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1.
Groundwater monitoring wells are present at most hydrocarbon release sites that are being assessed for cleanup. If screened across the vadose zone, these wells provide an opportunity to collect vapor samples that can be used in the evaluation of vapor movement and biodegradation processes occurring at such sites. This paper presents a low purge volume method (modified after that developed by the U.S. EPA) for sampling vapor from monitoring wells that is easy to implement and can provide an assessment of the soil gas total petroleum hydrocarbon (TPH) and O2 concentrations at the base of the vadose zone. As a result, the small purge method allows for sampling of vapor from monitoring wells to support petroleum vapor intrusion (PVI) risk assessment. The small purge volume method was field tested at the Hal's service station site in Green River, Utah. This site is well‐known for numerous soil gas measurements containing high O2 and high TPH vapor concentrations in the same samples which is inconsistent with well‐accepted biodegradation models for the vapor pathway. Using the low purge volume method, monitoring wells were sampled over, upgradient, and downgradient of the light nonaqueous phase liquid (LNAPL) footprint. Results from our testing at Hal's show that vapor from monitoring wells over LNAPL contained very low O2 and high TPH concentrations. In contrast, vapor from monitoring wells not over LNAPL contained high O2 and low TPH concentrations. The results of this study show that a low purge volume method is consistent with biodegradation models especially for sampling at sites where low permeability soils exist in and around a LNAPL source zone.  相似文献   

2.
As laser fluorosensors provide their own source of excitation, they are known as active sensors. Being active sensors, laser fluorosensors can be employed around the clock, in daylight or in total darkness. Certain compounds, such as aromatic hydrocarbons, present in petroleum oils absorb ultraviolet laser light and become electronically excited. This excitation is quickly removed by the process of fluorescence emission, primarily in the visible region of the spectrum. By careful choice of the excitation laser wavelength and range-gated detection at selected emission wavelengths, petroleum oils can be detected and classified into three broad categories: light refined, crude or heavy refined.

This paper will review the development of laser fluorosensors for oil spill application, with emphasis on system components such as excitation laser source, and detection schemes that allow these unique sensors to be employed for the detection and classification of petroleum oils. There have been a number of laser fluorosensors developed in recent years, many of which are strictly research and development tools. Certain of these fluorosensors have been ship-borne instruments that have been mounted in aircraft for the occasional airborne mission. Other systems are mounted permanently on aircraft for use in either surveillance or spill response roles.  相似文献   


3.
In recent years, leaking underground petroleum storage tanks have become a major environmental concern. Federal, state, and local agencies are making efforts to assess, control, and remediate petroleum product leaks. Because petroleum products are mixtures of many compounds and the composition frequently changes, there exists a need for a standard reference mixture that can be used as a basis for comparison in the study of fluid transport properties in porous media and to evaluate leak detection devices. The proposed standard presented here retains the most important liquid and vapor properties (such as vapor density, air diffusion coefficient, and basic chemical constituency) of gasoline mixtures. It also reduces the complexity of the mixture to make it an acceptable standard for routine use in laboratory and field experiments.  相似文献   

4.
A practical pumping system for the recovery of free petroleum hydrocarbon product from shallow aquifers has been developed. The system is patterned after suction-lift well point dewatering systems used in the construction industry. Pumping equipment consists of double-diaphragm suction-lift pumps manifolded to up to four recovery wells. Recovery wells are constructed with screens below the water table and sealed wellheads to enable vacuum-assisted flow of fluids to the wells. Pumps utilized are pneumatically driven, can be pumped dry without damage, induce a vacuum on the wells when pumping dry, and provide delivery of pumped fluids to fluid separation and storage facilities. The system is effective in both low- and high-permeability formations due to the wide range in available pumping rates afforded by the pumps.  相似文献   

