of the samples had As concentrations <10 μg L−1; in 27% As concentrations ranged from 10 to 50 μg L−1 and in 58% it reached 60–500 μg L−1. The coarse fraction (50–2,000 μm) hosts about 27% of the total As in the solid phase, being positively correlated to Ba (p < 0.01; r 2 = 0.93). About 70% is included in the <2 μm fraction and had positive correlations of As–Fe (p < 0.05; r 2 = 0.85) and As–Cr (p < 0.05; r 2 = 0.68). Soils and sediment sand fractions of vadose zones are the primary sources of As in shallow groundwater while adsorption–desorption processes, codisolution–coprecipitation, and evaporation during the dry seasons raise As concentrations in waters exceeding the guideline value for drinking water.  相似文献   

14.
The aim of this study was to design and test a new tool for (i) the quantitative in situ monitoring of Fe(III) reduction in soils and (ii) the tracking of the potential mineralogical changes of Fe-oxides. The tool consists of small (2 × 2 × 0.2 cm) striated polymer plates coated with synthetic pure ferrihydrite or As-doped ferrihydrite (Fh–As). These slides were then inserted within two different horizons (organo-mineral and albic) located in a wetland soil with alternating redox conditions. Dissolution was quantified by X-ray fluorescence (XRF) analyses of total metal contents before and after insertion into the soil. The crystallographic evolution of Fe-oxides was characterized by scanning electron microscope equipped with an energy-dispersive spectrometer (SEM–EDS). Over the months, the ferrihydrite progressively disappeared, at rates comparable to those previously measured in laboratory studies, i.e. in the 1–10 × 10−12 mol Fe m−2 s−1 range. SEM observations indicate that the supports were highly colonized by bacteria and biofilms in the organo-mineral horizon, suggesting a biological-mediated process, while the albic horizon appeared to be characterized by a mostly chemical-mediated process. In the albic horizon, Fe-sulphide and other micro-precipitates were formed after 7 months of incubation in balance with a quasi dissolution of initial Fe-oxides.  相似文献   

15.
马兰黄土和离石黄土的磁学性质   总被引：31，自引：0，他引：31       下载免费PDF全文
中国黄土-古土壤系列的磁学性质,如磁化率等被广泛用于古气候和古环境研究,这必须建立在对黄土-古土壤的剩磁的性质和获得剩磁的机制以及古土壤磁性增强的原因有深入了解的基础之上。作者通过对洛川和吉县剖面马兰黄土和离石黄土的磁学性质的深入研究,对黄土与古土壤磁学性质差异的各种表现,对它们剩磁的性质,对古土壤磁性增强的原因以及磁性变化对古气候、古环境研究的意义进行了讨论,并对利用某些磁学性质建立的黄土-古土壤形成的时间模式提出了质疑。  相似文献   

16.
We have analysed the halogen concentrations and chlorine stable isotope composition of fluid inclusion leachates from three spatially associated Fe-oxide ± Cu ± Au mineralising systems in Norrbotten, Sweden. Fluid inclusions in late-stage veins in Fe-oxide–apatite deposits contain saline brines and have a wide range of Br/Cl molar ratios, from 0.2 to 1.1 × 10−3 and δ37Cl values from −3.1‰ to −1.0‰. Leachates from saline fluid inclusions from the Greenstone and Porphyry hosted Cu–Au prospects have Br/Cl ratios that range from 0.2 to 0.5 × 10−3 and δ37Cl values from −5.6‰ to −1.3‰. Finally, the Cu–Au deposits hosted by the Nautanen Deformation Zone (NDZ) have Br/Cl molar ratios from 0.4 to 1.1 × 10−3 and δ37Cl values that range from −2.4‰ to +0.5‰, although the bulk of the data fall within 0‰ ± 0.5‰.The Br/Cl ratios of leachates are consistent with the derivation of salinity from magmatic sources or from the dissolution of halite. Most of the isotopic data from the Fe-oxide–apatite and Greenstone deposits are consistent with a mantle derived source of the chlorine, with the exception of the four samples with the most negative values. The origin of the low δ37Cl values in these samples is unknown but we suggest that there may have been some modification of the Cl-isotope signature due to fractionation between the mineralising fluids and Cl-rich silicate assemblages found in the alteration haloes around the deposits. If such a process has occurred then a modified crustal source of the chlorine for all the samples cannot be ruled out although the amount of fractionation necessary to generate the low δ37Cl values would be significantly larger.The source of Cl in the NDZ deposits has a crustal signature, which suggests the Cl in this system may be derived from (meta-) evaporites or from input from crustal melts such as granitic pegmatites of the Lina Suite.  相似文献   

