共查询到20条相似文献，搜索用时 171 毫秒
1.
Peiping Zhang Xiaoguo Chi Chunyan Tian Baojun Wang Huahua Lü Xuefa Shi . College of Material Science Engineering Jilin University Changchun Jilin China . College of Earth Sciences Jilin University Changchun Jilin China .Pivot Laboratory of National Ocean Department on Ocean Sediment Environment Geology the First Institute of National Ocean Research Qingdao Shandong China 《东北亚地学研究》2006,9(1):19-29
In order to make use of ocean clay reasonably and excavate its potential applications the properties of ocean clay in Chinese investigating area of the East Pacific have been tested with the chemical analysis, XRFS, ICP/MAS, granulometry and SSA, etc. The results show that the clay sediments of this area are rich in clay minerals, fine granularity, bigger SSA, bigger water absorbability and lower ion changing ability etc. To improve the adaptability of ocean clay and macromolecule materials, using the dry milling method with silane, aluminate, stearic acid coupling agents etc the properties of ocean clay are improved. The effect has been evaluated by testing the water absorbing of the modified ocean clay and their dispersing in paraffin liquid. The result is that KH550 is better than any other active reagents, and the best activation technics is that 1.5 % （volume） of KH550 quantity, 20min of milling time. The DTA, XRD, SEM and IR analyses and SSA testing show that the organic activation can not change the mineral structure but can densify the structure of clay, and activation mechanism is chemical covered mainly and chemical combined secondly. 相似文献
2.
To make use of the pelagic clay as polymer filling, the properties of clay sediments from the ocean investigation zone of China in the East Pacific were studied by the SSA, XRF, ICP/MAS, FHR, XRD, SEM, DTA/TG and granularity distributing etc. , and experiments were settled to improve the whiteness and activation of the clay based on these data. Compared with land clay, pelagic clay holds many particular features, such as fine particles and incompact accumulation, worse crystallization and more defects, high activity, complex mineral and chemical components, and low whiteness etc. Processing the purified pelagic clay with acids and zinc, then baked it at different temperatures, the whiteness of clay can be increased from 23.8% to 73.1%, and the optimized conditions is : consistency of vitriol 25%, ratio of clay to water 4:1, reaction time 4h, reaction temperature 90℃, dosage of zinc 2.0 g/L, and baking temperature 700℃. And the SSA of whited clay is increased too. Using the dry milling method to modify the pelagic clay with organic reagents, the optimized technique is KH550, concentration 1.5%, reaction time 20 min. XRD,FTIR and SEM testing indicate that the mechanism of organic activation was mainly surface absorbing and chemical combination secondly. 相似文献
3.
Peiping ZHANG Shufeng LIU Xuefa SHI Huahua LU Juanjuan LIU Xiaoguo CHI.College of Earth Sciences Jilin University Changchun China 《东北亚地学研究》2008,11(2):110-114
To make use of the pelagic clay as polymer filling, the properties of clay sediments from the ocean investigation zone of China in the East Pacific were studied by the SSA, XRF, ICP/MAS, FTIR, XRD, SEM, DTA/TG and granularity distributing etc. , and experiments were settled to improve the whiteness and activation of the clay based on these data. Compared with land clay, pelagic clay holds many particular features, such as fine particles and incompact accumulation, worse crystallization and more defects, high activity, complex mineral and chemical components, and low whiteness etc. Processing the purified pelagic clay with acids and zinc, then baked it at different temperatures, the whiteness of clay can be increased from 23.8% to 73.1%, and the optimized conditions is： consistency of vitriol 25%, ratio of clay to water 4： 1, reaction time 4h, reaction temperature 90℃, dosage of zinc 2.0 g/L, and baking temperature 700℃. And the SSA of whited clay is increased too. Using the dry milling method to modify the pelagic clay with organic reagents, the optimized technique is KH550, concentration 1.5%, reaction time 20 min. XRD, FTIR and SEM testing indicate that the mechanism of organic activation was mainly surface absorbing and chemical combination secondly. 相似文献
4.
