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1.
塔里木巴楚小海子正长岩杂岩体的岩石成因探讨   总被引:6,自引:4,他引:2  
位荀  徐义刚 《岩石学报》2011,27(10):2984-3004
巴楚小海子正长岩杂岩体是二叠纪塔里木大火成岩省的重要组成部分.SIMS锆石U-Pb定年显示其形成于279.7±2.0Ma,与本区辉绿岩脉和石英正长斑岩岩脉近于同时侵位.根据矿物学特征,小海子正长岩体可分为铁橄榄石正长岩和角闪正长岩两类.前者主要由碱性长石、铁橄榄石、单斜辉石、角闪石和少量石英、斜长石组成,后者主要由碱性长石、角闪石、黑云母和少量的石英、斜长石组成.小海子正长岩体为铁质、碱性系列,轻稀土相对富集,重稀土亏损,具有明显的Eu正异常,无Nb、Ta负异常,相对低的(87Sr/86Sr);(0.7033 ~0.7038)和正的εNd(t)值(+3.1~+3.8),暗示它们来自亏损的地幔源区,没有地壳物质的加入.主微量和同位素地球化学分析,暗示巴楚小海子正长岩的母岩浆为碱性的幔源玄武质岩浆经橄榄石、单斜辉石分离结晶后的残余熔体,并且含有堆晶的碱性长石.这种含有碱性长石堆晶的熔体,在相对还原的条件下结晶,形成铁橄榄石正长岩;在相对氧化的条件下结晶,并经过不同程度斜长石的分离结晶形成角闪正长岩.  相似文献   

2.
Geological studies on saturated to oversaturated and subsolvus aegirine-riebeckite syenite bodies of the Pulikonda alkaline complex and Dancherla alkaline complex were carried out. The REE distribution of the Dancherla syenite shows a high fractionation between LREE and HREE. The absence of Eu anomaly suggests source from garnet peridotite. The Pulikonda syenite shows moderate fractionation between LREE and HREE as reflected by enrichment of HREE and moderate enrichment of LREE. The negative Eu anomaly indicates role of plagioclase fractionation.Three distinct co-eval primary magmas i.e. mafic syenite-, felsic syenite- and alkali basalt magmas — all derived from low-degrees of partial melting of mantle differentiates and enriched metasomatised lower crust played a major role in the genesis and emplacement of the syenites into overlying crust along deep seated regional scale trans-lithospheric strike-slip faults and shear zones following immediately after late-Archaean calc-alkaline arc magmatism at different time-space episodes i.e. initially at craton margin and later on into the thickened interior of the Eastern Dharwar craton. The ductile sheared and folded Pulikonda alkaline complex was evolved dominantly from the magmas derived from partial melting of lower crust and minor juvenile magmas from mantle. Differentiation and fractionation by liquid immiscibility of mafic magma and commingling-mixing of intermediate and felsic magmas followed by fractionational crystallisation under extensional tectonics during waning stages of calc-alkaline arc magmatism nearer to the craton margin were attributed as the main processes for the genesis of Pulikonda syenite complex. Commingling and limited mixing of independent mantle derived mafic and felsic syenitic magmas and accompanying fractionation resulting into soda rich and potash rich syenite variants was tentatively deduced mechanism for the origin of Dancherla, Danduvaripalle, Reddypalle syenites and other bodies belonging to Dancherla alkaline complex at the craton interior. The Peddavaduguru syenite was formed by differentiation of alkali mafic magma (gabbro to diorite) and it’s simultaneous mingling with fractionated felsic syenitic magma under incipient rift. Vannedoddi and Yeguvapalli syenites were derived due to desilicification and accompanying alkali feldspar mestasomatism of younger potash rich granites along Guntakal-Gooty fault and along Singanamala shear zone respectively.  相似文献   

3.
《Gondwana Research》2002,5(2):453-465
The Kunduru Betta Ring Complex (KRC), at the southern margin of Dharwar craton, South India, comprises metaluminous sub-solvus syenites and quartz monzonite with a concentric disposition younging towards the center. An outer mafic syenite (of lamprophyric affinity) is followed by porphyritic monzonite, quartz monzodiorite and finally a quartz monzonitic stock at the centre.SiO2, Al2O3 and Na2O increase from the primitive lamprophyric mafic syenite to the quartz monzonite through the intermediate members, while CaO, MgO, Fe2O3T, TiO2, P2O5 and MnO show an opposite trend suggesting fractionation of hornblende, clinopyroxene, biotite, apatite, sphene, and iron oxide minerals. Rb, Th and U increase with a complementary decrease in Sc, V, Cr, Co, Cu, Sr and Ba from the outer mafic syenite to the inner quartz monzonite. Y, Zr and Hf decrease from lamprophyric mafic syenite to quartz monzodiorite and the trend is reversed in the final quartz monzonite phase. However, the suite is characterised by a compositional gap between quartz monzodiorite and quartz monzonite. Total REE gradually decrease from the mafic syenite to quartz monzonite and the REE distribution patterns show LREE-enriched and HREE-depleted parallel distributions with negligible Eu anomalies.The geochemical data suggest that the rock types were formed as products of progressive differentiation by crystal fractionation of calc-alkaline lamprophyric parent magma which was derived by partial melting of metasomatically enriched mantle in the Kabini lineament. Although the quartz monzonites conform to the trend of differentiated Kunduru Betta suite, the compositional gap between them and the quartz monzodiorite precludes their origin by simple differentiation. It is suggested that convective liquid fractionation might have resulted in the discrete body of quartz monzonite.  相似文献   