5.
This paper provides a new analytical model of airflow to inlet wells in soil vapor extraction systems. It is based on a recent analytical solution of airflow to a single vapor extraction well by Bahr and Joss (1995), which updated the previous model of Baehr and Hult (1991). Baehr and Joss (1995) treated the air leakage through the surface as an air flux boundary condition, whereas Baehr and Hult (1991) approximated the leakage as a distributed source imposed in the governing airflow equation. The new analytical model shows significant improvement on air-flow assessment over the previous model by Ge and Liao (1996), which could underestimate the efficiency of airflow to inlet wells by as much as 27% in a typical vapor extraction system.  相似文献   

6.
When operated properly, in situ soil venting or vapor extraction can be one of the most cost-effective remediation processes for soils contaminated with gasoline, solvents, or other relatively, volatile compounds. The components of soil-venting systems are typically off-the-shelf items, and the installation of wells and trenches can be done by reputable environmental firms. However, the design, operation, and monitoring of soil-venting systems are not trivial. In fact, choosing whether or not venting should be applied at a given site is a difficult decision in itself. If one decides to utilize venting, design criteria involving the number of wells, well spacing, well location, well construction, and vapor treatment systems must be addressed. A series of questions must be addressed to decide if venting is appropriate at a given site and to design cost-effective in situ soil-venting systems. This series of steps and questions forms a "decision tree" process. The development of this approach is an attempt to identify the limitations of in situ soil venting, and subjects or behavior that are currently difficult to quantify and for which future study is needed.  相似文献   

7.
ABSTRACT

The growing availability of smart devices with advanced sensors has increased the opportunities for citizen science applications for environmental monitoring. Accurate and widespread monitoring of river stage is vital for modeling water resources. Reliable data points are required for model calibration and validation in forecast studies. While current embedded monitoring systems provide accurate measurements, the cost to replicate these systems on a large domain is prohibitively expensive, limiting the quantity of data available. This project describes a new method to accurately measure river levels using smartphone sensors. Pictures of the same point on the river’s surface are taken to perform calculations based on the GPS location and spatial orientation of the smartphone. The proposed implementation is significantly more accessible than existing water measuring systems while offering similar accuracy. A case study is performed to evaluate the accuracy and sensitivity of the measurements to changes in distance.  相似文献   

8.
This study evaluates the theory, and some practical aspects of using temperature measurements to assess aerobic biodegradation in hydrocarbon contaminated soil. The method provides an easily applicable alternative for quantifying the rate of biodegradation and/or evaluating the performance of in situ remediation systems. The method involves two nonintrusive procedures for measuring vertical temperature profiles down existing monitoring wells; one using a thermistor on a cable for one‐time measurements and the other using compact temperature data loggers deployed for 3‐month to 1‐year period. These vertical temperature profile measurements are used to identify the depth and lateral extent of biodegradation as well as to monitor seasonal temperature changes throughout the year. The basic theory for using temperature measurements to estimate the minimum rate of biodegradation will be developed, and used to evaluate field measurements from sites in California where biodegradation of spilled petroleum hydrocarbons is due to natural processes. Following, temperature data will be used to evaluate the relative rates of biodegradation due to natural processes and soil vapor extraction (SVE) at a former refinery site in the North‐Central United States. The results from this study show that the temperature method can be a simple, cost effective tool for assessing biodegradation in the soil, and optimizing remediation systems at a wide variety of hydrocarbon spill sites.  相似文献   

9.
The soil and ground water at a General Motors plant site were contaminated with petroleum products from leaking underground storage tanks. Based on the initial assessment, the site was complex from the standpoint of geology (clay layers), hydrology (a recharge zone with a perched water table), and contaminant (approximately 4800 gallons of mixed gasoline and oil). After a thorough study of remedial alternatives, a synergistic remedial approach was adopted including pump and treat, product removal, vapor extraction, and bioventing. The system was designed and implemented at the site through 22 dual-extraction wells. Over a 21-month period, 4400 gallons of gasoline and oil were removed from the system, including 59 percent by vapor extraction, 28 percent by bioventing, and 13 percent by pump and treat. Synergism between the various remedial methods was demonstrated clearly. Ground water pump and treat lowered the water table, allowing air to flow for vapor extraction. The vacuum applied for vapor extraction increased the ground water removal rate and the efficiency of pump and treat. The vapor extraction system also added oxygen to the soil to stimulate aerobic biodegradation.  相似文献   

