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1.
Quantifying anthropogenic contributions to elemental cycles provides useful information regarding the flow of elements important to industrial and agricultural development and is key to understanding the environmental impacts of human activity. In particular, when anthropogenic fluxes reach levels large enough to influence an element's overall cycle the risk of adverse environmental impacts rises. While intensive groundwater pumping has been observed to affect a wide-range of environmental processes, the role of intensive groundwater extraction on global anthropogenic element cycles has not yet been characterized. Relying on comprehensive datasets of groundwater and produced water (groundwater pumped during oil/gas extraction) chemistry from the U.S. Geological Survey along with estimates of global groundwater usage, I estimate elemental fluxes from global pumping, consumptive use, and depletion of groundwater. I find that groundwater fluxes appreciably contribute to a number of elements overall cycles and thus these cycles were underestimated in prior studies, which did not recognize groundwater pumping's role. I also estimate elemental loadings to agricultural soils in the United States and find that in some regions, groundwater may provide a significant portion (more than 10%) of crop requirements of key nutrients (K, N). With nearly 40% of globally irrigated land under groundwater irrigation, characterizing nutrient and toxic element fluxes to these soils, which ultimately influence crop yields, is important to our understanding of agricultural production. Thus, this study improves our basic understanding of anthropogenic elemental cycles and demonstrates that quantification of groundwater pumping elemental fluxes provides valuable information about the potential for environmental impacts from groundwater pumping.  相似文献   
2.
This study describes normal fault zones formed in foreland arkosic turbidites (the Grès d'Annot Formation, SW French Alps) under deep diagenesis conditions (~200 °C) and highlights the occurrence of two markedly different fault‐rock types: (1) the foliated fault rocks of the Moutière‐Restefond area; and (2) the dilatant fault rocks of the Estrop area. The deformation of (1) is dominated by intra‐ and transgranular fracturing, pressure solution of quartz and feldspar grains and syn‐kinematic phyllosilicate precipitation resulting from feldspar alteration. The combination of these mechanisms results in a strongly anisotropic strain with intense shortening normal to the foliation (pressure solution) and extension parallel to the foliation (quartz‐ and calcite‐sealed extension veins). This deformation implies local mass transfer that may be achieved without (or with limited) volume change. The deformation of (2) is expressed as dilatant quartz‐sealed veins and breccia textures in which the main mechanisms are transgranular fracturing and quartz precipitation. Type (2) implies fault volume increase, isotropy of deformation and mass transfer at distances larger than in type (1). This study discusses the origins of (1) and (2) and shows that the permeability of (1) is anisotropic, with higher values than the host rocks parallel to the Y main deformation axis (i.e. perpendicular to the slip vector), whereas the permeability of (2) is isotropic and equivalent to that of the host rocks.  相似文献   
3.
Using a combination of geophysical and geotechnical data from Storfjorden Trough Mouth Fan off southern Svalbard, we investigate the hydrogeology of the continental margin and how this is affected by Quaternary glacial advances and retreats over the continental shelf. The geotechnical results show that plumites, deposited during the deglaciation, have high porosities, permeabilities and compressibilities with respect to glacigenic debris flows and tills. These results together with margin stratigraphic models obtained from seismic reflection data were used as input for numerical finite element models to understand focusing of interstitial fluids on glaciated continental margins. The modelled evolution of the Storfjorden TMF shows that tills formed on the shelf following the onset of glacial sedimentation (ca. 1.5 Ma) acted as aquitards and therefore played a significant role in decreasing the vertical fluid flow towards the sea floor and diverting it towards the slope. The model shows that high overpressure ratios (up to λ ca. 0.6) developed below the shelf edge and on the middle slope. A more detailed model for the last 220 kyrs accounting for ice loading during glacial maxima shows that the formation of these aquitards on the shelf focused fluid flow towards the most permeable plumite sediments on the slope. The less permeable glacigenic debris flows that were deposited during glacial maxima on the slope hinder fluid evacuation from plumites allowing high overpressure ratios (up to λ ca. 0.7) to develop in the shallowest plumite layers. These high overpressures likely persist to the Present and are a critical precondition for submarine slope failure.  相似文献   
4.
Three-dimensional surface visualization models derived from high-resolution LiDAR data provide new information about the type and scale of erosional processes below Late Wisconsin palaeo-ice streams traversing the boundary between Canadian Shield crystalline rocks with offlapping Palaeozoic limestones in central Ontario. The hard bed is directly analogous to that found below ice streams in East Antarctica and East Greenland and provides insight into the effects of abrupt changes in substrate type on subglacial processes. Erosion of hard crystalline Canadian Shield rock was largely ineffectual consisting of areal abrasion of rounded whalebacks and local lee side plucking. In contrast, fast flow over the strike of gently dipping well-bedded and jointed Palaeozoic limestones cut large flow-parallel grooves and ridges akin to mega-scale glacial lineations reflecting intense abrasion below narrow streams of subglacial debris dominated by hard crystalline Shield clasts (erodents). Regionally extensive plucking of structurally weak, well-jointed and bedded limestone produced large volumes of rubbly carbonate debris leaving a 25-km-wide belt of uncontrolled hummocky rubble terrain (long known as the Dummer Moraine in Southern Ontario) some 350 km long and locally as much as 10 m thick. Subglacial plucking and abrasion under fast flowing ice were highly effective in stripping limestone cover rocks from Precambrian basement, and over many glacial cycles, may have played a role in the location and excavation of numerous large and deep lake basins around the Shield–Palaeozoic boundary zone in North America.  相似文献   
5.