4.
The Oshurkovo Complex is a plutonic sheeted complex which represents numerous successive magmatic injections into an expanding system of subparallel and subvertical fractures. It comprises a wide range of rock types including alkali monzodiorite, monzonite, plagioclase-bearing and alkali-feldspar syenites, in the proportion of about 70% mafic rocks to 30% syenite. We suggest that the variation within the complex originated mainly by fractional crystallization of a tephrite magma.

The mafic rocks are considered as plutonic equivalents of lamprophyres. They exhibit a high abundance of ternary feldspar and apatite, the latter may attain 7–8 vol.% in monzodiorite. Ternary feldspar is also abundant in the syenites. The entire rock series is characterized by high Ba and Sr concentrations in the bulk rock samples (3000–7000 ppm) and in feldspars (up to 1 wt.%). The mafic magma had amphibole at the liquidus at 1010–1030 °C based on amphibole geothermometer. Temperatures as low as this were due to high H2O and P2O5 contents in the melt (up to 4–6 and 2 wt.%, respectively). Crystallization of the syenitic magmas began at about 850 °C (based on ternary feldspar thermometry). The series was formed at an oxygen fugacity from the NNO to HM buffer, or even higher.

The evolution of the alkali monzodiorite–syenite series by fractional crystallization of a tephritic magma is established on the basis of geological, mineralogical, geochemical and Sm–Nd and Rb–Sr isotope data. The geochemical modeling suggests that fractionation of amphibole with subordinate apatite from the tephrite magma leaves about 73 wt.% of the residual monzonite melt. Further extraction of amphibole and plagioclase with minor apatite and Fe–Ti oxides could bring to formation of a syenite residuum. Rb–Sr isotopic analyses of biotite, apatite and whole-rock samples constrain the minimum age of basic intrusions at ca. 130 Ma and that of cross-cutting granite pegmatites at ca. 120 Ma. Hence the entire evolution took place in an interval of ≤10 My. Initial 87Sr/86Sr ratios for the mafic rocks range from 0.70511 to 0.70514, and for syenites from 0.70525 to 0.70542. Initial Nd (130 Ma) values for mafic rocks vary from −1.9 to −2.4, and for syenites from −2.9 to −3.5. In a Nd(T) vs. (87Sr/86Sr)i diagram, all rock types of the complex fall in the enriched portion of the Mantle Array, suggesting their derivation from a metasomatized mantle source. However, the small but distinguishable difference in Sr and Nd isotopic compositions between mafic rocks and syenites probably resulted from mild (10–20%) crustal contamination during differentiation. Large negative Nb anomalies are interpreted as a characteristic feature of the source region produced by Precambrian fluid metasomatism above a subduction zone rather than by crustal contamination.  相似文献   


5.
The Mogou syenite intruded into the Mesoproterozoic Xiong’er Group is the main lithostratigraphic unit, along the southern margin of the North China Craton (NCC). This paper reports zircon LA-ICP-MS data, whole-rock major and trace element compositions of late Triassic magmatic rocks in the Mogou syenite, in order to constrain the formation age of the Mogou syenite, research the origin and evolution of the magma and analyse the geodynamic setting of the Qinling Orogen (QO) in Late Triassic. These rocks consist of medium- to coarse-grained syenite and fine-grained quartz syenite. Zircon U–Pb dating yields a crystallization age of 226.5±2.7 Ma. The syenites are characterized by high SiO2 (63.49–72.17%), alkali (K2O+Na2O of 11.18–15.38%) and potassium (K2O/Na2O of 2.88–28.11), are peralkaline or metaluminous (molar A/CNK of 0.87–1.02) and belong to shoshonite series. The syenites have ΣREE of 33.01–191.30 ppm, LREE/HREE of 14–20, (La/Yb)N of 11–24, with LREE-rich distribution pattern and obvious differentiation between HREE and LREE. Eu anomalies are positive for the medium- to coarse-grained syenite and weakly negative for the fine-grained quartz syenite. In addition, the syenites are enriched in large-ion lithophile elements (Ba, K, Sr, and Pb) but depleted in high strength field elements (Ti, Ta, Nb, Zr, and Hf), and have high differentiation indices of 91.69–97.06. These geochemical features indicate that the primary magma of the Mogou syenite most likely originated from a mantle source with minor crustal component, and underwent a fractional crystallization process during its emplacement. The late Triassic A-type Moguo syenite along the southern margin of the NCC was generated in the late stage of the syn-collision event of QO, recording a transition period from compression to extension at around 227 Ma.  相似文献   