In order to improve the properties of HDPE, the authors used the method of suspended diffusion for purification the pelagic clay, used silane coupling agent to increase its organic activation, and prepared the composites of organic pelagic clay/HDPE by melting them in different conditions. The affections of process conditions and quantity of pelagic clay to the properties of composites were analyzed by testing their mechanical properties, thermo stability and barrier properties. According to test the structure of composites, it is indicated that pelagic clay has good compatibility with HDPE. The result shows that the pelagic clay can improve mechanical properties, thermo stability and barrier properties of HDPE properties effectively. 相似文献
5.
湖泊沉积物的矿物组成、成因、环境指示及研究进展 总被引：5，自引：1，他引：4
金章东 《地球科学与环境学报》2011,33(1):34-44,77
湖泊沉积物是不同地质、气候、水文条件下各类碎屑、黏土、自生/生物成因矿物以及有机物质等的综合体。沉积矿物蕴含着丰富区域和全球环境演变信息,如湖水的化学组成、流域构造、气候、水文以及人类活动的相互作用等。相关信息可以赋存在矿物外部微形貌、内部微结构、化学组成、物理和化学性质、同位素组成、谱学特征、成因以及共生组合等方面。因此,湖泊科学的许多关键课题都离不开矿物学,特别是在利用湖泊沉积物进行区域及过去全球变化研究中,深入的机理研究归根到底都要涉及矿物学,如流域化学风化作用、粒度组成、生物壳体化学组成、测年材料的选择等。然而,由于湖泊沉积物中矿物的多源性、复杂性,如何有效提取和解译其中的环境信息,是一项长期困扰研究者的课题,湖泊沉积矿物学的研究往往被许多研究者所忽视,中国的相关研究也较为薄弱。笔者综述了湖泊沉积物中碎屑、黏土、自生/生物矿物的矿物组合、特征、成因在(古)环境反演中的作用及最新研究进展,提出除了继续加强对湖泊沉积物中矿物来源、成因和古环境示踪的深入研究以外,矿物相间的转变及其对湖水和孔隙水组成的响应、一些非晶质或隐晶质及低丰度矿物相在湖泊化学和动力学中的作用也是很有潜力的研究领域,最后提出了研究中存在的一些问题、面对的挑战以及对研究前景的展望。 相似文献
6.
广州地区地下水咸化现象由来已久,通过透射电子显微镜对广州珠江三角洲地下水的咸化原因进行了研究,并评价了其咸化程度。通过研究广州地区地下水中的微粒特征,包括观察微粒的形貌、结晶程度和化学成分等特征,同时对比现代海水微粒特征,讨论了微粒特征用于地下水咸化原因探究和评价的可行性。研究发现,在咸化程度不同的样品中,微粒中Cl含量不同,没有咸化的样品中难以找到Cl元素,咸化程度越高,微粒中Cl含量可以越高。同时,在受到海水入侵的地下水微粒中发现了具有海洋来源含Sr、Ba等微量元素的微粒,这些微量元素在一定程度上可视为海水的示踪剂,说明该组地下水受到了不同程度的海水浸染。通过透射电子显微镜分析研究了地下水中的微粒,结果表明,该研究区地下水中的微粒继承了海水中的微粒特征,广州市地下水的咸化是由于海水入侵所致,因此,利用微粒特征用于海水入侵的判别分析和评价是可行的。类似地,该方法同样可用于水污染调查以及地下水找矿研究。 相似文献
7.
论述了淄川—博山一带的伊利石化高岭石粘土岩的区域地质概况及成矿地质条件,按自然分布结合地质情况,划分为3个成矿带,叙述了各成矿带分布及含矿层特征。以南坡矿区为例,详细论述了矿层赋存特征,矿体的规模、厚度及其质量,研究了矿石类型、化学成分及主要物理性能指标,类比研究了加工技术性能,经简单水选即可达到较为理想的选矿指标,具有高效、低成本优势;结合有关研究,认为该类粘土岩是在较高温度条件下由高岭石粘土岩加钾水化转变而成。山东省该类矿床总体勘查程度低,具有较好的找矿潜力,但优质粘土资源找矿难度大。 相似文献
8.
