Microtectonic and geochemical characterization of thrusting in a foreland basin: Example of the South-Pyrenean orogenic wedge (Spain)     

B. Lacroix  M. Buatier  P. Labaume  A. Travé  M. Dubois  D. Charpentier  S. Ventalon  D. Convert-Gaubier 《Journal of Structural Geology》2011,33(9):1359-1377

In orogenic systems, thrust faults play a major role in stacking different tectonic units and may act as conduits for the expulsion of large amounts of fluid of different origins (metamorphic, diagenetic, meteoric). This study focuses on the Monte Perdido thrust unit emplaced in the Paleogene Jaca thrust-sheet-top basin, in the SW-central Pyrenees. We aim to decipher the mechanisms and P-T conditions of deformation in fault zones and characterize the related fluid involvement, through combined microstructural, geochemical and microthermometry analyses. Two thrust faults cutting platform limestones, marls and siliciclastic turbidites of the lower part of the basin-fill (Paleocene–lower Eocene) have been studied. The fault zones are characterized by metre-thick shear zones with highly deformed, foliated clay-rich sediments. Foliation is underlined by preferentially oriented phyllosilicates. Several generations of shear and extension calcite, quartz and chlorite-bearing veins attest to fluid-rock interactions during a multi-stage deformation. Microstructural observations and stable isotope analyses on calcite from veins and host sediments suggest that deformation was aseismic and dominated by diffusive mass transfer from pressure solution sites along cleavage and stylolites to the precipitation sites in veins, with mineralizing fluids in equilibrium with the host sediments. Our results suggest an essentially closed hydrologic system, and imply the absence of significant fluid flow along the studied fault zones. Microthermometric study on fluid inclusions present in calcite and quartz veins, and calcite-quartz oxygen isotopic fractionation determined for the first generation shear veins, allow a geothermal gradient of 34 °C/km to be estimated. Analytical results demonstrate an evolution of the fault zones in three stages. The first stage was related to the emplacement of the Monte Perdido thrust unit during the middle Eocene at a temperature of ～208 °C and a burial depth of ～5.7 km. The second stage corresponds to a fault reactivation at a temperature of ～240 °C and a burial depth of ～6.5 km. The latter deformation may have been related to folding of the Monte Perdido thrust unit during the emplacement of the underlying Gavarnie thrust unit during the late Eocene–early Oligocene, with deeper burial resulting from aggradation of the thrust-sheet-top basin-fill. The last event corresponds to the formation of a dilatant vein system likely related to the exhumation of the massif.  相似文献   

Difference in petrophysical properties between foliated and dilatant fault rocks in deeply buried clastics: The case of the Grès d'Annot Formation,SW French Alps     

Thibault Cavailhes  Pierre Labaume  Jean‐Pierre Sizun  Roger Soliva  Claude Gout  Jean‐Luc Potdevin  Martine Buatier  Aurélien Gay  Alain Chauvet  Delphine Charpentier  Anna Travé 《地学学报》2014,26(4):298-306

This study describes normal fault zones formed in foreland arkosic turbidites (the Grès d'Annot Formation, SW French Alps) under deep diagenesis conditions (~200 °C) and highlights the occurrence of two markedly different fault‐rock types: (1) the foliated fault rocks of the Moutière‐Restefond area; and (2) the dilatant fault rocks of the Estrop area. The deformation of (1) is dominated by intra‐ and transgranular fracturing, pressure solution of quartz and feldspar grains and syn‐kinematic phyllosilicate precipitation resulting from feldspar alteration. The combination of these mechanisms results in a strongly anisotropic strain with intense shortening normal to the foliation (pressure solution) and extension parallel to the foliation (quartz‐ and calcite‐sealed extension veins). This deformation implies local mass transfer that may be achieved without (or with limited) volume change. The deformation of (2) is expressed as dilatant quartz‐sealed veins and breccia textures in which the main mechanisms are transgranular fracturing and quartz precipitation. Type (2) implies fault volume increase, isotropy of deformation and mass transfer at distances larger than in type (1). This study discusses the origins of (1) and (2) and shows that the permeability of (1) is anisotropic, with higher values than the host rocks parallel to the Y main deformation axis (i.e. perpendicular to the slip vector), whereas the permeability of (2) is isotropic and equivalent to that of the host rocks.  相似文献   