6.
《International Geology Review》2012,54(12):1521-1540
The late Carboniferous Dongwanzi Complex in the northern North China Craton is composed of intrusive pyroxenite, hornblendite, gabbro, and syenite. The mafic-ultramafic rocks of the complex exhibit typical cumulate textures, curved-upward REE patterns, and variable contents of compatible elements, suggesting a cumulate origin. The syenite shows Sr-Nd isotopic ratios similar to the mafic-ultramafic complex and positive Eu anomalies in the chondrite-normalized REE patterns, suggesting that the syenite may represent residual melt after significant fractional crystallization of mafic melt. The mafic-ultramafic cumulates have low HREE abundance and high (Tb/Yb)N (2.5–4.2) and Dy/Yb ratios (>2), indicating that they may have originated from melting of garnet peridotite in the mantle. The Dongwanzi Complex is characterized by a large variation in Sr-Nd isotopic composition, with ISr = 0.7035 to 0.7052 and εNd(t) = ?4.0 to +5.2, which may be accounted for by mixing melts of depleted asthenospheric and enriched lithospheric sources. The radiogenic Os isotopic compositions of the complex ((187Os/188Os)i = 0.1344 to 0.3090) suggest slight contamination by mafic lower crust (≤2.5% based on Os isotopic modelling). The Dongwanzi Complex exhibits arc-related whole-rock and mineral geochemical affinities, such as enrichment in LILE (e.g. Sr, Ba, K) and depletion in HFSE (e.g. Nb, Ta, Ti). The abundance of hornblende and high CaO contents (22–24 wt.%) of clinopyroxene suggest that the source was rich in H2O, probably due to the formation above a subduction zone. We conclude that the Dongwanzi Complex and the related crust–mantle interactions probably reflect formation in a back-arc extensional environment related to the subduction of the Palaeo-Asian Ocean beneath the northern margin of the North China Craton in late Palaeozoic time.  相似文献   

7.
后石湖山杂岩体是与垮塌破火山口有关的碱性环状杂岩体, 主要由呈环形分布的碱性火山岩、环状岩墙(斑状石英正长岩)、嵌套的中心复式岩株(晶洞碱长花岗岩和斑状碱长花岗岩)和锥状岩席(石英正长斑岩和花岗斑岩)组成.LA-ICPMS锆石U-Pb年代学分析表明, 斑状石英正长岩环状岩墙、石英正长斑岩和花岗斑岩锥状岩席的侵位年龄分别为119±3Ma、121±2Ma和121±2Ma.该环状杂岩体火山岩与侵入岩的形成年龄相近, 体现了它作为火山-侵入杂岩体的特征.斑状石英正长岩富碱(Na2O+K2O=10.0%~10.5%), K2O含量较高(5.21%~5.42%), 具正的Eu异常(Eu/Eu*=1.05~1.40).碱长花岗岩和斑岩均具有富碱、高FeOtot/MgO、Ga/Al、Zr、Nb和REE值(Eu除外), 以及低Al2O3、CaO、MgO、Ba、Sr和Eu含量的特征, 都属于A型花岗岩质岩石.其中斑岩为铝质A型花岗岩, 具有高的初始岩浆温度(880~901℃).所有A型花岗质岩石均具有较富集的Nd同位素组成, εNd(t)值变化于-13.9~-12.2之间.斑状石英正长岩是下地壳中-基性麻粒岩和片麻岩部分熔融产生的熔体与幔源玄武质岩浆混合, 后又发生单斜辉石分离结晶的产物; 碱长花岗岩源于上地壳长英质岩石部分熔融产生的熔体与幔源玄武质岩浆混合, 随后经历长石的分离结晶作用而成; 斑岩是受幔源岩浆底侵加热的上地壳长英质岩石的部分熔融产生的熔体, 并经历了长石的分离结晶作用而产生.该环状杂岩体的形成过程可以概括为: (1)火山爆炸性喷发形成大量的碱性火山熔岩和火山碎屑岩; (2)地下岩浆房空虚导致压力下降, 其顶板围岩失稳而沿火山口周围近直立的环状断裂垮塌, 形成塌陷的破火山口.与此同时, 下覆岩浆房的岩浆被动挤入环状断裂而形成斑状石英正长岩环状岩墙; (3)浅部地壳的长英质岩浆房过压, 促使其高温过碱质A型花岗质岩浆上升侵位形成了中心的斑状碱长花岗岩岩株, 这些岩浆的上涌导致上覆围岩产生倾角中-陡的、内倾的锥状裂隙, 为石英正长斑岩锥状岩席侵位提供了空间; (4)浅部岩浆房复活, 高温过碱质A型花岗质岩浆再度上升侵位形成被嵌套的晶洞碱长花岗岩岩株.同样, 这种岩浆的再度上侵导致上覆围岩产生了倾角较陡而内倾的锥状裂隙, 为花岗斑岩锥状岩席提供了侵位空间.后石湖山碱性环状杂岩体的形成是华北东部早白垩世与克拉通破坏相关的伸展构造体制下的产物, 这种构造体制可能与古太平洋板块的俯冲作用有关.   相似文献   