Geotechnical and Geological Engineering - Many studies have investigated polyethylene terephthalate (PET) and polypropylene fibers in soil improvement. However, there is a lack of research using...  相似文献   
6.

The site characterization of unsaturated soils is well stablished based on laboratory tests, which are expensive and time-consuming. In-situ testing methods, such as the flat dilatometer test (DMT), are an alternative to the traditional approach of drilling, sampling, and laboratory testing. The literature on DMT interpretation is well established on saturated and well-behaved soils. Only few studies deal with DMT interpretation in unusual soils, and little is known about the influence of soil suction on this test. This paper presents and discusses the influence of soil suction on four DMT campaigns carried out in an unsaturated tropical soil site, also incorporating the soil suction influence on the DMT interpretation. Soil suction was estimated by the soil–water characteristic curve (SWCC) and water content profiles. The water content profiles range from 11.3 to 19.7% which corresponds to a suction range estimated by SWCCs mostly between 6 and 200 kPa. Soil suction significantly influenced DMT data up to 5 m depth at the studied site (the unsaturated active zone) increasing the intermediate DMT parameters. The average horizontal stress index (KD) was equal to about 1.7 and the average dilatometer modulus (ED) was about 4.7 MPa in the active zone and practically doubled their values due to in situ soil suction. The estimated peak friction angle (?) was 20–30% higher due to soil suction influence on DMT assuming the soil behaves as a sand like material. Soil suction must be considered to assess the behavior of the investigated soil by the DMT. The suction influence should be incorporated in the effective stress and this approach considerably improved the site characterization of the studied site.

  相似文献   
7.
Northwest Africa (NWA) 7533 is a Martian regolith breccia. This meteorite (and its pairings) offers a good opportunity to study (near‐) surface processes that occurred on early Mars. Here, we have conducted a transmission electron microscope study of medium‐ and coarse‐grained (a few tens to hundreds of micrometers) Ca‐rich pyroxene clasts in order to define their thermal and shock histories. The pyroxene grains have a high‐temperature (magmatic) origin as revealed by the well‐developed pigeonite–augite exsolution microstructure. Exsolution lamella characteristics (composition, thickness, and spacing) indicate a moderately slow cooling. Some of the pyroxene clasts display evidence for local decomposition into magnetite and silica at the submicron scale. This phase decomposition may have occurred at high temperature and occurred at high oxygen fugacity at least 2–3 log units above the QFM buffer, after the formation of the exsolution lamellae. This corresponds to oxidizing conditions well above typical Martian magmatic conditions. These oxidizing conditions seem to have prevailed early and throughout most of the history of NWA 7533. The shock microstructure consists of (100) mechanical twins which have accommodated plastic deformation. Other pyroxene shock indicators are absent. Compared with SNC meteorites that all suffered significant shock metamorphism, NWA 7533 appears only mildly shocked. The twin microstructure is similar from one clast to another, suggesting that the impact which generated the (100) twins involved the compacted breccia and that the pyroxene clasts were unshocked when they were incorporated into the NWA 7533 breccia.  相似文献   
8.
The Laurentide Ice Sheet was characterized by a dynamic polythermal base. However, important data and knowledge gaps have led to contrasting reconstructions in areas such as the Labrador Ice Divide. In this study, detailed fieldwork was conducted at the southeastern edge of a major landform boundary to resolve the relative ice flow chronology and constrain the evolution of the subglacial dynamics, including the migration and collapse of the Labrador Ice Divide. Surficial mapping and analysis of 94 outcrop‐scale ice flow indicators were used to develop a relative ice flow chronology. 10Be exposure ages were used with optical ages to confine the timing of deglaciation within the study area. Four phases of ice flow were identified. Flow 1 was a northeasterly ice flow preserved under non‐erosive subglacial conditions associated with the development of an ice divide. Flow 2 was a northwest ice flow, which we correlate to the Ungava Bay Ice Stream and led to a westward migration of the ice divide, preserving Flow 2 features and resulting in Flow 3's eastward‐trending indicators. Flow 4 is limited to sparse fine striations within and around the regional uplands. The new optical ages and 10Be exposure ages add to the regional geochronology dataset, which further constrains the timing of ice margin retreat in the area to around 8.0 ka. Copyright © 2019 The Authors. Journal of Quaternary Science Published by John Wiley & Sons Ltd.  相似文献   
9.
10.
Antigua is a small island at the northern end of the Lesser Antilles chain. Its geology is largely limited to the Upper Oligocene and it records with unusual fidelity the transition from island arc volcanism to quiescence and limestone deposition. Despite the apparent limitation of a rock record confined to a short stratigraphical interval, Antigua has a geodiversity that ranges from thick andesites through silicified logs and freshwater snails in cherts to limestones that include both shallow and deeper water facies, and fine karstic features.  相似文献   
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