10.
A reliable wastewater characterization is a prerequisite for the selection of an acceptable treatment strategy for produced water which exhibits significant differences due to the varied kinds of wells, seasonal changes, and formation types. A complete characterization of produced water generated from oil, gas, and oil–gas fields in Turkey was performed based on seasonal and locational variations. The results showed that the produced water generated from oil field wells was highly polluted and wastewater volume was higher in comparison to gas and oil–gas field wells. Besides, the characterization of produced water was varying in a wide range based on seasonal and locational variations. Useful relationships were observed between chloride, sodium, bromide, and total dissolved solids concentrations. The results can be used in the design, operation, and optimization of wastewater treatment systems of petroleum and oil industries for future studies.  相似文献   

11.
There have been major improvements in instrumentation, field survey design and data inversion techniques for the geoelectrical method over the past 25 years. Multi-electrode and multi-channel systems have made it possible to conduct large 2-D, 3-D and even 4-D surveys efficiently to resolve complex geological structures that were not possible with traditional 1-D surveys. Continued developments in computer technology, as well as fast data inversion techniques and software, have made it possible to carry out the interpretation on commonly available microcomputers. Multi-dimensional geoelectrical surveys are now widely used in environmental, engineering, hydrological and mining applications. 3-D surveys play an increasingly important role in very complex areas where 2-D models suffer from artifacts due to off-line structures. Large areas on land and water can be surveyed rapidly with computerized dynamic towed resistivity acquisition systems. The use of existing metallic wells as long electrodes has improved the detection of targets in areas where they are masked by subsurface infrastructure. A number of PC controlled monitoring systems are also available to measure and detect temporal changes in the subsurface. There have been significant advancements in techniques to automatically generate optimized electrodes array configurations that have better resolution and depth of investigation than traditional arrays. Other areas of active development include the translation of electrical values into geological parameters such as clay and moisture content, new types of sensors, estimation of fluid or ground movement from time-lapse images and joint inversion techniques. In this paper, we investigate the recent developments in geoelectrical imaging and provide a brief look into the future of where the science may be heading.  相似文献   

12.
Down-hole temperature and electrical-conductivity probes are attractive logging devices for use in monitoring wells, because they are readily available, relatively inexpensive, and allow for rapid measurements. Benefits of such logging are illustrated by examples from several small sites in complex hydrogeologic settings. Interpretation of the logs provided information on the effectiveness of well purging, aquifer heterogeneities and the rates of ground water movement, leaks and cross-flows within wells, and locations of transmissive fractures in bedrock wells. Thus the logs offered an inexpensive means of acquiring valuable field information to supplement the geologic, potentiometric and chemical data collected during construction or subsequent investigation of the wells.  相似文献   

13.
Increasingly, regulations by federal, state and local agencies are being developed that require the installation of vadose zone monitoring systems for hazardous chemical facilities in addition to, or in lieu of, conventional ground water monitoring wells. Compared to a ground water monitoring approach, vadose zone monitoring systems may permit earlier detection of chemical leakage and less costly cleanup of contamination. The effective use of vadose zone monitoring systems in detecting contamination depends on many factors. Without proper consideration of these factors, a vadose zone monitoring system may not give as high a level of reliability as a ground water monitoring system.
Major factors to consider in installing a vadose zone monitoring system are: type of instrument to use, number of instruments, depth and location of instruments, and frequency of monitoring. Means to evaluate these factors in a comprehensive fashion have been lacking. Based on recent experience in installing and operating vadose zone monitoring systems, criteria and methods useful in resolving the preceding factors have been developed. Types of instruments can be classified as either direct (lysimeter, vapor probe) or indirect (tensiometer, conductivity probe). A combination of the two is needed for reliability. The depth, location and number of instruments depend on the geometry of the facility, the number and size of likely contaminant leakage points in engineered barriers, properties of the material being monitored, the effective radius of monitoring for each instrument, vadose zone properties, and types of remedial actions that are available. The freqency of monitoring largely depends on the rate of movement of the contaminant. Evaluating the preceding factors requires some level of modeling and preliminary field testing.  相似文献   