8.
The Hongshishan mafic–ultramafic intrusion (SIMS zircon U–Pb age 286.4 ± 2.8 Ma) consists of dunite, clinopyroxene peridotite, troctolite, and gabbro. Major elements display systematic correlations. Trace elements have identical distribution patterns, including flat rare-earth element (REE) patterns with positive Eu anomalies and enrichments in large ion lithophile elements (LILE) but depletions in Nb and Ta, indicating fractional crystallization as a key factor in magmatic evolution. Petrologic and geochemical variations in drill core samples demonstrate that minor assimilation and progressive magma injections were closely associated with Ni–Cu mineralization. Mass balance estimates and Sr–Nd isotopes reveal that the Hongshishan parental magmas were high-Mg and low-Ti tholeiitic basalts and were derived from a lithospheric mantle source that had been modified by subducted slab metasomatism before partial melting.

Southward subduction of the Palaeo-Tianshan–Junggar Ocean is further constrained by a compilation of inferred, subduction-induced modifications of mantle sources in mafic–ultramafic intrusions distributed in the eastern Tianshan–Beishan area. Integrating the regional positive ?Nd(t) granites, high-Mg and low-Ti basaltic magmas (mafic–ultramafic intrusions), and slightly later high-Ti basalts in NW China suggests that their petrogenesis could be attributed to Permian mantle plume activities.  相似文献   

9.
The Roshtkhar area is located in the Khaf-Kashmar-Bardaskan volcano-plutonic belt to the northeastern Iran along the regional E–W trending Dorouneh Fault, northeastern of the Lut Block. There are several outcrops of subvolcanic rocks occurring mainly as dikes in the area, which intruded into Cenozoic intrusive rocks. We present U–Pb dating of zircons from a diabase dike and syenite rock using LA-ICP-MS that yielded an age of 1778 ± 10 Ma for the dike, indicating this Cenozoic dike has zircon xenocrysts inherited from deeper sources; and 38.0 ± 0.5 Ma, indicating an Late Eocene crystallization age for the syenite. Geochemically, the dikes typical of high-K calc-alkaline to shoshonitic magmas. Petrographic observations and major and trace element variations suggest that diabase melts underwent variable fractionation of clinopyroxene, olivine, and Fe-Ti oxides and minor crustal contamination during the differentiation process. Primitive mantle-normalized multi-element diagrams display enrichment in LILE, such as Rb, Ba, Th, U, and Sr compared to HFSE, as well as negative anomalies of Nb, Ta, P, and Ti, suggesting derivation from subduction-modified mantle. Chondrite-normalized REE plots show moderately LREE enriched patterns (<3.83 LaN/YbN <8.27), and no significant Eu anomalies. Geochemical modelling using Sm/Yb versus La/Yb and La/Sm ratios suggests a low-degree of batch melting (~1–3%) of a phlogopite-spinel peridotite source to generate the mafic dikes. The geochemical signatures suggest that the Roshtkhar mafic dikes cannot be related directly to subduction and likely resulted from melting of upper mantle in an extensional setting where the heat flow was provided from deeper levels. These dikes presumably derived the zircon xenocrysts from the assimilation of upper crust of Gondwanian basement. Processes responsible for partial melting of metasomatized lithospheric mantle and post-collision magmatism in NE Iran was triggered by heating due to asthenospheric upwelling in an extensional setting.  相似文献   