Under the effect of chemical etching, the macroscopic mechanical properties, mesoscopic structure, mineral content, and porosity of rocks undergo significant changes, which can lead to the geological disasters; thus, an understanding of changes in the microscopic and macroscopic structure of rocks after chemical etching is crucial. In this study, uniaxial mechanical tests and nuclear magnetic resonance (NMR) spectroscopy were carried out on sandstone samples that had been previously subjected to chemical erosion under different pH values. The aim was to study changes in properties and mechanical characteristics, including deformation and strength characteristics, of the rock, and microscopic pore variation characteristics, and to perform preliminary studies of the chemical corrosion mechanism. Results show that different chemical solutions have a significant influence on the uniaxial compressive strength, the axial strain corresponding to the peak axial stress, elastic modulus, etc. With the passage of time, porosity increases gradually with exposure to different chemical solutions, and exposure to chemical solutions results in large changes in the NMR T2 curve and T2 spectrum area. Sandstone exposed to different chemical solutions exhibits different corrosion mechanisms; the root cause is the change of mineral. 相似文献
9.
Corrosion behavior of steel in the juncture area of sea clay and sand was studied. The results show that galvanic corrosion occurred between steel samples buried in sea clay and sand, and that the polarity of the galvanic cell reversed after some testing later. The cause of reversing of polarity is discussed. 相似文献
10.
利用奇异谱分析法对大坝变形数据进行分析,提取趋势和周期分量,分析影响因子与各变形分量的相关性。结果表明,大坝变形主要与水位变化和时效因子有关,温度变化对大坝变形的周期成分贡献最大,其次为水位。另外在准确提取信号的基础上,利用奇异谱分析迭代法对大坝变形进行预测,并与多元回归分析方法和高斯过程模型进行对比,发现其预测精度明显高于后两者。 相似文献
11.
以四川盆地长宁构造地区古生界下志留统龙马溪组页岩为例,利用低压氮气吸附测试手段和分形法理论,分析了页岩的孔隙结构参数及分形维数,结合有机质含量和矿物组成分析,研究了页岩孔隙结构特征及其分形特征的影响因素。结果表明:龙马溪组页岩孔隙结构复杂,孔隙主要以两端开口的圆筒状孔、墨水瓶状孔等开放性孔为主,孔径主要在1~10nm之间,孔径主峰位于1.86nm附近;页岩平均孔径在1.807~4.343nm之间,与w(TOC)、石英含量呈负相关,与黏土矿物含量呈正相关,其中w(TOC)对其影响显著;页岩总孔容在0.010 76~0.025 04cm3/g之间,比表面积在5.416~25.958m2/g之间,页岩总孔容、比表面积与w(TOC)、石英含量呈正相关,与黏土矿物、碳酸盐含量呈负相关;页岩具有双重分形特征,大孔隙分形维数D1为2.091 8~2.653 7,小孔隙分形维数D2为2.724 8~2.857 5,说明大孔隙结构的复杂程度大于小孔隙;页岩孔隙的分形维数与比表面积和总孔容呈正相关,而与平均孔径呈负相关;与w(TOC)、石英含量呈正相关,与黏土矿物、碳酸盐含量呈负相关,其中w(TOC)、石英和黏土矿物含量对页岩孔隙结构复杂性影响较大。 相似文献
12.