Response-based method for determining the extreme behaviour of floating offshore platforms     

Said Mazaheri  Martine J. Downie 《Ocean Engineering》2005,32(3-4):363-393

The accurate prediction of extreme excursion and mooring force of floating offshore structures due to multi-variete environmental conditions which requires the joint probability analysis of environmental conditions for the worst case situation is still impractical as the processing of large amount of met-ocean data is required. On the other hand, the simplified multiple design criteria (e.g. the N-year wave with associated winds and currents) recommended by API known as traditional method does lead neither to the N-year platform response nor to the N-year mooring force. Therefore, in order to reduce the level of conservatism as well as uncertainties involved in the traditional method the response-based method can be used as a reliable alternative approach. In this paper this method is described. In order to perform the calculations faster using large databases of sea states, Artificial Neural Networks (ANN) is designed and employed. In the paper the response-based method is applied to a 200,000 tdw FPSO and the results are discussed.  相似文献   

Microtextural investigation (SEM and TEM study) of phyllosilicates in a major thrust fault zone (Monte Perdido, southern Pyrenees): impact on fault reactivation   总被引：1，自引：0，他引：1  

Martine D. Buatier  Brice Lacroix  Pierre Labaume  Virginie Moutarlier  Delphine Charpentier  Jean Pierre Sizun  Anna Travé 《Swiss Journal of Geoscience》2012,105(2):313-324

Thrusting fault zone in foreland basins are characterized by highly foliated zones generally enriched in phyllosilicates which can play a major role on the mechanical behaviour of the fault. In this context, investigations of synkinematic clay minerals permit to determine the origin of the fluid from which they precipitated as well as the mechanisms of deformation. Our study is focused on clay mineral assemblages (illite and chlorite) in a major thrust fault located in the Monte Perdido massif (southern Pyrenees), a shallow thrust that affects upper cretaceous-paleocene platform carbonates and lower Eocene marls and turbidites. It implied 3?km of displacement of the Monte Perdido thrust unit with respect to the underlying Gavarnie unit. In this area the cleavage development by pressure-solution is linked to the Monte Perdido and Gavarnie thrust activity. The core zone of the fault, about 6?m thick, consists of an interval of intensely deformed clay-bearing rocks bounded by major shear surfaces. The deformed sediment is markedly darker than the protolith. Calcite-quartz shear veins along the shear planes are abundant. Detailed SEM and TEM observations of highly deformed fault zone samples indicate that clay mineral enrichment in the core zone of the fault is not only related to passive increase by pressure-solution mechanism but that dissolution?Crecrystallization of phyllosilicates occurs during deformation. A mineral segregation is observed in the highly deformed zone. Newly formed 2M ₁ muscovite is present along the cleavage whereas IIb chlorite crystals fill S_V2 shear veins suggesting syntectonic growth of phyllosilicates in the presence of fluids in low-grade metamorphic conditions. These mineralogical reactions act as weakening processes and would favour Monte Perdido fault creeping.  相似文献   

The geochemistry of gem opals as evidence of their origin     

Eloïse Gaillou  Aurlien Delaunay  Benjamin Rondeau  Martine Bouhnik-le-Coz  Emmanuel Fritsch  Guy Cornen  Christophe Monnier 《Ore Geology Reviews》2008,34(1-2):113