10.
The Boziguoer A-type granitoids in Baicheng County,Xinjiang,belong to the northern margin of the Tarim platform as well as the neighboring EW-oriented alkaline intrusive rocks.The rocks comprise an aegirine or arfvedsonite quartz alkali feldspar syenite,an aegirine or arfvedsonite alkali feldspar granite,and a biotite alkali feldspar syenite.The major rock-forming minerals are albite,K-feldspar,quartz,arfvedsonite,aegirine,and siderophyllite.The accessory minerals are mainly zircon,pyrochlore,thorite,fluorite,monazite,bastnaesite,xenotime,and astrophyllite.The chemical composition of the alkaline granitoids show that SiO2 varies from 64.55% to 72.29% with a mean value of 67.32%,Na2O+K2O is high (9.85%-11.87%) with a mean of 11.14%,K2O is 2.39%-5.47% (mean =4.73%),the K2O/Na2O ratios are 0.31-0.96,Al2O3 ranges from 12.58% to 15.44%,and total FeOT is between 2.35% and 5.65%.CaO,MgO,MnO,and TiO2 are low.The REE content is high and the total SREE is (263-1219) ppm (mean =776 ppm),showing LREE enrichment and HREE depletion with strong negative Eu anomalies.In addition,the chondrite-normalized REE patterns of the alkaline granitoids belong to the "seagull" pattern of the right-type.The Zr content is (113-1246) ppm (mean =594 ppm),Zr+Nb+Ce+Y is between (478-2203) ppm with a mean of 1362 ppm.Furthermore,the alkaline granitoids have high HFSE (Ga,Nb,Ta,Zr,and Hf) content and low LILE (Ba,K,and Sr) content.The Nb/Ta ratio varies from 7.23 to 32.59 (mean =16.59) and the Zr/Hf ratio is 16.69-58.04 (mean =36.80).The zircons are depleted in LREE and enriched in HREE.The chondrite-normalized REE patterns of the zircons are of the "seagull" pattern of the left-inclined type with strong negative Eu anomaly and without a Ce anomaly.The Boziguoer A-type granitoids share similar features with A1-type granites.The average temperature of the granitic magma was estimated at 832-839℃.The Boziguoer A-type granitoids show crust-mantle mixing and may have formed in an anorogenic intraplate tectonic setting under high-temperature,anhydrous,and low oxygen fugacity conditions.  相似文献   

11.
We present new geochemical data on alkali and nepheline syenites from various complexes of different age within the Ukrainian Shield. The results reveal a correlation between the content of trace elements in the syenites, their assignment to a particular rock complex, the chemistry of primary melts, and the degree of their differentiation. The data also suggest regional geochemical heterogeneity in the ultramafic-alkaline complexes of the Ukrainian Shield. The alkali and nepheline syenites in the ultramafic-alkaline massifs from the eastern and western parts of the region exhibit similar REE contents and Eu/Eu* ratios but are markedly different in Nb, Ta, Zr, and Hf content and are of the miaskitic type. These rocks have lower REE, Nb, and Zr and higher Sr and Ba compared with early foidolites. The rocks of the gabbro-syenite complexes define a distinct Fe-enrichment fractionation trend from early syenitic intrusions to more differentiated varieties; they are also characterized by lower Sr, Ba, and Eu/Eu* and significantly lower contents of some major elements, e.g., Ti, Mg, and P. The agpaitic index and concentrations of Zr, Nb, Y, and REE increase in the same direction. A similar geochemical feature is observed in the alkali syenites genetically associated with anorthositerapakivi-granite plutons, which show incompatible-element enrichment and strong depletion in Sr and Ba. The distinctive evolutionary trends of alkali and nepheline syenites from different rock complexes of the Ukrainian Shield can be explained by different mechanisms of their formation. The main petrogenetic mechanism controlling the distribution of trace elements in the rocks of ultramafic-alkaline complexes was the separation of parent melts of melanephelinite and melilitite types into immiscible phonolite and carbonatite liquids. The gabbro-syenite complexes and alkali syenites from anorthosite-rapakivi granite plutons evolved via crystallization differentiation, which involved extensive feldspar fractionation.  相似文献   

12.
Voluminous Neoproterozoic mafic–ultramafic, felsic, and alkaline intrusions are found in the northern Yangtze Block, South China. Here, we present whole-rock major and trace element, and Sr–Nd isotopic compositions, together with zircon U–Pb ages, for syenite and gabbro samples from the Shuimo–Zhongziyuan alkaline intrusive complex in the Micang Mountains region at the northwestern margin of the Yangtze Block. Zircon U–Pb dating yields crystallization ages for the Na- and K-rich Shuimo syenites of 869 ± 4 (MSWD = 0.85, 2σ) and 860 ± 5 Ma (MSWD = 0.47, 2σ), respectively, and for the Zhongziyuan gabbros of 753 ± 4 Ma (MSWD = 0.23, 2σ), indicating that the syenites and gabbros represent different stages of magmatism. The syenites include both Na- and K-rich types and have high values of the Rittman index (σ), and high SiO2 and Na2O + K2O contents. These syenites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE), but depleted in high-field-strength elements (HFSE), with high (La/Yb)N values and small negative and positive Eu anomalies (Eu/Eu* = 0.74–1.17). In contrast, the gabbros have lower SiO2 and Na2O + K2O contents, are only slightly enriched in LREEs, are enriched in LILE but depleted in HFSEs, and have small negative and positive Eu anomalies (Eu/Eu* = 0.86–1.37). The syenites have low initial 87Sr/86Sr (0.703340) and ?Nd(t) values (+1.9 to +7.7). The gabbros have relatively high initial 87Sr/86Sr (0.703562–0.704933) and positive ?Nd(t) values (+1.6 to +4.5). These data suggest that the syenites and gabbros are isotopically similar and were largely derived from melts of depleted mantle. The syenites underwent significant fractional crystallization and small amounts of crustal contamination during magma evolution. In contrast, the gabbros were formed by partial melting (>15%) of a garnet lherzolite source and might also have experienced crustal assimilation. Taking into account the geochemical signatures and magmatic events, we propose that the Shuimo syenites formed in an intra-arc rifting setting, however, the Zhongziyuan gabbros were most likely produced in a subduction-related, continental margin arc setting during the Neoproterozoic, thus suggesting that the alkaline intrusive complex were formed by the arc-related magmatism in the Micang Mountains.  相似文献   