14.
Aerobic biodegradation can contribute significantly to the attenuation of petroleum hydrocarbons vapors in the unsaturated zone; however, most regulatory guidance for assessing potential human health risks via vapor intrusion to indoor air either neglect biodegradation in developing generic screening levels or allow for only one order of magnitude additional attenuation for aerobically degradable compounds, which may be overly conservative in some cases. This paper describes results from three-dimensional numerical model simulations of vapor intrusion for petroleum hydrocarbons to assess the influence of aerobic biodegradation on the attenuation factor for a variety of source concentrations and depths for residential buildings with basements and slab-on-grade construction. The simulations conducted in this study provide a framework for understanding the degree to which bioattenuation will occur under a variety of scenarios and provide insight into site conditions that will result in significant biodegradation. This improved understanding may be used to improve the conceptual model of contaminant transport, guide field data collection and interpretation, and estimate semi-site-specific attenuation factors for combinations of source concentrations, source depth, oxygen distribution, and building characteristics where site conditions reasonably match the scenarios simulated herein.  相似文献   

15.
Langseth DE  Smyth AH  May J 《Ground water》2004,42(5):689-699
Predicting the future performance of horizontal wells under varying pumping conditions requires estimates of basic aquifer parameters, notably transmissivity and storativity. For vertical wells, there are well-established methods for estimating these parameters, typically based on either the recovery from induced head changes in a well or from the head response in observation wells to pumping in a test well. Comparable aquifer parameter estimation methods for horizontal wells have not been presented in the ground water literature. Formation parameter estimation methods based on measurements of pressure in horizontal wells have been presented in the petroleum industry literature, but these methods have limited applicability for ground water evaluation and are based on pressure measurements in only the horizontal well borehole, rather than in observation wells. This paper presents a simple and versatile method by which pumping test procedures developed for vertical wells can be applied to horizontal well pumping tests. The method presented here uses the principle of superposition to represent the horizontal well as a series of partially penetrating vertical wells. This concept is used to estimate a distance from an observation well at which a vertical well that has the same total pumping rate as the horizontal well will produce the same drawdown as the horizontal well. This equivalent distance may then be associated with an observation well for use in pumping test algorithms and type curves developed for vertical wells. The method is shown to produce good results for confined aquifers and unconfined aquifers in the absence of delayed yield response. For unconfined aquifers, the presence of delayed yield response increases the method error.  相似文献   

16.
The objective of most ground water quality monitoring programs is to obtain samples that are "representative" or that retain the physical and chemical properties of the ground water in an aquifer. Many factors can influence whether or not a particular sample is representative, but perhaps the most critical factor is the method or type of sampling device used to retrieve the sample.
The sampling equipment available today ranges from simple to highly sophisticated, and includes bailers, syringe devices, suction-lift pumps, gas-drive devices, bladder (Middelburg-type) pumps, gear-drive and helical rotor electric submersible pumps and gas-driven piston pumps. New devices are continually being developed for use in small-diameter wells in order to meet the needs of professionals engaged in implementing elaborate ground water monitoring programs.
In selecting a sampling device for a monitoring program, the professional must consider a number of details. Among the considerations are: the outside diameter of the device, the overall impact of the device on ground water sample integrity (including the materials from which the sampling device and associated equipment are made and the method by which the device delivers the sample), the capability of the device to purge the well of stagnant water, the rate and the ability to control the rate at which the sample is delivered, the depth limitations of the device, the ease of operating, cleaning and maintaining the device, the portability of the device and required accessory equipment, the reliability and durability of the device, and the initial and operational cost of the device and accessory equipment. Based on these considerations, each of the devices available for sampling ground water from small-diameter wells has its own unique set of advantages and disadvantages that make it suitable for sampling under specific sets of conditions. No one sampling device is applicable to all sampling situations.  相似文献   