Seventy-seven gem opals from ten countries were analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) through a dilution process, in order to establish the nature of the impurities. The results are correlated to the mode of formation and physical properties and are instrumental in establishing the geographical origin of a gem opal. The geochemistry of an opal is shown to be dependant mostly on the host rock, at least for examples from Mexico and Brazil, even if modified by weathering processes. In order of decreasing concentration, the main impurities present are Al, Ca, Fe, K, Na, and Mg (more than 500 ppm). Other noticeable elements in lesser amounts are Ba, followed by Zr, Sr, Rb, U, and Pb. For the first time, geochemistry helps to discriminate some varieties of opals. The Ba content, as well as the chondrite-normalized REE pattern, are the keys to separating sedimentary opals (Ba > 110 ppm, Eu and Ce anomalies) from volcanic opals (Ba < 110 ppm, no Eu or Ce anomaly). The Ca content, and to a lesser extent that of Mg, Al, K and Nb, helps to distinguish gem opals from different volcanic environments. The limited range of concentrations for all elements in precious (play-of-color) compared to common opals, indicates that this variety must have very specific, or more restricted, conditions of formation. We tentatively interpreted the presence of impurities in terms of crystallochemistry, even if opal is a poorly crystallized or amorphous material. The main replacement is the substitution of Si⁴⁺ by Al³⁺ and Fe³⁺. The induced charge imbalance is compensated chiefly by Ca²⁺, Mg²⁺, Mn²⁺, Ba²⁺, K⁺, and Na⁺. In terms of origin of color, greater concentrations of iron induce darker colors (from yellow to “chocolate brown”). This element inhibits luminescence for concentrations above 1000 ppm, whereas already a low content in U (≤ 1 ppm) induces a green luminescence.  相似文献   

Zinc-rich clays in supergene non-sulfide zinc deposits     

F. Choulet  M. Buatier  L. Barbanson  R. Guégan  A. Ennaciri 《Mineralium Deposita》2016,51(4):467-490

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Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer system   总被引：15，自引：0，他引：15  

Vincent Cloutier  Ren Lefebvre  Ren Therrien  Martine M. Savard 《Journal of Hydrology》2008,353(3-4):294-313

The study of groundwater hydrogeochemistry of the Paleozoic Basses-Laurentides sedimentary rock aquifer system in Québec produced a large geochemical dataset. Groundwater samples were collected at 153 sites over a 1500 km² study area and analyzed for major and minor ions. The large number of data can lead to difficulties in the integration, interpretation and representation of the results. Two multivariate statistical methods, hierarchical cluster analysis (HCA) and principal components analysis (PCA), were applied to a subgroup of the dataset to evaluate their usefulness to classify the groundwater samples, and to identify geochemical processes controlling groundwater geochemistry. This subgroup consisted of 144 samples and 14 parameters (Ca²⁺, Mg²⁺, Na⁺, K⁺, , Cl⁻, , Fe²⁺, Mn²⁺, Br⁻, Sr²⁺, F⁻, Ba²⁺, HS⁻). Seven geochemically distinct clusters, C1–C7, resulted from the HCA. Samples from clusters C3, C4, C6 and C7 are mostly located in preferential recharge areas. The majority of these samples have Ca–Mg–HCO₃ recharge groundwater (C3, C6, C7) and Na–HCO₃ evolved groundwater (C4). Samples from the other three clusters (C1, C2, C5) are characteristic of an aquifer system under confined conditions. The majority of these samples have Na–HCO₃ evolved groundwater (C1, C5) and Na–Cl ancient groundwater that exhibits elevated concentrations in Br⁻ (C2). In addition to recognizing the importance of hydrogeological conditions on groundwater geochemistry, the distribution of clusters also showed the importance of the geological formations on minor and trace elements, such as Fe²⁺, Mn²⁺, Sr²⁺, F⁻ and Ba²⁺. The first five components of the PCA account for 78.3% of the total variance in the dataset. Component 1 is defined by highly positive loadings in Na⁺, Cl⁻ and Br⁻ and is related to groundwater mixing with Champlain Sea water and solute diffusion from the marine clay aquitard. The high positive loadings in Ca²⁺ and Mg²⁺ of component 2 suggest the importance of dissolution of carbonate rocks in this aquifer system. From their characteristic loadings, the first two components are defined as the “salinity” and “hardness” components, respectively. Components 3–5 are related to more local and geological effects. The integration of the HCA and the PCA, with conventional classification of groundwater types, as well as with the hydrogeological and geological contexts, allowed the division of the region into four main geochemical areas, providing an improved regional picture of the aquifer system dynamics and hydrogeochemical evolution of groundwater. The following factors were recognized as influencing the evolution of groundwater identified in every geochemical area: (1) geological characteristics including sedimentary rock type and till mineralogy; (2) hydrogeological characteristics represented by the level of confinement and the hydraulic gradient; and (3) the geological history including the latest glaciation and the Champlain Sea invasion. With its integrated approach, this hydrogeochemical study contributes to the characterization and understanding of complex groundwater flow systems, and provides an example of the long-term geochemical evolution of hydrogeological systems after a major perturbation, in this case seawater invasion.  相似文献   