13.
http://www.sciencedirect.com/science/article/pii/S1674987113000893   总被引:1,自引:0,他引:1  
Two petrologically distinct alkali feldspar syenite bodies (AFS-1 and AFS-2) from Chhotaudepur area, Deccan Large Igneous Province are reported in the present work. AFS-1 is characterized by hypidio-morphic texture and consists of feldspar (Or55Ab43 to Or25Ab71), ferro-pargasite/ferro-pargasite horn-blende, hastingsite, pyroxene (Wo47, En5, Fs46), magnetite and biotite. AFS-2 exhibits panidiomorphic texture with euhedral pyroxene (Wo47-50, En22-39, Fs12e31) set in a groundmass matrix of alkali feldspar (Or99Ab0.77 to Or1.33Ab98), titanite and magnetite. In comparison to AFS-1, higher elemental concentra-tions of Ba, Sr and PREE are observed in AFS-2. The average peralkaline index of the alkali feldspar syenites is w1 indicating their alkaline nature. Variation discrimination diagrams involving major and trace elements and their ratios demonstrate that these alkali feldspar syenites have a shoshonite affinity but emplaced in a within-plate and rifting environment. No evidence of crustal contamination is perceptible in the multi-element primitive mantle normalized diagram as well as in terms of trace elemental ratios. The enrichment of incompatible elements in the alkali feldspar syenites suggests the involvement of mantle metasomatism in their genesis.  相似文献   

14.
Field study of granitic rocks in the Gebel Abu Brush-Dahis (ABD) area, Southeastern Desert, Egypt, shows that they comprise two granitic groups, namely A- and I-type suites. The A type is distinguished mineralogically by abundant orthoclase and sodic plagioclase, ferrohornblende, monazite, and allanite. In contrast, the I type has more hornblende and biotite, which are more magnesian in composition, and less feldspar. The parental magmas of both suites have many similar geochemical characteristics, although the A type has slightly higher alkalis, Zr, Hf, Zn, and LREE, and lower CaO, MgO, Sr, Ni, and Fe+2. The geochemical properties characteristic of leucocratic A-type granites-such as high Ga/Al ratios, Nb, Y, HREE, and F contents-are only manifest in the more felsic members of the A-type suite. These features were produced by 70% fractional crystallization of feldspar, hornblende, quartz, and biotite. Geotectonically, the study revealed that the A-and I-type granites are typical of an arc setting, but the more felsic members of the A-type suite plot in a within-plate regime. Geochemically, the granites are subalkaline and peraluminous to metaluminous. The granodiorites/adamellites (I-type suite) have fractionated LREE and slightly fractionated or nearly flat HREE, with small or no Eu anomalies. The alkali-feldspar granites (A-type suite) have flat REE with large Eu anomalies, except for one sample, which shows increasing LREE and decreasing HREE with large Eu anomalies; the quartz-monzonites have fractionated LREE and nearly flat HREE with no Eu anomaly. The flat HREE and/or HREE enrichment is attributed to involvement of garnet and/or zircon in melt generation at the source.

The uranium and thorium contents in the granitic rocks are present in the accessory minerals—particulary in monazite, titanite, zircon, allanite, fluorite, apatite, and opaques. Anomalous high radioactivity in the bostonite (alkaline) dike as well as uranium mineralization are largely confined to contacts and fracture zones. Uranophane is the characteristic uranium mineral in the oxidation zone. An XRD study of the high anomalies in pegmatite and bostonite reveals that the uranium mineralizations produced uranophane (Usilicate), thorianite, soddyite, zippeite, and becquerelite.  相似文献   