17.
孙珂  单新建  申旭辉  孙林 《地震》2017,37(2):32-46
地下流体监测数据和地表断层调查都显示构造活动强烈期和大地震前后活动断裂带会伴有大量气体逸出。 中国即将发射的高分五号(GF-5)卫星搭载的大气环境红外甚高光谱分辨率探测仪及全谱段光谱成像仪两个传感器, 主要以大气气体的探测为应用目标。 本文基于两个传感器的参数设置, 使用大气辐射传输模型, 对断层逸出气体中的水汽、 CH4和CO2三种气体在大气中的含量变化对卫星传感器的辐射影响进行了仿真模拟, 分析了两个传感器对水汽、 CH4和CO2气体异常的探测能力。 结果表明, GF-5卫星两个红外传感器特定的光谱通道对大气水汽、 CH4和CO2气体异常变化均有不同程度的敏感性, 可以期待发展具有较高精度的相关气体遥感反演模型, 用于地震的监测及预测。  相似文献   

18.
The results of comprehensive field testing of on‐site vapor‐phase‐based groundwater monitoring methods are presented to demonstrate their utility as a robust and cost‐effective approach for rapidly obtaining volatile organic compounds (VOCs) concentration data from a monitoring well. These methods—which rely on sensitive, commercially available field equipment to analyze vapor in equilibrium with groundwater—proved easy to implement and can be tailored to site‐specific needs, including multilevel sampling. During field testing, low‐flow groundwater concentrations could be reasonably estimated using submerged passive vapor diffusion samplers or field equilibration of collected groundwater (R2 = 0.85 to 0.96). These two methods are not as reliant on in‐well mixing to overcome vertical stratification within wells as simpler headspace methods. The importance of well and aquifer‐specific factors on concentration data (and therefore method selection) is highlighted, including the effect of changing in‐well patterns due to seasonal temperature gradients. Results indicated that vertical stratification was relatively limited within the set of wells included in these studies, resulting in similar performance for short depth‐discrete passive vapor diffusion samplers (constructed from 40‐mL vials) and longer samplers (2.5 to 5 feet in length) designed to cover a larger portion of the screened interval. A year‐long, multi‐event evaluation demonstrated that vapor‐phase‐based monitoring methods are no more variable than conventional groundwater monitoring methods, with both types subject to similar spatial and temporal variability that can be difficult to reduce. Vapor sampling methods represent a promising approach for estimation of groundwater concentrations by reducing the cost liabilities associated with monitoring while providing a more sustainable approach.  相似文献   

19.
A field screening method was developed for rapid measurement of benzene and gasoline range total petroleum hydrocarbons (TPHg) concentrations in groundwater. The method is based on collecting photoionization detector (PID) measurements from vapor samples. The vapor samples are collected by bubbling air through groundwater samples (air sparging) with a constant volume, temperature and sparging rate. The level of accuracy, sensitivity, precision, and statistical significance of the estimated concentrations, derived from the screening method, are comparable to conventional laboratory analytical results at concentrations equal to or greater than 150 µg/L for benzene and greater than 50 µg/L for TPHg. The method's concentration estimations can assist in making real‐time decisions regarding location of dissolved plumes and light nonaqueous phase liquid (LNAPL) source zones at many fuel release sites. The screening method was tested in the laboratory and in the field with 208 and 107 samples, respectively. The study concludes that the screening method can be used as a tool to aid in completing a site conceptual model as well as analyzing groundwater from monitoring wells.  相似文献   

20.
When designing in situ soil vapor extraction systems, the number and placement of vapor extraction wells arc typically based on the radius of influence determined from some combination of pilot test data, theoretical considerations, and experience. In this report, we examine common methods used to determine the radius of influence, and through examples we illustrate how effective this remedial design approach is. Significant conclusions arc the following: (a) systems designed by radius of influence-based approaches may never achieve desired remedial goals: (b) systems designed by radius of influence-based approaches may result in longer operation times and higher total costs than a system that incorporates remedial goals and some level of fundamentally based predictive modeling: and (c) at best, the radius of influence-based approach ensures containment of contaminant vapors.  相似文献   

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