太白盆地黄土地层厚１６ｍ左右．发育有两层红褐色古土壤。化学分析与微结构鉴定表明该盆地黄土中的古土壤为ＦｅＯ３与Ａｌ２Ｏ３迁移深度大但无聚集的棕壤．并已成为明显的风化无，发育时的年平均降水量在１０００ｍｍ以上．太白盆地黄土中ＣａＣＯ３含量少，发育有淀积型的光性定向粘土．表明黄土地层发育时的降水量也在６００ｍｍ以上。该盆地黄土地层发育在距今约２０多万年前．指示从这一时期开始，中国黄土搬运高度已超过２０００ｍ。微结构的观察还表明，光性定向粘土不仅可用于降水量的研究，也可用于指示温度的相对高低． 相似文献
13.
宿鸭湖水库是一座综合利用的平原大型水库,经７５．８特大洪水考验后暴露出坝基渗漏及渗透稳定等诸多工程地质问题。本文通过对多次勘察及水库观测资料的整理分析,对洼地段坝后渗水的形成机制进行了论证,指出坝基粉质粘土（Ⅲ）的大孔隙结构与坝后排渗设施不完善、年久失修是该段坝后渗水的主要原因,并提出治理措施,建议被设计部门采纳。大坝经加固除险施工,水库运行１５年来证明,大坝安全,水库运行正常。 相似文献
14.
滨海含水层地层损害是指淡水驱替咸水过程中,释放后的黏土胶体发生絮凝沉降,导致地层孔隙被堵塞,引起含水介质的渗透性降低的现象。该文通过絮凝沉降实验和定流速砂柱实验,分析不同离子强度和阳离子价态(一价、二价)对胶体絮凝沉降的影响,结果表明:NaCl作为电解质时,絮凝发生的离子强度范围在0.032~0.034 mol/L之间,絮凝时间从82 min减少至39 min;而电解质为CaCl 2,离子强度为0.006 mol/L时,胶体的絮凝时间仅需6 min;钙钠比越高,黏粒絮凝发生的越快。砂柱实验结果显示,含水介质渗透性会随着电解质溶液的离子强度增加和阳离子价态的升高快速降低。当电解质为NaCl,离子强度分别为0.054 mol/L和0.017 mol/L时,含水介质渗透性降低20%所需时间分别为15 min和50 min;当电解质为CaCl2,离子强度为0.011 mol/L时,含水介质渗透性降低20%仅需5 min。因为高离子强度和高价阳离子可以加速胶体絮凝,多孔介质的孔吼更容易发生堵塞,研究成果对降低滨海含水层的地层损害有一定的实际应用价值。 相似文献
15.
Mohammed Hazaea HU Ke Mohammed Mattash CHEN Bing M.O.Al-Jabali Aref Mohammed Abdussalam 《世界地质(英文版)》2004,7(2)
The chemical composition of several thermal springs around Changbaishan area has been investigated.Cenozoic basaltic rocks are widely distributed in Northeast China and geothermal characteristics have been described.About one hundred hot springs exist around Changbaishan Volcano at the border between China and D.P.R.Korea with high temperature about 82℃. The pH values of the spring water range from 6.9 to 7.1 and the total flow rate is about 4.8 L /sec. The chemical composition of the thermal springs is sodium carbonate; the high-mineral contents of thermal water are believed to have medicinal properties. Bathhouses are already built along the hot springs to take the advantage of the supposed healing properties. The high quality of those hot springs is believed to be utilitized for mineral water. The chemical equilibrium temperatures were estimated at about 160℃ based on the Na-K-Ca geochemical thermometer. 相似文献
16.
鄂尔多斯盆地镇北地区延长组长4+5特低渗透储层微观孔隙结构复杂,应用常规方法较难对其品质进行合理评价。在利用铸体薄片、扫描电镜和物性分析等常规方法定性研究储层岩石学、孔隙类型的基础上,结合恒速压汞、核磁共振等非常规方法定量研究了其微观孔隙结构和可动流体特征。研究结果表明,沉积、成岩作用共同造成了储层微观孔隙结构和物性的差异,表现为平均喉道半径越大,特低渗透储层渗透率和可动流体饱度越大,储层品质越好,尤其当平均喉道半径小于1.26μm,气测渗透率小于1.0×10-3μm2时。综合研究表明,喉道是影响特低渗透储层微观孔隙结构和开发效果的主控因素。 相似文献
17.