15.
The South Dehgolan pluton, in NW Iran was emplaced into the Sanandaj–Sirjan magmatic–metamorphic zone. This composite intrusion comprises three main groups: (1) monzogabbro–monzodiorite rocks, (2) quartz monzonite–syenite rocks, and (3) a granite suite which crops out in most of the area. The granites generally show high SiO2 content from 72.1%–77.6 wt.% with diagnostic mineralogy consisting of biotite and amphibole along the boundaries of feldspar–quartz crystals which implies anhydrous primary magma compositions. The granite suite is metaluminous and distinguished by high FeOt/MgO ratios (av. 9.6 wt.%), typical of ferroan compositions with a pronounced A‐type affinity with high Na2O + K2O contents, high Ga/Al ratios, enrichment in Zr, Nb, REE, and depletion in Eu. The quartz monzonite–syenites show intermediate SiO2 levels (59.8%–64.5 wt.%) with metaluminous, magnesian to ferroan characteristics, intermediate Na2O + K2O contents, enrichment in Zr, Nb, REE, Ga/Al, and depletion in Eu. The monzogabbro–monzodiorites show overall lower SiO2 content (48.5%–55.9 wt.%) with metaluminous and calc‐alkaline compositions, relatively lower Na2O + K2O contents, low Ga/Al ratios, and FeOt/MgO (av. 1.6 wt.%) ratios, low abundances of Zr, Nb, and lower REE element concentrations relative to the granites and quartz monzonite–syenites. These geochemical differences among the three different rocks suites are likely to indicate different melt origins. We suggest that the South Dehgolan pluton resulted from a change in the geodynamic regime, from compression to extension in the Sanandaj–Sirjan zone during Mesozoic subduction of the Neo‐Tethys oceanic crust beneath the Central Iranian microcontinent. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

16.
云南个旧碱性岩体主要的岩石类型有碱性正长岩和似长石正长岩,其中,似长石正长岩中出现大量似长石矿物霞石、方钠石和碱性暗色矿物。本文根据矿物成分及特征,将这些似长石正长岩进一步划分为黑榴霞石方钠正长岩、霞石方钠正长岩、霞石正长岩及方钠霞石正长岩4类。岩石地球化学结果表明,4类岩石的地球化学行为整体表现出过碱质岩的特征,K2O+Na2O含量很高,为钾玄岩系列,同时表现出钾质的特点。分异指数高,呈现高度分异演化特点。稀土元素变化大,轻重稀土元素分异明显,富集轻稀土元素,亏损重稀土元素。微量元素富集大离子亲石元素Th、U及Zr、Hf等高场强元素,亏损Ba、Sr大离子亲石元素,而P和高场强元素Ta、Ti亏损,同时Cr、Co、Ni含量非常低,具有中等的负Eu异常和微弱的负Ce异常。研究表明,似长石正长岩在岩浆演化过程中表现出明显的分离结晶作用特征,且岩浆起源温度较高,约为835℃,起源较深。个旧似长石正长岩为A型岩套A1亚型,结合构造判别图解,认为其可能来自角闪石或者金云母相矿物存在的富集地幔,形成于燕山晚期伸展的构造背景,岩浆在较高温度下高度结晶分异,并在侵位过程中伴随陆壳成分的混染。  相似文献   

17.
The Serra da Graciosa Granites and Syenites comprise five distinct plutons in the Brasiliano/Pan-African Graciosa A-type Province, southern Brazil. Six petrographic series can be identified in these plutons: (1) Alkaline series 1, composed of amphibole-bearing alkali feldspar syenites with varied mafic mineralogy and quartz contents, from alkali feldspar syenites with calcic amphibole, clinopyroxene, olivine and allanite to alkali feldspar quartz syenites with sodic–calcic amphibole and chevkinite–perrierite and to alkali feldspar granites with sodic amphibole; (2) Alkaline series 2, characterized by amphibole-bearing alkali feldspar granites, with limited modal variations but amphibole compositions also varying from calcic to sodic; (3) Alkaline series 3, of limited occurrence, which includes alkali feldspar syenites with olivine and clinopyroxene and no amphibole; (4) Aluminous series 1, of widespread occurrence, with various petrographic facies of biotite granites with amphibole; (5) Aluminous series 2, characterized by alkali feldspar granites with biotite and only minor amphibole; (6) Monzodiorites, typically with biotite, calcic amphibole and augitic clinopyroxene, partially mingled with granitic magmas. The mafic minerals present are, in general, Fe-rich with correspondingly low Mg and Al contents. In Alkaline series 1, amphiboles crystallized in progressively more oxidizing and alkaline conditions, while in Alkaline series 2, the initial conditions were somewhat more oxidizing and shifted to reducing in the final stages. In Aluminous series 1 and Aluminous series 2, amphiboles are calcic and comparatively homogeneous. The amphiboles in the monzodioritic rocks, while also homogeneous, are more Mg-rich and show compositions quite distinct from the calcic varieties in the other associations, and this is also the case for clinopyroxene. Mg# in biotite decreases from the monzodioritic rocks to Aluminous series 1 and further to Aluminous series 2. Contrasting evolution of the various associations suggests that several coeval magmatic series are present in the Serra da Graciosa granites.  相似文献   