17.
A total of 240 three-component recordings from 80 rockbursts, which occurred in various coal mines in the Ostrava-Karviná Coal Basin (Czech Republic) between 1993 and 2005, was used to examine the decrease in maximum particle velocities ui (m/s) with a scaled distance of d = d/√E (m/√J) or d/3√E (m/3√J) and the rate of predominant frequencies of body waves. The energetic span of rockbursts was within the interval of E = 6.2 × 103 − 5.0 × 108 J, while calculated hypocentral distances d of four underground seismic stations varied from 0.6 to 7 km. The slopes b of regression straight lines for the maximum particle velocities ui (m/s) of P- and S-waves in the bilogarithmic scale correspond to the values of − 1.004, − 1.297, − 1.183 and − 1.527. The results of the linear regression are as follows:
Pmax-waves ui = 1.184 × 10− 4 × d− 1.004 (m/s) (square root scaling)
Pmax-waves ui = 3.055 × 10− 3 × d− 1.297 (m/s) (cube root scaling)
Smax-waves ui = 5.280 × 10− 4 × d− 1.183 (m/s) (square root scaling)
Smax-waves ui = 2.397 × 10− 2 × d− 1.527 (m/s) (cube root scaling).
The evaluation of the abovementioned dynamic parameters was based on seismic events data gathered in the database of the regional seismic array, and calculations were carried out either by using special programs applied as part of the automated data processing in the computation center, or by usual linear regression approaches. The aim of the detailed analysis of the maximum particle velocity and predominant frequencies was a) to set up input data from underground seismological observations for laboratory experiments dealing with the comparison of rock mass behaviour under modeled laboratory conditions simulating manifestation of rockbursts, and b) to incorporate particle velocity into the design of support in order to control damage and evident devastation of workings by rockbursts. The investigation of peak particle velocities was based on the recognition that they are the best criterion to assess vibration damage to surface structures and in mines.  相似文献   

18.
Silicophytoliths were produced in the plant communities of the Pampean Plain during the Quaternary. The biogeochemistry of silicon is scarcely known in continental environments of Argentina. The aim of this work is to present a synthesis of: the plant production and the presence of silicophytoliths in soils with grasses, and its relationship with silica content in soil solution, soil matrix and groundwaters in temperate ecosystems of the Pampean Plain, Argentina. We quantified the content of silicophytoliths in representative grasses and soils of the area. Mineralochemical determinations of the soils' matrix were made. The concentration of silica was determined in soil solution and groundwaters. The silicophytoliths assemblages in plants let to differenciate subfamilies within Poaceae. In soils, silicophytoliths represent 40–5% of the total components, conforming a stock of 59–72 × 103 kg/ha in A horizons. The concentration of SiO2 in soil solution increases with depth (453–1243 μmol/L) in relation with plant communities, their nutritional requirements and root development. The average concentration of silica in groundwaters is 840 umol/L. In the studied soils, inorganic minerals and volcanic shards show no features of weathering. About 10–40% of silicophytoliths were taxonomically unidentified because of their weathering degrees. The matrix of the aggregates is made up by microaggregates composed of carbon and silicon. The weathering of silicophytoliths is a process that contributes to the formation of amorphous silica-rich matrix of the aggregates. So, silicophytoliths could play an important role in the silica cycle being a sink and source of Si in soils and enriching soil solutions and groundwaters.  相似文献   

19.
Tunnel excavation at Äspö Island, Sweden, has caused severe groundwater disturbance, gradually extending deeper into the tunnel as present-day Baltic seawater intrudes through fractures connecting to the surface. However, the paleo-hydrogeochemical conditions have remained in the deep highly saline waters that have avoided mixing. A correlation has been observed between dissolved 4He concentration and Cl− ion concentration, measured every two years from 1995 to 2001 at Äspö. Groundwater mixing conditions can be examined by the correlations between 1/Cl, 36Cl/Cl, and 3H concentrations. Subsurface production is responsible for the majority of the 36Cl and excess dissolved 4He of interstitial groundwater in fractures. The secular equilibrium ratio of 36Cl/Cl in rock was theoretically estimated to be (5.05 ± 0.82) × 10−14 based on the neutron flux intensity, a value comparable to the measured 36Cl/Cl ratio in rock and groundwater. The degassing crustal 4He flux was estimated to be 2.9 × 10−8  1.3 × 10−6 (ccSTP/cm2a) using the HTO diffusion coefficient for the Äspö diorite. The 4He accumulation rate ranges from 6.8 × 10−10 (for the in situ accumulation rate) to 7.0 × 10−9 (ccSTP/(gwater · a) considering both 4He in situ production and the degassing flux, assuming 4He is accumulated constantly in groundwater. By comparing the subsurface 36Cl increase with 4He concentrations in groundwater, the 4He accumulation rate was determined from data for groundwater arriving at the secular equilibrium of 36Cl/Cl. The 4He accumulation rate was found to be (1.83 ± 0.72) × 10−8 ccSTP/(gwater · a) without determining the magnitude of degassing 4He flux.  相似文献   

20.
The present study aims to model iron speciation when interacting with natural organic matter. Experimental data for iron speciation were achieved with insolubilized humic acid as an organic matter analogue for 1.8 × 10− 3 M and 1.8 × 10− 4 M iron concentrations and 2–5 pH range. Combining EPR spectroscopy and chemical analysis allowed us to fit NICA-Donnan model parameters for both organic complexation of iron and oxides precipitation.  相似文献   

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