鲁西南(中西部)地区普遍存在地下水中氟化物及矿化度含量较高的问题。电阻率与地下水矿化度关系密切,高氟又易与高矿化度伴生存在,因此赋存高矿化度地下水的黏土层与赋存可饮用地下水砂土层电性上的差异为利用电法在该地区勘查出可饮用地下水提供了基础条件。综合区内区域地质、水文地质及地球物理特征,对重点区的电测深曲线进行了精细的定性及定量解释,划分出重点区内含水层的埋深、黏土层及砂土层分界线,推断出了深层高阻层主要为含淡水砂土层。根据物探推断成果在牡丹区沙土集及曹县常乐集重点区分别施工了2眼钻井。结果表明,钻井出水量丰富,水质较周边有明显改善,直流电测深是在该区域寻找可饮用水资源的一种经济、有效的勘查手段。 相似文献
18.
XIU Peng LIU Yuguang 《中国海洋大学学报(英文版)》2006,5(3):213-218
Based on the in situ optical measurements in the Bohai Sea of China, which belongs to a typical case-2 water area, we studied the characteristics of DCM （deep chlorophyll maximum） such as its spatial distribution, vertical profile, etc. We found that when the depth of the chlorophyll maximum is comparatively small, even in turbid coastal water regions, there is always a good correlation between the concentrations of chlorophyll maximum and the satellite-received signals in blue-green spectral bands; the correlation is even better than that between the surface chlorophyll concentrations and the satellite-received signals. The strong correlation existing even in turbid coastal water regions indicates that an ocean color model to retrieve the concentration of DCM can be constructed for coastal waters if a comprehensive knowledge of the vertical distribution of chlorophyll concentration in the Bohai Sea of China is available. 相似文献
19.
通过对2 131km高分辨率浅地层剖面资料分析和研究,揭示了威海市近海海域浅地层结构特征,分析了海洋灾害地质因素类型及分布特征,并绘制了主要灾害地质因素分布图。威海市近海海域65m以浅地层共分为5层,第一层为全新世泥质楔形体,地层厚度8~15m;第二层为末次盛冰期以来的海侵层,厚度一般小于3m;第三层为MIS2期的陆相沉积层,地层厚度3~8m;第四层为MIS3期的海相沉积层,厚度3~6m;第五层未完全揭示。近海海域灾害地质因素主要包括埋藏下切谷、浅部断层、浅层气、海底沙波沙脊、浅埋起伏基岩等5种类型;埋藏下切谷主要分布在南部海域U3地层单元中;浅部断层主要分布在南部海域水深大于20m的海底堆积平原;浅层气主要分布在北部海域,东部和南部海域面积较小;海底沙波沙脊主要分布在荣成成山头外海海域;浅埋起伏基岩主要分布在基岩海岸和岛屿较近的海域。 相似文献
20.
为提高胺类抑制剂的抑制性和抗温性,优选一种新型两亲性低分子多胺BHTA,设计页岩滚动分散实验、抑制膨润土造浆实验、粒度分布测试评价抑制性能.结果表明:BHTA抑制性优于传统的无机盐类抑制剂KCl和国外聚胺产品Ultrahib,能有效抑制黏土水化膨胀和分散,耐温性优良,可用作泥页岩水化抑制剂.采用Zeta电位测试、红外光谱分析、改性膨润土吸水实验及X线衍射分析测试黏土层间距等,探讨BHTA的作用机理,表明BHTA主要通过质子化胺基与黏土颗粒的静电作用、氢键吸附在黏土表面,以静电吸附为主,通过疏水屏蔽作用发挥抑制作用;BHTA单层吸附进入黏土层间,能最大限度降低黏土水化层间距,破坏黏土水化结构. 相似文献