18.
赵东辉  平先权  郑建平  艾磊  邓昊 《地球科学》2019,44(12):4203-4221
西秦岭东部发育大量小规模中酸性脉岩,但对这些脉岩的研究相对缺乏.在详细的野外观察和岩相学研究的基础上,对西秦岭天水铁堂峡石英正长斑岩进行了地球化学、锆石U-Pb年代学和Lu-Hf同位素研究.石英正长斑岩的锆石U-Pb定年结果表明它们的形成时代为~250 Ma,属印支早期岩浆产物.地球化学研究显示它们属于弱过铝质的高钾钙碱性岩系列,高Mg#,以富集Ba、Sr、K,强烈亏损Nb、Ta,且Eu异常不明显为特征.这些特征与埃达克岩的性质相似.铁堂峡石英正长斑岩的锆石εHf(t)值介于-1.44~+3.17,一阶段Hf模式年龄(tDM1)在765~945 Ma之间.铁堂峡石英正长斑岩形成于阿尼玛卿洋北向俯冲的大陆边缘弧环境,是俯冲洋壳及大洋沉积物熔体与上覆地幔楔作用的产物,并在浅部岩浆房中经历了轻微的分离结晶作用.   相似文献   

19.
颜丽丽  贺振宇  刘磊  赵志丹 《地质通报》2015,34(203):466-473
浙江雁荡山是中国东南部燕山晚期巨型火山-侵入杂岩带的重要组成部分。对其中央侵入相石英正长斑岩的暗色微粒包体中的斑晶和基质斜长石进行了详细的内部结构和成分分析,揭示了斜长石复杂环带的成因和相关的岩浆作用过程。斑晶斜长石由熔蚀的核部和表面干净的幔部组成,边部包裹有钾长石膜。核部斜长石呈浑圆状或港湾状,内部发育筛状结构,An成分显著低于幔部斜长石,代表来自酸性岩浆房中早期结晶的斜长石捕掳晶。同时,幔部斜长石与自形、表面干净的基质斜长石具有类似的An含量,且两者均含有针状磷灰石的包裹体,应结晶自与暗色微粒包体相应的基性岩浆。长石的复杂结构记录了雁荡山火山-侵入杂岩形成过程中的岩浆混合作用和岩浆演化过程。岩浆混合之后的火山喷发活动,造成岩浆房的压力突然减小,温压条件达到钾长石结晶的区域,在石英正长斑岩的斑晶斜长石和暗色包体中的斑晶与基质斜长石外均形成钾长石膜,构成反环斑结构。  相似文献   

20.
长江中下游庐枞火山岩盆地南侧钾质侵入岩带的成因   总被引:1,自引:0,他引:1  
庐枞火山岩盆地南侧的钾质侵入岩带由正长岩-石英正长岩-正长花岗岩组成,以石英正长岩为主。它们的形成时间介于123"130 Ma之间,峰值约为126 Ma,其中正长岩和石英正长岩的形成时间稍早,而正长花岗岩的形成时间略晚。整个钾质侵入岩带的侵位时间晚于庐枞盆地内的橄榄玄粗质火山作用约4"7 Ma,也是长江中下游地区除最东段的宁镇地区外中生代最晚的岩浆活动产物之一。地球化学上,该钾质侵入岩带以高钾、富碱、富集Rb、Th、U、K等强不相容元素和轻稀土元素、亏损高场强元素Nb、Ta和Ti为特征。它们的母岩浆主要是由富集型上地幔部分熔融形成的,从正长岩经石英正长岩到正长花岗岩的演化主要受矿物的分离结晶作用控制,地壳物质同化所起的影响不大。但与同样来自富集型上地幔部分熔融的庐枞盆地内火山杂岩的母岩浆相比,前者的母岩浆来源深度可能更大些或其中包含了更多来自软流圈地幔的组分。两者的演化路径也完全不同,钾质侵入岩带的母岩浆除经历过高压下的分离结晶作用外,晚期在低压下还经历过长石为主,可能还有黑云母的分离结晶,甚至上地壳物质一定程度的混染作用;而盆地内火山杂岩的母岩浆低压下矿物的分离结晶作用及上地壳物质的混染都不明显。庐枞盆地南缘的富钾侵入岩与盆地内的火山杂岩一样,地球化学上都具有明显的大陆弧的特征,暗示它们的岩浆源区可能形成于俯冲带环境,意味着扬子地块北缘先前(推测为古元古代晚期)曾发生过俯冲作用,上地幔的交代富集可能就与这次的俯冲作用有关。  相似文献   

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