Adsorption of REE(III)-humate complexes onto MnO₂: Experimental evidence for cerium anomaly and lanthanide tetrad effect suppression     

Mélanie Davranche  Olivier Pourret  Gérard Gruau  Aline Dia  Martine Le Coz-Bouhnik 《Geochimica et cosmochimica acta》2005,69(20):4825-4835

Experiments were conducted to evaluate the impact of organic complexation on the development of Ce anomalies and the lanthanide tetrad effect during the adsorption of rare-earth elements (REE) onto MnO₂. Two types of aqueous solutions—NaCl and NaNO₃—were tested at pH 5 and 7.5. Time-series experiments indicate that a steady-state is reached within less than 10 h when REE occur as free inorganic species, whereas steady state is not reached before 10 d when REE occur as REE-humate complexes. The distribution coefficients (K_d^REE) between suspended MnO₂ and solution show no or only very weak positive Ce anomaly or lanthanide tetrad effect when REE occur as humate complexes, unlike the results obtained in experiments with REE occurring as free inorganic species. Monitoring of dissolved organic carbon (DOC) concentrations show that log K_d^REE_organic/K_d^DOC ratios are close to 1.0, implying that the REE and humate remain bound to each other upon adsorption. Most likely, the Ce anomaly reduction/suppression in the organic experiments arises from a combination of two processes: (i) inability of MnO₂ to oxidize Ce(III) because of shielding of MnO₂ surfaces by humate molecules and (ii) Ce(IV) cannot be preferentially removed from solution due to quantitative complexation of the REE by organic matter. We suggest that the lack of lanthanide tetrad effect arises because the adsorption of REE-humate complexes onto MnO₂ occurs dominantly via the humate side of the complexes (anionic adsorption), thereby preventing expression of the differences in Racah parameters for 4f electron repulsion between REE and the oxide surface. The results presented here explain why, despite the development of strongly oxidizing conditions and the presence of MnO₂ in the aquifer, no (or insignificant) negative Ce anomalies are observed in organic-rich waters. The present study demonstrates experimentally that the Ce anomaly cannot be used as a reliable proxy of redox conditions in organic-rich waters or in precipitates formed at equilibrium with organic-rich waters.  相似文献   

Determination of the Earth rotation parameters by the Bureau International de l'Heure, 1962–1979     

Feissel  Martine 《Journal of Geodesy》1980,54(1):81-102

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Steroid and triterpenoid distributions in bransfield strait sediments: Hydrothermally-enhanced diagenetic transformations     

Martine Brault  Bernd R.T. Simoneit 《Organic Geochemistry》1988,13(4-6)

Recent sediments from Bransfield Strait, Antarctica have been analyzed for triterpenoid and steroid hydrocarbons, sterols and steroid ketones to consider the effects of hydrothermal fluids on the sedimentary organic matter. The steroid distributions in unaltered and altered sediments are controlled more by inputs from source organisms than by the effects of hydrothermal activity, which is suggested to be limited to low temperature alteration. Nevertheless, chemical reactions occurred in altered sediments and include dehydration of sterols to sterenes, isomerization of triterpenes and sterenes, rearrangement of sterenes to diasterenes and reductive processes leading to generation of phytane from phytol via phytenes.  相似文献